The influence on galvanic corrosion tests of resistance in the metalic conduction path

By use of a finite-difference model of an experimental galvanic cell, the effect of a resistance in the metalic conduction path on the potential and current distributions in the cell was predicted. The model predictions were compared with experimental measurements of potential profiles (measured by use of a scanning reference electrode) and galvanic currents. The predictions agreed well with the experimental measurements. Apart from this model, which is applicable in macroscopic cells (Le. with an electrolyte of low conductivity), a calculation procedure was developed to predict the effect of an external resistance on the galvanic current in a microscopic cell (high conductivity). The responses of the galvanic currents in the microscopic and macroscopic cells to changes in the external resistance were compared. From the similarity of the responses, a simple practical procedure for the evaluation of the external resistance (meter resistance) that can be tolerated is proposed.