Thermodynamics of the MnO-containing slags and equilibrium relations associated with Mn ferroalloy productions

- Organization:
- The Southern African Institute of Mining and Metallurgy
- Pages:
- 6
- File Size:
- 505 KB
- Publication Date:
- Jan 1, 2004
Abstract
Slag-metal and slag-metal-gas heterogeneous equilibria involving MnO-containing slags have been simulated using recently developed Mn-based alloy and IRSID oxide thermochemical databases. A large number of experimental equilibrium data have been used to verify the calculation results. The experimental slag-metal and slag-metal-gas equilibria in MnO-SiO2binary, MnO-SiO2-CaO and MnO-SiO2-Al2O3ternary, MnO-SiO2-CaO-Al2O3quaternary andMnO-SiO2-CaO-Al2O3-MgO higher-order system can be reproduced within experimental uncertainties. The influence of temperature, CO partial pressure and slag chemistry on the Mn-and Si-distribution equilibria have been quantitatively evaluated. This leads to a sound basis for optimizing the manganese ferroalloy production processes. Key words: MnO-containing slag, manganese ferroalloy, equilibrium simulation, thermochemical database
Citation
APA:
(2004) Thermodynamics of the MnO-containing slags and equilibrium relations associated with Mn ferroalloy productionsMLA: Thermodynamics of the MnO-containing slags and equilibrium relations associated with Mn ferroalloy productions. The Southern African Institute of Mining and Metallurgy, 2004.