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By Lawrence H. Van Vlack, Alfred S. Keh

The distribution of sulfur in iron was found to be dependent upon the time and temperature of the treatment as well as the chemical composition of the sulfide. With higher temperatures, the sulfide phase spreads more extensively between the iron grains. A complete network, however, does not form until approximately 1300°C (2372°F), ot which temperature the dihedral angle approaches zero. Silicon has little effect on this change. Aluminum, oxygen, and manganese all modify the temperature of sulfide network formation to a higher value. The microstructures which result and have significance in relation to hot-shortness are discussed. SULFIDE inclusions in steel were recognized by metallurgists before the turn of the century. Considerable attention has been paid to them, and numerous studies have been made on the working properties of steel as affected by them. It has been suggested that ho t-shortness of steel is due to the presence of an enveloping liquid sulfide film at the grain boundaries of the steel in the range of the hot-working temperatures. However, several facts have been observed in commercial steels which do not seem to be completely consistent with this explanation: 1) the frequent absence of continuous films of sulfide as observed under the microscope, 2) the absence of hot-shortness in some high sulfur and resulfurized steels, and 3) the limitation of hot-shortness to a definite temperature range. The role that manganese plays in steel to eliminate hot-shortness is well known, but the theory behind it is still under question. Moreover, the effect of de-oxidizers such as aluminum and silicon, and the effect of oxygen are still not clearly known. In this study, the effect of heat treatments and of additions of manganese, aluminum, silicon, and oxygen upon the distribution of sulfide inclusions in iron was investigated. Both the as-cast and the heat treated structures were studied, using microscopic and autoradiographic techniques. Part of the results were interpreted in terms of Smith's' concept of microstructure. Review of Literature Metallurgists used to consider sulfide inclusions as suspended particles. It was Wohrman' who first pointed out that sulfide inclusions are soluble in liquid iron. Many observed facts may be understood on the basis of this concept of solubility. Wohrman found that small castings contain small inclusions. and larger castings contain larger ones. Also, inclusion sizes are smaller near the chilled surface. For the same size ingot, the average inclusion size in a given heat of steel depends upon the rate of solidification. That is, with slow solidification, enough time for precipitation and agglomeration of these

Jan 1, 1957

By Harold R. Larson, John F. Elliott

The standard free energies of formation of several nzetallic sulfides have been measured by a reversible electromotive-force cell employing stabilized zir-conia as the electrolyte. The oxygen potential at the cathode was fixed by the use of pure oxygen gas at 1 atm. It was established at the anode by bringing to equilibrium the reaction between the sulfide and oxide species present. Thus, Gf: for the sulfide could be obtained from the cell potential and the standard free energies of formation of the oxides participating in the reaction. The results in calories per cam rnole for the temperature range 850" to 1100°C are: Use of the reversible electromotive-force cell having an oxide-ion electrolyte to obtain the standard free energies of formation of some of the more stable metallic sulfides offers a convenient experimental method that is very productive. It also avoids some of the problems inherent in the experimental methods' for such studies which rely on precise determination of gas compositions, particularly if these compositions lie near the limits of our capabilities for accurate chemical analyses. The reaction equilibrium between the lowest sulfide of a metal, SO2 at a fixed pressure, and an oxide of the metal has a characteristic oxygen potential. For example: and for metals whose lowest sulfide is much more stable than the oxides of the metal, the equivalent reaction might be:

Jan 1, 1968

By J. V. Gluck, Ping-Wang Chiang

The tellurium-rich region of the Sb-TI-Te ternary system was investigated by means of DTA, metallo-graphic, X-ray, and electron beam microprobe techniques on the sections Sb2Te3-T12Te3, SbTlTe2-Te, SbT1Te2-Sb2Te3, and SbTlTe2-T12Te3. The phase behavior of this region is summarized in terms of four ternary invariant reactions and a schematic reaction diagram is suggested. Isopleths for the sections SbT1Te2-Sb2Te3, Sb2Te,-T12Te3, and SbTlTe2-Te were constructed, and a schematic diagram of the projections of the liquidus lines and invariant planes is presented. No evidence was found to support the existence of the ternary compound "SbTlTe3", or pseudo-binary behavior of the section T12Te3-Sb2Te3, as reported by Borisova and Efremova. Electrical conductivity, Seebeck coefficient, and thermal conductivity measurements were made at room temperature on fully annealed samples. 1 HE phase relationships in chalcogenides are often complex and difficult to resolve, particularly since the approach to equilibrium is a rather slow process. For example, the phase diagram of the T1-Te binary system was in doubt until clarified by Rabenau et al.,1 the phase fields at compositions near Bi2Te3 in the Bi-Te binary system have only recently been satisfactorily elucidated by Glatz,2 and there may still be some question as to the extent of the Sb2Te3 field in the Sb-Te system.3-5 In ternary systems, the existence of the compound "AgFeTe2" was the subject of a number of conflicting reports6-8 and the stoichiometry of the composition "AgSbTe2" was in doubt for a period of time.9 Recently, questions have arisen regarding the existence of certain compounds in the ternary systems Bi-Tl-Te10-14 and Sb-Tl-Te.15 The impetus for studies of these latter systems stemmed from the report of Borisova et a1.10 of a congruently melting ternary compound, "BiTlTe3", which apparently had extremely favorable thermoelectric properties for room-temperature cooling applications. Attempts by other investigators to produce the compound or confirm the transport properties proved to be unsuccessful.12-14 Recently, Chiang and Gluck14 reported studies of the phase relations in the tellurium-rich region of the Bi-T1-Te system which indicated that the section T12Te3-Bi2Te3 was not pseudobinary as suggested by Borisova et a1.10 The contention of Spitzer and sykes12 was supported that the composition "BiT1Te3" was multiphase, with the primary constituent actually being BiTlTe2, a compound whose existence has been well demonstrated.16,17 The investigation reported in the present paper was prompted by a later report of Borisova and Efremova15 on a similar study of the section T12Te3-Sb2Te3 from the Sb-T1-Te system. They also claimed this section to be pseudobinary, and that a ternary compound "SbTlTe," was formed peritectically. Some "preliminary" crystallographic data were given for the compound and thermoelectric transport properties were presented. In view of the questions concerning the behavior of the Bi-T1-Te system and the existence of the compound "BiT1Te3" it was suspected that the Sb-T1-Te system might behave in a similar fashion, particularly in light of the known existence of a compound SbT1Te2, iso-structural with BiT1Te2.17 Consequently, an investigation was undertaken to clarify the phase relationships in the tellurium-rich region of the Sb-T1-Te system. It is the purpose of this paper to present the results of this study, including a representation of the phase relations, isopleths for various composition sections, and the determination of some phase compositions and transport properties. EXPERIMENTAL PROCEDURES Commercially available high-purity (99.999+ pct) elements, purchased from the American Smelting and Refining Co., were used for the sample preparation. All samples were made from thoroughly mixed powders of previously prepared master alloys: SbTlTe2, Te, Sb2Te3, and T12Te3. Stoichiometric quantities of the constituents for each 10-g sample were weighed into a specially cleaned fused silica tube and sealed under a vacuum of better than 5 x 10-5 torr. The sealed constituents were fused and reacted at 650° to 750°C for at least 4 hr under continuous agitation in a "rocking" furnace, and the resulting product was air-cooled. The tube was opened and the sample was ground to a powder. A portion of the powder was rebottled in a DTA tube under vacuum, and the rest of the material was similarly resealed in a separate tube, re-fused in the rocking furnace, and again cooled to make the ingots for electrical and microstructural studies. All samples were subjected to further heat treatments as discussed in the section on experimental results. Each DTA tube was made of 7-mm-OD fused silica tubing with a concentric 2-mm-ID depression about 4 mm long formed in the bottom to accommodate a thermocouple. The size of a DTA sample was 0.5 to 1.0 g. An Aminco Thermoanalyzer whose accuracy was within 2°C18 was used for the DTA measurements. The metallographic samples were prepared by conventional techniques. A solution of FeCL dissolved in a methanol-HC1 mixture was found to be the most satisfactory etchant. Electron beam microprobe scanning and point-count examinations were made on polished and unetched samples using an ARL Electron Microprobe at an electron beam voltage of 20 kv. The detectors were set to receive characteristic La1 radiation. Calibration standards of the pure elements were incorporated in each sample mount; quantitative point counts were calibrated by a method similar to Ziebold

Jan 1, 1969

(Members, are urged -to send in for this column any notes of interest concerning themselves or their fellow-members,). Members and guests R: ho called at Institute headquarters during the period Dec: 10, 1916 to Jan. 10, 1917: F. L. Antisell, Perth Amboy, N. J. William Kelly, Vulcan, Mich. F. J Brulé, Toronto, Ont., Canada. W. H. Lanagan, San Francisco, Cal. Zar T. Crittenden, The. Pas, Mau, Canada. S. Lefevre, Forest Glen, N Y Thomas F. Donnelly, Tucson, Ariz. ' D. A. Lyle, St..David's, Pa. - John Davenport, Brighton, 14 lass. -Domingo Nugués, Buenos Aires, Argon-. E. E. Ellis, Birmingham, Ala. tine. N. H. Emmons, 3d, Copperhill, Tenn. - H. L. Scaife, Clinton, S. C. W.. E. Erdofy, New York, N. Y. Mortimer A. Sears, Washington, D. C. C. L. French, New York, N. Y. E. Spurny, New York, N. Y.' , M. H. Gannon, Butte,. Mont. R. K. Stockwell, Santiago, Chile. R. E. Hoffman, Hannibal, Mo. Benjamin F. Tibby, Salt Lake City, Utah. C. Vey Holman, Rockland, Me. Arthur P. Watt, St. Francois, Mo. Arthur P. Allen has left the employ of the Calumet &- Hecla Mine and is now with the Highland Min. Co., Ashcroft, B. C., Canada. H: C. Bellinger has been appointed. general manager of the Chuqui- - c mata mine-of the Chile Exploration Co. -

Jan 2, 1917

By R. J. Robbins, D. L. Anderson

A tunnel boring machine has potential use in al- most any type of mining where the access shaft (or adit) is large enough or can be made large enough for its initial entry and where the orebody is of sufficient size to warrant its use. Some time will inevitably be lost in negotiating curves or making lateral moves and moving from level to level. Nevertheless, if the orebody is sufficiently large, advance scheduling can minimize the lost time encountered in such moves. Ideally, a mine will be planned for the use of these machines, thus eliminating access and transport problems. From the viewpoint of time involved, the rate of advance by boring as compared to conventional means is worthy of review. For instance, the Blanco Tunnel, one section of the Bureau of Reclamation's San Juan-Chama Project in southern Colorado, was bored in competent sedimentary rock with the following performance:

Jan 7, 1967

DeLamar, the largest silver mine in the United States outside the Coeur d’Alene District in Idaho, came into production in April 1977. It is a joint venture of Earth Resources Company and Canadian Superior Oil Co., with Earth Resources being the operator. The property is a consolidation of several old operations dating back to the 1800s; the better known of these are the DeLamar and Sommer-camp mines. DeLamar is situated in southwestern Idaho near the Oregon border in the Owyhee Mountains, 88 km (55 miles) southwest of Boise, Idaho. Heavy snowfalls and very low temperatures are common in the wintertime. Planned production was 77,500 kg (2.5, million oz) of silver and 5 13 kg (16,500 oz) of gold per year. Expected life at a milling rate of 1,540 mtpd (1,700 stpd) was 20 years, with an ore grade of 144 g Ag and 1.58 g Au per mt (4.2 oz Ag and 0.046 oz Au per st). Present production is at the rate of 1,900 mtpd (2,100 .stpd). The total cost to bring the mine into production was reported to be approximately $22 million, and the mill was reported to have cost about $10,000 per daily ton of design capacity. At DeLamar, naurnanite (Ag2Se) is the principal silver .mineral occurring with acanthite (Ag2S) disseminated through quartz veins and a silicified rhyolitic ash-flow tuff of Miocene age. The mineralization is relatively iron and manganese free and is readily amenable to cyanidation giving recoveries of 85% silver and 92% gold, which occurs free. When the plant was started, considerable difficulties were encountered in handling the wet sticky ore because of the high clay content. Following primary crushing, the ore is stockpiled. Due to the sticky nature of the ore, the vibrating feeders initially installed under the stockpile were replaced by a reclaim hopper and an apron feeder which was fed 24 hours a day by a front-end loader. The minus 200 mm (8 in.) ore is fed to a 5.5 m by 2.75 m (18 ft by 9 ft) autogenous mill followed by a 2.75 m by 4.57 m (9 ft by 15 ft) ball mill and cyclones. The mills are equipped with 750 kw and 520 kw (1,000 hp and 700 hp) motors. Both mills discharge to the same cyclone feed sump and a portion of the cyclone underflow is returned to the autogenous mill. Cyclone overflow, which is 20% plus 74 microns (200 mesh), is leached in four agitators in series for 72 hours (45 hours at the 2,100

Jan 1, 1981

By Persifor Frazer

THE following notes on the Whopper and adjoining mines in the Gunnison district of Colorado were made in the spring of this year. The time chosen for the author to visit the region was, unfortunately, the most unfavorable of an exceptionably unfavorable year. About the middle of May all the hill slopes, which at this period of the year are generally covered with pasture, were thickly covered with snow. The unusually large precipitation of this year caused local mountain torrents at every few hundred feet, which wore away the soft foothills into gulches, gouged great chasms out of the roads, and transformed miles of usually dry soil into dangerous quagmires. Travel was totally interrupted for weeks, except on horseback or afoot, and even then with great difficulty and some danger. The Whopper mine is situated on the Whopper Mountain, about two miles from the headwaters of Rock Creek, and on the right bank of that stream. The Whopper Creek flows into Rock Creek from the east, and, by a precipitous descent, offers excellent facilities for its utilization as a source of power. This stream, which pours past the picturesque Whopper Cabin .about thirty tons of water a minute, has a fall of 100 feet in 400 yards, and is said to be a stream of some size, even at the seasons of the year when-drought prevails. The Whopper claim extends down the bill a distance of about 250 feet to its intersection with the Whopper Creek (on the other side of which is a small tunnel on its extension called the "Teller ") and over the steep hill northwest to the limits of the claim about 1250 feet. The part of the mountain in which this mine is situated is remarkable for its splendid forest, the spruce, fir, and quaking asp covering the mountain-sides with a green growth of valuable timber. The distance from Gothic City to this mine is about eight miles along the valleys of East River and Rock Creek, and on the divide which separates them. The elevation of Gothic City is given from the engineer's notes as 9500 feet above sea-level, and the mean of several observations with a Beck watch-barometer made the elevation of Whopper Cabin (which is about fifteen feet above the floor of the Whopper upper tunnel) about 1250 feet above Skiles's Cabin in Gothic City. The record of this instrument must, how-

Jan 1, 1881

By George W. Powel

IN the nation's effort to raise its magnesium metal supply to meet the ever increasing demand, the Government is relying not only on standard established practice but has extended its support to developments not so well proved-at least, not commercially proved. Within the past few months considerable progress has been made, not only in the definite output of metal but in the exploitation of new processes, the successful adaptation of which should, in a reasonably short time, assure an adequate supply of magnesium. Recent months have also witnessed a reshuffling of the favored methods as well as of the likely raw materials, with the mineral dolomite gaining in interest over its richer but less abundant competitor, magnesite, while the lowly sea water appears to be losing ground to the higher magnesian brines of Michigan and western Texas. Every month sees a new alignment and there are signs that still newer methods or raw materials will be in use before the industry finally stabilizes itself.

Jan 1, 1942

By Herbert A. Stein, John B. Murdock

AN analysis of perlite expansion furnaces must be based upon one consistent theory which explains how and why perlite does expand when heated. There is more than one such theory, so to establish a basis for the rest of this paper, the authors will outline one theory and the data that support it before going into the construction details of different furnaces. JOHN B. MURDOCK, Associate Member AIME, is President, and HERBERT A. STEIN is Secretary, of the Perlite Corp., Phoenix, Arizona. San Francisco Meeting, February 1949. TP 2736 H. Discussion of this paper (2 copies) may be sent to Transactions AIME before Feb. 28, 1950. Manuscript received Jan. 3, 1949. Why Perlite Expands: Perlite is known to contain some dissolved or combined fluid, probably water, which is lost when the material is heated to fusion. It is generally agreed that when particles of this volcanic glass are heated to fusion in such a way that vaporization of this water into steam takes place at the same time as the glass becomes soft, the steam puffs up each particle into a mass of glass foam. It is a simple matter to expand perlite under a blow torch for demonstration purposes, but in commercial installations, the problem is made more complicated by the necessity of making efficient use of both raw material and fuel, and producing an expanded aggregate conforming to close specifications for size distribution and density, using many different types of perlite rock. The ability of a given operation to fulfill these requirements depends upon the proper handling of four variables. They are: (1) the nature of the perlite rock used, (2) the heating time taken to get the perlite particle up to its highest temperature, (3) the size of the particle, and (4) the maximum temperature the particle reaches. Types of Perlite Rock: Perlite may be classified in many ways, but the characteristics most easily correlated with its behavior in furnaces are its softening temperature, its effective water content, and its "liveliness." Actually there is a close correlation among these three characteristics so it is possible to describe a perlite using any one of them. Lively perlites always have low softening temperatures and high effective water contents, whereas the deader perlites have higher softening temperatures and lower effective water contents. These softening temperatures run from 1400°F to above 2000°F and the effective water contents run from over 2 pct down to 0.2 pct. Included in the category of lively glasses are the green pitchstone from the Edgar claim in Superior, Ariz., the red pitchstone on the Animas highway south of Lordsburg, N. Mex., and a gray glass from Beatty, Nevada. Examples of intermediate perlites (in order of decreasing liveliness) are the Guzman-Lobb perlite with obsidian

Jan 1, 1951

By Herbert A. Stein, John B. Murdock

AN analysis of perlite expansion furnaces must be based upon one consistent theory which explains how and why perlite does expand when heated. There is more than one such theory, so to establish a basis for the rest of this paper, the authors will outline one theory and the data that support it before going into the construction details of different furnaces. JOHN B. MURDOCK, Associate Member AIME, is President, and HERBERT A. STEIN is Secretary, of the Perlite Corp., Phoenix, Arizona. San Francisco Meeting, February 1949. TP 2736 H. Discussion of this paper (2 copies) may be sent to Transactions AIME before Feb. 28, 1950. Manuscript received Jan. 3, 1949. Why Perlite Expands: Perlite is known to contain some dissolved or combined fluid, probably water, which is lost when the material is heated to fusion. It is generally agreed that when particles of this volcanic glass are heated to fusion in such a way that vaporization of this water into steam takes place at the same time as the glass becomes soft, the steam puffs up each particle into a mass of glass foam. It is a simple matter to expand perlite under a blow torch for demonstration purposes, but in commercial installations, the problem is made more complicated by the necessity of making efficient use of both raw material and fuel, and producing an expanded aggregate conforming to close specifications for size distribution and density, using many different types of perlite rock. The ability of a given operation to fulfill these requirements depends upon the proper handling of four variables. They are: (1) the nature of the perlite rock used, (2) the heating time taken to get the perlite particle up to its highest temperature, (3) the size of the particle, and (4) the maximum temperature the particle reaches. Types of Perlite Rock: Perlite may be classified in many ways, but the characteristics most easily correlated with its behavior in furnaces are its softening temperature, its effective water content, and its "liveliness." Actually there is a close correlation among these three characteristics so it is possible to describe a perlite using any one of them. Lively perlites always have low softening temperatures and high effective water contents, whereas the deader perlites have higher softening temperatures and lower effective water contents. These softening temperatures run from 1400°F to above 2000°F and the effective water contents run from over 2 pct down to 0.2 pct. Included in the category of lively glasses are the green pitchstone from the Edgar claim in Superior, Ariz., the red pitchstone on the Animas highway south of Lordsburg, N. Mex., and a gray glass from Beatty, Nevada. Examples of intermediate perlites (in order of decreasing liveliness) are the Guzman-Lobb perlite with obsidian

Jan 1, 1951

E. R. JETTE*—The way this ternary was developed there are two directly determined points on each of the iso-thermals except the 700° isothermal, where I believe there is only one. How were the end points determined, and what was the basis for it? Whose work formed the basis for the silver copper line ? M. B. BEVER †—At most temperatures the authors determined three points of the isothermal line. For example it can be seen from Fig 3 and 4 how three points for the 600°C contour line were obtained. The authors took two additional points for each temperature from the copper-silver binary diagram contained in Hansen's volume on constitution diagrams. It is correct that the 700°C contour line is based only on one point in the ternary field which was found by a slight extrapolation of Fig 4. R. I. JAFFEE*—Are the tie lines representing phases in equilibrium parallel to the silver-copper boundary ? M. B. BEVER—Are you asking that as a matter of principle ? R. I. JAFFEE—I assumed that would follow from principle. I wonder if that is in accordance with the authors' ideas too. M. B. BEVER—I do not believe the authors obtained any information on the tie lines in the two-phase field. Of course, in the limiting case of very low gold contents the tie-lines approach to the silver-copper boundary, but generally in the two-phase field I do not think that the tie-lines have to be parallel to the boundary. E. R. JETTE—1 am quite sure they do not have to be parallel. You cannot tell from this work in which direction they go. E. A. GULBRANSEN*—Were any pycnometric measurements made to check the lattice parameters of the alloys ? M. B. BEVER—I did not hear any-

Jan 1, 1950

G. McMEANS*—This paper is a very good demonstration of the use of a new tool for the solution of industrial problems of a physical nature. To have solved this problem without the use of radioactive tracers would have required a far greater amount of investigation and work. The authors have described their work in such detail and in such a manner as to suggest the possibilities of the use of such tracer studies in the solution of many perplexing problems of industry. R. E. BREWER †—The authors are to be congratulated on this very excellent paper, which describes the results obtained by utilizing radioactive tracers in investigating the complicated reactions in the coking process. The paper has especial merit because the study was made under typical operating conditions in a commercial coke oven. Considering all the difficulties involved, the results obtained are excellent. My brief comments will relate primarily to the method used for determining the sulphur in the gas and to the value of the data obtained in stimulating further research. In discussing their results, the authors state (p. 17) that "Of the total sulphur charged to the oven in the coal 95 pct was accounted for in the coke and gas. Most of the sulphur unaccounted for is believed to have been lost in the gas, since the gas sampling system removed all the H2S but probably only part of the organic sulphur compounds present in the gas. Although sulphur in the acid-insoluble tar residue in the gas scrubbing bottles was determined and added to the total sulphur determination of each sample, it is doubtful whether an aliquot portion of tar for each sample was obtained." The reviewer believes that the authors might have obtained a better sulphur balance had they used an improved procedure for determining sulphur in the gas. The absorption train should have included a trap to remove the tar and am-moniacal liquor and a wash bottle containing 5 pct sulphuric acid to remove ammonia in the coke-oven gas before it entered the gas scrubbing bottles containing the ammoniacal cadmium chloride solution. Sulphur in the tar and

Jan 1, 1950

By JAS. F. McCARTHY

THE present Hecla Co. is a Washington corporation; the Hecla Co. of Idaho was the old company. The older corporation owned two claims, the Hecla and the Katie May, and was incorporated for 500,000 shares of one dollar par value. The principal shareholders and officials of the older company were among the early mining men of the camp. Among the active officials were John A. Finch and A. B. Campbell. Among the directors and share- holders were Patrick Clark, J. R. Smith, Frank Upman, F. J, Kipp, Chas. Kipp, B. A. Kipp and Carl Landsee. F. J. Kipp and Carl Landsee are now directors of the Company. All of the others mentioned have died, but the surviving members of their families retain their ownership in the Company's shareholders. B. A. ,Kipp, who recently died, was the largest shareholder at the time of incorporation and Patrick Clark was the second largest shareholder. B. A. Kipp is a brother 'of F. J. Kipp, director of the Company.

Jan 1, 1924

By E. B. Thornhill

In this paper on the recovery of mercury as sulphide, from the residues from the amalgamation and cyanide treatment of high-grade ores and concentrates, I will not discuss the many reactions, chemical and other- wise, that take place in the general process, but confine myself more particularly to the methods of recovering the mercury. I submit charts of two amalgamation-barrel charges, Figs. 1 and 2, which are self-explanatory. The flow sheet of the high-grade and the mercury extraction plants is showh in Fig. 3.

Jan 1, 1916

By C. K. Leith, W. J. Mead

In 1911, we published in the Transactions a brief account of the lateritic alterations of serpentine in eastern Cuba, producing the important iron-ore deposits of the Mayari and Moa districts.' The special feature of that article was a quantitative treatment of the alterations, based on analyses, to show just what had happened in terms of chemical, mineralogical, and physical changes. Professor Kemp has published an interesting account of these ores, containing additional quantitative observations of his own, tending essentially to confirm the nature of the changes that had been worked out.2 His discussion suggests to us the desirability of publishing certain additional quantitative data which were not included in our previous article. This seems especially desirable because quantitative measurements of lateritic alterations are rare, and this particular case may be regarded as typical of a fairly wide range of alterations of this kind. At the time of our examination of Mayari and Moa deposits 29 complete analyses were supplied us by the chemists of the Spanish-American Iron, Co., representing a graded series from the unaltered serpentine rock below to the ore at the surface. These analyses are given in the accompanying table. The mineralogical composition of the ores and rocks is comparatively simple and can be easily calculated from the analyses. In Fig. 1 the mineralogical changes from the serpentine rock below to the lateritic iron ore above, based on the analyses, are expressed in terms of weight, assuming alumina to have remained constant during the alteration. It is not easy by mere inspection of this table of analyses to determine what the progressive chemical changes have been in development of the ore. In order to bring this out clearly, the analyses have been graphically represented in Fig. 2 in such a fashion as to show the progressive additions and losses of substances during alteration.

Jan 1, 1916

By C. L. Dake

Iron is much more soluble in the ferrous than in the ferric form. Where, as in the case of the ferrous silicates and. the sulphides, the iron is already in the ferrous form, it may go at once into solution and be removed, upon the breaking down of the parent rock. If in the ferric form, it must first be reduced; usually by the decay of organic matter, the demand of the decaying carbonaceous matter for oxygen being so great that the latter is abstracted from the ferric compounds and the iron is thereby reduced and rendered soluble. The iron may go into solution as the sulphate, or in the presence of excess CO2 as ferrous carbonate. It is probably soluble as salts of the organic acids.' Recent work indicates that these are important in the formation of bog ores.2 There is considerable variety of opinion concerning the behavior of these organic compounds.3 The secretions about the roots of plants and trees also cause the solution and removal of iron and a consequent bleaching of the soil,4 While the matter is not yet well understood, we can probably say definitely that the so-called organic acids are a group of colloids which possess slightly acid properties, and the salts of which are partly soluble and partly insoluble.5 Their iron salts readily change from the ferrous to the ferric form, and their solubility is greatly modified by the presence of ammonia.

Jan 1, 1916

By F. F. Lines

It is not the intention of the writer to enter into a discussion of the relative merits of the duplex process as compared with the straight scrap and pig iron process, working under the same conditions, but rather to present in a general way several modifications of the former process, and then describe the method adopted by the Maryland Steel Co., as best suited to local conditions, and also to meet the metallurgical problem presented in the removal from the iron of an unusual constituent— chromium. The principal factors to be considered in. deciding whether or not duplexing should be employed are: (1) Chemical constituents of pig iron. (2) Variety and quantity of steel to be produced. (3) Relative cost of pig iron and scrap. (4) Regularity of operation. (5) Capital to be invested. (6) An existing Bessemer plant. Having decided to adopt the duplex process, several combinations may be used, viz.: (1) Acid-lined converter with basic open hearth. (2) Acid-lined converter with electric furnace. (3) Basic-lined converter with basic open hearth. (4) Basic-lined converter with electric furnace. (5) Basic open hearth with electric furnace. The combination of an acid-lined converter with a basic open-hearth furnace is the one most commonly employed, and as it is the one best adapted to the conditions encountered at the plant of the Maryland Steel Co., we will briefly outline the advantages and disadvantages of the different methods of working. There are two general methods of blowing, as follows: (1) The charge is desiliconized and partly decarbonized in the converter. On account of the difficulty in regulating the percentage of car-

Jan 1, 1916

By C. L. Pillar

TWO shafts have been completed since the spring of 1948 when underground development started, and three are now under construction. The new program provides two main ore shafts, Nos. 3A and 3B, spaced 195 ft apart and located on the south- western end of the orebody. It is planned that eventually 35,000 tons of copper ore per day will be hoisted by these identical four-compartment shafts. The third shaft of this new group is 600 ft from the present No. 1 shaft and will provide caged sup- plies for the underground mining operations. This No. 4 shaft has the largest cross-section of any shaft in Arizona.

Jan 7, 1954

By R. P. McLaughlin

In most branches of the mining industry it is a well-recognized fact that care must be taken to protect the mineral deposit from undue physical injury. It is comparatively easy to grasp this idea when the mineral is a solid and the lives of workmen depend directly upon the care with which it is removed from its natural position, but when the product is a liquid drawn up from pools several thousand feet beneath the surface of the ground through openings only a few inches in diameter, it requires some imagination to picture underground conditions and the changes which must often occur. The development of the petroleum deposits of California has been attended by numerous accidents, the results of which are readily noticed at the top of the wells and in the profit and loss accounts of the operators. Determination of the cause of these accidents has been the subject of considerable study, which naturally has fallen upon men familiar with technical methods. The greatest damage to the oil deposits of California has resulted from water finding its way into the oil-bearing sands, and it is the purpose of this paper to set forth briefly this phase of the oil industry. Much of the material here presented has previously appeared in publications issued by the California State Mining Bureau, which, under the direction of State Mineralogist Fletcher McN. Hamilton, has investigated the subject and taken steps toward improvement of conditions. The writer, having been in charge of this branch of the Bureau work, has gained considerable knowledge of existing conditions. Generally speaking, the oil-bearing formations of California are soft, unconsolidated sand beds, separated by clay strata, which are also soft. Some of the sand beds carry water instead of oil. All of the beds are more or less separated, probably being of lenticular shape. Very few of the beds in the oil fields lie flat or undisturbed over any great area. Folding and tilting are common, and faulting also occurs in some of the fields. The accumulation of oil is not confined to any single structural feature, such as the anticline, but occurs in many other structural features. Water-bearing strata occur in practically every oil field in the State. Complete data are not at hand for a comparison of the damage

Jan 1, 1916

By Joseph Daniels

The Fritz Engineering Laboratory was built under the direction of John Fritz, and presented by him to the University. A view of the building, looking east, is shown in Fig. 1. The building was started in 1909, and completed in 1910, although all of the equipment was not placed until later. Mr. Fritz gave his personal attention to the details of construction and equipment, and it was his custom to drive over every day to the University from his home in Bethlehem and spend some hours watching the work, offering suggestions, making changes, and planning new work. The result is a building and an equipment which embody his practical ideas. The laboratory structure is of the steel mill-building type, of light-colored brick, 91 by 114 ft., of which a section is shown in Fig. 2 and the floor-plan in Fig. 3. The steel frame carries the roof and traveling crane-way. Ample light has been provided by numerous windows in the side and end walls, in the clerestory, and by a skylight 84 ft. long and 9 ft. wide in the north roof. The main aisle of the building is 49 ft. 2 in. between centers of crane-columns, and has a clear height of 40 ft. The remainder of the width is taken up by two side aisles, 18 ft. high. The laboratory consists of four sections: (1) A general testing-section containing the testing-machinery, a small machine shop, and an office; (2) a cement-testing room; (3) a room for making and storing concrete test-specimens; (4) a hydraulic section.

Jan 1, 1912