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By V. G. Mooradian

THE diffusion of metal atoms into the crystal lattice of another metal and the assumption of regular positions to form a homogeneous alloy are some of the most fundamental phenomena of structural metallurgy. The mechanism of this process has been the subject of a great deal of study from many viewpoints, but the picture is still far from complete. It is generally believed that if one metal is to diffuse into another, the first must have some solubility in the second1. This means that the solvent must be able to accommodate the stranger atoms, either on points of its own lattice or in the interstices between, without losing its own crystal-lographic identity. It is also a general observation that cold-working is a distinct aid in the diffusion process, causing it to take place with greater rapidity at the same temperature or with the same speed at a lower temperature. There is considerable doubt, however, as to the real significance of the deformation in its effect on the diffusion mechanism. Several factors associated with the cold-working may be responsible for the increased diffusion rate. The plastic deformation causes a distor-tion of the solvent lattice, which may be an aid in the assimulation of atoms of another kind. There are many references2 in the literature that suggest that some distortion or "loosening" of the lattice is necessary for atomic migration and that diffusion cannot take place in the undis-

Jan 1, 1935

By J. L. O’Brien, M. Suenaga, K. M. Ralls, V. F. Zackay

The effecls of aging a1 400°C on tile resistive transition at 4.2°K of a superconducling 70Zr-30Nb alloy are reporled. Microstrclural changes were studied by critical temperature, resistiue critical field, residual resistiuily, and microhardness measurements and by X-ray diffraction, optical microscoby, ad replication electron microscopy. The result of the aging treat- A defect-free Type 11 superconductor in a magnetic field above Hc1 cannot sustain a transport current runt is a fine array of w-phase pavticles with a mean center to center interparticle spacing of about 800A. At an aging time of 300 hr the maximum onset critical current density is rcached. The particle size at the maximum current density if about 4202. At times longer than 300 hr effective particle impingement leads to lower onset critical current densities. perpendicular to the applied field without power loss in the sample.'-3 This power loss is due to flux line motion caused by the Lorentz force and is manifested by a longitudinal voltage.4-6 When defects are present in the material, flux lines are pinned until the Lorentz force exceeds the "pinning force". That is, it is thought that flux lines reside in free-energy wells existing at the defects, and the critical Lorentz force is that which when integrated over distance will supply the free-energy difference necessary to move the flux

Jan 1, 1968

By J. L. Lytton, J. E. Dorn, L. A. Shepard

Single aluminum crystals were subjected to creep in simple shear on the (111) planes in the slip direction. The activation energies for creep were calculated from the effect of small abrupt changes in temperature on the creep rate just before and immediately following the temperature change. The results definitely establish the fact that creep of single aluminum crystals occurs by-three unique processes, characterized by thethree distinct and isolatable activation energies: The 35,-500-cal-per-mole activation energy obtained at the highest temperatures was ascribed to a dislocativationtion climb process; the 28,000-cal-per-mole activation-energy process, occurring over the intermediate-temperature range was attributed to a cross-slip mechanism; and it was suggested thot the 3400-cal-per-mole process observed below 400°K may be the Peierls energy. THE most pertinent question regarding the phenomenon of creep in crystalline materials is concerned with the identity of the crystallographic mechanisms of deformation that control the creep rate. For many years slight progress was made in uncovering the basic mechanisms for creep. Over the past 10 years, however, two parallel lines of investigations have contributed to a more definitive understanding of the processes involved in creep. The extensive development and maturing of dislocation theories for deformation of crystalline materials' proved to be of paramount importance for this progress. And second in importance was the replacement of the former prosaic methods of creep testing by new techniques'." which were especially

Jan 1, 1959

By F. F. Schmidt, H. R. Ogden, E. S. Bartlett

ThE solubility of carbon in tantalum has been reported to be very low at temperatures below 1500 C,1'2 increasing to at least 0.02 wt pctl at the eutectic temperature of 2800°C. The solubility limits at low temperatures were based on metallo-

Jan 1, 1963

By Elliott J. Roberts

The theory is developed that the tons ground through a given mesh per day in a wet ball mill is proportional to the percent plus that mesh in contact with the balls and the net power applied to the balls at this point. A grindability test is described.

Jan 12, 1950

By AIME AIME

ONE unique distinction can be claimed by the new Chairman of the Coal Division, C. E. Lawall: he is the only A.I.M.E. member also a university president, though several engineering colleges are headed by Institute members. Only last year he was promoted from director of the school of mines to president of West Virginia University, following a term as acting head of that institution of over 3000 students. He was born in Catasauqua, in eastern Pennsylvania, on Nov. 21, 1891, and went to Lehigh, receiving an E.M. in 1914, and an M.S. seven years later. His engineering career began in the Pittsburgh Testing Laboratories. After three years there he came to Palmerton for

Jan 1, 1940

A Progress Report of The Engineering Foundation, which is a history of the Foundation and a report of its activities, has been printed. A limited number may be obtained by members of the Institute by writing to the office of the Institute or to the Secretary of the Foundation.

Jan 11, 1919

By H. M. Zoerb

Based on the belief that operating details are a definite contributing factor to major economies, this paper traces the development of crushing cavity design in Symons cone crushers to attain maximum liner utilization. Wear rates are analyzed and compared in this presentation and drawings illustrate succeeding design changes.

Jan 6, 1953

By A. L. Mular

Optimization strategies of possible interest to mineral processing are reviewed and typical strategies initiated in processing plants to date are discussed. Both On-Line and Off- Line optimization procedures have been employed by industry, assisted either by operators or by digital computers. In every case, dollar benefits have accrued.

Jan 1, 1976

By W. C. PAGE

HARVEY S. MUDD has the unusual distinction of having virtually inherited a Directorship in the -A.I.M.E., for he was appointed to the Board to fill the unexpired term of his father in 1926. Since then he has served as a Director continuously until 1936, and now he is a candidate for Vice-President. One of the first words that young Harvey tried to say was "ore," for he was born in Leadville, Colorado, in the heyday of that camp, where Seeley W. Mudd for years ran the Small Hopes mine. Stanford and Columbia gave him his mining education, and the Shattuck-Arizona, at Bisbee, his first job. Afterwards he examined many

Jan 1, 1937

By AIME AIME

BOB VAN PELTS boyhood days in the mining atmosphere of Colorado apparently influenced him to direct hip college education first towards geology, at. Cornell College, then to mining at Michigan College of Mines and finally to graduate work in geology at the University of Chicago. He taught geology at his alma mater. Cornell College. served as geologist for the National Park Service then was on the staff of the Illinois Geological Surrey investigating and mapping mineral resources, and in 1928 because chief of the department of geology, mining, and metallurgy in the newly organized Rosenwald Industrial Museum (now the -Museum of Science and Industry,). He was made assistant director of the Museum in 1931.

Jan 1, 1941

By G. Wranglen

On account of the possibility of isolating carbides in steel it is generally assumed that the electrode potential of iron carbide is more noble than that of ferrite.1,2,3,4,5 Differences from 0.032 V1 to 0.4 V4 have been recorded. However, it is important to realize that the more noble behavior of cementite in relation to ferrite is not an issue of thermodynamics but of reaction kinetics. Theoretically, cementite is less noble than ferrite, which is a direct consequence of its thermo-dynamic instability. With the value ?F°298 = +4700 cal per mol for the free energy of formation of cementite6 it is easily calculated that the electrode

Jan 1, 1950

By Richard H. Terhune

Slag and matte, in lead and copper smelting, are, for convenience of removal, tapped into pots of small capacity, usually of paraboloid form, of cast-iron, weighing 275 to 300 pounds, and holding the same weight of slag. As in many smelting districts one ton of ore makes a ton and a quarter of slag, a large number of pots is needed to equip an ordinary plant. Sudden and frequent expansion of the solid bowl causes the pots to crack at the bottom in a few months, and the matte, a very fluid sulpliide, enters these rough fissures and speedily corrodes its way through the vessel. 1 find, from one year of practice with a slag-

Jan 1, 1887

M. A. Hanna is investigating a nickel prospect near Riddle, Ore. Drilling is under way and a prospect shaft is being put down to obtain samples for metallurgical test work. The deposit is favorably situated for open pit mining. The property had been drilled previously by the USGS and by Freeport Sulphur Co. A $75,000 laboratory pilot plant will begin operations this year to determine if economic beneficiation of a deposit of low grade iron ore, being examined by M. A. Hanna in the Iron River, Mich., district, is possible. Three miles east of Randville 2560 acres of land have been acquired, and drilled, over the last 2 years. The ore is reported to be 34 pat Fe.

Jan 6, 1951

By P. Schwed

IN determining the mechanism responsible for sintering, the most direct procedure available is the comparison of the observed time and temperature dependence of the process with the dependence to be expected upon the basis of each conceivable mechanism. This was done by Kuczynskil who, in treating the mechanism of surface diffusion, postulated, in effect, that the concentration gradient of vacancies is different from zero only within the neck. This procedure was recently questioned by Cabrera' who assumed, on the contrary, that diffusion occurs only in the region outside the neck. In the present note, the calculations are performed without restriction on the region of diffusion. To carry out this objective it is first necessary to

Jan 1, 1952

By Ken Sublette

The mining industry has been a leader in the application of ultrasonic level monitoring systems, utilizing the "sonar-in-air" concept for the accurate inventorying of material not only as an end within itself, but going on to activate alarms, turn off feeders, operate tripper systems, and totalize the inventory in numerous bins as well as other more sophisticated applications. The virtues of ultrasonic level monitoring are no doubt appreciated by most users. However, to be of maximum service to the expanding mining industry, the manufacturer must be fair in pointing out ultrasonic's limitations as well as its virtues. The limitations can be surmounted with new technology and through a proper understanding of the principles of operation and application.

Jan 6, 1974

By R. K. Agarwal

Transforming from a mere novelty field of science to a well-recognized branch of engineering, the scientific discipline of rock mechanics continues to mature. The past decade has witnessed an unprecedented in- fusion of scientific research approach into mine design. In the preceding year alone, there were six national and international congresses which also indicated the increased interest, in rock mechanics and participation by scientific personnel with diversified backgrounds. It may be presumptuous to conclude that the time, effort and money spent thus far on procedures for mine structure design have necessarily resulted in the evolvement of design techniques; but certainly the prospects of evolving such techniques art: more promising at present than ever before.

Jan 1, 1970

By W. L. McMorris, Shiou-Chuan Sun

The Convertol process was first described in Ger- many by Muschenborn1 in 1952. In the U. S. Fraser2 reported this new process in 1953, and Brisse and McMorris-resented the results of a Convertol pilot plant at the Alpheus preparation plant in Gary, W. Va., illustrating the mechanics of the process by a series of sketches. The purpose of the present investigation was threefold: 1) to determine the relative effectiveness of various oils and hydrocarbons for recovering coal by the Convertol process, 2) to ascertain the behavior of coal pulps in this process under various operational conditions, and 3) to compare Convertol with flotation in the recovery of fine coals.

Jan 11, 1959

By B. F. Peters, J. Gordon Parr, E. R. Macgregor

A SERIES of seven hypoeutectoid alloys, up to 18.2 atomic pct Mn, was made by the levitation melting technique. The loss of weight on melting was considered to be entirely due to volatilization of manganese, and compositions were computed on this basis. Filed samples (—200 Tyler mesh) were helium quenched from 1000°C after soaking for 5 min by a technique already described.' Quenched Alloys -Assessments of the amounts of a phase produced and the hardness of the quenched alloys are summarized in Fig. 1. The experimental techniques and calculations involved have been described previously. The amount of a decreases as manganese content increases, until at 10.6 pct Mn only a trace of a' is observed. Previous

Jan 1, 1957

By Milton E. Wadsworth, Edward M. Eyring

Better understanding of solid surfaces and their associated adsorption products is of both academic and practical value. The study of detergents and their behavior in cleaning surfaces is fundamentally related to the nature of the products adsorbed and their ability to compete for certain surfaces. Similarly in flotation, the nature of the adsorbate before and after adsorption is basic to clear understanding of the process. The recently developed pellet technique employing infrared spectroscopy provides a powerful tool for the study of solid surfaces. Absorption bands, which are infrared-active, may be observed for adsorbed products. Also any changes in the surface substrate that occur as a result of adsorption may be detected by means of differential spectra

May 1, 1956