Surface Characterisation of Fergusonite

"There is currently very little information on the physico-chemical properties of rare earth elementbearing minerals, or on their processing. With the increasing demand for rare earths, this is something that needs to be addressed. This paper introduces some surface chemistry analysis of fergusonite (YNbO4), and the bubble-particle attachment. Zeta potential measurements indicate adsorption of sodium oleate and, to a lesser degree, potassium amyl xanthate onto the surface, and an increase in attachment to an air bubble is observed at pH 4.5 and 6.5. At a pH of 10.5, no attachment is observed, whether in the presence of the reagents or not. This analysis, although initial, will be used to initiate flotation tests, in order to facilitate the selective recovery of fergusonite. INTRODUCTIONRare earth elements (REE) are increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. An article in the New Scientist highlighted the importance of a number of REE, many of which most people are be unlikely to have heard mentioned (Crow, 2011). From batteries (lanthanum and cerium) to magnets (dysprosium and neodymium) and lighting (yttrium), the REE are crucial to the advancement of technology and energy saving devices. For example, neodymium is finding most use in the high end magnets that keep the motors turning that power wind turbines and electric cars. In the case of yttrium, the demand outstripped the supply in 2010, emphasising the need to develop deposits containing this and other REE (Crow, 2011). The impact of our dependency on REE has become even more apparent with the reduction in exports by China, which currently controls 97 % of the world’s rare earth production (Pitts, 2011).With the increasing demand for rare earth elements (REE), there is a drive to exploit the known resources around the world. However, the physical beneficiation of the rare earth element bearing minerals is a subject which will require a great deal of investigation to fill the knowledge gaps surrounding these developing rare earth projects. There are numerous articles on REE mineralogy as well as the hydrometallurgical processing of REE concentrates (Alex, Suri, & Gupta, 1998; Peter Gromet & Silver, 1983; Ring et al., 1993; Schnetzler & Philpotts, 1970; Uda, 2000), however a common feature amongst these resources is the lack of detailed descriptions of the physical beneficiation processes required to concentrate REE-bearing minerals. There is work being conducted into reagents and methods for use in recovering some rare earths from their associated ores (Bulatovic, 2010; Ni, Parrent, Cao, & Liu, 2011), but much more in-depth research is required."