Thermogravimetric Investigation of the Chlorination Behaviors of Some Common Metals and Their Oxides

Thermogravimetric analyses were used to formulate the chlorination and chloridization behaviors of such metals as iron, manganese, copper, tin, nickel, and zinc and their oxides; of lime and magnesia; and of such minerals as calcite, siderite, rhodochrosite, rhodonite, and apatite- all commonly encountered in ironmaking raw materials. Complexities of the reaction steps involved were indicated by plotting thermogravimetric analysis curves and the possible mechanisms were discussed based on the theoretical weight changes and thermodynamic considerations. The relative effectiveness of chlorine and hydrogen chloride as chloridizing agents was considered in the light of the experimental results.