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By Ernest O. Kartinen

This report is the accumulation of eight years of experience on only one small phase in the business of oil production. It is not intended as a final report but rather as a progress report dealing with the internal corrosion of oil field dehydrating tanks. The corrosion of dehydrating tanks continues to be a problem in the production of crude oil. The deterioration hy corrosion of these tanks falls into three general classifications: (1) Atmospheric corrosion of exterior areas, (2) corrosion of the underside of deck and the rafters and top area of the upper row of staves in that part of the tank which is known as the vapor space, and (3) corrosion of the bottom and shell areas, and the steam coils which are normally immersed in water and thus exposed to the corrosive action of the water. Atmospheric corrosion is primarily a paint problem, and has been omitted in this discussion. The corrosion in the vapor space, in this company's experience, which has been of great concern only in one area. has also been omitted in this discussion. The third, and most troublesome type of corrosion, and the one with which this report deals, is that which occurs in the water-exposed areas of dehydrating tanks, and, to a lesser degree. in some stock tanks. The operating temperature of these waters varies from 80°F to 160°F and the salt counts run from a few thousand to as high as 25.000 parts per million. Corrosion in these tanks occurs in three forms: (1) pits, (2) ringworm type of attack along the vertical and horizontal bolt seams, and (3) as a general attack, spread over a wide area. Steam Coils In dehydrating tanks, our experience has been that the steam coils are the first to show signs of corrosion, and then the shell and bottom areas. This action is not uniform throughout this company's operations. Some installations have coil troubles with very little tank trouble, and some show just the opposite. But in the majority of cases the coils are the more seriously corroded areas. This may be partly due to the fact that we have tried by periodic application to keep a protective coating on the interior areas of the tanks, and some protection has been afforded by these coatings. Through the years several types of hot and cold coatings have been tried with many various methods of cleaning the steel, ranging from use of cleaning solvents to hot and cold Oakite washes, as well as sandblasting. Although experience has shown that a longer life expectancy of a coating is possible after a very thorough steel cleaning job, it has still been necessary to recoat these tanks at least every two or three years. Until a few years ago, vertical spiral steam coil bundles were installed when the tanks were originally erected. When these coils needed replacement, in some cases within 18 months, it was necessary to remove a couple of shell staves to accomplish this task. This required a down time period of several days and was often very inconvenient to the production operations of the leases. This problem was considered on the basis that the coils were expendable, and thus. to eliminate any unnecessary down time when changing coils, the vertical spiral coils were discarded in favor of horizontal flat coils which could be taken in and out of the tanks by way of the cleanout openings, and put together with unions. This made a fairly easily replaceable and repairable coil. But it was still very much of a nuisance when repairs were necessary. Efforts to increase the useful life of the dehydrating tanks led to the adoption of galvanized tanks at an increased initial cost. The zinc coating was depended upon for protection and no other protective coatings were applied. In July, 1944. during the development of a new lease, a 3-ring 1,500 bbl, black iron water tank was converted into a dehydrating tank with steam coils to handle the new production. This tank was coated inside with a cold, brushed-on coating, for protection against corrosion. After approximately 18 months of service, holes developed in the tank and the steam coils. The tank was emptied and cleaned for repairs. The coils were so badly pitted that it was felt advisable to replace them. Coating Becomes Loose Inspection of the tank showed the protective coating to be still in place but loose, and numerous blisters were in evidence. A closer inspection showed that the interior of this tank was so badly pitted under the coating that any further attempt to use the tank was inadvisable. This tank was therefore discarded and a new galvanized tank ordered and set up at considerable expense and inconvenience. In April, 1946, another dehydrating tank installation was made on an adjoining lease. This installation consisted of a 1,500 bbl. 3-ring galvanized tank with two sets of flat steam coils 12 in. and 24 in. up from the bottom. In September, 1947. seventeen months after installation. salt showed up in the boiler feed water. When the dehydrating tank was opened and cleaned, the steam coils were found to be badly pitted — several holes having penetrated through the wall of the pipe. New coils were installed.

Jan 1, 1950

By E. S. Grumell

THE correct sampling of coal and coke is becoming important to an ever increasing number of producers and consumers. This, therefore, may be an opportune moment to examine where we stand with regard to existing and proposed methods. In this paper an attempt will be made to review, as briefly as possible, some of the considerable amount of painstaking research which has been done in the last 10 years, and which has unquestionably led to a much better understanding of the subject. In so doing we shall try, on the one hand, to make clear where substantial progress has been made, and on the other hand, to draw attention to points that require further investigation. The paper is divided into sections in order to emphasize the major divisions of the subject; further, in order to retain this emphasis, detailed consideration of some of the points has been relegated to appendixes. No attempt has been made to give a complete survey of the literature, as this has already been done by L. A. Bushell.2 The following abbrevia-tions will be used: A.E., average error; P.E., probable error; S.W.R., size-weight ratio; B.S.I., British Standards Institution.

Jan 1, 1939

By H. Kosmider, P. Coheur

New processes of blowing with an oxygen-enriched air or gas mixtures of oxygen and steam allow the steelmaker to produce, in a basic converter, a rimmed steel low in nitrogen (0.0020 pct), phosphorous (0.020 pct), and sulphur (0.020 pct). The physical properties (ductility) of the new steels are excellent. Furthermore, from the point of view of economy, these new methods of blowing offer outstanding possibilities. THE natural occurrence of geological deposits of iron ore and local economic circumstances led European blast furnace men to work large quantities of lean iron ore with a phosphorus content as high as 0.5 pct. The iron obtained from these ores generally contains 1.5 to 2.1 pct phosphorus, 3.6 to 3.9 pct carbon, 0.3 to 0.6 pct silicon, 0.04 to 0.08 pct sulphur, and 0.3 to 1.2 pct manganese. To produce steel from this pig iron, the steelmaker has at his disposal several processes. One of the simplest and most economical is the pneumatic process developed by S. G. Thomas in 1879. This process of steelmaking, called the Thomas process, consists of blowing through the bottom of a basic bessemer converter and is used widely in Western Europe, as shown in Table I. Due to the development of tonnage oxygen plants, this process has become more important because the use of oxygen offers new possibilities of steel manufacture. Not only may the quality of the steel be improved, but liquid pig iron also may be used, the composition of which does not meet the heat requirements of the blow with atmospheric air. It is not intended to present here a detailed scientific discussion of the basic bessemer process but rather to discuss briefly its industrial possibilities in the case of rimmed steel and when blowing with atmospheric air, oxygen-enriched air, or gas mixtures of oxygen and steam. This paper is based on the current practice at Klockner-Hüttenwerk Haspe's steel division, and at six Belgian and Luxemburg steel works. The latter are members of the Liege section of the C.N.R.M. (National Institute for Metallurgical Research) and are: ARBED, John Cocker-ill, Esperance-Longdoz, HADIR, Miniere et Metal-lurgique de Rodange, and Ougree-Marihaye, most of which are working with tonnage oxygen plants.' In order to avoid any misunderstanding, it should be noted that most of the techniques to be men- tioned, or similar ones, are used currently at many steel plants in Western Europe. Background The basic converters used in Europe have a capacity of 17 to 65 tons of steel, and are similar in shape to the one in Fig. 1. The lining is brick or rammed dolomite and has a life of 250 to 500 blows. The bottom is rammed dolomite and has a life of 40 to 80 blows. As far as we know, the type of blast used does not appear to have any influence on the life of the lining. Bottom life, on the contrary, depends very much upon the composition of the blast. It is only when

Jan 1, 1955

By P. M. Robinson, J. S. LI. Leach

The heats of solution oj' indiurrr, tin, lend, nrzd tellurium have been calculated from the measured heat effects when mechanical mixtres of indium and telLuium tin and tellurium, and lead and tellurium were added to liquid bismuth. The results are in good agreement xith publislzed values.s for the separate sollction of each eleltzent in bismuth. The heats oj solution of cadmium and tellurium calculated from the rneasuved heat effects on adding trechanical mixtures of these elements do not ugree zc,itl the published values jbv the separate solution of each element. It is shown that at 623°K Ile interaction between cadmium and tellurium dissolved in liquid bismuth is strong enough to led lo preciPitation of solid CdTc. The heats oj- jor-mation of CdTe at 273" nd 623°K (1)-c crilculated fi-or the measured heat ejlfecls. The calcnlaled az'erage deviation from the Kopp-l\'ez?,zunrz rule fov solid CdTe is less than 0.06 cat per g-atom- C over this lertzperalure range. Tlze importance 0.f these oDserl.ations to the determination of heals of formation hy metal solution calorimetry is considered. LIQUID metal solution calorimetry is a convenient method for determining the heats of formation of solid compounds. In this technique the heat of formation is the difference between the measured heat effects on dissolution of the compounds and of mechanical mixtures of the components in the liquid metal.' The heat of solution of the mechanical mixture may be calculated from the measured heat effect. At infinite dilution of the solutes, this heat of solution is equal to the sum of the heats of solution of the separate components. If the heat of solution of one of the components is known, the value for the other can be derived; if both are known, they may be used to check the accuracy of the calorimetric technique. The heats of formation of the tellurides of cadmium, indium, tin, and lead have recently been measured by metal solution alorimetr. The heats of solution of indium, tin, lead, and tellurium at infinite dilution in liquid bismuth at 623"K, calculated from the measured heat effects on solution of the mechanical mixtures, are in good agreement with the published values. The heats of solution of cadmium and of tellurium calculated from the measured heat effect on solution in bismuth at 623'K of mechanical mixtures of cadmium and tellurium, however, do not agree with values estimated from the literature. 1) EXPERIMENTAL PROCEDURE AND RESULTS The Heats of Solution of Indium, Tin, Lead, and Tellurium in Bismuth. The heat effects were measured when mechanical mixtures corresponding to the compounds In,Te, InTe, In2Te3, In2Te5, SnTe, and PbTe were dissolved in bismuth. The calorimetric procedure and the method of calculation have been described elsewhere.' The heats of solution of the mechanical mixtures were obtained by subtracting the change in heat content per gram-atom of the sample between the addition temperature (273°K) and the bath temperature (623"K), (H623°K - H273°K)S, from the measured heat effects. The calorimeter was calibrated with pure bismuth. The reported values of the measured heat effects are based on (HGoK - ^273oK)Bi = 4.96 kcal per g-atom.3 The measured heat effects are found to be linear functions of the solute concentrations of the bath in the dilute solution range. The values, extrapolated to infinite dilution, are listed in Table I, together with the heats of solution of the mechanical mixtures calculated using the published values of (H 623°K - H273°k)s for indium, tin, lead,3 and tellrium. All the error limits quoted in this work represent the spread of values obtained. The heats of solution in liquid bismuth at 623°K of mechanical mixtures of indium and tellurium in four different proportions were determined. Values of the heats of solution of the two components were then calculated from the resulting four simultaneous equations: The heats of solution at infinite dilution of tin and lead in liquid bismuth at 623°K were calculated from the heats of solution of the mechanical mixtures of tin and tellurium and of lead and tellurium using the heat of solution of tellurium calculated above. These values of the heats of solution are listed in Table I1 together with some published values for comparison.

Jan 1, 1967

By W. H. Schacht

IN THE Lake Superior District, the air indoors must be heated continuously during eight months of the year and occasionally during the remaining months. Incident with mining in this district, therefore, there is need for heating many of the buildings connected with these operations. In addition to the mine buildings, that is, shops, engine, houses, offices, change houses, etc., such public buildings as schools, library, and theater, when close to the mines, are often supplied from the mine heating mains. At the Copper Range Company's mines, Champion, Trimountain and Baltic, the heating surface thus supplied from the mine mains is over 50,000 sq. ft. (4645 sq. m.) which requires a steam consumption, at times, of 18,000 lb. (8165 kg.) per hour, or the equivalent of a rate of over 50 tons of coal per day (were live steam used). This figure is based on a consumption of 1/3 lb. per square foot of heating surface during the coldest weather, and provided the system is not wasting steam by blowing it to the atmosphere or into the return line on account of leaky traps, which so often is the case. Under the latter conditions, steam consumptions of three to four times the above rate are not uncommon. This shows that the cost of heating is of enough importance to be given serious consideration, especially at this time of rising prices of fuel. The power and heating value of exhaust steam are appreciated by most engineers, and its application for such purposes is general. At our stamp mills, the exhaust from the stamps is used to operate low-pressure turbines, thus reducing the former water rate per horsepower developed by more than 50 per cent.

Jan 8, 1920

By A. P., Svenningsen

ECONOMICAL handling of a minimum of 25,000 tons of minus 3/4-in. ore per day, grinding it to 2 per cent on 65 mesh, and effecting a high recovery of the copper at the lowest possible cost were the principal aims in the design of the new Morenci concentrating plant. Dealing with a tonnage of this magnitude, it is obvious that lost motion cannot be tolerated. When ore is carried on a conveyor an unnecessarily long distance or elevated to a greater height than necessary, or when pulp flows in a launder by a circuitous route thereby losing elevation and distance, we have lost motion which is always costly both from the standpoint of construction and operation. In addition to the 25,000 tons of ore which must be handled, 100,000 tons of water per day has to be carried through the plant in the treatment of the ore. Though water is not so difficult to handle as the ore, the combined tonnage represents a figure which could easily run into a considerable monetary loss per day if all phases of the design were not carefully followed with the idea of eliminating any unnessary handing of materials.

Jan 1, 1942

By Linn Bradley

F. H. WILLCOX, Pittsburgh, Pa. (communication to the Secretary*). -We must keep in mind, in balancing the savings-to be anticipated by the most efficient combustion of gas, the best heat absorption by stoves or boilers, and by heat conservation of the thermal equivalent carried in. blast-furnace gas-against the cost in operation, maintenance, depreciation and interest charges of the equipment required to realize the savings, that in boilers and hot-blast stoves we are basing our economies upon two different, combustion phenomena. In a boiler, evaporating water at a heat efficiency of 70 per cent., approximately 47,550 B.t.u. is consumed per boiler horsepower. Taking the blast, furnace gas cited in the above paper, we are using about 38 ¾ lb. of cold-washed gas per boiler horsepower. Using the hot-cleaned gas, the same equivalent heat is furnished by 34 1b. of the gas , This leaves of the 38 ¾ lb. required in the case of cold-washed gas, 4 ¾ lb. or 6,650 B.t.u. available for raising more steam when dry-hot gas is used, which means that an equivalent amount of coal firing can be dispensed with. Per ton of iron, this figure 2/3 X 12,000/38.75 X 4.75 = 980 lb. gas or 1,372,000 B.t.u. or 100 lb. coal. At $1.50 per ton of coal, the net saving per ton of pig iron produced by the use of dry-hot over wet-cold cleaning will, therefore, be about $0.06 2/3. At a stove heating 8,500 lb. of air per toil iron from 150° F., one-quarter of the dry-hot cleaned gas, or 3,000 lb., would heat the air to 1,450° F. 3,000 X 1,400 X 0.70 = (8,500 X 0.255) = 1,300. The cold-wet gas would heat the same amount of air to 1,280° F. 3,000 X 1,225 X 0.70 = (8,500 X.0.255) = 1,130.

Jan 4, 1917

By Jacob T. Wainwright

This stove has been designed to meet the requirements of a fur nave that must be operated with either a reducing or a neutral flame ; and more particularly to make feasible the operating of re duction-furnaces with the cheaper grades of gas-fuel, which has heretofore been impracticable. In general, cheap gas-fuels result from incomplete combustion, and, being suited for further combustion, answer very well for heat ing purposes; and high temperatures may be attained with them, when they are used in conjunction with regenerative stoves. But, in operating a reduction-furnace, a high temperature is not the only requirement. It is also necessary that the fuel shall not be cansumed beyond a certain degree, in order to insure a re ducing flame for the reduction-process ; consequently, it becomes necessary to dispense with combustion as much as possible previous to the use of the fuel-gases in the reduction-furnace. Moreover, these gases must be preheated to a high degree, in order that a sufficient temperature may be maintained in the furnace; and, since this preheating cannot be accomplished by a previous, partial combustion of the gases themselves, it follows that the stoves for pre heating these gases should be heated to as high degree as it is pos sible to attain with an inferior fuel. This result can best be accom plished by complete combustion of the heating gases, and is further facilitated by preheating all of the air and gas used for this com plete combustion. It is more particularly desirable to preheat the air, since the combustible gases used may generally be obtained directly from the furnace, or gas-producer. The reducing gases, escaping from a gas-fuel reduction-furnace, are capable of considerable further dilution with air to secure com plete combustion, and consequently may be utilized for heating the stove to a high temperature, provided the air be sufficiently preheated.

Jan 1, 1889

By Emery R. Hayhurst

SILICOSIS has been described in a report of the American Public Health Association as a disease due to breathing air containing silica, characterized anatomically by generalized fibrotic changes and the development of miliary nodulations in both lungs, and clinically by shortness of breath, decreased chest expansion, lessened capacity for work, absence of fever, increased susceptibility to tuberculosis (some or all of which symptoms may be present), and by characteristic X-ray findings. ... The disease is divided arbitrarily into first, second, and third stages for convenience of description and possible compensation purposes. At least two distinct types of silicosis are recognized, acute and chronic. The acute form was reported as early as 1713, when a British patent for grinding flint by wet methods was granted because the dry powdered material "proved very destructive to mankind, so much that any person, ever so healthful, working in that business cannot possibly survive over two years."

Jan 1, 1936

By J. M. Karpinski

The need for standard test methods in the minerals beneficiation industry is growing with the increasing complexity of our processes and the more stringent requirements imposed on the quality and uniformity of our products. Although solutions of our problems have never been easy, they will become increasingly difficult to achieve unless we can develop a reliable and reproducible set of test methods. Historically speaking, our need was greatest for methods of chemical analysis. As these methods developed, they improved our ability to determine the grade of ore and measure the effect of our beneficiation attempts. The entire concept of grade and recovery is only as old as chemical analysis. Then came physical measurements. Each new concept in minerals beneficiation was related to certain properties and required corresponding test methods: specific density for jigging, magnetic susceptibility for magnetic separation, and tumbler strength for pellets. And associated with each process was the need for size determination. Size measurement is probably the first physical test ever conceived, and yet we are still improving on it. Dry sieving was quite acceptable for direct-shipping ores, but we had to go to wet sieving to control pelletizing and flotation. Subsieve analyzers have extended our routine measurements to the subsieve sizes, hut not below a few microns. As we all know, the solution of slimes- beneficiation and pollution-abatement problems is hampered by the lack of reliable and reproducible test methods in the fine-particle size range.

Jan 1, 1971

Meeting of May 22, 1914.-President Thayer. announced the appointment of the following Committee on Arrangements for the San Francisco meeting of 1915: Charles W. Merrill, Chairman; F. W. Bradley, Abbot A. Hanks, S. B. Christy, and H. C. Hoover. President Thayer announced the appointment of the following Committee on Organization for the Utah-Nevada Local Section: R. C. Gemmell, Chairman; C. D. Blood, Lafayette Hanchett, Ernest Gayford; Duncan MacVichie, and George W. Riter. The President of the Institute offered $100, to be known as the "President's Prize," to be used as prizes for the best papers submitted by members of the Affiliated Student Societies, to be divided as follows: First Prize, $50; Second Prize, $30; Third Prize, $20. A committee, consisting of J. F. Kemp, Chairman; W. L. Saunders, and T. T. Read, was appointed to report on the conditions to govern the award. The President announced the appointment of the Committee on Mining and Milling Methods, the personnel of which is shown on a subsequent page of this Bulletin. The following were appointed on the Advisory Committee to the U. S. Bureau of Standards, to represent the manufacture of the various non-ferrous metals as indicated: Copper, F. L. Antisell; Nickel, David H. Browne; Lead, H. O. Hofman; Aluminum, J. W. Richards; Zinc, G. C. Stone. It was voted to hold a meeting of the Institute under the auspices of, the Iron and Steel Committee, the Committee on Petroleum and Gas, and the Committee on Coal and Coke, in Pittsburg, Pa., Oct. 8, 9, and. 10, 1914.

Jan 7, 1914

(Members, are urged -to send in for this column any notes of interest concerning themselves or their fellow-members,). Members and guests R: ho called at Institute headquarters during the period Dec: 10, 1916 to Jan. 10, 1917: F. L. Antisell, Perth Amboy, N. J. William Kelly, Vulcan, Mich. F. J Brulé, Toronto, Ont., Canada. W. H. Lanagan, San Francisco, Cal. Zar T. Crittenden, The. Pas, Mau, Canada. S. Lefevre, Forest Glen, N Y Thomas F. Donnelly, Tucson, Ariz. ' D. A. Lyle, St..David's, Pa. - John Davenport, Brighton, 14 lass. -Domingo Nugués, Buenos Aires, Argon-. E. E. Ellis, Birmingham, Ala. tine. N. H. Emmons, 3d, Copperhill, Tenn. - H. L. Scaife, Clinton, S. C. W.. E. Erdofy, New York, N. Y. Mortimer A. Sears, Washington, D. C. C. L. French, New York, N. Y. E. Spurny, New York, N. Y.' , M. H. Gannon, Butte,. Mont. R. K. Stockwell, Santiago, Chile. R. E. Hoffman, Hannibal, Mo. Benjamin F. Tibby, Salt Lake City, Utah. C. Vey Holman, Rockland, Me. Arthur P. Watt, St. Francois, Mo. Arthur P. Allen has left the employ of the Calumet &- Hecla Mine and is now with the Highland Min. Co., Ashcroft, B. C., Canada. H: C. Bellinger has been appointed. general manager of the Chuqui- - c mata mine-of the Chile Exploration Co. -

Jan 2, 1917

By DOOLITTLE E. M.

(Canal Zone Meeting, November, 1910.) The following notes are contributed, not with the idea of offering a complete history of the development of this very important process as applied to the Leadville district, but with the hope that the practice, as it was carried out in the Bi-Metallic Smelter, may still be of interest to others. The Bi-Metallic Smelter, at Leadville, Colo., was the first to make a commercial success of the process described in the following pages, which consisted essentially of smelting raw silver- and copper-bearing sulphide ores in blast-furnaces to form a matte, which was generally re-smelted with siliceous ores for a second high-grade matte. Robert Sticht, in his excellent monograph on the subject,1 has outlined briefly the plant belonging to this company. He says, in effect: The Boulder, Mont., enterprise set the example for others with whom the patentee (w. L. Austin) had been negotiating, and the old La Plata lead-smelter at Leadville, Colo., was fashioned into a crude, temporary experimental plant for the Bi-Metallic Company, and the feasibility of the process demonstrated by a trial run. Subsequently, the plant was considerably improved, and, being supplied with very favorable ores, continued to run without interruption from August, 1892, to June, 1893. In September, 1893, smelting was resumed in a completely remodeled establishment, some $200,000 having been expended upon the new work. Thus, aside from the Montana experiments, which, under the direction of W. L. Austin, began as early as- 1885 2 at Toston, and continued with indifferent success for six or seven years, the Bi-Metallic plant at Leadville may be said to have * Formerly Superintendent, Bi-Metallic Smelting Co. + Formerly Chief Assayer and Chemist, Bi-Metallic Smelting Co. 1 Modern Copper Smelting, E. D. Peters, 7th ed., p. 415 (1895). 2 Trans., xvi., p. 259 (1887-88).

Dec 1, 1910

By A. E. Nehrenberg

THE mechanism by which austenite forms in steels has received a great deal of attention in the literature in past years.'-'* Our present knowledge concerning this mechanism has been recently summarized quite concisely by Bain and Vilella,1 while a few years ago the literature was carefully reviewed by Roberts and Mehl.² The consensus is that any ferrite-carbide interface is a potential site for the nucleation of austenite during heating above the Acl temperature, and that the new austenite generally grows freely to produce approximately equiaxed grains, whether the carbides are initially present in the lamellar or the spheroidal form. In the case of eutectoid steels, growth of the new grains of austenite continues until contact is established with other grains. Then growth stops and an initial austenite grain size is established which does not change until the heating is continued to some high temperature at which grain coarsening begins. In the case of pearlitic steels which are not of eutectoid composition, the proeutectoid ferrite or carbide may interfere with the growth of the austenite if the temperature is not above that designated the A63 or the Acm, respectively. Although a large amount of work has been done to establish the mechanism of austenite formation in steels, it became clear to the present author while he was studying the transformation characteristics of a new 0.25 C Mn-Si-Ni-Mo hypoeutectoid steel" that the manner in which austenite grows in steels depends upon some factor, or factors, not previously considered. This was indicated by the fact that when this steel in the spheroidized condition was heated above the Ae1 temperature the new austenite which was formed did not envelop the carbides and grow in an equiaxed manner as described by Bain³ or spheroidized steels. Instead, in this steel, the austenite was observed to grow much more readily in certain directions than in others with the result that at temperatures within the Ac1-Ac³ ransformation range the austenite grains were acicular in shape. The excess ferrite was also found to be acicular with the distribution of these phases being such that a lamellar pattern was developed. This unusual directional growth of austenite in this new steel initially in the spheroidized condition is illustrated by fig. 1. A search of the literature revealed that this type of growth was not necessarily peculiar to this steel for similar microstructures had been observed by other investigators.4-8 However, the full significance of these microstructures does not appear to have been appreciated, and no work has been done to determine the conditions responsible for this directional growth of austenite or to arrive at an understanding of it. It was for this purpose that the work described in the present paper was carried out. Material: During the course of this investigation a total of 15 steels was studied. They consisted of hypoeutectoid, eutectoid and hypereutectoid carbon steels, and hypoeutectoid and hypereutectoid alloy steels, all of which were obtained in the annealed condition from commercial warehouse stock. As received, the carbon and alloy hypereutectoid steels had microstructures which consisted of spheroidal carbides in ferrite, whereas the eutectoid steel and the hypoeutectoid steels were pearlitic. The grades of steel represented were 1050, 1080, 10110, 3310, 4140, 4340, 4615, 6145, 8620, 9260, 9442,

Jan 1, 1951

By George Comstock

Results are given of scleroscope and Brinell tests on specimens of cast 10-per cent. aluminum bronze, quenched and reheated at various low temperatures. The scleroscope was not found as reliable as the Brinell machine for measuring the hardness, for the size of the piece tested seemed to affect the scleroscope results. The maximum hardness was obtained by quenching and reheating to between 315° and 370° C. Softening was produced by reheating above 370° or 400° C. A series of polished and etched microsections showed a more reddish color in those that had been reheated above 400° C., and a change in microstructure above 500° C. IT HAS been known for many years that the alloy containing 90 per cent. copper and 10 per cent. aluminum can be hardened, like steel, by quenching from a suitable temperature, and that the hardened alloy can be softened again by annealing or drawing the temper. It does not seem to be generally appreciated, however, that the effect of the first slight reheating after quenching is actually increased hardness, the softening effect not taking place until a certain temperature of "drawing" has been exceeded. This paper gives the results of a few experiments on various specimens of cast 10-per cent. aluminum bronze, quenched for maximum hardness, and subsequently annealed at different temperatures. The hardness measurements were made with both a scleroscope and a standard Swedish Brinell machine; some peculiarities of the scleroscope test on this material are described. The author is not aware of many previous investigations of the hardness of this alloy when quenched and drawn, but two important papers on the subject should be mentioned. The earliest was by Portevin and Arnou,1 in which it was stated that tempering quenched 10-per cent. aluminum bronze at 400° C. increased the hardness as compared with the quenched untempered alloy and that reheating above that temperature was necessary to obtain any softening effect.

Jan 7, 1924

By N. E. Bonn

IT is well known that most of the materials entering into the manufacture of thermocouples are subject to variations in their thermoelectric characteristics, the chief causes of which are: differences in chemical composition; the previous .history, which includes mechanical working, ageing, oxidation, and contamination; and mode of use, such as depth of immersion, etc. In the case of a very extensively use thermoelement, the iron-constantan couple, neither iron nor constantan are absolutely uniform, and a number of checks are made during the process of manufacture. As both are subject to diversion from a standard value, neither, can be used for checking the other. It is, therefore, necessary to find a third metal against, which iron and constantan maybe checked. It was to find such a metal; that the present investigation was undertaken. To be a reliable, checking standard, the metal must possess a fairly high melting point? it must be obtainable in sufficient purity, and it must be uniform and constant with respect to its thermoelectric qualities. The choice is, as a result, limited to a few metals, such as copper, gold, and silver. Copper has the advantage of low cost, which makes it possible to use each wire only once and thus avoid any variations due to continued use, although previous investigators have found1 that continued use does not affect the calibration of a copper-constantan thermocouple. Copper also has the advantage of a large thermal electromotive force against constantan and would be desirable as a checking standard if it could be shown that it possessed the proper thermoelectric characteristics. The investigation, accordingly, resolved itself into three phases: the uniformity of commercial electrolytic copper, the effect of aging and method of annealing, and the calibration of the copper-constantan thermocouple.

Jan 9, 1919

The following is an incomplete list of members and guests who called at Institute headquarters during the period July 10, 1919, to Aug. 10, 1919. Howard C. Arnold, Washington, Pa. J. S. Lane, New York City, N. Y. L. M. Banks, Denver, Colo. H. W. Lawrie, Washington, D. C. George S. Blair, Pittsburgh, Pa. J. L. McAllen, Latouche, Alaska. Richard H. Catlett, Newark, N. J. David F. McFarland, Urbana, Ill. George L. Clark, Council Bluffs, Iowa. James F. Magee, Lancaster, Pa. Capt. Frederick S. Cook, Portland, Ore. A. G. McGregor, Warren, Ariz. John J. Croston, Atlanta, Ga. Emory M. Marshall, Santa Fe, N. M. Thomas Davis, Seattle, Wash. Benjamin L. Miller, Bethlehem, Pa. J. C. Dick, Salt Lake Cite, Utah. 2d Lieut. C. 0. Noble, U. S. Army. Chris. G. Dobson, Vancouver, B. C. Irving Perrine, Hutchinson, Kans. H. S. Emlaw, Grand Rapids, Mich. Fred S. Porter, Seattle, Washington. F. A. Fahrenwald, Cleveland, Ohio. Capt. H. R. Robbins, Peking, China Lieut. James L. Head, St. Louis, Mo. Joseph P. Ruth, Jr., Denver, Colo. A. A. Holland, Napanu, Canada. William A. Simkins, San Francisco, Calif. W. E. Hopper, Washington, D. C. T .V. Smirnoff, Siberia. Harry Hotchkin, Chicago, Ill. Harrison Souder, Cornwall, Pa. L. L. Hutchison, Tulsa., Okla. F. J. Sur, Denver, Colo. Paul S. King, Wilmington, Del. Harry Wolf, Denver, Colo. George K. Anderson, Jr., lies accepted a position as manager for Wight & Co., producers of air-cooled blast-furnace slag, at Longdale, Va. J. M. Armstrong, with the Caribbean Petroleum Co., has been transferred from Philadelphia to Maracaibo, Venezuela. Fred Sherman Baker, who has been with the Oriental Consolidated Mining Co., at Unsankinko, Chosen, Korea, is now at Columbia City, Ind. Ray J. Barber has removed from Roxbury, Mass., to New York City, and is now consulting engineer for the Roxbury Cold Mines, Inc.

Jan 9, 1919

By LUDWIG VOGELSTEIN

WE are indebted to Mr. Barbour for his valuable contribution to the literature on copper statistics; it is to my knowledge the only intelligent attempt to throw light on a much misunderstood subject. If I should appear to criticize some of his findings and arguments, I do not want to leave the impression that I do not appreciate the article; I think Mr. Barbour has been painstaking, and even where one might not agree with his conclusions, he has opened our eyes and stimulated us in our search for the truth.' It might be well to define the term "secondary copper" and to make a few remarks about the origin and the reasons for the variation of the supply. Mr. Barbour has touched on these points, but not sufficiently to make them clear to those not in the business.

Jan 1, 1931

By George F. Weaton

Although an almost continuous campaign had been carried on by various experimenters since 1885 to find a commercial process of smelting zinc by electrothermic means, no commercial success was attained in the United States. The St. Joseph Lead Co., appreciating the theoretical possibilities of such a process, such as the ability to construct units of large capacity, quality control, and the possibility of treating complex and refractory ores, decided in 1926 that the process was worthy of further investigation, and in that year, at one of its southeast Missouri plants, began the development of the electrothermic zinc-smelting process according to the invention of the late Earl C. Gaskill. Late in 1929 the process reached a stage of commercial significance, and in 1930 the erection of a modern electrothermic zinc smelter was begun, at Josephtown, Beaver County, Pa. The site is 3 miles from Monaca, which is on the main line of the Pittsburgh & Lake Erie Railroad, and a spur of the railroad has been constructed to the plant site. The site borders upon the Ohio River, which is navigable for 600 to 800-ton barges. This district was selected for the plant after an economic survey involving such questions as cost and availability of electric power, reduction fuel, transportation facilities, and the transportation charges on raw and finished materials, labor conditions, and taxes. The initial unit of the plant was designed to treat daily 120 tons of 58 per cent zinc sulphide concentrates from the company's mines in St. Lawrence County, New York. The plant equipment is housed in seven modern steel-frame buildings, and includes: Roasting and Acid Plants 3000-ton concentrate storage. Two Nichols-Herreshoff 21 ft. 6-in. diameter, 12-hearth roasters with usual cast-iron airshaft supporting chromium-alloy rabble arms and rabbles. SO2 gas purification system consisting of: One double-compartment hot-dust Cottrell precipitator. Cast-iron sinuous air-contact gas cooler.

Jan 1, 1937

CRUSHING and concentration flow-sheets of western mills have become greatly simplified and more or less standardized of recent years with the introduction of modern grinding methods and flotation. Improvement has not stopped, however, and advancement is continually being made in crushing and milling practice. A case in point, where remarkable improvements in efficiency have resulted from comparatively minor changes in the flow-sheet, is in the New Cornelia mill of the Calumet and Arizona Mining Co. at Ajo, Ariz. This mill, completed in 1924 for the concentration ,of the sulfide ores of the New Cornelia mine, was originally designed for a 5000-ton capacity. Before recent changes and additions were made the five 1000-ton units were handling 6500 to 7000 tons per day, giving a flotation feed of approximately 14 per

Jan 1, 1930