Use of Naturally Available Peat for Mitigation of Metalliferous Acidic Rock Drainage

The adsorption capacity of peat collected from a proposed mine development in northern Sweden has been determined using laboratory column experiments in which peat was irrigated with a simulated (acidic) waste rock dump leachate. The simulated leachate was made using a hydrogen peroxide leach of composite waste rock from the proposed mine development. The waste rock samples were composited in proportion to their predicted extractable tonnage for the mine development in order to generate a more representative leachate solution for the waste rock facility. As expected the test revealed that the peat material shows a very high affinity for attenuation with greater than 70% of Co, 90% of Ni and 95% of Cu removed from influent solutions through the majority of the tests demonstrating the potential benefits in mine water treatment. In contrast, it was found that Fe is initially released from the peat at concentrations up to 100 mg/L and can mean potential problems for the water released depending on the receiving environment. The exact mechanisms for Fe release is uncertain, though it is suspected that ion exchange / competitive desorption is responsible. Inspection of the laboratory results and drainage data from the natural peat wetland receiving drainage during overburden prestriping and mine development at the mine site are comparable, confirm the validity of the experiments, and further emphasize the potential for future use of pre-stripped peat material in managing water quality.