The Thermal Decomposition of Sodium Ethyl Xanthate Adsorbed on Activated Carbon

The thermal decomposition of sodium ethyl xanthate (SEX) adsorbed onto activated carbon was studied by coupled thermogravimetric analysis-Fourier transform infrared spectroscopy (TG-FTIR). Two discrete mass losses were observed, in the temperature ranges 100 - 230¦C and 200 - 340¦C. The same two gases, carbonyl sulphide (COS) and carbon disulphide (CS2), were the main gases evolved in each of the mass losses. Samples of activated carbon from two industrial plants were obtained and analysed by TG-FTIR. COS and CS2 were not detected in one of the samples. The other sample did show evidence of COS and CS2, which indicated that fouling of the carbon by SEX was still present. Other organic compounds were detected in the evolved gas stream of both samples, indicating the presence of organic reagents other than SEX.