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By H. R. Gardner

THE wide variation in tension and compression properties' which exist between the a,ß and ? phases of plutonium indicate that a study of the impact properties would give a greater insight into the variables affecting the mechanical properties and formability of plutonium. In tension the a phase is quite brittle with elongations less than 1 pct. The ß phase at normal test speeds is unusually ductile; elongations up to 621 pct have been obtained. However, the ß phase is quite sensitive to strain rate; elongations decrease rapidly as strain rate is increased. The y and 6 phases are less ductile than the ß phase, with the 5 phase the more ductile of the two. Neither are very sensitive to strain rate. Considering the brittle nature of a Pu in tension and compression and the strain rate sensitivity of ß -phase Pu, both unnotched Charpy specimens and standard V-notched Charpy specimens were fabricated for testing. In addition, since iron in amounts greater than 500 ppm forms a Pu-PlgFe eutectic network which inhibits microcracking in as-cast plutonium,' it was decided to prepare impact specimens with low and high iron contents. Chemical analysis and density data for the impact specimens are presented in Table I. A total of 55 impact specimens, 32 unnotched and 23 with the standard Charpy V-notch were tested at temperatures from —45' to 330°C. The test results for both unnotched and notched specimens are illustrated in Fig. 1.

Jan 1, 1962

By F. J. Smit

The Tintic Division of Kennecott Copper Corporation operates the Burgin Mine in the East Tintic District near Eureka, Utah, approximately 75 miles south of Salt Lake City. The Division was organized in 1963 to develop concealed replacement orebodies in the area located by Bear Creek Mining Company, Kennecott's domestic exploration subsidiary. Several accounts of the discovery of these orebodies and the general geology of the area have been given (1, 2). The ore is very complex and of varying degrees of oxidation and alteration. The principal metal values are lead, zinc, silver, and cadmium. The Burgin No. 2 shaft was sunk in 1963 to provide access for mining the orebodies. Much of the ore mined after this shaft was sunk was high grade and shipped directly to smelters, but concurrently it was recognized that concentration would be required to upgrade the lower grade ore in the deposits. Accordingly, in January 1967, authorization was received to construct a 500 tpd concentrator. From the beginning it was expected that the characteristics of the mill feed would vary widely and unpredictably as mining progressed. This paper summarizes the characteristics of the ore, the test work upon which the plant design was based, the engineering and construction, and the present operation of the facility eighteen months after startup. ORE CHARACTERISTICS The Burgin ore is a complex assemblage of minerals from replacement of limestone. The replacement and alteration occurred in at

Jan 1, 1970

By S. F. Shaw

THE principles involved in lifting oil in wells flowing naturally are identical with those underlying the flowing of wells by means of the air-gas lift, and information of a dependable nature obtained in the study of the air-lift can be applied to wells with natural flow. A well flowing naturally is one in which the lifting is done by means of the gas-lift, for which the gas is supplied entirely by the formation from which the oil is derived. In air-gas lift operations, there is insufficient gas supplied by the formation to lift the oil to the surface in an efficient manner, therefore additional gas for this purpose must be furnished from an outside source. There may, at times, be conditions obtaining in natural flowing wells different from those in wells flowed by gas-lift, but these differences do not at all conflict with the main principles of gas-lift work. One such condition is met with in wells in which the gas supplied by the formation is in considerable excess of that required to lift the oil to surface; this excess may be so great as to reduce the quantity of oil that can be lifted through the particular diameter of casing or tubing that has been lowered into the well. This same condition can be brought about, however, by supplying a large excess of gas from an outside source to an artificial gas-lift well, and a study of the effects obtained from injecting a large excess into the well can be applied directly to handling wells flowing naturally which have a large excess of gas supplied by the underground reservoir.

Jan 1, 1929

By C. E. Beecher

IN the course of the experimental and development work of Henry L. Doherty in an endeavor to obtain an increased yield of oil from oil-bearing sands, it was Mr. Doherty's claim and contention that oil in an undisturbed pool was different in character and behavior than, the same oil when raised to the surface of the earth, and that the gas dissolved in the oil caused a marked reduction in its viscosity and surface tension. Prior to 1924 no information to support this contention could be found in the literature or by a discussion of the subject with technical men in Government and private laboratories. So far as could be ascertained no experimental work had been carried on to indicate that Mr. Doherty's claim was either right or wrong. All parties consulted agreed that the viscosity of the oil would be affected by gas dissolved therein to the extent that natural gasoline was present in the gas, but so far as could be determined any additional effect of the natural gas was unknown. Accordingly, it was necessary to devise equipment and carry on experiments which would either prove or disprove Mr. Doherty's contention or claim. Such apparatus was built under Mr. Doherty's direction and experiments were carried on to determine definitely the viscosity and the surface tension of the crude oils which contain dissolved gases under different pressures. The results of the experimental work carried on have proved that the claim and contention of Mr. Doherty were correct in every particular, as will be seen from the discussion of the subject and the data contained in this paper.

Jan 12, 1926

By F. E. Bash

About three years ago, the writer presented a paper1 on the rate of heating and cooling of a 24-in. round ingot. The present paper deals with work done on larger ingots at the plant of the Allis Chalmers Mfg. Co., Milwaukee, Wis., in August, 1919. Sufficient data on ingots of all sizes were desired to enable one to calculate in advance the rate at which any ingot could be raised to a forging temperature without injury to the steel, determining also the temperature gradient between different sections of the ingot and the length of time necessary to heat to the center. This has now been experimentally determined for 24-in. and 45-in. ignots by the writer and for a 18-in. cube by E. F. Law.2 J. F. Harper has also made tests on heat-treating temperatures on 30-in, ingots; which data are included in this paper. No attempt is made here to work out a formula for the heat penetration of steel, for too many factors are involved concerning which we have not sufficient information, as for instance, the specific heat of steel up to 2300' F. It is hoped that eventually a set of formulas will be developed so that one may calculate maximum allowable temperature differences within an ingot for any particular kind of steel and the rate of absorption of heat and temperature gradient within the ingot for a definite temperature head. EXPEEIMENTAL INGOT The ingot tested was 45 in. in diameter, having been forged into the shape shown in Fig. 1 from 54 in. diameter. Seven -in. holes were

Jan 1, 1923

By F. E. Bash

About three years ago, the writer presented a paper1 on the rate of heating and cooling of a 24-in. round ingot. The present paper deals with work done on larger ingots at the plant of the Allis Chalmers Mfg. Co., Milwaukee, Wis., in August, 1919. Sufficient data on ingots of all sizes were desired to enable one to calculate in advance the rate at which any ingot could be raised to a forging temperature without injury to the steel, determining also the temperature gradient between different sections of the ingot and the length of time necessary to heat to the center. This has now been experimentally determined for 24-in. and 45-in. ignots by the writer and for a 18-in. cube by E. F. Law.2 J. F. Harper has also made tests on heat-treating temperatures on 30-in, ingots; which data are included in this paper. No attempt is made here to work out a formula for the heat penetration of steel, for too many factors are involved concerning which we have not sufficient information, as for instance, the specific heat of steel up to 2300' F. It is hoped that eventually a set of formulas will be developed so that one may calculate maximum allowable temperature differences within an ingot for any particular kind of steel and the rate of absorption of heat and temperature gradient within the ingot for a definite temperature head. EXPEEIMENTAL INGOT The ingot tested was 45 in. in diameter, having been forged into the shape shown in Fig. 1 from 54 in. diameter. Seven -in. holes were

Jan 1, 1923

By A. W. Ambrose

THE underground losses of oil exceed by hundreds of thousands of barrels all the oil that has been lost in storage, transportation, or refining. The quantity lost is, of course, indeterminate; but when it is considered that the contents of an entire oil field have been excluded from recovery by invading waters, some idea of the amount wasted may be gained. Similarly, enormous quantities of gas have been lost underground. Conservation of the oil, therefore, should start before it is brought to the surface rather than after it is placed in storage tanks. Water is one of the most important causes for underground losses and the operator should give as serious consideration to an underground flood of water as he would to a destructive surface flood. The best insurance, of course, is to have the wells drilled in such a manner that water has no access to the productive oil and gas horizons, and on abandonment the wells should be properly plugged. The encroachment of edge water and the occurrence of water in the base of an oil sand present a very serious problem to an oil company; sooner or later these waters are bound to cause considerable damage, if they do not entirely destroy the possibilities of further production. Too often, however, a field has been considered to be in a hopeless condition, whereas wells in as bad a condition in other areas have been repaired and the life of the field appreciably lengthened. The corrections are very often suggested by technical study. Very successful results have been accomplished by detailed underground work in the California oil fields, in Cushing, Oklahoma, and in other areas.

Jan 9, 1920

By Richard S. McCaffery, Joseph F. Oesterle, Oscar O. Fritsche

The method of obtaining the data on which this paper is based is explained in detail in the paper on Determination of Viscosity of Iron Blast-furnace Slags.' The work was made possible by a grant of funds from Engineering Foundation, and it gives the results now obtained, continuing the general subject of our previous work and reported in former papers2 The data experimentally obtained are in the form of a temperature-viscosity curve for any slag of particular composition. (See Fig. 1.) From these curves, the viscosity of a slag of a definite composition and at a definite temperature is taken off and is plotted on a plane triaxial diagram showing compositions of silica lime and alumina on a plane representing constant-magnesia content (Fig. 4). The temperatures at which these results were plotted are 1300°, 1350°, 1400°, 1450°, 1500°, 1550" and 1600" C. and since the constant magnesia plane sections were an even 1 per cent. magnesia apart, magnesia analyses not of even unit magnesia composition were projected to these even unit magnesia planes. For example, 1.78 per cent. magnesia and 2.35 per cent. magnesia were projected to the 2 per cent. magnesia plane. The triaxial diagrams on which this first plotting was made were drawn on celluloid sheets, a transparent material on which it was easy to draw. When all the experimental work was plotted on celluloid in this way, the sheets representing a definite temperature were stacked in the proper order and were examined by transmitted light. Where

Jan 1, 1932

By L. Graydon Carpenter, Donald E. Garrett

Probably the largest single tungsten deposit in the U. S. is one that has yet to produce any tungsten; it is not even listed in tables showing U. S. reserves. This deposit is at Searles Lake, Calif., where the brine contains about 70 ppm WO3. Small though the concentration is, the amount of brine in the lake is so great that it is estimated at 170 million lb of WO3 (8.5 million units), equaling the total of all other known reserves in the U. S. This dry lake is located in the basin formed by the Argus and Slate ranges in the northeastern corner of the Mojave Desert (Fig. 1). It consists of a massive salt body some 35 sq miles in extent, varying in thickness from 0 to 120 ft and containing more than 3 billion tons of salt. A central section of about L. G. CARPENTER and D. E. GARRETT are with the Research Dept., American Potash & Chemical Corp., Trona, Calif. TP 47881. Manuscript, Nov. 4, 1958. AlME Trans., Vol. 214, 1959. 8 sq miles is exposed salt; the remaining area is overlain by mud. Except for the exposed sodium chloride (10 to 15 ft thick) the body consists of a very complex and heterogenous mixture of soluble crystals, containing at least eight major phases. It is only about 53 pct solid, the voids being occupied by a dense brine which is the raw material for two chemical companies operating in the valley.

Jan 3, 1959

PENNSYLVANIA ANTHRACITE LOCAL SECTION On Saturday evening, Jan. 31, 1914, about 40 members of the Institute met at the Hotel Sterling, Wilkes Barre, Pa., for the purpose of discussing plans for the formation of a local section in the Pennsylvania anthracite region. President Rand; Prof. Joseph W. Richards, of the Board of Directors; Dr. H. M. Chance, Chairman of the Committee on Coal and Coke, and Secretary Stoughton were among the guests present. R. V. Norris acted as Master of Ceremonies, and the arrangements were all made in advance by a Committee under the leadership of Charles Enzian, to whom an enthusiastic vote of thanks was accorded at the dinner. An address was made by President Rand, followed by .Professor Richards, who outlined the procedure necessary for the formation of a Local Section. Addresses were then made by W. J. Richards, F. W. Chase,. C. F. Huber, R. J. Foster, F. A. Hill, H. M. Chance, Bradley Stoughton, and others, after which a rising vote was taken, and it was unanimously decided to petition the Board of. Directors for the establishment of the Pennsylvania -Anthracite Local Section. More than the required number of members then signed -the petition, and President Rand announced the appointment of a Committee to organize the Section and arrange for a meeting in accordance with their By-Laws, consisting of R. V. Norris, W. J. Richards, R. J. Foster, Edwin Ludlow, C. F. Huber, Charles Enzian, Douglas Bunting, F. A. Hill, and J. M. Humphrey.

Jan 2, 1914

By H. A. Kursell

IN pre-war days, the mining industry of Russia occupied in the industrial life of the Empire a place of ever increasing importance. The peak of produc-tion was reached in 1913 and 1914, the years of greatest prosperity, and a rapid growth of the mineral industry seemed assured, especially as regards base-metal mining. Exceptions were the gold production, for which a gradual decline was anticipated, and the platinum out-put which was expected to remain steady. A greater productivity of labor, corresponding to better working facilities was noticeable, and the economic status of the working classes was constantly improving. The tremendous strain on Russia's economic life caused by the World War did not materially alter the prospects of the mineral industry and the fundamental changes began only with the revolution in the spring of 1917. Their scope and character are illustrated by the figures in Table 1 which compare, for the parts of the Russian Empire under Soviet (R. S. F. S. R.) control, the average mineral production of 1913 and 1914 with that of 1920, 1921 and 1922, as supplied by bolshevik sources.1The latter three years in Russia's history were characterized by the firm establishment in power of the Communist party as a new ruling caste. Silver, lead, zinc, tin, nickel, tungsten, barite, etc., were either produced in negligible quantities, or not at all. However, before the revolution the development of several argentiferous lead-zinc deposits in western Siberia had reached a stage which seemed to assure an appreciable output of the white metals for the near future.

Jan 7, 1923

By Hillary W. St. Clair

An equation is derived for the rote of reaction of a sphere of metal oxide in a restricted enclosure through which a reducing gas is flowing. The equation takes into consideration the reaction rate coefficient, transport through the gas and through the porous shell of reduced oxide, the rate of gas flow, THIS paper describes a mathematical study of the chemical and physical processes that determine the rate of reduction of solid metal oxide with a reducing gas. The study was a part of a theoretical study leading to the development of a mathematical model for the simulation of the thermochemical behavior of the iron blast furnace. An essential feature of such and the volume of- space surrounding the sphere available for gas flow. The equation is applied to experimental data on vote of reduction of iron oxide in hydrogen. The equation serves as a model for predicting the course of reduction of a particle of. metal oxide in a shaft furnace. a model is an adequate mathematical relationship defining the rate of reaction in terms of all the important chemical and physical phenomena that affect the rate of reaction. This includes not only the reaction rate coefficients, equilibrium ratios, gas composition, and temperature, but also the relevant physical properties of the oxide, rate of gas flow, and relative volumes occupied by gas and solid. In many previous experimental studies of the rate of reduction of oxides by hydrogen or carbon monoxide, the rate of reduction was assumed to be controlled primarily by the chemical reaction at the

Jan 1, 1965

Papers in Classes A-Metal Mining, B-Milling and Concentration, H-Industrial Minerals, and I-Mining Geology are distributed in MINING TECHNOLOGY, which is issued every Other month. Papers in Classes C-Iron and Steel Division, D-Nonferrous Metallurgy and E-Institute Of Metals Division are distributed in METALS TECHNOLOGY, which is issued twice quarterly. Papers in Class G-Petroleum Division are distributed in PETROLEUM TECHNOLOGY, which is issued every Other month. TECHNICAL PUBLICATIONS in Classes F-Coal Division, J-Mineral Industry Education Division, K-Mining Administration, and L-Geophysics, are issued as separate pamphlets. Contributions are papers that when printed Or mimeographed are available, but Only On request. All the TECHNICAL PUBLICATIONS Of the F, J, K Or L classes, the TECHNOLOGYS and the CONTRIBUTIONS issued in 1945 are available at Institute headquarters, unless Otherwise noted. They are also On file in many public, university and technical libraries and, when so indicated in the list, the papers may be found in the TRANSACTIONS. An Institute member is entitled to One copy Of any TECHNOLOGY, TECHNICAL PUBLICATION Of the F, J, K Or L classes, Or printed Or mimeographed CONTRIBUTION. Copies Of TECHNOLOGYS and TECHNICAL PUBLICATIONS Of the F, J, K Or L classes listed have been mailed to members Of the Institute according to their registration by classes. CONTRIBUTIONS will he sent upon request. A member may purchase an additional copy Of a TECHNICAL PUBLICATION Of the F, J, K Or L classes, a paper in a TECHNOLOGY, Or a CONTRIBUTION at One cent a page; minimum charge, 25¢.

Jan 1, 1946

By T. Egleston

The treatment of the residues from the manufacture of sulphuric acid which contain small amounts of copper, silver and gold, has attracted considerable attention in Europe. They are successfully treated in several works on the continent, and in as many as twenty establishments in different parts of England. As the process must sooner or later attract attention in this country, I have put together my notes made in three of the most important establishments in Europe. These are the works at Hemixem near Antwerp, of Duisbourg in Westphalia, and of Oker in the Hartz. In the last works only, the ores are produced in the vicinity of the place where they are treated. The works at Duisbourg treat ores which come from the Rio Tinto mines in Spain, which often contain considerable quantities of arsenic. They are roasted in a number of different works along the Rhine for the manufacture of sulphuric acid. They are brought by boat and are landed at the works by steam-cranes. They are carried at once by a double-inclined plane worked by steam to the storagehouses to be kept, until treated. The wagons, after being weighed, are dumped. The ore is assayed at once, the assay-sample being taken from the boat while the ores are being discharged. They are all fine, and contain two to eight per cent. of copper and about sixty per cent. of iron, and a small amount of silver and gold. Their average composition is given below:

Jan 1, 1886

MODERN mining is based on drilling--everything else stems from that. U. S. and Canadian mining companies and suppliers of mining equipment are constantly seeking new techniques and tools for increased drilling efficiency. Ultimate goal is increased bit-against-rock time. Just how important their efforts are can be seen through a legitimate extension of available statistics. In Canada some 70 million ft of drilling per year is required. While the number of feet actually drilled in the U. S. is unknown, it is possible to compare U. S. and Canadian mineral production, excluding oil and coal. In the U. S. mineral value was $4200 million and across the border $836 million. Taking into account the number of drilled feet required to produce Canada's total, the U. S. total would be 365 million ft in 1953. A saving of 14 per ft would reduce over- all metal and nonmetal mining costs some $3.65 million per year. This does not take into account other indirect savings. Methods have changed and there have been structural and metallurgical advances in blasthole practice in the last ten years. The Editors of MINING ENGINEERING in the articles on the following pages present the most significant innovations coupled with results in the field. Environment plays an important role in selection of materials and equipment -but while unanimity does not exist throughout the industry in reference to drilling problems, a definite trend is evident. For the story of that trend read the articles on the following pages.

Jan 9, 1954

By W. P. Blake

Forty-five years have passed since I discovered the extensive and remarkable diatom-earth beds at Monterey, California., and now I have the satisfaction of bringing to notice still another wonderful deposit in the heart of Arizona. The Monterey beds mere described at the Philadelphia Academy,* and specimens were sent to Prof. J. W. Bailey, West Point, N. Y., at that time the leading American authority upon such microscopic relics of organic life. The earth from both localities is snow-white and pulverulent. It rubs off' like soft chalk upon the fingers when handled, and has the general appearance of chalk. But, unlike the Monterey beds, these newly-discovered deposits consist largely of volcanic ash, through which the siliceous shells of the diatoms are distributed. These deposits are in the central portion of the San Pedro valley,† in the southeastern corner of Pinal county. The region of their greatest development is a few miles south of the mining town of Mammoth, on the east bank of the stream, and near Redington, some 40 m. N. of Benson, on the Southern Pacific railway. The altitude is about 2600 ft. above tide. This portion of the San Pedro valley lies between the high Catalina and Rincon ranges on the west and the Galiuro mts. on the east. The Catalinas are composed chiefly of crystalline DIRECTOR OF THE ARIZONA SCHOOL OF WINES,

Jan 1, 1903

By Alfred Boyles

"Heredity"1 in cast iron has been a subject of much discussion. Numerous experimenters have found that the properties of gray iron may vary greatly without corresponding variations in composition or thermal treatment. The main structural difference in such cases is in the size and distribution of the graphite flakes and the explanations given usually attribute this difference to some chemical element not shown by ordinary analysis or to some physical factor, such as inclusions in the melt. It cannot be said that any of these theories is completely satisfactory. Much remains to be learned about cast iron and for this reason a study of the material was undertaken as a part of the program of fundamental research at Battelle Memorial Institute. A review of the literature indicated that very little systematic work had been done on the mechanism of freezing in cast iron. The experiments described below are largely concerned with that problem. Normal and "Dendritic" Cast Iron As examples of variation in type of structure, photomicrographs of two test bars of cast iron are shown (Figs. 1 and 2) and the composition and properties are given in Table 1. Both are common, unalloyed gray iron. Test bar No. 13 has normal graphite flakes while No. 49 has very fine, lacy graphite arranged in a dendritic pattern, the matrix in both being pearlite. These two types of cast iron are well known to foundry-men and need no detailed description.

Jan 1, 1937

By W. Hume-Rothery

IN recent interesting papers,1,2 Bardos et al. have described ternary Laves phases of the type A2(BsSi) and A4(B5Si3) where A = titanium vanadium, niobium, and so forth, and B = manganese, iron, cobalt, or nickel; other more complex formulae have also been established. In these phases, silicon plays the part of the smaller B atom of a Laves phase AB2, and the interatomic distances show that the effec- tive silicon radii lie between 1.16 and 1.21Å, and are thus very much smaller than the metallic radius of silicon for CN = 12. It does not seem to have been pointed out that these small atomic radii are almost the sape as the normal covalent radius of silicon (1.174Å). If, therefore, silicon acts as an acceptor of electrons as suggested by Bardos et al.,1 it appears to do so, not by the building up of a negatively charged silicon ion which would be large, but by the formation of what are very nearly or may be actually normal covalent bonds. Since a covalent bond contains two electrons, its formation would reduce the number of electrons available for bonding in other parts of the structure, and in this way the effect of silicon in stabilizing the o phase at high electron concentrations might be understood.

Jan 1, 1965

By W. Blaschke, E. Malysa

INTRODUCTION In recent years in Poland, a problem connected with the occurrence of a considerable amount of liberated galena grains in size fractions under 1mm has arisen in the zinc-lead processing area. Operating practices have included crushing of ore particles under 0.2 mm followed by flotation. Jigs were applied to separate the concentrates from size fractions under 10 mm and to prevent the galena overgrinding. However, the fractions being too wide, the jigs have not worked effectively, in spite of the great differences in specific gravities of galena, blende and gangue minerals. Fine galena grains move into light fractions in considerable amounts and hence are overground. Therefore, the flotation becomes difficult and galena is lost in its tailings. These losses could be avoided by introducing separation in the grinding and classification circuits. The amount of 0-1 mm fraction is great; therefore, the application of concentrating tables or other kinds of jigs is impossible from an economic point of view. Taking these factors into account, the possibility of application of pinched-sluices was investigated. These are simple devices without moving parts, they have a high output for the unit areas, and their water and energy consumptions are low. In this paper, the results of zinc-lead ores beneficiation in pinched-sluices are presented.

Jan 1, 1980