The Use Of Electrothermal Excitation Atomic Absorption Spectrophotometry In Geochemical Prospecting Analysis

It is now 32 years since Walsh's classic publication (1) heralded the beginning of atomic absorption spectrophotometry (AA) as we know it today. During this time, AA has developed into the most widely used analytical techniques for the determination of the metallic elements. The years have seen progressive changes in instrumentation so that today it is a highly sophisticated technique. One area of development in AA that is experiencing renewed attention is in the area of electrothermal excitation. In this technique a flame is not used by the analyte solution is atomised by an electrically heated graphite furnace. For a large number of elements the graphite furnace atomic absorption spectrophotometer (GFAA) is considerably more sensitive than flame work. It is common to be able to detect concentrations one hundred times smaller than those possible by flame. Today's geochemists are finding that they can gain valuable information out of very low limits of detection. Electrothermal atomic absorption spectrophotometry (or GFAA) allows for low limits of detection and can be seen to be a valuable aid to geochemical prospecting Analysis.