Threshold Shock Initiation Parameters of Liquid Phase Ammonium Nitrate

Ammonium Nitrate (AN) is most commonly encountered as either a prilled solid or a highly concentrated aqueous solution, with or without organic ( e.g amine) nitrates. Under certain conditions of fire exposure involving prilled or solid AN, the molten state can be formed. The shock sensitivity of the molten material at temperatures greater than 220 Celsius has been found to be much higher than that of the prilled or solid form. Molten AN can be a precursor to events leading up to explosion of a bulk prill storage pile as a result of fire exposure. The explosion hazards presented by molten AN are a function of two factors; 1) its shock sensitivity and the deflagration to detonation ( DDT ) properties of the molten material, and: 2) the ability of large masses of unfueled prilled AN to be initiated and detonate. This paper presents the results of tests designed to determine the shock initiation and DDT properties of the solid ( prilled ) and molten AN.