The Application Of Cyclic Voltammetry Coupled With Surface Plasmon Resonance Measurements To Thiol-Collector Interactions With Gold Surfaces

Surface Plasmon Resonance spectroscopy (SPR), combined with cyclovoltammetry, has been successfully used to study the interactions between ethyl xanthate, heptyl xanthate, dithiophosphate and propyl trithiocarbonate flotation collectors and a gold surface. Large, easily measurable responses have been obtained in the potential areas where the thiol collectors are known to interact with gold. The four collector types lead to differing SPR maximum values, with longer alkyl chains resulting in higher SPR responses, and the trithiocarbonate leading to the highest response values. The SPR responses differ considerably from the current density response at very anodic and cathodic potentials. There are indications that thiols might still be adsorbed at potentials as low as -300 mV (vs SHE). Keywords Flotation collectors; thiol collectors; cyclovoltammetry; surface plasmon resonance spectroscopy.