The Kinetics Of The Oxidation Of Zinc Vapour By Carbon Dioxide And Water Vapour On Quartz, Zinc Oxide, Sinter And Coke Substrates (Invited) (7316026c-6fba-489a-81b2-4d2e0bfeacb8)

The oxidation of zinc vapour plays a very important part in the operation of the Imperial Smelting Process. The kinetics of the reoxidation of zinc vapour by carbon dioxide and water vapour onto quartz and zinc oxide substrates is qualitatively understood and this pertains to the conditions found as the gases are being transferred from the furnace to the splash condenser. However, re-oxidation also occurs in the shaft of the furnace where the solid substrates are sinter and metallurgical coke. It was found that there was a threefold increase in the rate of oxidation on sinter, compared to quartz and a 30 to 300 increase in rate on the coke. This was attributed to the high surface area offered by these materials.