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By Charles A. Ashburner

The existence of natural gas-springs in Pennsylvania and the adjoining States west of the crest of the Allegheny Mountains was known to the earliest settlers. Possibly the first gas obtained from a well was at Fredonia, Chautauqua County, N. Y., where a well was sunk on the bank of Canadaway Creek, near the Main Street bridge, in 1821, and sufficient gas obtained for 30 burners, the inn having been illuminated by the gas when General Lafayette passed through the village about 1821. In 1858 another well was drilled, which supplied 200 burners. A still larger one was drilled to a depth of 1200 feet in 1871. According to Mr. E. J. Crissey, Secretary of the Fredonia Natural Gas Light Company, the average monthly supply of these wells in 1880 was 110,000 cubic feet. Since 1859, when the drilling of oil-wells in Western Pennsyl-

Jan 1, 1886

By F. M. Yans, A. D. Donaldson, A. R. Kaufmann

Beryllium was mixed by powder. metallurgical techniques with copper, nickel, iron, and chromium, respectively, to form beryllium -rich binary alloys which Mere then extyuded and rolled transtverse to the extrusion direction. The effect of each alloying element was determined by tensile testing. In solid solution, small amounts of iron and nickel had an embrittling effect, while copper in solution increased the strength but had no effect on ductility. The effect of chromium was complicated and not readily explainable. Observations concerning the planes and modes of fracture were made. BERYLLIUM possesses some very attractive properties for general design applications, especially its strength to weight ratio which is approximately twice that of aluminum and three times that of stainless steel. Equally significant, however, is its combination of high moduli , high strength (approximately 70,000 psi tension and 40,000 psi shear), and low density (0.0658 Ib per in.3), which has made it a potentially important structural material for use in high-speed aircraft and missiles. The main attractions of beryllium are most marked when compared to other constructional alloys now in use. For example, while its density is approximateiy that of magnesium, its modulus of elasticity is approximately seven times that of magnesium, three times that of titanium, four times that of aluminum, and 1 1/3 times that of steel. Furthermore, its relatively high strength and high melting temperature permit design for service temperatures to about 1100°F. It is felt by the aircraft industry in general,' that the high cost of beryllium can easily be amortized by the savings in fuel costs, and increases in aircraft payload and range. The only factor which has prevented the use of the metal in structural applications is its lack of sufficient ductility. It is this property that has retarded the development and utilization of beryllium. Beryllium's modes of deformation, Fig. 1 indicate that the main fracture planes at room temperature in a randomly oriented sample are the (0001) basal planes; the (1150) prism planes are the planes of secondary fracture.' Klein, Macres, Woodard, and Greenspan3 obtained elongations of up to 40 pct in beryllium sheet rolled above 700°C when the (0001) basal planes were oriented parallel to the plane of the sheet (see Fig. 2).

Jan 1, 1962

By R. J. Wysor

MORE than two years ago, in making efficiency tests on our hot-blast stoves, I was surprised to discover a marked difference in temperature as indicated by a pyrometer inserted near a stove on blast, and the regular recording instrument situated near the bustle pipe. A special hole was then provided at the junction of the hot-blast main and the bustle pipe, and portable pyrometers with bare fire ends were used, both at this point and in the stove necks. I had occasion to make a number of such tests on various stoves on the same furnace, the difference in temperature as shown by the two pyrometers varying chiefly with the temperature of the blast, and the distance of the stove from the furnace. However, this difference was always great, often averaging above 100° F., for the entire period of a stove on blast. Later, experiments were made with similar results on another group of stoves. The pyrometers used were properly standardized and checked against each other before and after each test. However, there was still a slight doubt as to the accuracy of the results obtained, as subsequently explained. But I have obtained corroboration of the magnitude of heat losses from blast-furnace hot-blast mains from two independent sources. I have learned from H. A. Brassert, Superintendent of Blast Furnaces, South Works, Illinois Steel Co., that he has recently clone some experimental work similar to my own, and found temperature drops of the same order of magnitude. Also, C. R.. Lyle, of the Armstrong Cork Co., has made some interesting theoretical calculations, based oil the thermal conductivity of fire brick, for the particular conditions of several of our tests; and his theoretical interpolations, all facts being considered, check our actual observations fairly well. I understand that Mr. Lyle expects to publish the results of his investigations.

Jan 10, 1915

By George Rice

SOME form of longwall mining is generally used in Continental Europe; also in Great Britain where the coal is weak and friable, or the coal bed provides material for pack walls and filling, or where the bottom is soft and squeezes up easily, or the roof is pliable, or the bed is thin and brushing provides building material, or the thick multiple seams are mined in layers, such as the 24-ft. seam at Weymss, Scotland or the 10-yd. pitching bed near Coventry, England. Pillar methods have been retained in British fields where the coal beds are from 5 to 9 ft. (1.5 to 2.7 m.) thick, and free from thick partings or binders or without draw slate, which would provide waste rock for pack walls, or where the roof is hard and requires shooting to bring down and also the bottom or floor is comparatively hard. The room-and-pillar system, by which probably 95 per cent., of the coal of the United States is produced, is now found in only a few mines in Wales, where it is known as the pillar. and .(single) stall method. The American room-and-pillar system is not equivalent to the bord-and-pillar or stoop-and-room system. The essential difference between the bord-and-pillar and the average American room-and-pillar system is probably due to natural conditions. The majority of the coal mines in the United States have a depth of less than 700 ft. (213.m.). The bulk of the coal mined in Europe comes from a depth of more than 1200, ft., while the deepest mines in Great Britain, Belgium, and France reach 3500 to 4000 ft. In deep workings wide spans are impracticable, even with the use of abundant timber; accordingly, as the mines in the United States become deeper the rooms will become narrower and the pillars thicker, and the bulk of the coal will be extracted on the retreat. It is generally conceded, without reference to the cost of production, that the larger the pillars left on the first mining, the more thoroughly can the, coal be extracted. In Europe complete extraction is generally compelled either by the lessors or by the governments; whereas in this

Jan 2, 1921

By G. S. Rice

Some form of longwall mining is generally used in Continental Europe; also in Great Britain where the coal is weak and friable, or the coal bed provides material for pack walls and filling, or where the bottom is soft and squeezes up easily, or the roof is pliable, or the bed is thin and brushing provides building material, or the thick multiple seams are mined in layers, such as the 24-ft.seam at Weymss, Scotland, or the 10-yd. pitching bed near Coventry, England. Pillar methods have been retained in British fields where the coal beds are from 5 to 9 ft. (1.5 to 2.7 m.) thick, and free from thick partings or binders or without draw slate, which would provide waste rock for pack walls, or where the roof is hard and requires shooting to bring down, and also the bottom or floor is comparatively hard. The room-and-pillar system, by which probably 95 per cent. of the coal of the United States is produced, is now found in only a few mines in Wales, where it is known as the pillar and (single) stall method. The American room-and-pillar system is not equivalent to the bord-and-pillar or stoop-and-room system. The essential difference between the bord-and-pillar and the average American room-and-pillar system is probably due to natural conditions. The majority of the coal mines in the United States have a depth of less than 700 ft. (213 m.). The bulk of the coal mined in Europe comes from a depth of more than 1200 ft., while the deepest mines in Great Britain, Belgium, and France reach 3500 to 4000 ft. In deep workings wide spans are impracticable, even with the use of abundant timber; accordingly, as the mines in the United States become deeper the rooms will become narrower and the pillars thicker, and the bulk of the coal will be extracted on the retreat. It is generally conceded, without reference to the cost of production, that the larger the pillars left on the first mining, the more thoroughly can the coal be extracted. In Europe complete extraction is generally compelled either by the lessors or by the governments; whereas in this country it has been more largely a question of competitive cost of production, or the support of the surface in the flat farming districts of the

Jan 1, 1922

By G. H. Kesler, C. E. Dryden, J. H. Oxley

Rates of heat- and mass-transfer from rods to recirculating air were determined within a one-quarter-scale model of a metals deposition bulb. The dependence of local and averaged rates of transfer upon outlet geometry, number of rods, position upon a rod, and airflow rate was established for flow patterns created by radial and tangential air inlets. The results are given a qualitative interpretation in terms of rates and distribution of metal deposition in a prototype deposition bulb. IT is well known that a number of metals can be prepared from volatile compounds containing them by causing dissociation of their compounds to occur at heated surfaces. Examples of such metals include silicon, titanium, zirconium, and aluminum, which can be prepared from their halides. While the ability to prepare high-purity metals by this technique is of importance in itself, the rate of deposition of metal also is important in considering the commercial potential of such a process. If the over-all process of deposition is broken down into separate steps of transport of materials to and from the heated deposition surface and establishment of chemical equilibrium at the surface, as was described in a recent paper,1 then since surface temperatures are usually high and surface equilibrium is attained very rapidly, the rate-controlling step can be considered as either that of transport of reactants to the surface or of transport of products other than deposited metal away from the surface. These two transport steps are related through the reaction stoichiometry. It can be shown1 that the rate and distribution of metal in such a transport-controlled process are determined by the over-all and local mass-transfer coefficients in conjunction with the equilibrium conversions at the hot surfaces. The rate relationship is: w = [KA(y a-y s)] B.E where the bracketed group is the rate of arrival of the reactant at the surface of area A as determined by the mole fraction driving force (y a - y s) and the convective transport constant K. The factor B is the weight fraction of metal in the reactant, and E is the equilibrium fractional conversion to metal. Numerical values of y, and y, are fixed by the vapor composition and the equilibrium compositim of reactant at the surface; and E can be determined by thermodynamic calculations or by experiment. However, values for the convective coefficient K are available generally only for systems of simple geometry, such as cross-flow past a rod or sphere or parallel flow past a flat plate or through a tube. Often it is necessary to work with systems of more complex geometry and in which the vapor flow may not be uniform or exactly parallel or perpendicular to the surface. It is possible, of course, to establish working correlations for these more complex systems by direct experiment; but the experiments usually are costly in both time and money. To circumvent this objection and to aid in arriving at an understanding of the relationships and interactions of the process variables, it is helpful to construct a model of the flow system in which air, water, or other convenient fluids can be substituted for the process vapors and with which mass-transfer measurements or analogous he at-transfer measurements can be made upon a simulated deposition surface. By this means, a large number of measurements can be made in a reasonable time, and the correlation of these results can be applied to the prototype system. Examples of the application of these techniques are to be found in the literature (e.g., Ref. 2). It is the purpose of this paper to illustrate these techniques by description of a model study which was done at Battelle Memorial Institute. The work to be described was of a preliminary nature; the investigation subsequently was extended to develop quantitative relationships among the significant dimensionless transport, geometric, and flow parameters. This more detailed study will be the subject of a future paper.

Jan 1, 1962

William B. Cogswell, member of the Institute since 1872, died on June 7, 1921, at his home in New York City, after an illness of about six weeks occasioned by an infection of the middle car. Mr. Cogswell is survived by his wife, Mrs. Cora Brownell Cogswell; a son-in-law, and three grandchildren. His first wife died in 1877. William Cogswell was born at Oswego, Sept. 22, 1834, and was taken to Syracuse by his parents when he was four years old. He attended Hamilton Academy and private schools in Syracuse and Seneca Falls. In 1843, he visited England with his parents and brought back a set of drawing instruments, which led to a series of lessons in architecture under Luther Gifford, the only architect in Syracuse at the time. The boy drew many building plans and one set was used for the old Globe Hotel in Syracuse, erected in 1846 and 1847. In 1848, when only 14, he spent a year with a party that was surveying the route of the Syracuse & Oswego R. R. and relaying the tracks of the Utica & Syracuse R. R. He studied civil engineering at the Rensselaer Polytechnic Institute, Troy, for three years, but left that institution in 1852 without receiving his degree. Many years later, in 1884, the degree of C. E. was conferred upon him. During the three years following 1852, Mr. Cogswell served as an apprentice in machine shops at Lawrence, Mass., under the superintendence of John S. Hoadley. About 1856, he was made manager of the machinery department of the Marietta & Cincinnati R. R., at Chili-cothe, Ohio, and three years later became superintendent of the Broadway foundry at St. Louis, Mo. In 1860, in Syracuse, Mr. Cogswell was associated with William A. and A. Avery Sweet in the formation of Sweet Bros. & Co., which later became the Whitman & Barnes Mfg. Co. At the outbreak of the Civil War, Mr. Cogswell received a civilian appointment as mechanical engineer in the United States Navy. During 1860 he was located at Port Royal, S. C., having general supervision over the work of fitting up repair shops at five widely separated stations on the Atlantic seaboard and Gulf of Mexico. In this year his genius and resourcefulness were notably shown. He literally launched a naval machine shop, so that warships could be repaired without leaving, and thereby weakening, blockades against Southern ports. The machine shop was assembled by Mr. Cogswell and shipped by boat to Port Royal. There an old whaler was made over for machine shop purposes and Mr.

Jan 1, 1922

William B. Cogswell, member of the Institute since 1872, died on June 7, 1921, at his home in New York City, after an illness of about six weeks occasioned by an infection of the middle car. Mr. Cogswell is survived by his wife, Mrs. Cora Brownell Cogswell; a son-in-law, and three grandchildren. His first wife died in 1877. William Cogswell was born at Oswego, Sept. 22, 1834, and was taken to Syracuse by his parents when he was four years old. He attended Hamilton Academy and private schools in Syracuse and Seneca Falls. In 1843, he visited England with his parents and brought back a set of drawing instruments, which led to a series of lessons in architecture under Luther Gifford, the only architect in Syracuse at the time. The boy drew many building plans and one set was used for the old Globe Hotel in Syracuse, erected in 1846 and 1847. In 1848, when only 14, he spent a year with a party that was surveying the route of the Syracuse & Oswego R. R. and relaying the tracks of the Utica & Syracuse R. R. He studied civil engineering at the Rensselaer Polytechnic Institute, Troy, for three years, but left that institution in 1852 without receiving his degree. Many years later, in 1884, the degree of C. E. was conferred upon him. During the three years following 1852, Mr. Cogswell served as an apprentice in machine shops at Lawrence, Mass., under the superintendence of John S. Hoadley. About 1856, he was made manager of the machinery department of the Marietta & Cincinnati R. R., at Chili-cothe, Ohio, and three years later became superintendent of the Broadway foundry at St. Louis, Mo. In 1860, in Syracuse, Mr. Cogswell was associated with William A. and A. Avery Sweet in the formation of Sweet Bros. & Co., which later became the Whitman & Barnes Mfg. Co. At the outbreak of the Civil War, Mr. Cogswell received a civilian appointment as mechanical engineer in the United States Navy. During 1860 he was located at Port Royal, S. C., having general supervision over the work of fitting up repair shops at five widely separated stations on the Atlantic seaboard and Gulf of Mexico. In this year his genius and resourcefulness were notably shown. He literally launched a naval machine shop, so that warships could be repaired without leaving, and thereby weakening, blockades against Southern ports. The machine shop was assembled by Mr. Cogswell and shipped by boat to Port Royal. There an old whaler was made over for machine shop purposes and Mr.

Jan 1, 1922

By Robert Ammon

THE milling practice at Mascot, at present, consists of dry crushing to 5/8 in., jigging, fine grinding, and flotation. The ore arrives at the mill from two mines, No. 1 mine shaft being located in the mill proper, and No. 2 mine shaft being situated about 2000 ft. east of the mill. No. 2 mine is served by a coarse-crushing plant and aerial tramway to the mill bins. In jigging the No. 2 mine ore, 50 per cent. of the mill feed is rejected by the jigs as a jig tailing ranging from 5/8 in. to 10 mesh; the balance of this ore, after removing a jig concentrate, is ground to flotation feed. In jigging No. 1 mine ore, approximately 80 per. cent. of the mill feed is rejected as a coarse jig tailing, and the balance is ground to flotation feed without the removal of a jig concentrate. The difference in the treatment is due to the fact that No. 2 mine ore carries a higher content of zinc than that from No. 1 mine. Of the total concentrates produced, 30 per cent. are made on jigs and 70 per cent. by flotation. At present, 1350 tons of No. 2 ore and 800 tons of No. 1 ore are treated each 24 hours. The recoveries for a typical week are as follows: Heads 3.55 Jig concentrates 61.30 Jig tails 0.80 Flotation concentrates 60.60 Flotation tails 0.09 Extraction 86.50 The associated minerals are a straw-colored sphalerite, dolomite, calcite, pyrite, quartz, and a small amount of greenockite, which occurs as a stain and sometimes small crystals along with sphalerite, but is comparatively rare. Pyrite is present in small quantities, usually less than 0.5 per cent.; quartz occurs in bands a few inches thick. A complete analysis of the ore is as follows:

Jan 9, 1924

By H. T. McAdams

Current theories of fracture maintain that brittle materials contain flaws or regions of weakness at which fracture originates. Whether a particular flaw grows depends upon the stress distribution in its vicinity and upon the presence of other stress relieving mechanisms capable of absorbing the applied energy. Under load, therefore, certain of these flaws will be activated, and the resulting fragments will have a size distribution determined by the spatial distribution of active flaws. Gaudin and Meloy,1 assuming a random occurrence of flaws, have derived the size distribution of fragments as

Jan 1, 1965

By Joseph S. Malesky

The discovery and development of explosives mark one of the most important findings in the history of civilization. Without explosives our vast economic enterprise concerning the mining of coal, copper, iron, aluminum, and various other ores could not function. Explosives are used in all kinds of construction works, in the razing of old buildings, blasting of trenches, driving of tunnels, and in many other instances common to our everyday life. For these reasons explosives are rightfully referred to as the forerunner of progress. An explosive may be defined as a substance (usually a mixture) that, when flame or shock is applied, yields readily to rapid combustion or oxidation, accompanied by the formation of such relatively large quantities of gases as to produce much violence and pressure which, in turn, react against their surroundings and cause what is termed an explosion. By their very nature the action of explosives is destructive and disruptive of adjacent materials. Decomposition of explosives can occur through deflagration, which is rapid burning or combustion, as in the case of black powder, or through detonation, which is an almost instantaneous disruption, as in the case of dynamites and blasting agents. HISTORY OF BLASTING WITH EXPLOSIVES At one time workmen obtained stone blocks for building by grooving the rock with crude picks, driving wooden wedges into niches in the rock, and pouring water on the wedges; the swelling of the wood forced out the blocks. As late as the 17th century, fires were placed against the face of rock to crack it, and water was sometimes dashed on the heated rock to shatter it by sudden cooling. The progress of our country is synonymous with advancement of the improved manufacture and extended use of explosives. Coal had been

Jan 1, 1981

By Alexandre Mussard

How do you make a mine out of 500 000 kg (1.1 million lb) of uranium oxide contained in a low-grade deposit with high clay content? Confronted with these limited reserves and mineralogical problems at France's St. Pierre du Cantal uranium deposit, engineers adopted a rather unusual mill process to keep capital costs to a minimum. Crushing and grinding were eliminated by using a high pressure monitor to slurry ore directly from stockpiles. After mechanical separation of the high-grade fines from low-grade sand, the sand fraction is washed of clay to increase permeability and then it is heap leached. Fines are sent to agitated vessels for acid leaching, and the pulp from this operation is diluted by pregnant solution from the heap leaching.

Jan 10, 1979

By Gary E. Parish

TABLE OF CONTENTS Contents I. Introduction II. Purpose of the Paper III. Historical Perspective A. Existing Sources B. New Sources (NSPS) C. Hazardous Pollutants (NESHAPS) D. Enforcement/Judicial Review 1. Title I Enforcement 2. Title III Enforcement 3. Information Gathering E. Summary IV. The Clean Air Act Amendments of 1977 (1977 Act) A. SIP-Related Provisions 1. Section 107(d) - Geographic Boundaries 2. Section 108 - Air Quality Criteria 3. Section 109 – NAAQS 4. Section 110 – SIPs 5. Section 122 and Sections 402 and 403 of P.L 95-95 – Unregulated Pollutants 6. Emission Offsets – Interpretive Ruling (I.R.) B. PSD Provisions - Part C. 1. Regulations Under the 1970 Act 2. The 1977 Act 3. Regulations Under the 1977 Act C. Visibility Protection - Part C, Subpart 2 D. Non-Attainment Provisions - Part D E. Monitoring and Modeling F. NSPS G. NESHAPS H. Enforcement/Judicial Review 1. Title I 2. Economic Enforcement 3. Title III Enforcement/Judicial Review (a) Section 304 (b) Section 307 4. Summary V. Special Problems and Opportunities for the Uranium Industry A. End Use B. Transportation C. Milling/Processing D. Extraction E. Exploration/Discovery F. General VI. Conclusions Appendix A Footnotes

Jan 1, 1979

By L. D. Godshall

The extreme difficulty of obtaining a short and, at the same time, exact method for the determination of gold and silver in copper-materials has been well illustrated in "Assays of Copper and Copper-Matte," and its discussion, by Dr. A. R. Ledoux and other leading authorities on this subject.* Two general methods were used by the numerous assayers who took part in the symposium initiated by Dr. Ledoux, and whose results are given in the paper and discussion. One of these is the dry or fire-method, consisting of scorification and cupellation, the former being repeated if the percentage of copper is very high, all slags and cupels being assayed and the results so obtained added to the ordinary assay; and the copper retained by the silver buttons being determined and deducted from the combined weight of the buttons obtained from the assay of the original material, the scorification-slag, and the cupel. The other is the wet or combination-method, which, while not involving so much work, requires a longer time. Briefly, it is as follows : The material to be assayed is dissolved in nitric acid, the solution is diluted, and the fine undissolved gold is collected by means of sulphate of lead, formed by the addition of lend acetate and sulphuric acid to the solution, After standing from 12 to 24 hours, the precipitate is filtered off, and the silver in the filtrate is precipitated as a chloride or bromide, and collected by means of sulphate or bromide of lead. The solution containing this precipitate in suspension is again allowed to stand until the precipitate has settled. It is then filtered; both precipitates, containing the gold and silver, are dried, ignited and scorified, either separately or together, and the result is cupelled in the usual way.

Jan 1, 1901

Thus far virtually the sole theme of the conservationist has been the preservation of natural resources. Little thought has been devoted to the conservation of America's most significant asset-her people. True, considerable effort has been devoted to conserving man's physical strength by the invention and application of labor-saving machinery. Notable progress has been made also in the conservation of man's health through important discoveries in medicine. However, little if any positive success has been achieved in the conservation of the most valuable attributes of man-intellect, skills, manpower. Human resources are interrelated and interdependent. There is no monopoly on knowledge or skills' or human energy. No one must sell them short. All the knowledge and all the skills and all the energy possessed by all men are required to render all the services needed by all men. One of the major sources of wasted manpower is found in the nation's schools, with an educational system based on the outmoded theory of uniform education for all. Actually, if democracy means free initiative for the individual, and unlimited progress at the maximum rate of speed of which the individual is capable, then our public schools are not democratic in-

Jan 1, 1950

By M. L. Fuller

DURING the last several years many papers have appeared dealing with the structure of highly polished metal surfaces. The awakening of interest in this subject is due to the applicability of the electron diffrac-tion technique to the study of surfaces. The original theory of Beilby1 considered the surface of polished metals as of the nature of a super-cooled liquid or a vitreous, amorphous solid. The electron diffraction effects from polished metals have been interpreted by many to be a direct experimental proof of the correctness of the Beilby theory. This inter-pretation has been strongly opposed by others, so that at the present time the subject is in an uncertain and controversial state. In the present paper new, and hitherto unpublished, electron diffrac-tion effects from polished zinc are described. These observations indicate that the polished surface of zinc is crystalline.

Jan 1, 1938

By J. PARK

Discussion of the paper of J. PARSE CHANNING, presented at the New York meeting, February, 1915, and printed in Bulletin No. 99, March, 1915, pp. 529 to 538. FRED H. RINDGE, JR., * New York, N. Y.-It is interesting to note that although this movement was started only seven years ago at Yale, it has spread in that brief time to 200 colleges and technical schools, anti thousands of men are interested in it. There are 3,000 graduates who became acquainted with the movement in college days anti are now promoting the industrial betterment idea all over the country. Some of these men are employed entirely in this work, and the number of such workers is constantly increasing. We feel we are really doing a very fundamental thing in getting so many coming engineers and prospective employers of labor to interest themselves in these things which we have been discussing this morning; these things which are so vital to efficiency and success in any line of business or engineering to-clay. Of course the institutions located in our large industrial centers have the greatest opportunity for practical service. But I have just returned from one college, Pennsylvania State College, where 300 engineering students in three clays signed up as interested in this movement and as anxious to take active part in the work this summer. That is one of a number of colleges situated in towns where there are 110 industrial opportunities. Therefore, their field of service must be where they work

Jan 5, 1915

By Frederic P. Dewey

The improvement in leaching introduced by the Russell process has stimulated the development of processes for refining lixiviation-sulphides. In the early days several processes for dealing with the sulphides were proposed, and some of them were tried more or less ; but the business finally settled down to sending the sulphides to the smelters, although this was known to be both troublesome and expensive. In 1891 Mr. C. A. Stetefeldt* introduced at the Marsac mill, Park City, Utah, an unpatented process, built up out of the general fund of information available. It consisted in matting the sulphides, grinding, roasting, grinding again, and dissolving the copper out in diluted sulphuric acid, then melting the silver and crystallizing the bluestone. It did not yield fine bullion, hence the bullion had to be refined as well as parted; besides, there was some loss. This process was thoroughly tried at the Marsac refinery and then a year's run was made, the net result of which was that it did not prove sufficiently better than the sending of the sulphides to the smelters to warrant its substitution for that practice. In 1893 the Dewey-Walter Refining Company undertook the refining of the Daly sulphides in the Marsac refinery by the sulphuric acid process, upon which two United States patents ? have been issued to the writer. Naturally, difficulties were encountered in starting a new process, and most of 1893 was taken up in getting it into smooth working order; but in 1894 a run was started, in which all the regular sulphides produced by the

Jan 1, 1897

By D. L. Albright, G. A. Colligan

An investigation has been conducted to determine the nature of the crystallographic substructure of nickel and a 1.0 wt pct Ag-Ni alloy which had been undercooled 105°C prior to solidification. A rotating back-reflection X-ray technique and modified Weissmann diffractometer were used to orient single-crystal sections from these poly-crystalline ingots and to determine the substruc-tural features of these single crystals, The sub-grain size in the pure nickel ingot is 0.5 mm diam while the silver-doped nickel subgrain size is only 0.1 mm diam. The misorientation between adjacent subgrains is approximately 1 deg of arc in both ingots, and the spread of orientation of sub-grains about the mean orientation of the crystal is 5 deg of arc in both ingots. The addition of silver results in a stable impurity substructure which is preserved during isothermal solidification and subsequent cooling to room temperature. In the absence of silver the initial impurity substructure is destroyed by dislocation interactions which produce a secondary substructure which grows to a size five times larger than the initial substructure. THE process of undercooling a metal entails cooling of the molten sample below the equilibrium freezing point without the occurrence of solidification, i.e., by exercising proper constraint over the experimental variables contributing to nucleation in the melt. The current work of walker1 and Colligan Metal reports undercooling large continuous samples of nickel by imposing appropriate restrictions upon the parameters of solidification. The silver-nickel equilibrium diagram3 reveals the presence of a monotectic reaction at 1435°C. At this temperature the maximum solid solubility of silver in nickel is approximately 3 wt pct, but this solubility decreases with decreasing temperature and the solute is rejected as a silver-rich liquid phase at temperatures below 1435°C. Thus, the 1.0 wt pct solute should be held in solution during undercooling and solidification and subsequently precipitate as a silver-rich liquid phase at grain and subgrain boundaries following solidification during cooling below 1435. This assumes no solute segregation sufficient to cause the monotectic reaction. One would expect this second phase to inhibit grain and subgrain growth by retarding dislocation motion after solidification is complete. The effectiveness of silver addition in growth retardation of high-angle grain boundaries has been demonstrated by Colligan and suprenantS4 The principal [l00] dendrite growth directions in a 2 wt pct Ag-Ni alloy undercooled 53 all radiated from the nucleation site. A similar pure nickel ingot undercooled 59°C exhibited a random orientation of [l00] dendrite directions with respect to the nucleation site. Since undoped nickel ingots do not retain any evidence of the casting or solidification texture and silver-doped ingots do retain this texture, it is reasonable to assume that considerable grain growth has taken place in the pure nickel. These particular experiments were performed in order to reveal the differences, if any, in the features of the crystallographic substructure of undoped undercooled nickel and silver-doped undercooled nickel. 1) EXPERIMENTAL PROCEDURE Data are reported on selected specimens from two massive (approximately 260 g) undercooled ingots of nickel. One ingot consisted of electrolytic nickel and the other of this same material with 1.0 wt pct addition of high-purity silver. Powder patterns were taken of both the as-received and as-solidified materials; in all cases the reflections recorded were attributable to the individual elements nickel and/or silver. Fig. 1 is a. schematic diagram of the apparatus employed for the undercooling experiments. The equipment consists in part of a fused silica crucible for containing the charge. A fused silica tube encloses the system, which is covered by a brass cap to permit partial sealing of the inert atmosphere. This cap contains a hole through which a Pt-Pt 13 pct Rh thermocouple is inserted for temperature measurement. The charge is inductively heated under a purified argon atmosphere.

Jan 1, 1963

By W. F. Wheeler

In the study of the coals of Illinois now being carried on by the State Geological Survey, an attempt is being made to determine the most satisfactory basis of comparison between different coals. The following discussion is based upon work done for the Survey in the laboratories of the State University and under the general direction of Prof. S. W. Parr. "Pure coal" has been defined by Mr. A. Bementl as ash- and moisture-free coal, and the use of this pure coal" as a basis for comparing different bituminous coals has lately been much discussed among engineers in the middle West. By some the B.t.u. of the pure coal is being used to check calorimetric results, and to calculate the calorific value of different coal-samples from the same seam, for which purposes it is necessary to assume—first, that the composition and calorific value of pure coal from different parts of the same coal-seam are uniform, and, second, that these values remain constant after the coal is mined, both of which assumptions there are reasons to believe are inconsistent with the facts. Certain variables are included in pure coal, as ordinarily defined, and disregard of them may lead to serious error. In any event, where delicate shades of difference are involved, no sure interpretation of results car] be made, unless these variables be eliminated. As a basis of comparison between coals, ash- and moisture-free coal is much to be preferred to " dry coal," and still more is it to be preferred to moist coal," as ordinarily reported in analyses. There are, however, two constituents other than ash

Jan 1, 1908