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By Charles J. Potter

There are many sources of energy available for consumption. Some available are solar, tide and wind. However, in terms of relatively large usage, only four principal sources are used for primary energy today. They are coal, oil, natural gas and water power. Such additional items as wood and nuclear energy, although supplying quantities of energy today, do not in the aggregate amount to any real significant quantity, but nuclear energy must be considered for future use. In addition, such a thing as gas from distillation of coal and oil is not considered primary energy. The principal markets for primary energy are the electric power utilities, space heating, industrial uses and transportation. The electric utility use of energy is primarily from coal, followed by natural gas and water power. Space heating is primarily a gas market, followed by oil and then coal. Space heating by electricity is only considered in the generation of electric power. Transportation's principal source of energy is oil. Coal has practically no market left in this field.

Jan 4, 1962

By C. F. Wang

Page I. Introduction............:.............. 395 Manchuria in General ....................... 395 Pen-hsi-hu............................ 397 Pen-hsi-hu Coal & Iron Co., Ltd................... 399 I1. organization........................... 400 III. Coal Deposit........................... 402 Location..............................402 Geology............................. 403 Coal Mining...........'.................. 404 Mining Methods........................407 Mining Cost.........................408 IV. Coal Washing Plant.......................408 V. Coking Plant..........................410 VI. Iron Deposit...........................413 Magnetite Belt.......................... 413 Origin of Deposit......................... 414 Iron Mining........................... 415 VII. Concentration Plant........................ 417 VIII. Briquetting Plant.......................... 418 IX. Blast-furnace Smelting...................... 418 iNTKODtrCTION Manchuria in General Manchuria. called the "Three Eastern Provinces" in Chinese. forms the northeastern corner of China and is bordered by Siberia on the north and northeast. and by Korea on the east. It is a land famous in Chinese annals as the place of origin of the Ching dynasty. and in more recent times it has bcen an arena for diplomatic maneuvering and commercial competition between the Russians. advancing from the north. and the Japanese from the southeast. It derives its name of "three eastern provinces" from the fact that it is divided into three provinces; Hei-

Jan 1, 1918

By Charles Eichrodt

THE ore that is being treated by the present plant lies between the leached zone, or capping, and the mixed sulfide and oxide zone. The principal copper minerals are chalcanthite (CuSO4.5H20), brochantite (CuS04 3Cu (OH)2) and atacarnite, (CuC12.3Cu (OH)2). There are, in addition, some other minerals such as cuprite and kröhnkite (CuSO4. Na2SO4.2H20). These minerals, with many others, occur in a greatly crushed granodiorite rock. Most of the copper-bearing minerals occur in the cracks and veinlets, but there are disseminated values and it is probably the relative proportion of these that accounts for some otherwise unexplainable variations in extraction. The entire mineralization of the ore is complex and varies with depth. This variation, the problems presented thereby, and the effect of various constituents of the ore will be taken up in detail. An analysis of an unweighted composite of the ore treated during 1927 follows:

Jan 1, 1930

By G. O. Hiers

THE object of the experiments reported in this paper is to determine the eutectic composition of copper and tin and to determine the location of the part of the liquidus line immediately above the eutectic composition in copper. Three methods were used in the investigation: (1) the method of dissolving copper in a bath of molten tin at constant temperature, with the idea that when the bath was saturated with copper its copper content, by analysis, together with the temperature at which the saturation took place would locate a point on the liquidus line (2) the method of the differential cooling curves, and (3) the method of microscopic examination. This paper is principally concerned with the results of the last two methods mentioned. The results of the first method, that of dissolving copper in molten tin, did not agree with the .results of Miller,1 by the same method, nor with the results of other investigators by other methods, nor yet with the results of the cooling-¬curve experiments and microscopic examination reported here.

Jan 1, 1929

By T. S. Lundy, R. E. Pawel

Effects of short-circuiting paths on observed diffusion behavior in real crystalline systems are considered. It is concluded that experimentally measured diffusion coefficients may vary widely from values associated with true lattice diffusion to those appropriate for short-circuiting paths alone depending upon the conditions of the experiment and the sensitivity and completeness of the data. IN 1961 Harrison1 classified experimentally observed diffusion behavior in systems involving both lattice and dislocation-enhanced atomic transport into three categories. His types A and C were limiting cases where the measured diffusion coefficients using the usual serial sectioning techniques were representative of lattice diffusion (with only slight effects of dislocations) and dislocation-network diffusion (with only slight effects from lattice diffusion), respectively. In both cases A and C for a sectioning experiment in which the diffusion couple has the semi-infinite geometry and unidirectional diffusion takes place from a plane source located at the origin of the coordinate system, he pointed out that Gaussian penetration behavior should be observed. For case A the lattice coefficient should be slightly enhanced by dislocation contributions, and the model of Hart2 can be used to predict the amount of this enhancement. For case C the observed coefficient should be that for the dislocation network and have little or nothing to do with lattice diffusion. Hart's model in its general form is still applicable, but the apparent diffusion coefficient for this case is virtually independent of dislocation density. Harrison's case B is that for which non-negligible contributions exist for transport by both mechanisms and "the concentration distribution does not approximate to any simple form." With the possible exception of very low temperatures where diffusion distances approach atomic dimensions, any real diffusion specimen will in general show non-Gaussian behavior provided the data are complete enough to uncover it. Thus, a "complete" set of data for any real system cannot be expected to be totally amenable to treatment by a simple mathematical model which does not take into account the relative distribution of transport by the various modes or submodes. For a particular sensitivity of specimen analysis and at a given temperature of annealing if the concentration profile could be observed as a function of time, "the behavior will initially be type C, and will develop into type B. and ultimately type A".1 Thus, it appears that the type of diffusion behavior which is experimentally observed in a given system depends very much upon the particular experimental conditions and the particular tools available to obtain the data. Interpreted in this fashion, Harrison's classification refers not to the diffusion behavior as a whole but to the relative sensitivity of the method of examination and completeness of the data. In the present paper we will: 1) assume that the measured penetration behavior follows the same general classification as that proposed by Harrison; 2) give, for diffusion in tungsten, examples of the range of diffusion coefficients that it is possible to obtain in a single experiment; and 3) speculate that some arguments which consider the possibility of short-circuiting effects being responsible for "anomalous" diffusion in several bcc metals may have been discarded prematurely.3 Both monocrystalline and polycrystalline tungsten were used in this work. The former was obtained as triple-pass, electron-beam zone-refined 6.0-mm-diam rod from Materials Research Corp.. Orange-burg. N.Y. The latter was swaged, high-purity bar stock which was annealed for 2 hr at 2200°C and 10-9 torr to yield an average grain diameter of about 25 /i. The tracer Nb95 was received in oxalate solution from the Isotopes Division, Oak Ridge National Laboratory. Experimental procedures of specimen preparation, isothermal diffusion annealing, serial sectioning by anodizing-and-stripping, and y counting of the individual sections to determine the tracer penetration profile after a given diffusion anneal have been described elsewhere.4 However, it should be noted that the anodizing-stripping sectioning technique has the particular advantage for this research of permitting sectioning to be accomplished over a wide range of

Jan 1, 1970

By Z. Moser, W. Ptak

The experiments were carried out by the method of measuring the electromotive force of concentration cells having zinc as a reference electrode, the second electrode being the liquid alloy Zn-Sn-Cd-Pb. The electrolyte consisted of liquid chlorides and had zinc ions. The measurements were made for seventy -five alloys of different mole fractions within the temperature range of 714° to 877°K. The experimental results enabled the calculation of the activity of zinc in tested solutions. The activities of zinc were calculated by means of Krupkowski's formulas.3 In addition, the formulas for coefficients of activity of zinc, tin, cadmium. and lead as the function of composition and temperature were given. Activity of zinc was compared with the values obtained from experimental results, and good agreement has been observed. On this basis it can be stated that the theoretical formulas are suitable for determining the thermodynamic properties of liquid quaternary metal solutions. IN the metallurgical processes being carried out at present multicomponent liquid metal solutions take part. For the thermodynamic analysis of these processes it is necessary to know the thermodynamic properties of these solutions. Therefore, many experimental and theoretical papers deal with this problem. The theoretical papers are generally based on the assumption that the structure of liquid metals is similar to their structure in the solid state. In this manner the model of liquid solution, consequently described by means of statistical thermodynamics, has been accepted. This method is being lately developed, especially for solid solutions. Statistical thermodynamics was applied among others by Guggenheim 1 for describing the thermodynamic properties. Unfortunately, the formulas of statistical thermodynamics are often not suitable for the interpretation of experimental results. Attention should be drawn to the relations obtained by means of formulas of phenomenological thermodynamics which always have constants derived with the aid of experimental methods. In the case of the multi-component solutions which contain some additions of impurities besides the basic metal, wagner2 introduced interaction parameters. Equations for the relationship between the activity coefficients and composition were also given by Krupkowski." he application of these formulas requires a good knowledge of the thermodynamic properties of the corresponding binary systems. In these formulas, as in Wagner's, there appear constants which should be determined from ex- perimental data. Nowadays, different experimental methods are applied for evaluating the thermodynamic functions of solutions, for instance: vapor pressure measurements, calorimetric methods, and the measurements of electromotive force of concentration cells. In the present paper this last method for evaluating the thermodynamic properties of four-component systems, Zn-Sn-Cd-Pb, was applied. For instance in the case of Zn-Sn solutions Alabyshev and Landratov, 4 Fiorani and Valenti, 5 and ptak6 performed the investigations. The Zn-Pb system was worked out by Kleppa 7 and Cd-Pb and Cd-Sn by Elliot and chipman.' This method was also applied for determining the activity of zinc in ternary solutions. 1) EXPERIMENTAL METHOD The experimental arrangement with detailed description is given in Fig. 1. It consists of resistance furnaces, one serving for melting samples and the other containing the flat-bottomed, measuring quartz tube with the liquid electrolyte. Liquid metals and alloys are in glass supremax tubes, which have an opening in their lower part above the metal level. This opening allows the filling of the tubes by the electrolyte. In these tubes tungsten wires are placed which by means of suitable conductors are connected with a potentiometer. It is assumed that tungsten dissolves Fig. 1—Schematic diagram of the experimental arrangement for the investigation of the thermodynamic properties of liquid metal solutions: 1, resistance furnaces; 2, autotransfor-mers; 3, galvanometers; 4, regulator of temperature; 5, gas purifier with concentrated H2SOP; 6, U-tube with P2O5; 7, thermostats; 8, steel block for thermostating; 9, supremax tubes for alloys; 10, tungsten electrodes; 11, inlet and outlet of argon; 12, measuring quartz tube; 13, tube for melting samples; 14, tube for thermocouple; 15, cover of quartz tube; 16, rubber seal; 17, bottom cover; 18, outlet of electrodes to potentiometer; 19, outlet of thermocouples to potentiometer; 20, upper view of the quartz tube cover; 21, orifices for cover screws; 22, orifice for argon inlet; 23, orifice for thermocouple; 24, orifices for tubes containing liquid metals; 25, inlet for water-cooling system.

Jan 1, 1969

By J. T. Raleigh, D. L. Flock

This study investigated the nature of formation plugging with bacteria and attempted to relate its characteristics to physical rock properties. Fifteen core samples of four specific formation types were defined and plugged using a commonly occurring, uniform sized dead bacteria, Bacillus subtilis. Two of the formation types were fairly uniform-grained sandstones and two were heterogeneous carbonates. The injection rate and concentration of solids in the brine were held constant during the test runs. The pore geometry factor G was a significant petro-physical rock characteristic for correlation with depth of plugging, but lacked importance as a parameter for rate of plugging. Although the G factor may not completely describe porous rock geometry for plugging predictions, for reservoirs with multi-pore systems, there is evidence that the pore geometry factor might form a basis for establishing injection water specification in more llornogeneous reservoirs with only primary porosity development. INTRODUCTION GENERAL PURPOSE Injecting water into oil-bearing formations to increase recovery is common practice in the petroleum industry. One of the most serious operational problems involved with water injection wells is the tendency of the porous rock immediately adjacent to the injection wellbore to plug partially. This results in increased injection pressures and/or a decrease in the rate of injection. This plugging in injection wells can result from a number of causes, including bacteria contained in the injected water.1 The purpose of this work was to investigate the nature of injection plugging with bacteria and to attempt to relate its characteristics to physical rock properties. Many variables exist in research of this type, so, to reduce them, injection rate and concentration of bacteria in brine were held constant. The bacteria used for plugging was a uniform-sized, dead bacteria, Bacillus subtilis, a micro-organism commonly found in water, air and soils. Four specific porous rock types were plugged—two consolidated sandstones and two heterogeneous carbonates. The experimental work involved two distinct phases. The first concerned determining the physical rock properties and the second was the experimental work of actually plugging the selected core samples. PORE GEOMETRY FACTOR Capillary pressure is necessary to displace a wetting fluid from a capillary opening with a nonwetting fluid. The factors which govern capillary pressure are the surface or interfacial tension of the fluids involved, the system wettability and the equivalent pore radius. Thus: P,= 2ucososrd..........(1) Thomeer used the idea that the location and shape of the capillary pressure curve reflect characteristics of the pore structure of any porous media sample.' He presented the mathematical description of capillary pressure curves and of indicated differences in pore geometry of samples. where G = pore geometry factor PC = capillary pressure Pi = displacement pressure (V,)p, = fractional bulk volume occupied by the displacing fluid at any capillary pressure (V,), = fractional bulk volume occupied by the displacing fluid at infinite pressure or total interconnected pore volumes. The shape of the curve is defined by the pore geometry factor G. The curve shape is related directly to the sorting and interconnection of the pores of the sample. The location of an infinite number of curves can be defined by the same asymptotes. However, these curves differ in shape, each curve being described by a specific value of G. Thus, the description of a curve is unique when, in addition to the position of its asymptotes, its shape is defined. These curves can be used graphically to determine the characteristic parameters of any arbitrarily located curve. Those parameters that can be approximated from any capillary pressure curve are: (1) total interconnected pore volume, represented by (V,),- ; (2) extrapolated displacement pressure, the abscissa axis; and (3) pore geometry factor, by the curve shape. PROPERTIES OF BRINE AND BACTERIA The fluid used throughout this study was an aqueous solution of sodium chloride, 25,000 ppm by weight. The addition of salt to fresh water was intended to eliminate clay swelling in the sandstone cores and to retard leaching in the limestone cores. The viscosity of the brine solution at 100F, the temp-

Jan 1, 1966

By J. Paone, S. Tandanand

This paper studies the behavior of rock at the initial state of crater formation resulting from stresses created under a drill bit. The purpose of this study is to determine which mechanical properties of rock are important in rock fragmentation by drilling. Although a definite relation between the drilling strength and relevant mechanical properties has not been established, maximum yield strength or hardness of rock is apparently a parameter of drillability of rock. The strengths of rock were considered from the Mohr-Coulomb criterion from which the surface of failure was constructed. The results from previous triaxial tests on Solenhofen limestone were adopted in establishing a limit of failure. Inelastic behavior of Solenhofen limestone was observed under a low velocity impact of a hemispherical bit and under static indentation with a similar bit. Permanent set at low applied loads in the indented area was measured with an interferometric technique. A quantitative determination of strengths of the rock was made under static indentation. The maximum yield strength estimated from the average stress over the contact area for plastic deformation was used as the crushing strength of rock under a drill bit. Much research has been done on energy requirements and mechanisms of energy dissipation to perfect rock fragmentation by a drilling process. But more needs to be done. More needs to be known about the mechanisms of energy dissipation or failure criteria of rocks in the drilling process in order to evaluate the efficiency of energy requirements in specific rock fragmentation. This paper examines some published studies on rock failure and energy dissipation and presents some findings in that phase of research concerned with rock fragmentation by drilling. This work is specifically concerned with rock behavior at an early stage of failure induced by a concentrated load. Consideration is limited to the primary phase of the crater formation under drill bit, i.e., before chipping takes place. Failure Phenomena of Rocks: Failure of rocks can be classified into two types, fracture and plastic flow. Both involve separation of material to form new surfaces with complete or partial loss of cohesion. Fracture is further classified as extension (or cleavage) fracture and shear fracture. Extension fracture involves separation in a plane without shear stress component, while shear fracture involves slippage along a plane as a result of combined stresses. Then, shear fracture inclines to the axes of the principal stresses. Plastic flow occurs under combined stresses, especially at high confining pressure and temperature, and denotes macroscopically irrecoverable deformation of rocks. Flow mechanisms have been classified as in-tergranular failure, intragranular gliding, and re-crystallization of mineral constituents.6 Failure phenomena in rocks are complicated because they include fractures and plastic flow as well as a friction process developed intrinsically as the internal stresses increase. All can occur in one rupture process, depending on the varying stress conditions. Both fracture and plastic flow are encountered in rock drilling. Rock failure under a drill bit as observed in drop tests simulating a single blow of a percussion drill, consists of two types, crushing and chipping. Crushing is considered as a separation of material particles by many fractures resulting from the application of high compressive stresses exceeding the strength of rock at the contact area. Chipping results from subsurface fractures extended to the face surface; this phase is preceded by crushing or surface deformation. The state of stress under the drill bit and the strength of rock create and control these two types of failure. The state of stress under the bit and in the vicinity of the contact area depend on the bit configuration and the magnitude of applied force. The strength of rock, characterized by its ability to resist penetration, depends on its composition and structure. However, the term "strength" quantitatively defined, is still ambiguous and may or may not correspond to the tensile, compressive and shear strength obtained from simple tests. Rock Failure Criterion: Rocks are weak in tension, their tensile strength being many times less than their compressive strength. This characteristic excludes

Jan 1, 1967

By John D. Price

R. W. Campbell (Jones and Laughlin Steel Carp., Pittsburgh)—As usual John Price has presented an excellent paper. I know of no one who has devoted more time and conscientious thought to this subject than he has, and his efforts have produced scientific data and conclusions of real value. Results of similar studies made by the Jones and Laughlin Steel Corp. on the blending of Pennsylvania coals may be of interest. During 1935 the late F. W. Wagner and the present writer developed an empirical physical fuel value formula for evaluating the combined physical tests of metallurgical coke, see Table IV. In the development of the formula, the tumbler test, shatter test, screen test, and porosity of coke have been taken into consideration. Each of these tests brings out some physical property not expressed by the others, and in estimation of the importance of these tests as a medium for evaluating coke for the blast furnace, their worth has been graded as follows: It was thought that some additional penalty should be applied to cokes that do not show a uniform screen size, assuming that coke larger than 4 in. was not desirable and that this size was an indication of irregular size. Therefore the screen test factor is further corrected by applying a penalty of 1 pct for each 1 pct material greater than 4-in. size as shown by the screen test. The physical fitness of coke for blast furnace use depends upon four fundamental characteristics: l—gen-era1 strength, as indicated by the shatter test; 2— abradability, or the resistance of cell walls to reduction in size by attrition, as indicated by the tumbler test; 3—porosity; and 4—size and uniformity. Each of these characteristics is not of equal importance, but surely, in an attempt to determine an accurate physical value, the individual value of each should be taken into consideration. The formula is used as a yardstick, so to speak, in determining variations in the normal production of metallurgical coke and in making comparisons between normal coke and experimental blends with other coals. Table IV gives results of coking tests on raw and washed high volatile coals and these same coals with blends of coke breeze, anthracite coal, char and low volatile coals, all from Pennsylvania. The table also gives the source of the coals and coke breeze, as well as their proximate analyses. It will be noted that the washing of the raw high volatile coal increased the physical fuel value from 26.17 to 39.16, showing the effect of removing shale and slate which produces a detrimental fracturing and weakening of the coke. It is a well known fact that many Pennsylvania high volatile coals contain an excess of resinous material or binder which has a tendency to weaken the coke, owing to its high evolution of gases during carbonization. Tests were therefore made with coke breeze, an inert material, in an attempt to alleviate this condition. Blends of washed coal with 5 pct and 7.5 pct coke breeze collected from the coke plant quenching sump (82.9 pct through 1/8-in. screen) resulted in cokes with a physical fuel value of 20.75 and 16.73 respectively, lower than results obtained from 100 pct raw high volatile coal. It will be noted that the percentage of + 4-in. coke increased but that the tumbler test was very low. Undoubtedly better results could have been obtained if the coke breeze could have been crushed extremely fine. During World War II the government asked the coking industry to consider the use of anthracite coal as a substitute for high quality low volatile coal, which was extremely scarce at the time. The next series of tests was made with blends of raw and washed high volatile coals and 5, 10, and 15 pct Pennsylvania No. 5 buckwheat anthracite (100 pct through l/8-in. screen). It was necessary to use some raw high volatile coal in these blends because of insufficient washer capacity at the time. It will be noted that the physical fuel values

Jan 1, 1954

By Albert S. Trube

The purpose of this paper is to clarify the definition of compressibility and to present a uniform basis upon which instantaneous compressibilities of liquids and gases can be compared. The equations gaverning the instantaneous compressibilities of imperfect gases are derived and the concept of pseudo-reduced compressibility is introduced. Part of the data presented by Brown, Katz et a1 on compressibility factors for natural gases has been rearranged. A graph of pseudo-reduced compressibility vs pseudo-reduced pressure for various pseudo-reduced temperatures is presented. The need for additional work in relating the compressibilities of liquids and gases is discussed. This information should be of value to reservoir engineers in making non-steady state performance calculations in gas reservoirs. It should be of further use irz pointing the direction for additional research in the nature of liquid and gas compressibilities. INTRODUCTION With the increasing use of steady and non-steady state well and reservoir data, there is a corresponding increase in the importance of the various factors entering into such calculations. Increasing emphasis is being placed on the necessity for obtaining reasonably accurate estimates of the physical properties of the reservoir fluids well in advance of the more accurate laboratory data. One such factor is the isothermal coefficient of expansion of the media which are transmitting and attenuating the non-steady state pressure waves. The average isothermal coefficient of expansion, or "compressibility" is a complex function controlled by the physical properties of the formation and the fluids contained therein. The isothermal expansion coefficients for reservoir gases are usually quite variable, in many cases being highly-pressure sensitive. The coefficients for reservoir liquids tend to be pressure sensitive, but not nearly so much as reservoir gases. The coefficients for solids, usually expressed in terms of a "modulus of elasticity" are relatively insensitive to pressure variations within their elastic limits. For this reason, and also because many previous applications have been limited to rel- atively small pressure ranges, there has been a tendency to ignore the variable nature of isothermal expansion coefficients and treat them as constants. Also, the term "compressibility" by which these coefficients are generally designated is commonly confused with a similar term, z, used to define the deviation of an imperfect natural gas from the perfect gas laws. A clear distinction should be made at the outset between the term "compressibility", which is an isothermal coefficient of expansion of a substance, and the term "compressibility factor", z, which refers to the deviation of a gas from the perfect gas laws. Although the scope of this paper is limited to the compressibility of single phase natural gases, it is definitely related to the problem of accurately estimating the compressibilities of single phase hydrocarbon reservoir liquids, which will form the basis of a future presentation. BASIC PRINCIPLES The coefficient of isothermal compressibility of a substance, c, is usually determined from pressure-volume or pressure-length -measurements depending upon whether the substance is single phase gas, liquid, or solid. A convenient method for making such estimates for a finite change in pressure and volume at constant temperature is to use the well known equation V1-V2/V1 (p2 - p1) .....(1) Eq. 1 is negative because the volume of a confined substance decreases as the pressure is increased. In this case V1 > V2 and p2 > p1. This equation is useful in approximating the compressibilities of single phase gases and liquids undergoing small pressure changes. It is evident, however, that this equation is almost identical with the determination of Young's modulus of elasticity for solids. If the assumption is made that change in length is directly proportional to change in volume, as would very nearly be the case for a steel rod in tension within its elastic limit, then E5=-L1 (p2 - p1)/L1 - L2 .......(2) in which E. is the isothermal expansion coefficient, or Young's modulus of elasticity, for a solid. And further, for this special case L1 (p2 - p1)/L1 - L2 .......(3)

Jan 1, 1958

By D. G. Oss, S. E. Erickson

An automatic control method for the ferrosilicon heavy media process maintains media density within 0.01 specific gravity points. Continued demands for higher grade, competitive products from the Mesabi Range have resulted in experimental work such as that detailed for one concentrator. Various methods, step by step procedures and instruments used at an iron ore beneficiation plant in the development of an automatic control system are described. Work continues and it is hoped that further applications of control instrumentation can be made in the next operating season. The need for instrumentation and automatic control of the various parameters in the heavy media process of iron ore beneficiation has been apparent for some time. Continued demands for higher grade, competitive products from the Mesabi Range have made it necessary to increase the efficiency of the process in every possible way. In a typical heavy media flow scheme for iron ore beneficiation (Fig. 1) a sized, prepared feed (generally about —1% in. to +% in.) is fed to a heavy media separatory vessel, along with a ferrosilicon slurry. A separation of the feed is made on the basis of specific gravity. Low density particles overflow a tailings discharge weir, while high density ore particles sink to the bottom of the high density pool and are moved away to the concentrate discharge chute. Both products are passed over drainage screens and then are cleaned thoroughly of attached ferrosilicon on wash screens. Float material is generally stockpiled, while the sink product is shipped as a final concentrate. Undersize from the drain screens is returned directly to the circulating media sump. Wash screen undersize is cleaned of contaminating ore particles and slimes by passing through magnetic separators. Provision is also made for splitting a portion of the tailings drain undersize into the cleaning circuit if necessary for control of depth of tailings overflow, or for additional cleaning as required. Cleaned ferrosilicon is stored in a densifier and returned to the Circulating media sump as make-up material. Dilution water is also added to this sump to maintain a desired specific gravity of the circulating media. As in any process, operational intelligence is secured only by keeping records of the process variables. Generally apeaking, plant operators have neither the inclination nor the time to keep complete and detailed records of these variables over the course of their shift. Before instrumentation was added to aid the operator, specific gravity was measured by weighing a given volume of pulp at intervals of from 30 to 60 min. Scale readings were made at the beginning and end of each shift. No records were kept of operating conditions, such as rpm of the separatory ves-sel, media level in the machine, tons per hour of the products, and so forth. These items were recorded only when spot checks were made by the metallurgical staff. CONTlNlJOUS DENSITY RECORDING The first process instrument used, other than the usual ammeter on the drive motor of the separatory vessel, was a nuclear density gauge and its associated circular chart recorder. These instruments were used to indicate and record specific gravity of the circulating media. This was a tremendous aid to the operator in that tie was able to observe and correct the specific gravity at any time. There was also added incentive to make frequent corrections because of the permanent record made by the recorder of the densities. The addition of the nuclear density gauge was influential in securing optimum quality and recovery of the heavy media product. Manual control was improved, and it became possible for a good operator to main control within f.05 specific gravity units. This compares with an unknown quantity, estimated at f0.15 gravity units, when manual measurement and control was used. An example of the improvement in manual control over the course of one season's operations is shown in Fig. 2. Chart A is typical of the records made shortly after the gauge was installed. Needless to say, it was difficult for operators and foremen alike

Jan 1, 1962

By R. L. Slobod, H. A. Blum

A semiquantitative method for measuring the wettability of reservoir rocks has been developed. These data are needed for reservoir analysis and for interpretation of laboratory displacement studies. The wettability of a core sample is measured by the contact angle for the system oil-water-solid. These contact angles are calculated from the displacement pressure (threshold pressure) obtained by use of the centrifuge, using first oil-water and second air-oil in the same core sample. This method is based on the assumption that the air-oil and oil-water interfaces occupy similar positions in the porous medium when desaturation of the wetting phase is initiated. The assumption is also made that the Contact angle for the air-oil-solid system which is close to zero in value does not change appreciably even when the contact angle for the oil-water-solid system experiences marked changes. "Apparent contact angles'' for five different solids ranging from 31" to 82" have been determined, and changes irr the "apparent contact angle" of a given sample with laboratory use from 33" to 53' {lave been observed. INTRODUCTION Reservoir rocks vary in their wettability, 1,2,3,4 some being preferentially water wet while other are apparently preferentially oil wet. The degree of wettability, in theory, is measured quantitatively by the contact angle for the system solid-oil-water, hut in 1)practice this quantity is extremely difficult to determine." The need for obtaining some measure of this quantity has become obvious in recent years as a result of both laboratory. and field observations. Several reservoir.: such as the Bradford Sand in Pennsylvania and the Wilcox' at Oklahoma City are reported to be oil wet. If these report:: correctly reflect the true nature of the surface of the rock in the ground, then these reservoirs probably will not perform as predicted on the basis of a water wet rock. In the laboratory many core samples have been Observed to be oil wet. These samples, while perhaps not correctly representing the reservoir, have markedly different properties from water wet rock. The location of the phases is different (oil is in contact with rock instead of water), and other quantities such as the connate water, the capillary pressure curve; residual oil. relative permeabilities. and the recovery of oil by water flooding are markedly affected by the value of the contact -4 A further complication observed in the laboratory is the chang-ing of the wettability of a rock specimen with use. such changes mean that repeat runs on the same core are not the duplicate tests desired, but represent new experiments on a more oil wet material. The changes in surface characteristics are sometimes so rapid that by the time an experiment requiring several days is completed, the results may not be representative of the core as originally described, The, rock material itself (Silica. carbonates. etc.), whell Clean and uncontaminated, is water wet. There seems b( : little evidence of the presence of oil wet minerals such as heavy metal sulfides. The oil wetness of reservoir samples, therefore, is believed to be caused by the accumulation of an adsorbed film in which the polar group of a large organic. molecule is adsorbed on the surface leaving the organic or hydrocarbon part of the molecule projecting out from the solid. Such a surface is much more readily wet 17" oil than by water. These considerations indicate the need for a method which will provide some measure of tile wettalbility (Contact(angle if possible) for reservoir rock ..samples) The method should be capable of (1.1 distinguishing between tile wettalility of dif. ferent formation,.. (2) detecting (change. ill wettalbility of a core with use. and (3) measuring the changes in Wettability which may be accomplished with cleaning operations. such as the use of sodium silicate for increasing water wrettalbility." A preliminary report on such a method is preseted below. not with the idea that this procedure alone will Solve the wettabil-ity problem. but rather that it may provide encouragement to

Jan 1, 1952

By R. E. Jenkins

The Bell Canyon member of the Delaware Mountain group has yielded quite a large number of fields in which completion and production problems have been numerous and complex. Reserves are difficult to estimate due to the problem of evaluating the formation water saturation, and the feasibility of water flooding is questionable. Extensive laboratory investigations were undertaken to determine if normally measured rock and contained fluids properties could account for many of the peculiar characteristics of the formation. A statistical study or routine core-analysis data was made. Capillary-pressure data were obtained by several techniques. Fresh-water and brine permeabilities were measured and relative permeabilities of oil, water and gas were determined. Some qualitative wetta-bility tests were performed, and the petrography of a few thin sections was studied. The results of this work are presented, with typical or average data shown for each test. The permeability -to- water characteristic of the Delaware was found to be abnormally poor. Correlations of laboratory and field performance data indicate high water saturations in much of the formation. Pore geometry is highly uniform. INTRODUCTION The Delaware formation has undergone extensive exploration and development in the past few years. This has resulted in the discovery of quite a number of fields—producing oil for the most part. A large percentage of the productive wells have produced water along with the oil. Often there is no apparent pattern for the percentage of water cut experienced. In several instances vertical displacments of over 200 ft have been established between communicating wells in which the formation appears to be about the same, yet the structurally high wells yield a much higher water cut than the lower wells. Drill-stem tests have contributed little to well completion because they nearly always show small amounts of water (usually mud filtrate), regardless of what is produced later in the life of the well. Other formation evaluation methods have had no more than limited success in indicating ultimate productivity. Consequently, predicting the type of fluid productivity of Delaware wells has been very difficult. Hydraulic fracture treatments are almost universal, and unstimulated Delaware wells have not exhibited the productivity that normally would be expected of wells with the specific permeabilities encountered. Some operators have indicated that their Delaware wells need frequent re-stimulation. The uncertainty of reservoir water saturations reported for the Delaware has made difficult the task of evaluating oil in place in the reservoirs and estimating primary recovery. The unreliability of this data also will cause feasibility studies for water flooding or other secondary-recovery methods to be problematical. Several opinions have been voiced to explain why the Delaware performs as it does. Chronically poor well completions, dynamic water and tilted water tables, capillary inequi-libria, peculiar relative permeability characteristics and oil-wetness are among the suggested reasons. The dual purpose of this paper is (1) to describe the principal rock characteristics, and (2) to present an evaluation of those characteristics so that approaches can be made to explain the irrational behavior of wells completed in the Delaware. STUDY OF ROUTINE CORE-ANALYSIS DATA A statistical study of routine core-analysis data has been made to relate fundamental rock properties and characteristics of the formation to well productivity. For the most part, well production data were obtained from operators and augmented by production data from commercial information services. Only data which were available in detail and which were considered to be accurate were used. The core data used were obtained on samples from the perforated or open interval only and, thus, may not always represent the total productive interval in a well. All the core-analysis data included in this study are from the Bell Canyon member of the Delaware and were obtained by "plug-type" techniques, as opposed to whole-core or full-diameter techniques. Porosity values were obtained by the summation-of-fluids technique, permeability values are air permeabilities corrected for slippage to an equivalent liquid permeability, and the oil and water contents were determined by means of a high-temperature downdraft retort. All the procedures used are discussed at length in Ref. I. The core-analysis data were sorted

By L. Larson

SMELTERMEN in the copper industry know that punching the tuyeres of a copper converter is a difficult, disagreeable, and at times a hazardous job. Knowing this, many men in the industry have given serious consideration to punching by mechanical means. As evidence of such consideration, a great many patents have been issued covering various mechanical devices or machines for doing this task. In 1942, as war-created manpower shortages became more acute, it became increasingly difficult to get men to punch tuyeres. Faced with this situation at the McGill smelter, it was decided that an all-out effort should be made to develop some sort of a mechanical punching device. The various patents were studied over thoroughly but none of the devices seemed suitable, all were discarded and it was decided to develop one, using the ideas of the personnel at McGill. Initial test work indicated that a separate punching device should be attached to each tuyere. This meant that an adapter would have to be developed which would accommodate such a device; the adapter to be so constructed that it could be substituted for the regular Dyblie valve head, and be punched either by mechanical means or by hand. Also a method for quickly attaching or detaching the punching unit would have to be devised. If the punching unit was attached to the adapter, then the punch rod and tip would have to remain inside of and reciprocate within the tuyere pipe. This last requirement meant that the punching device, the adapter, the piston rod, and punch rod must be in perfect alignment. The whole arrangement thus would become an integral part of the converter and would rotate along with the tuyere line to all the positions required for converter operation. If the puncher was to rotate with the converter, there was also a problem of limited clearance. The construction of a device to meet all of these conditions imposed many problems. In the latter part of 1942, two pieces of equipment were constructed and tried out under test-stand conditions. Both of these devices were very crude, but test-stand operation indicated that progress was being made. Neither of the units was considered good enough to be attached to and tried out on a tuyere of an operating converter. In May 1943, work was started on another device and in August of that year it was attached to and actually punched a single tuyere of a converter on an experimental basis (fig. 1). This unit was essentially a cylinder 3 in. in diam and about 15 in. long inside. Valve ports were so located as to provide a 1-in. cushion on each end of the stroke. The cylinder ports were piped to a 3/4-in. four-way disk valve. High pressure air (90 psi) was delivered to the valve by means of a long hose, thus making it possible to supply air to the device at all operating positions of the converter. The forward and return punching strokes were accomplished by shifting the valve handle as required. With the 3/4-in. valve, stroke velocities from 15 to 18 fps were achieved. Punching with this experimental arrangement was carried on for some time, but many difficulties were encountered. The punch rod tips often stuck in the tuyere accretion, indicating that more energy of some sort was necessary to avoid sticking the punch rod. To overcome sticking, experiments continued with a speeded up unit and although progress was made, troubles of various kinds continued to appear. On this unit, piston cup seals passed the valve ports which proved to be of very poor construction. Also the piston, driven forward at approximately 28 fps, would often bottom metal to metal in the forward end of the cylinder causing both mechanical and operational trouble. Sometimes the punch rod and at other times the piston rod would break loose and be shot through the tuyere pipe into the converter. Bottoming and poor timing of valve reversal caused a bounce and a hesitation at the end of the forward stroke, with the result that the punch rod

Jan 1, 1951

By Louis Raymond, John E. Dorn

The object of this investigation was to analyze the recovery that arises when the stress on a specimen undertaking creep is reduced. For this purpose annealed specimens of high-purity aluminum were precrept under a stress of 1000 bsi to a strain of 0.08 following which the stress was reduced for various periods of time to 10, 250, 500, or 700 psi. When the original stress was reapplied the subsequent creep curve lay above that for the unre-covered state and below that for the original annealed state. Analyses on the kinetics of this recovery as a function of the temperature gave a stress-sensitive activation energy that decreased as the reduced stress was increased from a value of 64,000 cal per mole at 10 psi to 37,000 cal per mole at 750 psi. Recovery was also detected and measured during creep under the reduced stress. Following a short initial period, the creep rate under the reduced stress increased monotonically until it reached the secondary-creep rate for the reduced stress. The temperature dependence of this phenomenon was also shown to be correlatable in terms of the previously deduced activation energy for recovery. The activation energies for creep of most pure metals at high temperatures have been shown to agree well with those for self-diffusion.'j2 Since the true secondary stage of creep is usually due to the steady-state balance between the rate of strain hardening and the rate of recovery, it is generally thought that the activation energy for recovery of the creep-induced substructure equals that for creep itself. A shoft time ago, however, Ludemann, Shepard, and Dorn~ found that the activation energy for recovery of the creep-induced substructure in high-purity aluminum under zero stress was almost twice that for self-diffusion, namely about 65,000 cal per mole; obviously recovery under reduced stresses differs in some significant way from the recovery that accompanies the secondary stage of creep. The major purpose of this investigation is to study the effect of stress on the re- covery of the creep-induced substructure in order to provide a better understanding of the recovery mechanism itself. EXPERIMENTAL TECHNIQUE High purity aluminum, containing 0.004 pct Cu, 0.002 pct Fe, and 0.001 pct Si, used in this investigation, was in the form of 0.100-in.-thick sheet which has been cold-rolled to the H-18 temper. Creep specimens were milled from the sheet with their tensile axes in the rolling direction. All specimens were then heated at 686°K for 1 hr followed by air cooling in order to produce an annealed structure which exhibited a uniform equiaxed grain size of about 4 grains per mm. Tests were run in creep machines fitted with Andrade-Chalmers type of lever arms so contoured as to maintain the stress constant to within 0.05 pct of the reported values. Constant temperatures to *O.l°K were obtained by complete immersion of each specimen in a temperature-controlled and agitated bath of molten KN02-KNOs mixture. Where changes in temperature were involved, the change was effected in less than 2 min by manually replacing one bath by another controlled at the second temperature. Displacements over the gage section were sensed by linear differential transformers, the output of which was autographically recorded. The calculated strain measurements were sensitive to 5x EXPERIMENTAL PROCEDURE The following analyses are based on extensions of the previously announced effect of the temperature on the creep strain,2 namely for a = constant, where e = the total true tensile creep strain for a given applied true tensile stress, t = the duration of the test, R = the gas constant, T = the absolute temperature, Q, = the activation energy per mole for creep which is independent of the stress, / = a function of 8, = and of the stress, and a = the stress. The validity of this correlation for high-purity aluminum is demonstrated in Fig. 1 for temperatures in the near vicinity of 600°K; the activation energy for creep, Q,, which is approximately that for self-diffusion, is insensitive to the applied stress

Jan 1, 1964

By D. G. Westlake

Alloys of poly crystalline Nb-H have been tensile tested at 77" and 120°K after slow-cooling and after quenching from room temperature. A rationale has been developed to explain the effect of cooling rate on ductility in terms of microstructure. The inferior ductility of the slow-cooled alloys in this temperature range can be attributed to the precipitation of coarse hydride particles that fracture in the early stages of plastic deformation. Quenching Produced much smaller hydride particles and a decreased tendency for initia-tion and popagation of cracks. Prismatic dislocation loops, punched into the matrix of quenched alloys, eliminate the yield point and may Play some role in the low temperature ductility of the quenched alloys. The difference in ductility between quenched and slow-cooled V-H alloys was even greater than that observed in the N b-H alloys. It is well known that the ductility of Nb-H and V-H alloys decreases with increasing hydrogen concentra-tion and with decreasing temperature.1-l1 The follow-ing are some of the numerous mechanisms that have been adopted in attempts to explain these observations: 1) hydrogen-dislocation interarction,4'6 2) lowering of the crack surface energy by adsorbed hydrogen,9'10 3) localized lowering of the niobium bond strength,9 and 4) exertion of pressure inside voids by molecular hydrogen.6 A recent study1' indicates that, in some way, the embrittlement is related to the precipitation of a hydrogen-rich phase, because embrittlement and hydrogen solubility have the same temperature dependence. Most of the investigators observed that at very low temperatures there was a return of the ductility. Thus, hydrogenated niobium and vanadium may be said to exhibit a low temperature ductility minimum."1'8'9 It has been reasoned by most observers that diffusion is required for the embrittlement mechanism to be operative, and that as hydrogen becomes immobile at very low temperatures, the ductility increases. This investigation of the mechanical behavior of Nb-H al-loys under various conditions is an attempt to gain a better understanding of the low temperature ductility minimum. EXPERIMENTAL Tensile specimens, with gage length dimensions 20 by 3 mm, were machined from sheet stock" and both faces were ground on wet 600 grit Sic paper to obtain a final thickness of 0.5 mm. Annealing as described earlier12 resulted in average grain diameters of 0.3 mm. The recrystallized niobium tensile specimens were electropolished in 90 parts H2S04, 10 parts HF (48.9 pct) by volume, at 287°K and 30 v. Hydrogen, which may have been present in the starting material and/or added during specimen preparation, was removed by annealing at 1073°K in a dynamic vacuum of 2 X 10-6 torr. Hydrogenated specimens (1.15 at. pct H) were prepared by reaction with a known quantity of pure hydrogen (obtained by thermal decomposition of UH3) at 1073oK, followed by cooling at the rate of 100" per hr. These were vacuum encapsulated, homogenized at 573°K for 3 to 5 hr, and furnace-cooled. Tensile tests were conducted on an Instron machine at a strain rate of 4 x l0-5 per sec. The gripping device was such that the specimen was positioned below the crosshead. Thus, subambient test temperatures could be obtained by immersion of the device in a cooling bath of either liquid nitrogen or Freon-12. The temperature of the Freon-12 was controlled within ± 0.1°K of the desired temperature by automatically monitoring the flow of liquid nitrogen through a copper coil in the bath. Slow-cooling to 77°K was accomplished as follows. The testing device was surrounded by a rubber jacket, open at the top and with small holes in the bottom. Liquid nitrogen, brought up to the bottom of the jacket, entered the holes and vaporized quickly. The temperature was monitored at the specimen with a copper-constantan thermocouple, and a constant cooling rate of 2 deg per min was easily achieved by controlling the level of the liquid nitrogen outside the jacket. RESULTS AND DISCUSSION Low Temperature Ductility Minimum. Resistometric studies of both Nb-H12 and V-H13 indicated that at tem-peratures less than 150°K, virtually all of the hydrogen

Jan 1, 1970

By Gerald G. Griswold, James O. Greenslade, Cherie Tilley, Richard Reseigh

INTRODUCTION The Harrison Western Corporation, a leading Denver based mine contracting and engineering concern, is presently engaged in sinking two 1,006 m (3,300 ft) shafts for the Phillips Uranium Corporation at their Nose Rock Project, approximately 13 miles northeast of the small community of Crownpoint in McKinley County, New Mexico. The Nose Rock Project is the first attempt by the Phillips Uranium Corporation to tap the deep uranium reserves in what has become known as the Grants Mineral Belt. (See Figure 1) Project Description Phillips Uranium Corporation's plan for the large 2700 metric ton per day (2950 tons/day) mining facility calls for a series of deep access and ventilation shafts ranging from 4.27 m (14 ft) to 5.49 m (18 ft) in diameter to approximate depths of 1,006 m (3,300 ft). The initial pair of shafts consists of one production shaft and one ventilation shaft separated by a distance of 91 m (300 ft). The interbedded layers of sedimentary sandstones and shales to be penetrated by the shafts contain several major water producing aquifers, the deepest being the mineralized zone called the Westwater Canyon Member of the Morrison Formation. A series of temporary and permanent water pumping stations is planned. Generally, the temporary stations are located above major aquifers to facilitate water removal while sinking through the aquifer and the permanent stations constitute what, in the final mode, will be the mine dewatering system. In addition, Phillips Uranium Corporation has In- stalled and is maintaining a system of depressurization wells that temporarily pump the major aquifers and considerably reduce the water inflows during shaft construction. The major aquifers are also chemically grouted prior to sinking. Site work for the project was initiated in the fall of 1976. Full scale shaft sinking commenced in November of 1977 on the 4.88 m (16 ft) diameter ventilation shaft and on the 5.49 m (18 ft) production shaft by another contractor. Harrison Western Corporation began work on the project on November 4, 1979 wlth the production shaft at a depth of 633 m (2,076 ft) and the ventilation shaft at a depth of 474 m (1,554 ft). This paper will address only the portion of shaft sinking completed by Harrison Western. Geology and Hydrology The Nose Rock Project is located on the Chaco Slope in the southern extreme of the San Juan Basin in northwest New Mexico. The southern San Juan Basin is generally bound by the Defiance Uplift to the west, the Zuni Uplift to the south and the Nacimiento Uplift to the east. The Grants Mineral Belt occupies most of the southern portion of the San Juan Basin and this project is located on the northern extreme of the Grants Mineral Belt. The San Juan Basin is comprised of sedimentary rock of continental, marginal-marine and marine origin, that dip northward from the Zuni Uplift and Chaco Slope into the interior of the San Juan Basin. (See Figure 2) Major Formations The major geologic formations to be penetrated range from mudstone and shales to siltstones and sandstones. The sandstones are highly productive aquifers which, under static conditions, would flow artesian. Water temperatures in the aquifers are high and therefore are a force to be dealt with. Temperatures range from 18ºC (65OF) in the upper aquifers to 48ºC (118º'F) in the lower. The mudstones are generally bentonitlc. (See Figure 2) GALLUP SANDSTONE: The Gallup Sandstone is the first major regressive wedge in the San Juan Basin of the Cretaceous era and at this project is about 35 m (115 ft) thick. It is medium grained and prior to depressurization carried a hydrostatic water pressure of over 72.5 kg per cm2 (1,031 psi) which 1s artesian. Compressive strength ranges from 334.7 kg per cm2 (4,760 psi) to 421.8 kg per cm2 (6,000 psi). Water temperature is approximately 30°C (86°F).

Jan 1, 1982

By J. J. Gilman

Examination showed that characteristic cleavage step patterns are observed on the cleavage surfaces of undeformed, slipped, bent, twinned, compressed, and indented zinc crystals; and the effect of temperature is discussed. Dimples were seen to produce cleavage steps in a treelike pattern in otherwise undeformed crystals. The steps seem to originate when cracks intersect screw dislocations. IT has been known for a long time that the path of fracture in polycrystals may be discontinuous (see Jaffe, Reed, and Mannl for review). Recently, Kies, Sullivan, and Irwin2 have proposed, and given evidence, that crack propagation is discontinuous within individual crystals as well. Other evidence has been given by Low.' When discontinuous cracks within a crystal join together to make a macrocrack, the lamellae between each set of two cracks are torn somewhere, forming small cliffs. These cliffs appear as lines when the cleavage surface is observed microscopically.4,5 The lines have been called vein, tree, and riverlike markings by various authors, and they have sometimes been mistaken for fissures. The descriptive term cleavage steps is used in this paper. Cleavage steps vary in height over a wide range of values, from molecular dimensionsG to lor. and larger. Kies, Sullivan, and Irwin,2 as well as George,' have shown that the gross cleavage step patterns for plastics, polycrystalline metals, and for mono-crystals are sometimes similar. Thus, they depend mostly on the mechanical variables that prevail during cleavage and are relatively insensitive to the structure of the material. For example, parabolic markings2,7,8 sometimes result when cracks open up ahead of, and not coplanar with, the main crack front. If the advance crack has the same velocity as the main crack, their intersection line is a parabola, otherwise it is a hyperbola or an ellipse. The patterns are strongly affected by differences in crack velocities. This results in chevron patterns which point to the place of origin of the main crack. It is the purpose of this paper to demonstrate the existence of a mechanism of cleavage step formation which is a continuous rather than a discontinuous process. Also, certain characteristic step patterns are described, and the strong effect of temperature is shown. The specimens were zinc monocrystals (grown from 99.999+ pct pure metal). These were cleaved at room temperature and at — 196°C. Results and Discussion Cleavage step patterns are highly variable from point to point on a given specimen, as well as from one specimen to another. Although the patterns shown in the photographs are typical, they have been selected for graphic illustration. Figs. la and lb compare undeformed crystals that were cleaved at —196 °C and room temperature, respectively. Cleavage at room temperature (Fig. lb) resulted in a higher density of high steps (dark black lines) and enhanced the visibility of the fine background markings. Deformation by simple slip caused no marked change in the step patterns until the glide strain reached about 1.0. But, as Fig. lc shows, the density of high cleavage steps was greatly increased by large glide strains. Corrugations lying perpendicular to the slip direction may also be seen in Fig. lc. These are caused by deformation bands. The cleavage resistance of the crystal of Fig. lc was very high compared to undeformed crystals (estimated by the force on a needle required for cleavage). Striking and varied cleavage step patterns were observed on bent crystals. Two characteristic patterns that were observed on crystals bent at 25°C, and cleaved by reverse bending at —196°C, are shown in Figs. 2a and 2b. The first, Fig. 2a, consists of V-shaped lines similar to the parabolas of other materials2,7 Fig. 2b shows a pattern that is the equivalent of Fig. la, consisting of faint background lines with a few higher step markings. Cleavage of bent crystals at room temperature resulted in Figs. 2c and 2d. Now, the cleavage step lines show a strong tendency to follow one of two perpendicular paths. In Fig. 2c (bent once), many of the cleavage step components that lie parallel to the bend axis are assembled into irregular lines. In Fig. 2d (bent twice), the cleavage steps again tend to consist of two perpendicular components, but neither of the components is assembled into lines. Also, the step density is higher.

Jan 1, 1956

By H. W. Schull

The Alligator Ridge gold deposits are located in northwest White Pine County at the southwest end of Alligator Ridge. Alligator Ridge is on the west side of Long Valley in the range of hills that separates Long and Newark valleys. The nearest population center is Ely, about 113 km (70 miles) to the southeast. Access to the Alligator Ridge gold mine from Ely is via US Highway 50 and the Long Valley Ruby Marsh Road. The latitude and longitude is approximately 39° 45' north and 116° 30' west. The Alligator Ridge gold deposits occur in the lower 61 m (200 ft) of the Mississippian-Devonian Pilot Shale formation, a laminated calcareous carbonaceous siltstone. The gold deposits contain carbonaceous, oxide, and jasperoid type gold ore. For more details on the geologic features of the deposits, see Schull, Sutherland, and Ilchik (in press). The discovery story of Alligator Ridge began in the spring of 1976 when the areas mapped as jasperoid on the 1:250,000 scale geologic map of White Pine County (Hose and Blake, 1976) were examined and sampled. Seventeen samples, about 23 kg (50 lb), were collected from an area about 0.65 km2 (0.25 sq mile). Of these 17 samples 10 reported atomic absorption values of less than 0. 1 ppm Au and 7 reported values in the 0.1 to 1.0 ppm Au range. In June of 1976 20 lode claims were staked to claim the area of the rock chip sampling. The claims' end and side center lines were used as a grid for soil sampling. Sample stations were 91 m (300 ft) apart and sample lines were 229 m (750 ft) apart. The samples were sieved to - 180 µm (- 80 mesh). Out of 99 soil samples, seven samples reported Au values in the 0.1 to 1.0 ppm range. Of the seven auriferous samples, five were located over the jasperoid outcrops previously sampled; one over unmineralized Pilot Shale a few hundred m (ft) downslope from some Au-bearing jasperoid; and one from a 15 x 15 m (50 x 50 ft) talus outcrop area of hitherto unnoticed mineralized Pilot Shale. Subsequent sampling, mapping and drilling would show that this 15 X 15 m (50 x 50 ft) outcrop area was the top of the Vantage 1 ore body, about 1.27 Mt (1,400,000 st) of over 3 g/0.9 t (0.11 oz/st) Au. Late in the summer of 1976 about 30 more 1.4 to 2.2 kg (3 to 5 lb) rock chip samples were collected in the course of preliminary geologic mapping. This mapping and sampling showed that the gold-bearing jasperoids occurred at the contact between the Pilot Shale and the underlying Devils Gate Limestone. Rock chip samples of 0.1 ppm Au or greater were restricted to the jasperoids and the mineralized outcrop area of Pilot Shale located by the soil sample survey. Rock chip samples from the area of mineralized Pilot Shale were in the 3 to 5 ppm Au range. Activity resumed in the summer of 1977 with a more detailed soil geochemical survey. The jasperoid areas were defined as large geochemical gold anomalies of values greater than 0.1 ppm and locally greater than 0.2 ppm Au. Soil samples from the area of mineralized Pilot Shale outlined a greater than 0.1 ppm gold anomaly 61 x 152 m (200 x 500 ft) in size. Further geologic mapping showed that elsewhere, even where bleached and silicified, the Pilot Shale areas were geochemically very low in gold (less than 0.1 ppm Au). In November, 1977 twelve rotary percussion drill holes were drilled to test the gold-bearing jasperoid areas and the mineralized Pilot Shale area. Drilling of the jasperoid areas showed that the jasperoids gave way at shallow depths [less than 24 m (80 ft)] to unmineralized unaltered Devils Gate Limestone. A five hole cross pattern was drilled to test the area of mineralized Pilot Shale. Four of the five holes re-

Jan 1, 1985

By F. C. Bond, J. T. Wang

H. J. Kamack (E. I. du Pont de Nemours & Co., Inc., Wilmington, Del.)—Rittinger's law usually is stated to the following effect: "The work (or energy) consumed in particle size reduction is proportional to the new surface area produced." The law has been stated substantially in this way by Taggart20 Berry21 Dalla Valle22 Coghill and DeVaney,23 Richards and Locke," Gross,25 and many others, and, according to Gaudin,26 was originally expressed by Rittinger in the same form. Consequently there can be little doubt that this is the understanding of the law among most workers in the field of particle size reduction. Bond and Wang, however, express the law in the form "the useful work accomplished . . . ." (italics theirs). The distinction is critical, for in the form used by Bond and Wang the law becomes, as they themselves remark "merely a more or less arbitrary definition of useful work," while in its usual sense the law expresses a physical hypothesis which has been verified experimentally within certain limitations. Considering the way the law has been used, it might be stated more explicitly as follows: "In a given machine operating under a given set of constant operating conditions, the work consumed in the particle size reduction of a given material is proportional to the new surface area produced." Or, as Coghill and deVaney have said,27 "the (Rittinger) law holds only when the tests being compared are made under analogous conditions." There are occasions when the law transcends these limitations; for example, the surface area produced per unit energy consumption for a given material in a ball mill does not vary much over a fairly wide range of operating conditions. But by and large, the surface area production per unit energy consumption will vary with the operating conditions, the type of machine, and the material. The essence of Rittinger's law is that the surface area production per unit energy consumption is independent of the particle size, and this has been verified experimentally by numerous workers for numerous materials, within certain limits. An important limitation is that when one grinds to very small particle sizes, agglomerative forces may tend to interfere with size reduction so that the surface area increases less rapidly than Rittinger's law would predict. Within such limitations, Rittinger's law can be regarded as empirically established. The law has, however, certain theoretical implications, and it seems to be chiefly against these that Bond and Wang direct their criticism. Solids are believed to possess surface energy which is proportional to surface area. Thus, Rittinger's law implies a proportionality between surface energy produced and mechanical energy expended (for a particular material in a particular machine). It does not imply that all or most of the mechanical energy is transformed into surface energy; in fact it is known that most of the mechanical energy is transformed into heat. Bond and Wang assert that most of this heat arises from the damping of elastic vibrations of stressed particles. This may possibly be true for crushing (with which they are chiefly concerned), although in grinding it is probable that much of the heat arises from friction between particles. However, the fact that the surface energy is small compared to the heat energy does not invalidate Rittinger's law, which implies merely that they are proportional. The authors also criticize Rittinger's law on the grounds that "this theory cannot be justified mathematically, since work is the product of force times distance, and the distance factor is ignored," and "energy input must be the product of force times distance, and the Rittinger theory completely ignores large variations in the distance (strain dimension or deformation) throughout which a force must act to produce breakage of different materials." However, the quantities force and distance as such are irrelevant to Rittinger's law, which considers energy input as an integral quantity. The fact that different materials require different forces and strains (hence, different amounts of energy) to break them is incontrovertible but again is irrelevant to Rittinger's law, which, as mentioned before, applies -only to a single material. Even in theory, it would not be expected that the surface area produced per unit energy consumption would be the same for different materials, because the surface energy per unit area is presumably specific to each material. Bond and Wang advance another argument of a

Jan 1, 1952