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By Delciane Porfiro, Tiago de Mattos Serodre, Antônio Eduardo Clark Peres, Valdirene Gonzaga de Resende

The evaluation of the effect of the addition of carbon nanotubes (NTCs) directly to a etheramine on the flotation recovery of the quartz at pH 10.5 was carried out by means of microflotation tests in Hallimond tube. The quartz flotation was evaluated using 0.1% (w/v) etheramine solution with different percentages of carboxylic functionalized NTCs. The increase in the percentage of functionalized NTCs increased the flotation recovery to a maximum and from this it was observed a reduction of the recovery of the mineral. Pure etheramine and etheramine with the NTCs were characterized by FTIR spectroscopy and thermal analysis. FTIR spectra of both pure etheramine and etheramine with NTCs clearly showed peaks with the same wavelengths and diagnostics of the cation etheramine and acetate anion. Thermogravimetry indicated that the etheramine + NTCs-COOH mixture lost approximately the same weight percentage over a larger temperature range. In addition, the interaction of the nanotubes with the etheramine caused them to decompose at a lower temperature.

Oct 3, 2019

By Eric Yoshimitsu Sako

One of the main difficulties in the operation of trough and runners at Arcelor Mittal Tubarão (AMT) Blast-furnace no.02 is the reduced amount of time available for repair procedures. The consequence is that the castable installation must often be performed during hot conditions and the installed castable could easily detach from the base material during the early stage of operation, exposing the previously oxidized base material to molten iron and corrosive slag attack. When events like this happen, emergency repairs must be executed, resulting in increased refractory unit consumption and an unplanned shutdown of unit operation. Considering these targets, Nippon Crucible Co. and Saint-Gobain HPR Brazil have developed a high-performance Al2O3-SiC-C composition based on an entirely novel anti-oxidation technology. Oxidizing reactions could be attenuated by adding an oxidant inhibitor and a water reducing agent. As a result, the open porosity was significantly reduced, resulting in an improvement of campaign life in terms of pig iron throughput when compared with the regular castable. An analysis of this life improvement showed successful results for the material after 250 days of campaign. The main reason for such successful results was that the deterioration caused by the oxidation was significantly less and that this change made on the high cohesive structure of the base material was maintained for a long time. The attained results allowed Arcelor Mittal Tubarão to achieve longer trough campaigns, and avoid any unplanned stoppages with zero breakdown risks.

Oct 30, 2017

By Dagoberto Brandão Santos, Kairo de Barros Guimarães, Túlio Magno Füzessy de Melo

The effect of the cooling conditions on the microstructure and hardness of a Dual Phase hot-rolled steel 800 MPa strength was investigated. Simulations of the cooling conditions using a dilatometer were carried out from samples of a hot rolled coil with variations of the intermediary temperature from 620 to 740°C, isothermal holding time between 1 and 10 s and coiling temperature between 50 and 400°C. In addition, two CCT (Continuous Cooling Transformation) diagrams were developed to evaluate the effect of the isothermal holding time on the phase transformations of the remaining austenite. It was observed that the intermediary temperature has a strong influence on the kinetics of the phase transformation, as well as the isothermal holding time influences the amount of ferrite formed and, consequently, the final microstructure and hardness of the material. The coiling temperature did not cause significant changes in the amount and morphology of the ferrite, but a gradual replacement of martensite with bainite was observed, which, in addition to the self-tempering effect, contributed to the hardness reduction.

Oct 1, 2019

By Johanna Alegría-Ortega

Cr/CrN bilayer coating was deposited on AISI 440C by Cathodic Arc. The composition and structure of the Cr/CrN coating were investigated by scanning Electron Microscope, X-Ray Diffraction and X-ray Photoelectron Spectroscopy. The results show that crystal structure obtained was CrN phase with preferred [220] orientation. The hardness and adhesion of coating also were studied. The evaluation of erosion-corrosion (EC) on 440C bare and coated with Cr/CrN was performed by carrying out wear tests using a slurry jet with impingement angle 90° at 4 and 8 m/s. Corrosion, erosion and synergism wear rate were evaluated following the procedure described in ASTM G-119-09. This study presents that the synergism wear rate exceeds 40% of the total mass loss for coating and 60% of mass loss for the 440C, being the most aggressive wear component. The increase in impact velocity generated a rise in mass loss for both 440C bare and coated. The Cr/CrN coating offers better corrosion and erosion–corrosion resistance under all the tested conditions.

Aug 8, 2018

By Maurizio Massimo

Danieli developed the “3Q” suite of process control technologies to address three critical principles: delivering the highest product Quality, in the required Quantity, with Quickness of response required for today’s casting machines. Ever increasing market demands for productivity and slab quality necessitate the latest advances/improvements in equipment design, process technology, and control software for all types of slab casters, and Danieli boasts a unique experience that extends from ultra high-speed thin slab casters to extra high-thickness conventional slab casters. The “3Q” system is monitored and controlled by a unique, intelligent HMI incorporating. Touch screen technology and Operator Assistant tablets. Operator Assistant is a tablet based system that guides the operator through the plant process, so that in the event of a process change or an alarm the operator is automatically presented with the choice of possible solutions / actions. The comprehensive range of technological packages cover all aspects of caster design and automation control, from feeding of liquid steel into the tundish to the final slab leaving the caster.

Aug 17, 2017

By Vitor Vianna de Castro Moreira, Danilson Gonçalves de Melo e Silva, Gabriel Augusto da Fonseca

The present work aims to describe the changes made in the operational procedure of the reheating shell furnace, of the hot-rolling of seamless tubes line at Barreiro Plant of VSB, during non-production periods, focusing on reducing natural gas consumption. According to the previous procedure, the furnace was kept at 750°C on these periods, using the main burners. With the new procedure, the furnace is naturally cooled, maintaining only the auxiliary burners with a pilot light turned on, without worrying about the conservation of temperature. Subsequently, the furnace is heated with a rate of 150 ºC/h until it reaches the setpoint temperature of production. This procedure change was successful and didn’t cause operational and security problems. The minimum stoppage time needed for the natural cooling to be economically favorable is 6 hours and 30 minutes. The new procedure reduced the natural gas consumption in 4.500 Nm³, considering 24 hours of stoppage, achieving an estimated annual economy on the thermal energy costs of R$440.000,00 in 2019.

Oct 3, 2019

By Yasser Ghobara

Phosphorus is a problematic impurity that has challenged steelmakers for decades. Steel producers have developed specific technologies to eliminate phosphorus prior to and during steelmaking. These process technologies reduce phosphorus to various degrees and increase the cost of making steel. The state-of-the art dephosphorization technologies are described and operating costs compared for each of the established technologies. Costs are discussed in terms of price penalties for high P iron ore and selling premiums for low P steel. From this, strategies to control P in a cost effective manner are described.

Aug 17, 2017

By Claudio Pereira Diogo

A lot of galvalume/aluzinc steel sheet was furnished to a metallic roof manufacturer intended for tile fabrication. But, according with the roof manufacturer, that coils develops a different superficial aspect during processing. The purpose of this work was to provide an explanation for the appearance of the observed surface on one side of the coils. In order to find out the origin of the problem, mechanical and microstructural characterization tests were done at INSPEBRAS with the support of a partner laboratory. The results are described in this paper with their analysis and conclusions.

Aug 16, 2017

By Roman Vaynshteyn

In places where Blast Furnaces are usually located, climatic factors may be unfavorable. Raw materials may be exposed to e.g. rain during transport/storage, bringing moisture into the process with consequences for stability and hot metal cost. This paper describes a technology for drying and pre-heating pellets and coke in the stockhouse. It does not require additional handling or logistical equipment and does not introduce extra transfer steps and degradation. Not only can moisture content be reduced, it can be controlled to a stable level by the operator.

Aug 16, 2017

By Fábio Heiji Yamada, Marcelo Koiti Fugihara, Ruano Fonseca Araujo

Conception the simulation and optimization technologies for industrial processes applied in the mining environment: tools and methodologies. Clarifications provided about the differences of these techniques when compared with static analysis (intuition, use of static spreadsheets, etc.). Presentation of practical cases at several big mining companies in Brazil. These projects will be presented and illustrated through dynamic simulation models developed at those companies, each one with its set of objectives, scope and results (for example: sizing the number of equipment, silo, piles related to the mining processing, logistics, ROM transportation, mine operations plan, etc.).

Oct 3, 2019

By Cristiano José Scheuer

The effect of low-temperature plasma carburizing treatment on the micro-abrasive wear resistance of AISI 420 steel was investigated by mean of a CSM Calowear ball-cratering equipment. Carburized samples were treated at temperatures of 350, 400, 450 and 500°C for a fixed time of 12 h, using a gas mixture containing 99.5% (80% H2+20% Ar)+0.5% CH4. Micro-scale abrasive wear tests were conducted with a 25.4 mm AISI 420 steel sphere, using an abrasive suspension of alumina (Al2O3) with particle size of 1 ?m (abrasive concentration of 0.11 g/cm³). The contact normal force, abrasive flow and ball rotation speed were fixed at: 0.5 N, 0,2 drop/s, and 120 rpm. The wear craters were analyzed using a confocal laser microscope, Olympus OLS 3000. The wear analyses were performed for test times of: 30, 60, 90, 120, 180, 360, 540, 720 and 900 s (equivalent sliding distance: 0.84, 1.68, 2.52, 3.36, 5.04, 10.09, 15.14, 20.19 and 25.23 m, respectively). The results indicate that the wear coefficient in the outer layer and in the diffusion layer are different, being lower in the latter. It was also verified that the wear coefficient on the outer layer region decreases with increasing treatment temperature in the range of 350 to 450 °C, and increase again for 500ºC. The diffusion layer wear coefficient is similar for all the carburized samples. Finally, for all studied conditions, the analysis of the wear craters surface indicates the occurrence of grooving and micro-rolling abrasion wear modes.

Aug 8, 2018

By Delvaux Carlos de Miranda Sobrinho, Hegler Zurick Arantes Assunção, Marco Venicio Mendonça de Souza, Luciano Toledo Ribeiro

This paper aims to present the development of a 600mm U-Pile that was done in Gerdau’s Ouro Branco Heavy Section Mill in order to feed the local market with a product.The focus of this study is to show the developmental process the Mill went through until it was prepared for hot trials. All roll pass and guide designs were developed by our own team. Analytical tools like Finite Element Analysis and reduced scale lead trials will be shown and how these tools impacted on the development timeframe and accuracy of the final results on steel.

Oct 1, 2019

By Vitor Guarnier Domiciano

The need to adjust the monolithic refractories to increasingly severe and unstable Blast Furnace casthouse operating conditions has been a major challenge for refractory suppliers in order to guarantee the runner’s safety and its availability for operation. This paper presents the properties of a new robust single line Al2O3-SiC-C refractory castable developed to endure the severe operating conditions that main runners are facing in today's Blast Furnace casthouse scenario. Practical results during almost one year of testing revealed a significant lower wear speed of the new refractory lining when compared to a standard product.

Aug 1, 2018

By Lindaura de Souza Cândido d’Ávila, Robert Nogueira de Azevedo, Itavahn Alves da Silva, Mariana Carvalho Araújo

The present study aims at the reduction of the dolomitic limestone by the addition of lime added with high MgO (magnesium oxide) content in the sintering process. To verify the feasibility of the use of additive lime as an alternative source of magnesium oxide, sintering tests were carried out at pot grate with different percentages of additive lime addition and with proportional reduction of the calcite lime dosage, evaluating the effects on the sintering process. The results showed that the additive lime is a good source of MgO for consumption in the sintering process of iron ore.

Oct 1, 2019

By Renata Cristina Teixeira

The lubricant oil is a complex mixture of different basestocks and additives. Engine oils evolved from the use of pure mineral basestocks back in the early years of automotive industry to the advent of synthetic, fully formulated, low ash lubricants. This evolution was driven by a number of factors, such as new engine designs, extended durability needs, increased fuel economy needs, environmental concerns, feedstock prices and availability and legal issues. This paper uses technology prospecting on literature and patents databases to allow an investigation on the historical evolution of engine oils. Main basestocks (mineral, hydrotreated, polyalphaolefins, esters) and additives (antioxidants, antiwear, friction modifiers, detergents and dispersants) are characterized according to their research effort. Technology prospecting data is crosschecked against the evolution of engine oil classes, allowing an analysis of how the main drivers push the development of lubricant oil quality. A research effort was identified in late 1990’s until mid-2000’s and related to the adoption of chemical limits for lubricants. Different patterns for the articles and patents publication account for the high value technological knowledge has in this industry. Technology prospecting is seen as a useful methodology for the understanding and forecast of lubricant technology movements.

Jul 31, 2018

By Werner Klein

The utilization of production facilities in an optimum way, with reliable due date fulfillment, reducing raw material and energy consumption, are challenges iron and steel companies are facing in their business every day. By using an APS system such goals can be achieved to increase the competiveness of iron and steel producers. A sophisticated APS supports the overall planning process by applying complex rules based on product and order mix, its production routings with corresponding processing and transport times and resource availability. Specific technological as well as steel grade and energy related constraints are also considered to meet company specific KPIs. A core feature of APS solution is to react online on deviations to plan during the production process. Deviations such as nonconformance of intermediate material attached to an order, sudden production delays, unavailability of important production resources, makes it necessary to update the production plan. In general the task of APS is to support the preferred work-to-order concept, by assigning work-orders to available production facilities along the product specific process route and generate optimized material sequences for critical work centers.

Aug 17, 2017

By Anderson Pereira

SORM 3plus (SORM = Superfast Optical Roughness Measurement) is a system enabling online measurement of roughness parameters during continuous strip processing. Increased requirements for new materials and more complex components call for ever increasing process safety. The roughness parameters are important quality features of uncoated and surface refined strips. The traditional method of measurement involves using a mechanical stylus based instrument. For this purpose the operator must stop the production line or samples are taken from the end of the coil and measurements are made offline in the lab. SORM 3plus, however, is a non-contact, online surface roughness measurement system that can be used for metallic and many non-metallic surfaces at strip speeds of up to 2400 m/min. The surface roughness data are stored in the system computer, displayed to the operator and if needed are fed into a higher-level network. The operator is alerted, if the limited values preset by him are exceeded or if any changes within the line will put at risk the production process. SORM 3plus calculates the roughness parameters as defined in the standards, such as the arithmetic average roughness (Ra) and the peak count (RPc).

Oct 8, 2019

By Hiroshi Ichikawa

In 2013, Nippon Steel & Sumikin Engineering Co., Ltd. (hereafter referred to as NSENGI), Tenova HYL and Danieli have entered into an agreement to combine ENERGION DR technology into blast furnace technology and/or with syngas technologies. This new alliance will allow the three companies to combine research and development activities with their respective expertise in ENERGIRON DR technology, Blast Furnace technology and Syngas (by-pro gas and coal gasification) technology, with the ultimate objective to develop breakthrough iron making technologies and create such EPC projects. This paper introduces the concepts and the features of our breakthrough technologies of combining of ENERGIRON DR technology, Blast Furnace technology and Syngas technology.

Aug 16, 2017

By Marco A. Ramírez-Argáez

A 2D mathematical model was developed for the plasma arc welding process. Computational simulations based on mass and momentum conservation equations as well as Maxwell equations were performed by using the commercial software PHOENICS. The model predicts the electric characteristics of the arc column, flow patterns, temperature contours and electrical potential, by varying the composition of the cover gas, in this case, argon and nitrogen. It was found that an arc of nitrogen with respect to one of argon generates more intense jets, greater voltages, and lower temperatures in the arc column for welding arcs current of 150 A and 10 mm arc length.

Oct 30, 2017

By Karl Berger, Roman Schneeweis, Dietrich Mathweis

With increasing demands from customers to provide flat strip with tighter tolerances on material properties, particularly flatness of e.g. martensitic steel grades (M1500), it has become necessary to develop strategies to improve flatness without influencing the tensile properties for such hard steel grades. Usual skin pass mills are not capable to apply sufficient tension and roll force for these kinds of material to improve the flatness. Therefore, alternatives had to be searched for. This paper describes skin pass - / temper – rolling methods from the classical one to new alternatives in order to satisfy the demanding market of higher material properties and idle running mills in rolling plants.

Oct 1, 2019