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By James P. Graham

In this paper the authors present the background information to preheating and its development and describe the facilities available at the British Carbonization Research Association. The results obtained at BCRA including those collected during commissioning of the new plant at BCRA are summarized and reference is made to the research work planned for the next stage. The enlarged test-plant facilities at the British Carbonization Research Association embrace both 10-t (4.2 m high) and 17-t (6.5 m high) test ovens and two types of preheater, the preheated coal being charged by either gravity or pipeline. During the commissioning of the new equipment, an extensive programme on preheating was initiated and the paper includes the results obtained so far. These cover tests on wet and preheated coals and commercial blends, the use of Rosin- and Cerchar-type preheaters and charging by both gravity and pipeline systems to the 10-t and 17-t ovens. Accordingly, for the first time a direct comparison is possible of both the performances of the plants and the qualities of the respective products. The paper also outlines the findings from a study of the carryover of solids during the charging of preheated coal and of the treatment of those solids.

Jan 1, 1977

By William B Price, Ralph W. Bailey

Arsenic, antimony and phosphorus are now used in the brass industry as standard inhibitors in preventing dezincification in condenser tubes. This subject has been thoroughly covered by Barry,l who de- scribed the testing procedure by total immersion of suitable specimens in a I per cent cupric chloride solution at definite temperatures. Effects of dezincification were then determined by loss in tensile strength and elongation of the test specimens after definite periods of immersion. In the crystallography of the chemical elements as tabulated by William Hume-Rothery,2 phosphorus (metallic), arsenic, antimony and bismuth are placed in group V-B and the type of crystal lattice for arsenic, antimony and bismuth is given as rhombohedral. The Metals Handbook3 lists them as 'rhobomhedral hexagonal," with the additional notation that for arsenic this is the ordinary form at 20°C.; other modifications known or probable at other temperatures. In view of these statements and of the fact that phosphorus, arsenic and antimony are effective in increasing the resistance to dezincification, it was natural to assume that bismuth would act in the same manner. A series of tests was therefore carried out employing the methods described by Barry. Much to our surprise, bismuth did not inhibit dezincification, but rather seemed to accelerate it. Tensile-test speci-

Jan 1, 1942

By I. N. Knapp

Foreword I HEREWITH present some notes on the use of Portland cement to cement in the casing, and for plugging, to exclude water from oil and gas wells, and the methods employed. I have used my best efforts to make each step of the operation of cementing wells perfectly clear. The information is the result of actual experience and observation. The illustrations are from original drawings made especially for this paper. Portland Cement It is not necessary to discuss here the manufacture of cement. Any established brand of the slower setting Portland cements may be purchased with the confidence that it will harden, if properly used, and exclude water from and plug wells efficiently. Setting.-By the setting of cement is meant its initial change from a soft or plastic mortar to a friable solid. After the cement has become thoroughly set it is still very weak and can be readily pulverized in the fingers. Setting is thought to be effected by the crystallizing out of the silicate and the aluminate of lime, which are soluble in water in their anhydrous form. After dissolving in the water they pass to the hydrated state, in which they are insoluble, and hence are precipitated in a crystalline form.

Jan 3, 1914

The American Institute of Mining Engineers, the second of the four great national engineering societies established in the United States, was organized in 15,71. Its membership is composed of men engaged in the different branches of mining, metallurgy, geology, and chemistry. It includes both those who have worked their way up from the ranks and graduates from mining schools and universities, and at all times has counted in its membership leading technical educators. By a letter ballot of the members of the Institute, it was voted, at the annual business meeting of the Institute on February 18, 1919, to change the name of the American Institute of Mining Engineers to the American Institute of Mining and Metallurgical Engineers. The vote for the amendment to the Constitution making this change was a heavy one for such matters. It is the consensus of opinion that this marks an epoch in the history and usefulness of this Institute, and it is expected that the change will presage a large and healthy growth in metallurgical fields. Many metallurgists who knew nothing about min¬ing were loath to join a society of mining engineers, despite the fact that over 35 per cent. of the papers published in our Transactions during the past five years have dealt with metallurgical subjects.

Jan 1, 1923

By Ralph W. Bailey, William B. Price

Arsenic, antimony and phosphorus are now used in the brass industry as standard inhibitors in preventing dezincification in condenser tubes. This subject has been thoroughly covered by Barry,l who de- scribed the testing procedure by total immersion of suitable specimens in a I per cent cupric chloride solution at definite temperatures. Effects of dezincification were then determined by loss in tensile strength and elongation of the test specimens after definite periods of immersion. In the crystallography of the chemical elements as tabulated by William Hume-Rothery,2 phosphorus (metallic), arsenic, antimony and bismuth are placed in group V-B and the type of crystal lattice for arsenic, antimony and bismuth is given as rhombohedral. The Metals Handbook3 lists them as 'rhobomhedral hexagonal," with the additional notation that for arsenic this is the ordinary form at 20°C.; other modifications known or probable at other temperatures. In view of these statements and of the fact that phosphorus, arsenic and antimony are effective in increasing the resistance to dezincification, it was natural to assume that bismuth would act in the same manner. A series of tests was therefore carried out employing the methods described by Barry. Much to our surprise, bismuth did not inhibit dezincification, but rather seemed to accelerate it. Tensile-test speci-

Jan 1, 1942

By C. M. Marquardt

The minerals industry in general should bow in homage to the uranium milling industry. Those in the uranium milling industry have "spark- plugged" more progress in the application of instrumentation and control in the last 5 years than has been made in 50 years by the industry in general. Part of this real progress in the application of instrumentation and control has been born of necessity because milling processes are more complex. A lot of the impetus for instrumentation and control has come from the fact that the industry is new, the processes are new, and there are no hide-bound conventions to overcome. Part of it comes from the fact that much of processing is more chemical than metallurgical and the thinking of the process chemist has carried over into the plants. One need not elaborate on what instrumentation has done for the process chemical industries. Each new mill that is constructed, if of appreciable size, seems to employ more instrumentation than the previously completed plant. Plant A makes a break-through in the application of instrumentation to a particular part of the process and Plant B accepts this and goes one step farther, while Plant C, anticipating Plant B, makes two or three more steps before Plant B is entirely leveled out.

Jan 9, 1958

By A. R. Troiano, E. A. Steigerwald, F. W. Schaller

D. N. Williams(BatteZle Memorial Institute)-The authors have presented an extensive collection of arguments pertaining to the role of stress in hydrogen embrittlement. The basic assumption of these arguments is that stress is essential as a driving force for diffusion of hydrogen. However, in view of the rapid diffusion rate of hydrogen in steel at low temperatures as evidenced by the ability to alloy with hydrogen by electrolytic charging, it seems unlikely to me that stress acts in this manner. Instead, I would like to suggest that stress may be essential for the nucleation of hydrogen in steel. I believe that such an assumption would equally well satisfy the experimental data presented by the authors. I should also like to comment on the interpretation of the data presented in Figs. 5 and 6. Fig. 5 shows the effect of hydrogen content on ductility in a rupture test. The curve as drawn by the authors indicates an abrupt transition from ductile to brittle behavior at about 0.001 amp per sq in. (5 ppm). The data points would equally well support a gradual transition from ductile to brittle behavior extending over the range from 0.0008 to 0.02 amp per sq in. (4 to 8 ppm). A gradual transition would be the ex-

Jan 1, 1962

By J. N. Ong, J. P. Ratledge, J. H. Boyce

Since German operators opened the Tsumeb mine in the early 1900's, continuous operation has been interrupted only by enforced shutdowns during two world wars and the depression of the 1930's. Original metallurgical practice was blast furnace smelting. This was applicable only to low zinc ore, leaving large tonnages of high zinc ore to be stockpiled on the surface. A gravity concentrator using tables, buddles, and jigs operated for several years, but differential flotation of the ore did not get beyond the experimental stage. When the property was put up for sale by the South African Custodian of Enemy Property there was an estimated 434,000 tons of ore on surface dumps. The dump material, assaying 4.48 pct Cu, 15.8 pct Pb, and 10.9 pct Zn, had become highly oxidized during a stay of many years on the surface. But these dump ores had to be used in evaluating possible metallurgy because the shaft became flooded after the 1940 shutdown and underground ore was unavailable. Many companies examined Tsumeb but quickly lost enthusiasm because of the formidable metallurgical problems presented by the dump ore. However, on the basis of extensive test work, the present company decided that differential flotation would be successful and purchased the property after competitive bidding.

Jan 4, 1955

By Ralph W. Bailey, William B. Price

INTRODUCTION ARSENIC, antimony and phosphorus are now used in the brass industry as standard inhibitors in preventing dezincification in [ ] condenser tubes. This subject has been thoroughly covered by Barry,1 who described the testing procedure by total immersion of suitable specimens in a I per cent cupric chloride solution at definite temperatures. Effects of dezincification were then determined by loss in tensile strength and elongation of the test specimens after definite periods of immersion. In the crystallography of the chemical elements as tabulated by William Hume Rothery,2 phosphorus (metallic), arsenic, antimony and bismuth are placed in group V-B and the type of crystal lattice for arsenic, antimony and bismuth is given as rhombohedral. The Metals Handbook3 [ ] lists them as "rhombohedral hexagonal," with the additional notation that for arsenic this is the ordinary form at 20°C.; other modifications known or probable at other temperatures. In view of these statements and of the fact that phosphorus, arsenic and antimony are effective in increasing the resistance to dezincification, it was natural to assume that bismuth would act in the same manner. A series of tests was therefore carried out employing the methods described by Barry. Much to our surprise, bismuth did not inhibit dezincification, but rather seemed to accelerate it. Tensile-test speci-

Jan 1, 1942

By Ralph W. Bailey, William B. Price

ARSENIC, antimony and phosphorus are now used in the brass industry as standard inhibitors in preventing dezincification in [ ] condenser tubes. This subject has been thoroughly covered by Barry,1 who described the testing procedure by total immersion of suitable specimens in a I per cent cupric chloride solution at definite temperatures. Effects of dezincification were then determined by loss in tensile strength and elongation of the test specimens after definite periods of immersion. In the crystallography of the chemical elements as tabulated by William Hume-Rothery,2 phosphorus (metallic), arsenic, antimony and bismuth are placed in group V-B and the type of crystal lattice for arsenic, antimony and bismuth is given as rhombohedral. The Metals Handbook3 [ ] lists them as "rhombohedral hexagonal," with the additional notation that for arsenic this is the ordinary form at 20°C.; other modifications known or probable at other temperatures. In view of these statements and of the fact that phosphorus, arsenic and antimony are effective in increasing the resistance to dezincification, it was natural to assume that bismuth would act in the same manner. A series of tests was therefore carried out employing the methods described by Barry. Much to our surprise, bismuth did not inhibit dezincification, but rather seemed to accelerate it. Tensile-test speci-

Jan 1, 1942

By A. U. Seybolt

As is well known, many questions affecting the properties and uses of a metal cannot be answered without careful consideration of the state of purity realized in the various operations of preparation, refining, or special treatment that have brought the product to its final state. The occurrence of an impurity in minute quantity offers no guarantee that its effect will be inconsiderable because dissolved substances often modify the properties of a metal quite out of proportion to their concentration. In such cases the determination of solid solubility must be accepted as a problem of considerable difficulty, requiring the use of especially purified materials and methods not ordinarily used in the metallurgical laboratory. This aspect of the equilibrium between metals and their oxides is especially important and a search for fundamental data reveals little except .conflicting opinion even concerning the systems of common occurrence and interest. Rhines and Mathewson1 in 1934 studied the solubility of oxygen in solid copper by annealing to equilibrium in air and gave reasons for the failure of other methods, notably the ordinary procedure of heat-treatment followed by microscopic examination, to yield reliable results. In this paper, a similar study has been made of the solubility of oxygen in cobalt. The simple theory of this method is outlined below.

Jan 1, 1935

By P. L. De Bruyn, R. J. Charles

The transfer of kinetic energy of translation into other forms of energy by impact is a fundamental process in most crushing and grinding operations. During and after the impact process the original source energy may be accounted for in any of the following possible forms: 1) Kinetic energy of translation of both the impacted and impacting objects. 2) Kinetic energy of vibration of the components of the impact system. 3) Potential energy as strain energy of the components of the system or in the form of residual stresses. 4) Heat generated by internal friction during plastic deformation or during damping of elastic waves. 5) New surface energy of fractured materials. At any instant during the impact process only the strain energy of the components of the system can contribute directly to the brittle fracture process. If fracture is the desired result, as in comminution, it would seem advantageous to choose or arrange the conditions of impact so that a maximum amount of the original kinetic energy could be converted to strain energy at some moment during a single impact. The present work deals with determination of these desirable conditions for a simple case of impact and application of the principles involved to general cases of impact.

Jan 1, 1956

By A. U. Seybolt, C. H. Mathewson

As is well known, many questions affecting the properties and uses of a metal cannot be answered without careful consideration of the state of purity realized in the various operations of preparation, refining, or special treatment that have brought the product to its final state. The occurrence of an impurity in minute quantity offers no guarantee that its effect will be inconsiderable because dissolved substances often modify the properties of a metal quite out of proportion to their concentration. In such cases the determination of solid solubility must be accepted as a problem of considerable difficulty, requiring the use of especially purified materials and methods not ordinarily used in the metallurgical laboratory. This aspect of the equilibrium between metals and their oxides is especially important and a search for fundamental data reveals little except conflicting opinion even concerning the systems of common occurrence and interest. Rhines and Mathewson1 in 1934 studied the solubility of oxygen in solid copper by annealing to equilibrium in air and gave reasons for the failure of other methods, notably the ordinary procedure of heat-treatment followed by microscopic examination, to yield reliable results. In this paper, a similar study has been made of the solubility of oxygen in cobalt. The simple theory of this method is outlined below.

Jan 1, 1935

By W. R. Davison, C. A. Brown, J. P. Carstens

INTRODUCTION The phenomenon of heat-weakening of rock with 10.6 micron radiation from a continuous-wave C02 gas laser has been investigated in detail at the Massachusetts Institute of Technology for over 5 years. The programs at MIT have explored the basic nature of the heat-weakening phenomena and rock fracture caused by heating (e.g., Refs. 1 and 2), and have resulted in quantitative estimates of the relationship between the amount and parer level of heating and the resulting decrease in the modulus of rupture of a rock beam in a three-point bend test (Ref. 3). Results of the tests reported in Ref. 3 indicate a greater than 90% reduction in the modulus of rupture for granite beams heat-weakened by a laser. These results prompted the U. S. Department of Transportation to seek an assessment of the expected feasibility of employing the heat- weakening concept in a full-scale tunnel boring operation. Present- day continuous rock-tunneling machines have demonstrated tunneling time and cost savings over drill-and-blast methods, when used in rock types that are easily broken by the cutters. However, cutter bits have not yet been developed which can easily penetrate very hard rock

Jan 1, 1971

By John W. King

Uranium ore was first discovered in the Edgemont district of the southern Black Hills in the summer of 1951. The discovery was not made known for some time, but after the news leaked out prospecting became intense, and several hundred claims were staked in the spring of 1952. The Hot Springs Sub Office of the Atomic Energy Commission was established at that time and airborne radiometric surveys were commenced by the Government and by private companies. During the succeeding summer another important discovery was made by private airborne surveys in the northern Black Hills, and the area favorable for uranium ore was expanded many times. Between that summer of 1952 and the present, many individuals and groups have explored, developed, and exploited their claims until now uranium ore is produced in significant quantities and substantial reserves have been developed. The Black Hills portion of the geologic map of the U. S. issued by the U. S. Geological Survey is shown in Fig. 1. Sedimentary formations are exposed as a series of cuestas and hogbacks in a roughly annular pattern with the older sediments resting on the pre-Cambrian core, which is exposed in the eastern and southern portions of the dome.

Jan 1, 1956

By A. J. Fenn

Long experience with underground mining inspired the unusual idea of using an underground crusher-conveyor system as a substitute for surface haulage at the Cananea open-pit copper mine in Sonora, Mexico. Now implemented and working well, the system has born out the expectations of its originator, Cia. Minera de Cananea S.A. de C.V., that it would effect substantial cuts in the high cost of haulage. The Cananea deposit is a large, low-grade orebody above the mined-out Colorada pipe which was once one of the largest high-grade underground deposits in the district. Present facilities at the pit consist of: (1) A large open-pit mine capable of moving 80,000 tons of material per day with a shovel-truck, underground crusher and belt conveyor haulage system. (2) A 25,000-tpd concentrator equipped for four stages of crushing, rod mill-ball mill grinding with cyclone classification, and flotation in conventional machines. (3) A dump leaching process producing 1 million lb of copper per month in a tin-can scrap precipitation plant. (4) A two-reverberatory, six-converter smelter which can make 140 tons of blister copper per day. (5) A well-integrated contingent of supporting departments running the gauntlet from housing to power generation.

Jan 3, 1969

By R. T. Hukki

IT is no great exaggeration to say that present grinding practice and economics are largely determined by lining design. A record of outstanding liner wear can be achieved with any liner surface pattern that will positively lock the outer layer or layers of grinding media. With no slippage, lining wear is bound to be slight. At the same time, popular practice calls for tumbling loads of about 50 pct of mill volume to obtain maximum grinding capacity. Innumerable parallel grinding investigations have verified that optimum speed for such a mill lies within 70 to 85 pct of theoretical critical speed. If the mill is speeded up to 100 pct of critical, little or no grinding can be accomplished. Earlier Work on Supercritical Grinding: First investigations concerning grinding at supercritical speeds seem to be very old. Remarkable work on the subject has been performed by White,1 and his experiments have been described and summarized by Richards1 White's contributions seem to have passed unnoticed by Fahrenwald, 2,3 whose extensive experiments have been well presented, yet apparently very little appreciated. Additional work on grinding at supercritical speed has been reported, e.g., by Lewenson and Tscherny,4 USSR; Anselm5 and Grunder,6 Germany; and Rose and Evans,[6] Great Britain.

Jan 5, 1958

By Hassell E. Hunter

The Wyoming Minerals - Conoco Crownpoint Joint Venture represents the first time that big hole drilling has been exclusively used to develop a privately financed mine. Three shafts, one ten feet in diameter and two six feet in diameter, have been successfully drilled to depths of 2243', 2188' and 2188' respectively and lined with hydrostatic designed steel casing. The largest shaft is to be used to as a development shaft to handle muck and water from enlargement and station excavation of the other two shafts. A reverse fluid air assist circulation system with potassium base mud was used during drilling. The mud was cleaned by settling in steel lined tanks with assistance from cyclone type sand separators. Deviation was monitored with wireline gyroscopic surveying instruments at 30 foot intervals. Horizontal departure did not exceed 16 inches off perpendicular. Casing was designed to withstand full hydrostatic pressures with a 1.5 safety factor for the large shaft and 1.25 safety factor for the two smaller shafts. All casing welds were x-rayed prior to lowering the casing into the hole. Cementing the annular space completed the operation. The total time to mobilize, drill and move off the three shafts was 363 days. The drilling operation was completed ahead of schedule and under budget.

Jan 1, 1982

By E. O. Wagner, V. F. Parry, W. S. Landers

Following investigations by the Denver Bureau of Mines on drying fine coal in the entrained state, Texas Power & Light Co. employed the fluidized technique to upgrade Texas lignite for use in power plants. Because of the rapidly rising cost of natural gas in Texas the company agreed to cooperate with the Bureau of Mines in studying further the upgrading of lignite by low-temperature carbonization, since potential value of the tar would help off- set the cost of fuel. Considerable interest was aroused, therefore, when Aluminum Co. of America decided to use dried lignite in its 240,000-kw power plant at Rockdale, Texas, operated by Texas Power & Light. Carbonization of coal before burning in a power plant is not new. Plants in Germany have been operated for many years on carbonized brown coal and lignite briquets produced in large integrated plants. Large-scale experiments in carbonizing pulverized coal with hot flue gases were made 30 years ago at Milwaukee, and many inventors have proposed other processes. In the U. S., technical and economic problems have prevented successful operation of large plants on carbonized coal, but new techniques of handling solids in fluidized beds may overcome these difficulties, particularly if the higher volatile noncoking coals are used.

Jan 1, 1956

By E. S. Machlin

The alternate processes by which solute atoms can limit the migration of grain boundaries have been considered. At the lowest solute concentrations the controlling process is "mechanical breakaway" in which the solute atoms affect the driving force and not the mobility. In the next higher range of solute concentration, solute atoms are bound to the boundary and diffuse by boundary diffusion along cusps in the boundary developed at the solute atoms. In this region the boundary velocity is controlled by the component in the direction of boundary migration of the rate at which the bound solute atoms can diffuse along the boundary. At still higher concentrations, it is predicted that boundaries break away from the binding solute atoms by thermal activation. The specific behavior Predicted is consistent with the observations of Aust and Rutter. The most striking agreement between prediction and experiment is that obtained for a range of solute concentration in which the boundary velocity is inversely proportional to the cube power of the solute concentration. MaNY models have been devised for the atomic steps in the motion of a grain boundary. McLean1 has listed some of these models and Aust and utter' have evaluated these and other models. If there are

Jan 1, 1962