Techniques To Understand Metal Leaching From Ore Minerals In Mine-Waste Material

Suites of monomineralic sulfide and carbonate minerals, as well as mine-waste composite samples, were analyzed using chemical and microanalytical techniques to understand behavior and bioavailability of mine waste elements such as Cu, Fe, Pb, or Zn. Petrographic, scanning electron microscopy (SEM), and laser-ablation inductively-coupled mass spectrometry (LA-ICP-MS) studies of mineralogical residence sites of trace elements are important because trace elements affect the chemical and physical behavior of minerals. Leachate solutions show that chalcopyrite, bornite, azurite, malachite, and galena are host to the trace elements Ag, Al, As, Cd, Co, Cr, Mn, Ni, Pb, and Zn. SEM studies reveal whether these trace elements occur within mineral inclusions or are substituted within lattice structures. SEM analysis reveals mineral phases not identified by X-ray diffraction (XRD), such as inclusions of sphalerite and cobaltite(?) within chalcopyrite.