The importance of the curing stage in the fixation of arsenic in pressure oxidation

In the processing of refractory gold-bearing sulfides, pressure oxidation (POX) is commonly known for its role in liberating the gold in solid-solution via oxidation of the sulfide occlusions. For deposits that contain arsenic-bearing species including arsenian pyrite and arsenopyrite, POX serves an important secondary function in the fixation of arsenic, via the hydrothermal precipitation of stable arsenates such as scorodite and basic ferric arsenate sulfate (BFAS). There have been various investigations on the impact of different POX conditions on arsenic precipitation and the stability of the formed phases, but less is known about the changes to the arsenic carrier that occur in the curing stage, which follows directly from POX. The primary function of curing is to coax the dissolution of sulfates to reduce lime consumptions during cyanide leaching, and the slurry is kept at elevated temperatures near 100°C to achieve this. While the arsenic-bearing phases are expected to undergo transformation during this stage, there has thus far been limited experimental evidence. In this study, the effect of curing time and curing temperature on the arsenic-bearing species and arsenic deportment in the POX product has been investigated. Leaching of the curing products was also conducted to examine the stability of the arsenic species in the solid precipitates.