Upgrading of ferruginous manganese tailings by hydrogen-rich reduction for the ferroalloy industry

This paper investigated the prereduction of ferruginous manganese tailings from the Nchwaning mine by isothermal reduction between 650 °C and 1050 °C. The treated tailings underwent subsequent magnetic separation to upgrade the Mn/Fe ratio and manganese grade so that the tailings can be used as high-quality ferroalloy feedstock. The tailings contain recoverable manganese but is penalised by elevated and complex iron content. There is a high degree of mineralogical variability found in the untreated tailings. Iron is present both as hematite and in solid solution within manganese minerals such as bixbyite, braunite, and braunite II. A hydrogen atmosphere was used in this paper as it is sufficiently reducing to produce metallic iron that can be separated magnetically. Lime and silica additives were investigated to determine their influence on Fe reduction kinetics and globule formation, which impacts the separability of Fe and Mn. Optical microscopy and SEM analysis of the treated material revealed distinct metallurgical behaviour between iron reduced from hematite – forming larger globules (50 µm to 600 µm) – and iron reduced from Mn-hosted phases, which formed smaller globules (0.1 µm to 2 µm). Relatively milder reducing conditions achieved the highest Mn/Fe ratio of 4.52 and an Mn grade of 57 wt.%. While below the desired target specification (Mn/Fe of at least 7.5 wt.% and Mn grade of at least 44 wt.%), this can still be met by blending the product stream with other low-grade Mn ores that contain minimal Fe. These findings highlight the potential for the upgradation of ferruginous manganese tailings.