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By H. T. Kennedy, S. M. Avasthi

An equation developed for gaseous hydrocarbon mixtures predicts molal volumes with an average absolute deviation of 0.73 percent when applied to 264 natural gas and condensate systems including 2,043 PVT points. Another equation developed for liquid hydrocarbon mixtures predicts molal volumes with an average absolute deviation of 1.12 percent when applied to 346 crude oil systems including 1,759 PVT points. Both equations require composition of the mixture to be expressed as mole fraction of methane through heptanes-plus, hydrogen sulfide, nitrogen and carbon dioxide, together with the characteristics of the heptanes-plus fraction in addition to the temperature and pressure. The equations cover wide ranges of the variables involved, and their accuracy is considerably better than that of other available methods. The equations were differentiated to allow calculation of the coefficients of isothermal compressibility and isobaric thermal expansion. (In this paper the coefficient of isothermal com-pressibility and the coefficient of isobaric thermal expansion will be expressed as compressibility and thermal expansion coefficient, respectively.) Equations to calculate these quantities are presented. INTRODUCTION Calculations of reservoir performance for petroleum reservoirs require accurate knowledge of the volumetric behavior of hydrocarbon mixtures, both liquid and gaseous. Compressibilities are required in transient fluid flow problems, and thermal expansion coefficients are important in thermal methods of production. An accurate laboratory investigation of the PVT behavior of each reservoir fluid encountered would be costly and time consuming. For this reason various correlations for predicting fluid properties have been developed and recorded in recent literature. Correlations have been presented in the form of graphs, tables and equations. Since an increasing number of studies are being conducted with the aid of electronic computers, recent efforts have been directed toward development of correla-tions suitable for computer programming. Application of computers permits the use of more complex correlations which otherwise are not feasible. Moreover, methods for predicting reservoir performance, particularly those based on the compositional material balance, depend upon the capability of accurately expressing the molal volumes and other fluid properties as functions of pressure, temperature and composition. The coefficient of isothermal compressibility c is defined by

Jan 1, 1969

By Robert Peele

TWO outstanding members of the Institute will be honored at the Annual Meeting this month: Robert Peele, who will accept his election to the small group of Honorary Members; and Clinton Hoadley Crane, president of the St. Joseph Lead Co. and William Lawrence Saunders Medalist for 1936. Eminence in the profession character, interest in Institute activities, and general recognition as a gentleman and a friend by so many people, have contributed to the election of Professor Peele. The Saunders Medal is for "achievement in mining." In awarding it to Mr. Crane the citation reads "For distinguished achievement in the successful development and operation of low-grade lead mines."

Jan 1, 1936

By AIME AIME

WILLIAM BAYARD HEROY, Director of the Institute since 1935 and Vice-President for the past year, has been active in both geological and engineering circles of the petroleum industry for many years. "Bill," as he is generally called, was born in New York City in 1883, and graduated from the department of geology at Syracuse University in 1909 with a Ph.B. degree. Immediately he joined the U. S. Geological Survey, where he established an enviable record during the next eleven years. While with the Survey he acted variously as chairman, chief, and advisory engineer for a variety of Governmental bodies, many concerned with power.

Jan 1, 1939

The curve of Fig. 3 for pyrite requires modification. There 11% a range of pH values from 6.2 to 7.8 for which no cyanide is required to prevent contact. From 7.8 to 11.3 a small amount of cyanide is required, with a sharp maximum of 20 mg. per liter at pH=9.6. The mistake arose from considering too few solution compositions (17 were considered) in constructing the curve. Subsequent work with other collectors indicates that the corrected curve is typical for such systems; it illustrates the further development of the dip in the pyrite curve of Fig. 5.

Jan 1, 1938

West Virginia University, Engineering Experiment Station, Morgantown, W Va C E Lawall, Director. For copies of Bulletins or other information address the Director Two classes of the Bulletins published by the Engineering Experiment Station are of particular interest in this directory- Research Bulletins, and Extension Bulletins, or bulletins published for use in extension work They are. Research Bulletin 1, The conservation of natural gas in West Virginia (1918), 2, Acceleration stresses in hoisting ropes (1927), 3, Classification of gas wells for operation (1927), 4, Mining methods in West Virginia (1929), 5, The whiteware industry of West Virginia, Extension Bulletin 1, Electricity in mines, series

Jan 1, 1933

EVERY forward-looking mining company realizes the need for employing graduate mining engineers so that there will be a supply of qualified men from which to draw for company officers, executives, and mine managers. The mining industry is competing today with numerous other fields of engineering for its supply of technical men, many of which are more attractive than mining because of better pay, living conditions, and well- regulated company training programs. The Ontario Mining Association and the mining companies of Ontario are conducting a postgraduate training plan which if adopted in the United States, might well encourage top quality men to study mining.

Jan 3, 1950

A new Military, Engineering School has been established at Camp A. A. Humphreys, Virginia. This camp was used throughout the summer and fall of 1918 for the Engineering Officers Training School in preparing engineer officers for the United States Army. The camp and the courses prescribed were laid out on an ambitious scheme, which since the armistice has been signed, have been directed wholly, toward the permanent establishment of an Engineering Training School for Officers of the regular Army. Those young officers who were graduated from Nest Point at the end of a two-year course, necessitated by the emergency, have been ordered to Camp Humphreys to complete their engineering education.

Jan 3, 1919

By K. Y. Lo, R. S. C. Wai, R. K. Rowe, L. Tham

Laboratory tests for the determination of thermo-mechanical proper- ties of three rock types were performed at temperatures up to 400°C. Results showed that for the medium and coarse Granitic Gneisses, the coefficient of thermal expansion and Young's modulus are strongly temperature and temperature history dependent. A threshold temperature exists for each rock type above which material nonlinearity becomes important, and is associated with the progress of thermal cracking. Finite element computations were performed to illustrate the influence of material nonlinearity and boundary constraint on thermal stresses. Finally, a case history of thermal spalling was analyzed and it is shown that the results of analysis are consistent with field observations.

Jan 1, 1982

By C. Richard Tinsley

As discussed in the economics section of this article, the main processing consideration is whether manganese will be recovered, as this has major implications for reagent consumption. Nodule processing can be classified into three sections; smelting, roasting, and leaching. Many patents have been issued for various stages of these techniques. Since extensive laboratory and pilot plant testing is continuing, it is certain that some companies are close to full-scale commercial processes. Published data does not include all of the possible concepts for nodule treatment. In fact, one may suspect that published flowsheets are those that have been rejected or have since been extensively modified.

Jan 4, 1975

(Under this heading will be published notes sent to the Secretary of the Institute by members or other persons. ) Position of laboratory assistant in metallurgy, pyrometry, and physical testing is vacant. Salary $80 to $100 to start. Knowledge of metallography desirable. Opening for a mine superintendent familiar with stoking methods on narrow gold quartz veins; also for a. superintendent of a 50-ton fine-grind-in, cyanide mill. College man under 40 preferred. Position in sales department is open for a mining engineer, with experience in mine ventilation and possessing some knowledge of fan design; one competent to lay out ventilating systems to meet various conditions.

Jan 10, 1913

By Paul Soros

Terminal facilities were recently completed at Conneaut, Ohio, on Lake Erie, for the Bessemer and Erie Railroad Co. (a wholly-owned subsidiary of U.S. Steel Corp.) which may become the blue- print for all future coal shipping terminals. Design and engineering of the new facility was by Soros Associates, New York, N. Y. Unlike terminals of conventional design, for example, those at Toledo and Newport News, which load coal directly from the railroad car to the vessel, the new installation passes the coal into temporary storage, loads the vessel from temporary storage and provides alternative reclaiming systems in case of major system failure.

Jan 1, 1966

By William Allen

For the past six years gravity surveys have been used for underground prospecting in the copper mines at Bisbee, Ariz. The primary purpose of the surveys has been to reduce the diamond drilling and crosscutting necessary for exploration. Since many of the orebodies are small, and geologic control is not always apparent, any information that will direct the drilling and crosscutting is highly desirable. Because of extensive development and exploration work in the copper mines at Bisbee, it has been possible to cover more than 630,000 ft of crosscuts on 30 levels with the gravity surveys. In the process the gravity procedures have been refined to a high degree.

Mar 1, 1956

By G. A. Wells

The consumption of barytes in certain paints, polyurethane foams, seamless flooring, glass, brake linings, plastisol gaskets for food containers, and in fluids used for gastrointestinal X-ray examinations relies on the unique properties of barium sulfate. There are no readily available mineral substitutes. Barytes are also the essential raw material for the manufacture of industrially important barium chemicals. High quality barite ore has become scarce throughout the world. Processing ore into quality end products is both capital and energy intensive. These factors have tended to limit availability and increase Prices which have encouraged the use of alternative or competitive materials and restricted market growth.

Jan 1, 1981

By Raymond E. Zimmerman

Abstract-The Swirl Cyclone developed in Japan, although based upon the same principles as the standard cyclones for heavy-media or water-only cyclones for cleaning coal, is novel in that it is invested with the apex on top, discharging rejects at the top, and clean coal at the bottom. It also uses a variable air vent tube for controlling the vortex. Tests conducted indicate that its efficiency is not only as sharp as standard cyclones but it also performs using a much coarser grain magnetite, promising higher magnetite recovery. The author describes the results of tests conducted in Japan on a very difficult coal.

Jan 2, 1978

By T. F. Adams, L. G. Margolin

The Bedded Crack Model (BCM) is a constitutive model for brittle materials. It is based on effective modulus theory and makes use of a generalized Griffith criterion for crack growth. It is used in a solid dynamic computer code to simulate stress wave propagation and fracture in rock. A general description of the model is given and then the theoretical basis for it is presented. Some effects of finite cell size in numerical simulations are discussed. The use of the BCM is illustrated in simulations of explosive fracture of oil shale. There is generally good agreement between the calculations and data from field experiments.

Jan 1, 1982

By Harold V. Pearce

The fire which occurred in the fall of 1906, at the works of the Boston & Colorado Smelting Co., Argo, Colo., destroyed entirely the gold- and silver-refinery of the plant, and in view of the development of modern practice in the refining of copper-mattes, etc., the management decided that it would be inadvisable to rebuild that part of the works for the continued use of the process which had been conducted therein for so many years as a metallurgical secret. This decision probably removes altogether from the sphere of practice the '(Pearce" method for the separation of gold. At all events, it removes the busi-

Jan 1, 1909

By R. L. Blackwood

The solid inclusion cell for absolute in situ stress measurement has been found to give reliable results in coal. The cell is described briefly, along with the methods of installing, overcoring and taking readings in underground coal mines. The validity of the cell performance is demonstrated by reference to the stress-relief curves obtained during overcoring and a three-dimensional B.I.E.M. analysis of the installation to test for stress anomalies deriving from the geometry of the overcoring groove-borehole-cell arrangement. Case studies of two stress measurement projects using the cell are presented for coal mines in New South Wales, Australia.

Jan 1, 1982

By R. S. Rickard, H. D. Peterson, M. C. Fuerstenau, J. D. Miller

The flotation characteristics of the oxide copper minerals, malachite, azurite, and cuprite, have not presented the difficulty for concentration as have those of the copper silicate, chrysocolla. The copper carbonates and oxides respond reasonably well to flotation with conventional collectors, whereas chrysocolla will not respond to flotation with fatty acids or xanthates under normal flotation conditions. In this view then, other reagents will have to be devised to function as collectors for chrysocolla. The most obvious general class of reagents for this purpose would seem to be the organic copper chelating compounds. The utility of chelating agents as collectors in flotation systems has already been demonstrated.1-6

Jan 4, 1966

By Fred W. Shultz

The process engineer is familiar with the in any methods employed in the past for analyzing various materials. These include panning. eyeballing, and wet chemistry. Of those mentioned only wet chemistry has been and will continue to be a standard measure for the elemental content in a given material. However, wet chemistry, by the very nature of the method, can be excessively time-consuming and thus reducing obviously the number of samples that may be processed in a given period. The analysis by X-ray, in most cases, requires nothing more than assurance that the sample is in a suitable state for presentation to the X-ray spectrometer.

Jan 1, 1964

By Raymond E. Zimmerman

The Swirl Cyclone developed in Japan, although based upon the same principles as the standard cyclones for heavy-media or water-only cyclones for cleaning coal, is novel in that it is invested with the apex on top, discharging rejects at the top, and clean coal at the bottom. It also uses a variable air vent tube for controlling the vortex. Tests conducted indicate that its efficiency is not only as sharp as standard cyclones but it also performs using a much coarser grain magnetite, promising higher magnetite recovery. The author describes the results of tests conducted in Japan on a very difficult coal.

Jan 1, 1979