The Calculation Of An Internal Energy Balance In The Smelting Of Calcium Carbide

The smelting of calcium carbide has always been plagued by eruptions, too often with serious injury y or loss of life. To find their causes, the author calculated an internal energy balance using 1992 data for CaC2 and CaO, and older data for the remaining items. The heat content of the charge, and that of the hot gases formed at the reduction temperature, showed that only a fraction of its heat content can be supplied by these gases. Laboratory data on the electrical resistivity of fine mixtures of coke and non-conductive solids were extrapolated to a commercial carbide charge, and then used to calculate the heat produced by current flowing through the mix from the electrode surface to the hearth, which, under favourable conditions, sufficed to bring the charge to 1900 K and higher, at which temperatures reduction could take place.