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By Alexander Field

The hot-rolling properties of a series of high-sulfur steels are described. From a consideration of the sulfur, manganese, and zirconium contents of these steels, it is shown that zirconium reacts with the sulfur content of molten steel in accordance with the equation Zr + 2S = ZrS2. Zirconium disulfide appears in the finished state as gray-colored inclusions, similar to manganese sulfide in plastic behavior and general appearance. Zirconium completes its act of deoxidation before proceeding to combine with sulfur and indirectly increases the effective sulfur-combining power of any manganese which may be present. IN A previous paper,1 the experimental methods used and some of the results obtained in an extensive investigation of steels containing zirconium were described. The present paper considers in greater detail one of the most interesting of these effects, namely, the elimination of "red shortness" and the occurrence in steel of a compound of zirconium and sulfur. A consideration of the actual percentages of zirconium, manganese, and sulfur in numerous steels in the light of behavior during rolling has led to new conclusions of the most practical import regarding the reciprocal relationships of these elements. The microscopic examination of high-sulfur steels containing zirconium has also been productive of interesting results. Before discussing the experimental data in question, it may be stated, briefly, that the reaction between zirconium and sulfur in molten steel may he represented by the simple equation, Zr + 2S = ZrS2, and that the zirconium sulfide thus formed occurs in the finished steel in the form of gray-colored inclusions, closely resembling manganese sulfide and, like the latter, exhibiting plasticity at rolling temperatures. Molten steel containing zirconium retains such a negligibly small amount of oxygen in solution that the foregoing reaction goes to completion.

Jan 2, 1924

By Edward W. Parker

At the Seventy-sixth meeting of the Institute, held in New York, N. Y., February, 1899,I presented a paper on this subject entitled, Coal-Cutting Machinery,' which has become somewhat out of date, in view of the decade's development in this feature of the coal-mining industry. It should be explained that the present paper is limited to the use of mining-machines in bituminous mines. Practically all of the anthracite mined is "shot from the solid," no undercutting being done. Anthracite-mining is therefore not considered in the statistics or other references. The statistical record as compiled by the U. S. Geological Survey shows that in 1898, the year preceding the presentation of my former paper, there were 32,413,144 short tons of coal undercut by the use of machines. In 1907 the machine-mined coal-product amounted to 138,547,823 short tons. In sympathy with the general decrease in coal-production during 1908, the output of machine-mined coal decreased to 123,183,334 short tons, but the proportion of machine-mined coal to the total output, nevertheless, showed an increase, from 35.1 per cent. in 1907 to 37 per cent. in 1908. In 1898 only 19.5 per cent. of the total product was unclercut.by the use of machines. The number of in use in the bituminous mines of the United States has increased from 2,622 in 1898 to 11,144 in 1907, and to 11,569 in 1908. The total production of bituminous coal in the United States in 1908 mas almost exactly double that of 1898, while the machine-

Jan 1, 1911

By Keijiro Nishio

At a time of great antiquity when our Yomato tribe had not yet found its way throughout the country, there lived in Japan barbarous tribes of the stone age, whose dwellings were vertical caves covered with roof's of twigs and weeds. In a cave lately discovered at the village of Morita, 10 miles west from the port of Aomori, there were found pieces of micaceous iron-ore and psilomelane, with oval holes pierced from both sides. Apparently these objects were regarded as ornaments or curios, without being applied to any practical use. Among the traditions given in the Nihonshoki, an ancient history of Japan, there is one relating to the mining industry. According to this tradition, in the mythological age Izanami-no-Mikoto gave birth to Kanayamahiko-no-Mikoto, god of mines, and Amaterasu-Okami (the sun-goddess) was armed with swords. It came to pass at one time that she concealed herself in Ama-no-Iwato ("Heavenly Cave"), and several gods made contrivances to entice her out. Among them, Ishikori-dome, a smith, made a mirror with copper obtained from the Ama-no-Kagoyama, by means of a pair of bellows known as the Ama-no-habuki, which was made of a deer-skin. It is recorded also that Susanb-no-Mikoto, her younger brother, observed the abundance of gold and silver in Korea, where his descendants were to reign, and urged them to provide themselves with boats to convey them across the Sea of Japan. In the course of time he accomplished his object, proceeding to Korea with his son, Isotakeru-no-Mikoto. These accounts

Jan 1, 1913

By J. T. Pardee

INTRODUCTION PLACER is a Spanish word, the definitions of which include "an extensive bank of sand or gravel" and "a place where currents of water deposit particles of gold."l The term, probably first used in the western hemisphere by Spanish or Mexican gold miners, is now generally applied to all detrital deposits that yield valuable minerals by washing. In the Western States placer products other than gold, including the silver alloyed with it, are chiefly sapphires, produced in Montana, and platinum alloys recovered in California and Oregon. During the war tungsten ore (scheelite) was obtained from placers in the Atolia district, California, and a number of diamonds have been found in the Sierra Nevada gold belt. Small amounts of stream tin have been produced in the Black Hills of South Dakota and a little monazite sand in the Boise Basin. Idaho. Magnetite, chromite, ilmenite, zircon, and other useful minerals are more or less abundant in the beach placers of the Pacific coast and in the heavy residues of placer mining elsewhere, but the problems of profitably separating and marketing them remain to be solved. Minerals of lead, quicksilver and other metals occur in many of the placers and although not plentiful enough as a rule to be worth recover-ng, their presence has, in several instances, led to the discovery of valuable lodes, notably at Leadville, Colorado. Historical summary.-In New Mesico, Arizona, and Southern California, placer gold was mined by Mexicans and Spanish priests in the first half of the 19th century or earlier. With these exceptions history of placer mining in the Western States begins with Marshall's discovery of gold in northern California in 1848. During the next twenty years placers were found in all of the principal mining districts that are known today. The richer deposits were soon mined out but a relatively large production was maintained from the leaner deposits chiefly by hydraulic

Jan 1, 1933

By T. G. Fulmor, William Wraith

What impelled The Anaconda Company to dismantle and move a concentrator 25 miles that was already operating at a rate of 35,000 ton per day? The answer to that question takes in almost exactly 49 years and perhaps 10 complete cycles of the metallurgical wheel in the Anaconda, Mont., mill. One could say with truth that the move is a logical next-step in the development of metallurgy in The Anaconda Co. In the old concentrator at Anaconda, the background story is unfolded: - Gravity separation by jigs, later supplemented with gravity tables, 1905. - Separate sand and slime froth flotation, 1915. - Acid bulk froth flotation, 1917. - Bulk alkaline flotation, 1926. - Alkaline flotation of total ore without sand- slime separation due to change in ore type. 1939.

Jan 5, 1964

By Y. S. Bonillas

Page I. Introduction.......................... 286 II. Physiography.......................... 286 : 111. Introductory Geology...................... 287 IV. Rocks of the District ...................... 288 (A) Sedimentary Rocks..................... 288 Pinal Schist ........................ 288 Bolsa Quarteite....................... 289 Abrigo Limestone...................... 290 Capping Quartzite..................... 291 Martin Limestone...................... 292 Escabrosa Limestone .................... 295 Naco Limestone....................... 296 Cretaceous Deposits..................... 296 Glance Conglomerate................... 296 Morita. Mural and Cintura Formations........... 297 (B) Igneous Rocks........................297. Pre-Cambrian Granite.................. 297 Pre-Cretaceous Granite Porphyry............. 298 Rhyolite........................301 Other Dikc Rocks.................... 301 V. Structural Geology........................ 304 General Structure of Mule Mountains............. 304 Fault Blocks and Other Divisions............. 304 Igneous Rocks...................... 312 Copper Queen Block..................... 313 Fault Blocks...................... 313 Intrusions....................... 315 Don Luis Block....................... 315 Intrusions and Orebodies................. 316 VI. Geologic History......................... 316 VII. Metamorphism and Mineralization................. 318 General Metamorphism.................... 318

Jan 1, 1917

By R. U. Fitting, A. C. Bulnes

Field experience with limestone and sandstone production indicates the existence of wide differences between the reservoir behavior of these two types of formation. Little attention appears to have been given to the separate study of the flow of fluids and the retention of fluids in limestones. This paper presents data and arguments to demonstrate the existence of a difference between the two types of formation, and urges the separate intensive investigation of limestone reservoirs. AH experimental data presented pertain to dolomitic limestone formations in west Texas and New Mexico. Two kinds of Porous media are recognized— intergranular and intermediate. Intergranular rocks are those in which the porosity and permeability are determined by the geometrical properties and the sorting of the sedimentary units; intermediate rocks, those in which there is no direct relationship between grain properties and the porosity and permeability. Limestones in general are intermediate media. The partial relationship between porosity and permeability of any class of Porous media is represelried by an area of .finite extent and definite shape on the permeability-porosity plane. The horizontal and vertical variations of porosity and of permeability in limestone and sandstone formations are discussed and compared. Comparisons are made of connate-water content, the relative permeability-saturation relationship, and capillary phenomena in the two kinds of rocks. A number of tentative conclusions are drawn relative to the reservoir properties of lime- stones; in particular, (I) dolomitic limestones are oil bearing and apparently are oil productive in zones of permeability less than 0.1 millidarcyj and (2) primary depletion (by gas expansion) oil saturations may be lower in dolomitic limestones than in sandstones. Introduction It is well known that the reservoir performance of limestones displays numerous irregularities when compared with that of sandstones, and that the departures from "normal" behavior of limestones are more frequent and generally more marked than in sandstones. This is particularly true of fractured limestones and those that have undergone considerable development of secondary porosity' A review of the literature of production research published during the past 15 years reveals a startling absence of theoretical and experimental investigations directed specifically toward explaining and predicting the performance of limestone reservoirs, even. though such problems as the prediction of water encroachment and the estimation of ultimate recoveries continue at the "inspired guess" stage. By far the greater part of the experimental data reported pertain to measurements on sandstone core samples, while the theoretical studies, almost without exception, are developed from the assumption of an ideal porous medium and therefore seldom are applicable to limestone formations. The chief cause of this situation appears to be the common belief that, to all practical intents and purposes, sandstones and the majority of producing limestone formations

Jan 1, 1945

By C. H. Mathewson, E. M. Thalheimer

In planning the present experiments, we have made a particular effort to secure that adjustment of working conditions which would render the forthcoming tests most serviceable by way of indicating the comparative properties of the three different commercial grades of copper used. More specifically, we have endeavored to obtain certain definite information with respect to the relative behavior under test of ordinary electrolytic copper and furnace-refined lake copper containing (a) a moderate percentage of arsenic and (b) a rather large percentage of arsenic, in addition to the usual content of silver and other impurities. These comparisons were made systematic and comprehensive by testing throughout a series of (eight) reductions running from 0 to 70 per cent. in the case of cold-rolled metal, and throughout a series of (15) temperatures running from 100' C. to 1,000" C. in the case of annealed metal. In other words, a survey of properties similar to that made by Grard,' in the case of electrolytic copper, was here repeated (with modifications) and extended to two other commercial varieties of copper. The great importance of copper both as a material of construction and as the base of our most important alloys (aside from steel) has led to innumerable investigations of its properties, particularly in commercial forms. Naturally, the merits of furnace-refined lake coppers us. those of the very pure electrolytic product have furnished the subject of much experimental work and animated discussion, wherein the effect of arsenic has by no means been overlooked. In the literature of the past 10 years,

Jan 1, 1917

By V. N. Krivobok

THE study and use of low-carbon manganese steels have been curiously neglected in the general history of developments in alloy steels. Hadfield1 made an extensive study of manganese-iron-carbon alloys about 1886, which culminated in the wide application and use of Hadfield austenitic manganese steel. His alloys were nearly all high in carbon, as compared with the steels discussed in this paper, and he found a marked tendency towards brittleness in the alloys of medium and low manganese content, that is, below 7 per cent. manganese. As a result, there has been a widespread prejudice against the use of manganese steels containing between 1.0 to 3.5 per cent. manganese with comparatively low carbon. Steels of this composition have never been studied adequately in comparison with other alloy steels, and have had little use in practice. In a very recent paper by Sir Robert Hadfield2 the following statement appears: ?. . . manganese-iron alloys with little or no carbon do not seem to offer any practical employment; they only become valuable in the presence of quite high percentages of carbon, 0.90 to 1.50 per cent." The results of the present investigation are so contrary to the findings of Hadfield that the writers feel fully justified in presenting the preliminary report incorporated in this paper.

Jan 1, 1927

By Rex B. McLellan, W. A. Oates

FROM a consideration of the application of the Gibbs-Duhem equation to multicomponent systems arken' derived the following equation applying to dilute solutions of a solute, 2, dissolved in a binary solution, 1-3:

Jan 1, 1969

By Alfred Boyles

The experiments described below are a continuation of work on the graphitization of cast iron conducted as part of the program of fundamental research at Battelle Memorial Institute. In previous work it was found that melting in hydrogen increased the amount of eutectic carbide appearing in certain alloys and in others produced marked changes in the size of the graphite flakes. These effects seemed to be closely related to the amount of sulphur and manganese present in the material studied. Iron-carbon-silicon alloys did not respond to hydrogen in the same manner as cast iron and there was no evidence to show that hydrogen was able to stabilize the carbide in such alloys unless additions of sulphur were made. The two alloys examined contained about 2 per cent of silicon. The present paper is concerned with alloys of lower silicon content and describes the structural changes produced by melting in various atmospheres at pressurcs ranging from a partial vacuum up to 300 lb. per sq. inch. Experimental Method The experimental technique was similar to that previously employed, so that direct comparison might be made with earlier work. Alloys were

Jan 1, 1939

By Alfred Boyles

The experiments described below are a continuation of work on the graphitization of cast iron conducted as part of the program of fundamental research at Battelle Memorial Institute. In previous work it was found that melting in hydrogen increased the amount of eutectic carbide appearing in certain alloys and in others produced marked changes in the size of the graphite flakes. These effects seemed to be closely related to the amount of sulphur and manganese present in the material studied. Iron-carbon-silicon alloys did not respond to hydrogen in the same manner as cast iron and there was no evidence to show that hydrogen was able to stabilize the carbide in such alloys unless additions of sulphur were made. The two alloys examined contained about 2 per cent of silicon. The present paper is concerned with alloys of lower silicon content and describes the structural changes produced by melting in various atmospheres at pressurcs ranging from a partial vacuum up to 300 lb. per sq. inch. Experimental Method The experimental technique was similar to that previously employed, so that direct comparison might be made with earlier work. Alloys were

Jan 1, 1939

By C. E. Sims, G. A. Lillieqvist

The following presentation is more a summation of observations made and conclusions drawn over a period of three to four years than a report of experiments made with a definite objective. Tests were made, of course, to verify hypotheses, but the large mass of data was collected incidental to other work. Lack of space forbids the presentation of more than a few of those data. On the other hand, it is unfortunate that some of the most illustrative examples are not available. The work is admittedly incomplete but is presented in the hope that it will stimulate further work along a similar line. The answers to many of the questions left unanswered by this paper will be found only after long and painstaking study, such as is scarcely possible in a commercial laboratory where problems of immediate importance consume most of the time. It is also hoped that this study will in some measure throw light on some of the dark spots of steelmaking, and help to clarify some of the annoyingly vague references to "good practice." Only cast steel was studied and the conclusions apply to cast steel, but it is the authors' opinion that the quality of rolled or forged steel is largely dependent on the quality of the ingot, which is a casting. Although this discussion deals almost entirely with inclusions, it is important that the reader understand that only those natural inclusions which owe their origin to the solubility of certain materials in steel and to the chemical reactions of steelmaking are considered. Accidental inclusions, such as entrapped particles of slag, nozzle, runner, or mold arc outside its province and are not considered. Such accidental inclusions are always dangerous and should be carefully avoided. Relation between Ductility and Nonmetallic Inclusions In September, 1928, an acid electric furnace was put into operation at the Indiana Harbor plant of the American Steel Foundries. Following the usual practice, aluminum additions were made in order to obtain sound castings. Immediately the problem of low ductility arose. Previous to that time, only open-hearth steel was produced, and, aluminum being used rarely in that steel, there had been practically no trouble with low ductility in the lower carbon range.

Jan 1, 1932

By C. O. Burgess, W. D. Forgeng

DESPITE the increasing interest in and the technical importance of iron-chromium-manganese alloys, very little published information is available regarding their constitution. F. M. Becket's paper1 in 1930 represents the first correlated effort in the field of these alloys. The paper served particularly to draw attention to the commercial possibilities of iron-rich alloys containing chromium and manganese in balanced proportions. The duplex structure of alloys within the commercial range was briefly discussed, but exposition of their structural constitution was necessarily limited because the physical properties and corrosion resistance of the alloys were the main subjects of the paper. Both prior to and following the publication of F. M. Becket's paper, and at his instigation, an extensive investigation of the constitution of iron-chromium-manganese alloys of commercial purity was in progress at the Union Carbide and Carbon Research Laboratories, Inc. The present paper is based on the results of that investigation. In the last few years, investigations covering various portions of this alloy system have also been made in Europe. W. Koester briefly mentioned the effect of annealing on chromium-manganese steel2 and later3 constructed approximate sections of the iron-chromium-manganese equilibrium diagram. M. Schmidt and H. Legat14 even more recently studied this system, and their article and conclusions are of interest as representing an entirely independent study of a number of iron-chromium-manganese alloys. Koester's sections are shown in Fig. 1. The figures summarize the effect of manganese additions to iron alloys containing 5, 10, 15 and 20 per cent Cr as well as the effect of increasing chromium content on iron alloys containing 3, 8, 20 and 30 per cent Mn. These diagrams, within their composition limits, substantiated in some measure the results of our investigation. However, in our work some differences as regards the position of the mixed alpha-gamma fields were found as compared to Koester's work, and we were able to detect the presence of

Jan 1, 1938

By Henry Mulryan

THE largest and purest known deposit of diatomite is being actively mined and processed 3 ½ miles south of Lompoc, Santa Barbara County, Calif., by the Johns-Manville Products Corporation. The workings FIG. 1.-LOCATION OF DIATOMITE DEPOSIT AT LOMPOC. cover 4000 acres, the depth of economically recoverable diatomite being 1000 ft. (Fig. 1). Lompoc, a community of 2500 population, is situated in the Santa Ynez River Valley 10 miles inland from the Pacific Ocean. It is 44 miles

Jan 1, 1936

THOSE MARKED THUS * ARE MEMBERS, MARKED THUS ?ARE ASSOCIATES. THESE SIGNS DOUBLED INDICATE LIFE MEMBERS AND ASSOCIATES RESPECTIVELY. THE FIGURES AT THE END OF THE ADDRESS INDICATE THE YEAR OF ELECTION. HEAVY-FACED TYPE SIGNIFIES HONORARY MEMBERSHIP. *AARONS, J. BOYD, Vivian Gold Mining Co., Ltd., Harris, West. Australia. '05 *ABADIE, EMILE R., Cons. and Min. Engr., 214 Union Savings Bank Bldg., Oakland, Cal. '76 ?ABBÉ, MAX F., Prest., Abbé Engineering Co, 220 Broadway, New York, N.Y. '07 ? ABBÉ, PAULO., Secy.,Abbé Engineering Co., 220 Broadway, New York, N.Y. '07 *ABBOTT, AI ARTHUR Morococlia, Peru, So. America. '95 *ABBOTT, CLARENCE Chief EDgr., Iron Mines, Dic Tennessee Caol, Iron & R. R. Co., Bessemer, Ala. '04 *ABBOTT, JAMES W., Min. Engr: Ploche, Lincoln Co., Nev. '94 *ABE, MASAYOSHI, Prof. of Mining, Imperial University Kyoto, Japan. '05

Jan 1, 1910

By A. C. Boyle

PaGE I. Introduction.........68 II. Location of the District,....... • 70 .. III. Stratigraphy...........73 Description of the Rocks.......73 Triassic Eruptives (Andesite Flows and Tuffs) ....73 Triassic Sediments (Shales and Slates)..75 Areal Geology ............75 Structure...-.......76 Folds............. 76 Faults..........79 Shear ...........80 Intrusives..........81 Alaskite Dike.........81 Andesitic Intrusion.......82 IV. PetrogRaphy of thE Rock Types......83 Andesite Flows.........84 Tuff 8...........84 Andesite Tuff........84 Rhyolite Tuff.....-.......85 Alaskite-Porphyry.......89 Andesite Dike........91 V. Description of the Mines......92 VI. Metalliferous Deposits ........ 95 Character of the Ores...........97 Mineralogy of the Ores.......97 Metallic Minerals.......97 Microscopic Character of the Ores...98 Secondary Enrichment....... 103 Genesis of the Ores ...........104 VII. The Sulphate Deposits.......109 Gypsum ..... HO Anhydrite......... ,... 110 Barite............ 110 Origin. with special reference to Gypsum....111 VIII. Summary.............. 113 IX. BIblYogRaphY.............114

Jan 1, 1915

By C. A. Zapffe, C.E. Sims

Many hundreds of publications have appeared during the past 78 years that treat the subject of hydrogen in iron and steel.l05 but conclusions regarding the functions of hydrogen in causing some important defects in steel are still unsatisfactory to many; and other hydrogen-caused phenomena yet remain to be identified with this gas. The most widely discussed of these defects is hydrogen embrittlement, but the conception, perhaps the popular one, that embrittlelnent is due to hydride formation aoes not conform to the known facts.l04 The true identity of hydrogen embrittlement seems instead to lie in a mosaic nature of metal crystals, which is a concept not Yet accepted by most metallurgists. A study of hydrogen embrittlement therefore provides new viewpoints in regard to the crystalline substructure of steel.

Jan 1, 1941

THOSE MARKED THUS * ARE MEMBERS, MARKED THUS ?ARE ASSOCIATES. THESE SIGNS DOUBLED INDICATE LIFE MEMBERS AND ASSOCIATES RESPECTIVELY. THE FIGURES AT THE END OF THE ADDRESS INDICATE THE YEAR OF ELECTION. HEAVY-FACED TYPE SIGNIFIES HONORARY MEMBERSHIP. *AARONS, J. BOYD, Vivian Gold Mining Co., Ltd., Harris, West. Australia. '05 *ABADIE, EMILE R., Cons. and Min. Engr., 214 Union Savings Bank Bldg., Oakland, Cal. '76 ?ABBÉ, MAX F., Prest., Abbé Engineering Co, 220 Broadway, New York, N.Y. '07 *ABBOTT, CHARLES W., Min. Engr. Pioche, Nev. ?08 *ABBOTT, JAMES W., Min. Engr: Ploche, Lincoln Co., Nev. '94

Jan 1, 1917

By E. Orowan

LONG before the role of dislocations in the plastic deformation of crystals was recognized, the stress-strain field around dislocations received considerable attention in the theory of elasticity. It seems that Weingarten1 was the first to consider dislocations as simple and typical sources of internal stress in elastic solids, and Volterra2 and Timpe3 investigated their elastic field. Fig 3-1 shows the two basic types of dislocations considered by Volterra. The first arises by making a straight-edged .plane cut in a solid, displacing the two surfaces of the cut in their own plane relatively to one another by a constant amount in a direction perpendicular to the edge, and welding them together; this is shown in Fig 3-la, where the outer cylindrical surface represents the boundary of the solid, and the thin spiral cylinder around the edge of the cut has been removed in order to avoid infinities of stress and strain. The second type of dislocation is shown in Fig 3-lb; here the surfaces of the cut have been displaced relatively to one another by a constant amount parallel to the edge, and then welded together. After J. M. Burgers,4 these two types are called edge and screw dislocations, respectively. They represent simple limiting cases; in the general case, the surfaces of the cut are displaced by a constant vector that lies in the plane of the surface but has components both parallel and perpendicular to the edge of the cut. This vector is the Burgers or slip vector. The name “dislocation” was given by A. E. H. Love;5 it was bor-

Jan 1, 1954