The Application of Florrea 8920, a New Hydroxamate-Based Flotation Collector for the Flotation of Rare Earth Minerals

"IMBSRE, one of the largest rare earth element (REE) producers in China, produces a rare earth oxide (REO) concentrate as a by-product by floating the middlings stream from a low intensity magnetic separation step in the main iron ore processing stage. As the mine depth has increased, flowsheet changes in the main iron ore circuit have reduced the REO grade and increased the magnetite to REO ratio in the middling product used as flotation feed for the REO circuit. Extensive laboratory work was carried out and identified a new modified hydroxamic acid product, Florrea 8920, that could provide better metallurgical results over the standard hydroxamic acid used as the main collector. This paper briefly reviews the use of hydroxamates in the flotation of oxide minerals, provides detailed information on the different hydroxamates available from Florrea and then provides a case study of the successful implementation of the Florrea 8920 product in a commercial Chinese REE flotation plant. The case study consists of a one year program of pilot plant testing and industrial trials to confirm the results of laboratory tests. The implementation of the new collector resulted in an improvement in grade and recovery to 61% and 64% respectively. The new collector also provided significant economic and environmental benefits.INTRODUCTIONThe flotation of rare earth element (REE) bearing minerals is a topic which has been dominated in the English language literature by the work conducted on the Mountain Pass bastnäsite deposit (Pradip, 1981; Fuerstenau, Pradip, Khan, & Raghavan, 1982; Pradip & Fuerstenau, 1983, 1985, 2013; Fuerstenau & Pradip, 1991; Fuerstenau, Pradip, & Herrera-Urbina, 1992; Herrera-Urbina, Pradip, & Fuerstenau, 2013). By far the most important collector type used for the flotation of rare earth minerals (REM) is hydroxamates. These reagents were initially extensively described as REM collectors in the English literature by Pradip (1981) however they have been successfully applied to numerous other minerals such as: cassiterite (Sreenivas & Padmanabhan, 2002); pyrochlore (Gibson, Kelebek, Aghamirian, & Yu, 2015); hematite, chrysocolla, rhodonite, hubnerite and pyrolusite (Fuerstenau, 2005); and malachite (Lenormand, Salman, & Yoon, 1979) amongst others."