The role of Infrared and Raman Spectroscopy in Solving Mineral Processing Problems

Infrared and Raman spectroscopy have been used to study a range of solid state and aqueous solution species which are of interest in extractive metallurgy. In the solid state new Cu(II)/CN'/NH3 complexes have been detected, iron impurities in kaolin characterised, aluminium substitution in hematite and goethite quantified, and the crystallinity and orientation of zircon determined in heterogeneous crystals. In aqueous solution metal cyanide complexes and equilibria were readily characterised, the thermal decomposition of SO2 monitored and products identified, and complexation of AI(III) by hydroxycarboxylates observed. Attempts to monitor the early stages of the gelling of silicate solutions were less successful, with only changes in the gel being detected. However, the degradation of 12-tungstosilicic acid was readily monitored as a function of both time and pH.