Simulation of cells with anodes of large surface area for electrolysis of alumina dissolved in a chloride melt

Carbon anode cells were studied by two-dimensional computer simulation to evaluate their suitability for alumina electrolysis at high superficial current densities. The most efficient anode arrangement was needed to overcome the electrochemical disadvantages of alumina's low solubility in chlorides. Cells with packed-bed anodes might provide practical superficial current densities greater than 0.67 A/cm2 when the granule size was less than 1 cm, but in the process of electrolysis the granules within the active zone would be consumed and become smaller, affecting alumina concentration transport. For zones of very small granules a concentration-dependent model should be considered; for more complete consideration a time-dependent model can be introduced to describe the variation of granule size and its influence on mass transfer and polarisation