Yttrium Recovery From Bokan Mountain, Alaska

The Bokan Mountain area on Prince of Wales Island, AK, contains vast quantities of heavy rare earth minerals. To lessen the US dependence on foreign sources, the US Bureau of Mines (USBM) investigated yttrium recovery from this ore. By sulfating the ore at 250 ° C for 1 hr at an H2S04:ore ratio of 1:1 and then water leaching the sulfated material for 1 hr at 20% solids and 25ºC, over 74% of the yttrium, cerium, and lanthanum were solubilized. Solvent extraction (SX), using a synergistic combination of OPAP and DEHPA, selectively loaded 100% of the yttrium. Yttrium was stripped directly as a solid using a 2M, 35 ° C NaOH liquor. When the OPAP/DEHPA mixture was tested in a continuous SX circuit, yttrium loading and stripping were 100% and 96%, respectively. The organic showed excellent recyclability properties with minimal solvent loss.