The Potential Use of Various Metallurgical Slag and Fly Ash from South Africa as Cement Extenders

The amount of raw material used in the production of cement can be reduced by partially supplementing it by pozzolanic waste material without changing its properties negatively. This paper discusses results of an investigation using slag from the Pt industry, from the production of steel using Midrex processes as well as fly ashes from different coal power plants in South Africa. These are blended in a 20 per cent slag or fly ash to 80 per cent cement ratio. The properties of the mixtures depend on the phase composition, chemistry, grain size and the sources of the materials. The results are promising, but show variable behaviour depending on slag and cement composition. Compressive strength tests as well have heat flow curves showing the hydration behaviour, indicating that 20 per cent addition of slag or fly ash to ordinary Portland cement is viable. There is a large potential to use slag in cement mixtures and this study can be used to develop cements that will positively influence CO2 emissions and help to reduce large slag and fly ash stockpiles.