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By Edgar C. Bain, William E. Griffiths

The results of an inquiry into the structural nature of some 70 iron alloys containing both nickel and chromium over a considerable range of concentration are briefly described in this paper. This study is a part of a comprehensive program of investigation into alloys involving chromium in progress at the Union Carbide and Carbon Research 1aboratories. All the compositions studied contained carbon in amount comparable to commercial alloys. The B Constituent In addition to locating the limits of composition for the three principal types of structure (polyhedral ferrite, martensite and austenite) and their combinations, certain other features of the system were observed. A hitherto undescribed brittle constituent (designated here as the "B constituent") was discovered. It is very hard, non-magnetic and forms in two modes from chrome-ferrite by recrystallization. It is the stable low-temperature condition for the equal-proportion chromium-iron materials containing less than 10 per cent. nickel. Although it partakes of the nature of an inter-metallic compound, yet it may exist over a considerable range of composition. It is non-existent above a temperalure zone, varying with composition, from 800° C. to 950° C., and heating above this critical temperature develops chrome ferrite persistent after average cooling rate; a few hours just below this temperature will develop the complicated brittle crystalline type. The B constituent, when found in the grain boundaries of alloys of lower chromium content, contributes a serious brittleness removable, however, by heating and cooling rapid enough to prevent its re-format'ion. By suitable means of precipitution, the hard B constituent can be made to strengthen the already stiff alloy matrix in the manner of submicro-scopic particles, as exemplified in duralumin or the Sykes iron-tungsten and iron-molybdenum alloys. A possible explanation is offered for the familiar brittleness developed in chrome iron at temperatures above about 475" C. and removable by

Jan 1, 1927

By F. C. Kelley, L. L. Wyman

In order to clarify and amplify the existing data concerning the action of the cementing material in cemented tungsten carbide alloys, the authors have initiated this investigation of the entire range of cobalt-tungsten carbide alloys. Inasmuch as the ultimate objective is relative to what actually goes on during the sintering of cemented tungsten carbide materials, this work was necessarily restricted to heat treatments similar to those used in actual production of these materials. In the course of numerous experiments, the authors have noted several conditions that indicated that there was a solubility to be considered. Among these factors are the following: 1. Many of the alloys showed a much larger amount of binding constituent to be present than could possibly be accounted for by the cobalt content. 2. In many areas, grains of the carbide constituent are much larger than the particles of carbide originally added. In addition, these grains are of very regular contour. 2a. In samples of cemented tungsten carbide which had been fused in the atomic hydrogen torch in the presence of excess binder constituent, immense grains are formed, and their shapes are very regular. This is also true when the cemented tungsten carbide of 13 per cent. Co content is fused alone in the atomic hydrogen torch. Contrary to general expectation, chemical analysis of this material, after fusion in the atomic hydrogen torch, checks the analysis of unfused material. 3. In making the cemented tungsten carbide materials by the process of exerting the pressure at the time of heating a certain portion of the ' contents squeezed out of the mold. Chemical analysis has shown that this material contains approximately 12 to 20 per cent. of tungsten. The microstructure shows a cored dendritic structure interlaced with eutectic network, and some graphite, as shown in Fig. 1. 4. Thermal analysis of these materials has consistently indicated an arrest point close to 1350" C.

Jan 1, 1931

A GIFT of $10,000 to the endowment of Engineering Foun-dation, made by the Central Hudson Gas and Electric Corporation, has been announced. In transmitting this gift T. R. Beal, president of the corporation, made the follow-ing interesting statement: "You may be interested to know that this amount was in fact earned by our employees by their more efficient opera-tion of the physical properties under their care. It rep-resents $10,000 of return premiums paid during the past year on accident insurance, as the result of the company's excellent record in preceding years, so that we take greater satisfaction in making this gift as it is related, in some degree at least, to the higher standards of engineering and operating practice to which the work of the Foundation per-tains."

Jan 4, 1928

By A. B. Johnson, J. S. Browning

The USBM has developed new and improved physical beneficiation techniques for economically recovering potash minerals from high-clay and low-grade ore from the Permian Basin of New Mexico. With the depletion of the high-grade ores a need for changes in industry's standard methods of recovery is a must. Technology may be improved in the beneficiation of the ore prior to mineral flotation and in brine clarification from the desliming phase to effect a reduction of losses of fine potash and brine in the disposal of the clay slimes. This report summarizes the results of these tests and demonstrates the feasibility of producing products that meet the requirements of the agriculture market, namely, 95% KCl equivalent to 60% K2O with recoveries ranging between 80 and 90%.

Jan 1, 1973

By Dale I. Hayes

Combined loader and transport, the Gismo is now built for sale in one size, 5 to 6 tons. It will operate in a minimum opening of 7x7 ft and can be built to operate at lower heights. Where space limitations are not a factor it could be designed with much greater carrying capacity-12, 18, or 25 tons-to be powered with a standard heavier tractor. The Gismo is mounted on crawler tracks of the same design as the tracks of the small Allis- Chalmers HD-6B tractor used to power it. With the HD-6B tractor it will negotiate upgrades of 12 pct and downgrades of 20 pct. The next tractor size would make the device feasible for steeper grades or for a machine of larger capacity at moderate grades.

Dec 1, 1956

By George A. Jr. Dornin

A TRULY sound ingot can be made only from steel that is completely deoxidized. Given this condition, there is one further basic requirement-the steel in the ingot must solidify progressively from the bottom to the top. Any method of making the ingot that produces this type of solidification will yield sound products. Since a big-end-down ingot will not satisfy this condition, all sound steel today is produced in big-end-up ingots, the standard tool being the big-end-up mold fitted with some sort of refractory hot top. No one uses hot tops from choice, be cause of the bother and expense involved and because of the low yield resulting from their use-they are used because there has been no alternative where sound steel was required.

Jan 1, 1947

By Dave H. Barnett, Brij M. Moudgil

The flotation technique as employed by Florida phosphate producing companies for the beneficiation of fine phosphate particles has been standardized over the years. Lower recoveries of coarse Phosphate rock by froth flotation technique, however, led to the development of new methods based on skin flotation of phosphate agglomerates. Recent developments of floating coarse rock in large flotation machines have not yet convinced the rock Producers of their higher separation efficiency. It is interesting to note that the selection of a particular machine is still bared on equipment preference by an individual company as well as proven performance of a particular machine for upgrading a specific material. Various techniques which have been developed to beneficiate the coarse phosphate rock have been discussed. Performance of the individual techniques is presented.

Jan 3, 1979

By Dave H. Barnett, Brij M. Moudgil

The flotation technique as employed by Florida phosphate producing companies for the beneficiation of fine phosphate particles has been standardized over the years. Lower recoveries of coarse phosphate rock by froth flotation technique, however, led to the development of new methods based on skin flotation of phosphate agglomerates. Recent developments of floating coarse rock in large flotation machines have not yet convinced the rock producers of their higher separation efficiency. It is interesting to note that the selection of a particular machine is still based on equipment preference by an individual company as well as proven performance of a particular machine for upgrading a specific material. Various techniques which have been developed to beneficiate the coarse phosphate rock have been discussed. Performance of the individual techniques is presented.

Jan 1, 1980

NEW MEMBERS The following list comprises the names of those persons who became members during the period Mar. 1 to 15, 1914: Members ADAMS, JOHN H., Cons. Engr First National Bank Bldg., Birmingham, Ala. ALEXANDER, WILLIAM H., Miner 80 Maiden Lane, New York, N. Y. AUSTIN, EDGAR TAYLOR, Asst. Smelter Supt., Mond Nickel Co., Ltd., Coniston, Ont., Can. BAKER, DANIEL, JR., Asst. Treas., Standard Lime & Stone Co. 524 Equitable Bldg., Baltimore, Md. BALL, MAX WAITE, Geologist U. S. Geological Survey, Washington, D. C. BARREN, HARRY B., Supt. Blast Furnaces, Inland Steel Co., Indiana Harbor, Ind. BAUMANN, HENRY N., JR., Amalgamator 365 Lynn St., Seattle, Wash. BLACK,, THOMAS B., Min. Engr Care Vulture Mines Co., Wickenburg, Ariz. BRADT, HARLAN H 429 West 111th_ St, New York, N. Y.

Jan 4, 1914

By L. Massé, Th. Koulomzine

NOTE ON HAALCK'S FORMULA QUANTITATIVE interpretation of magnetic anomalies is admittedly a difficult process. Few authors have attempted a general approach to this problem. A [ ] number of publications can be found widely scattered through scientific periodicals, which present particular solutions obtained by the introduction of simplifying assumptions, such as the reduction to an equivalent magnet or pole, or the hypothesis of a very thin vein. The practical applications of these solutions are necessarily very restricted though they have given satisfactory results in isolated cases. Probably the most widely known equation of this type was given by Haalck.l His classic work contains curves calculated for typical conditions, and has now become a standard reference. However, a close scrutiny of Haalck's derivation reveals that, aside from the hypothesis of a thin vein, it rests on the

Jan 1, 1947

By L. Massé, Th. Koulomzine

Note on Haalck's Formula Quantitative interpretation of magnetic anomalies is admittedly a difficult process. Few authors have attempted a general approach to this problem. A number of publications can be found widely scattered through scientific periodicals, which present particular solutions obtained by the introduction of simplifying assumptions, such as the reduction to an equivalent magnet or pole, or the hypothesis of a very thin vein. The practical applications of these solutions are necessarily very restricted though they have given satisfactory results in isolated cases. Probably the most widely known equation of this type was given by Haalck.' His classic work contains curves calculated for typical conditions, and has now become a standard reference. However, a close scrutiny of Haalck's derivation reveals that, aside from the hypothesis of a thin vein, it rests on the

Jan 1, 1949

By Richard W. Greene, Joel S. Hirschhorn

MATERIALS containing very large amounts of porosity, in the order of 50 to 90 vol pct, are extremely difficult to evaluate according to conventional mechanical behavior tests. This is usually a consequence of their low strength and brittleness, and the difficulty of preparing standard test specimens. A simple fatigue test has been developed and used successfully on porous nickel sheet materials requiring no specimen preparation; it could also be used for configurations other than sheet or plate. Samples of the sheet. 2 in. sq and about 0.025 in. thick, are placed in a vessel that is evacuated to about 50 f Hg by a mechanical pump. Distilled and deairated water is allowed to enter the vessel thereby filling the porosity (virtually all the porosity in these nickel ma-

Jan 1, 1970

By M. Cepak, K. Donovan, W. G. Pariseau

This paper examines the difficulties of applying the finite element (FE) method of analysis to quantitative design of cable bolt systems. Cable bolt systems are in general use for ground control in VCR (Vertical Crater Retreat) topes throughout the world. However, despite their widespread use and importance, design of cable bolt systems is highly subjective. Two difficulties with the FE approach are examined: (i) the use of standard elements with a high aspect ratio (slender elements) to represent bolts, and (ii) the influence of cable bolts on hanging wall stability of a VCR study stope. Analysis results indicate that the use of slender elements for bolts is practical in large scale finite element analyses of VCR stopes. There are significant advantages in this approach to the engineering design of cable bolt systems in underground mining.

Jan 1, 1984

By Walter Miller

Construction of new large refineries was small in 1937, but extensive modernization and expansion of existing plants were made, bearing out the observation of the Bureau of Mines that the trend is strongly toward fewer and larger refineries. Building the first large combination skimming and cracking unit of 20,000-bbl. capacity was a startling achievement four or five years ago, but it has been exceeded many times since, and at least four units with a capacity of 30,000 bbl. or more were contracted for during 1937, as well as many other units of smaller but still substantial capacity. Installation of polymerization plants for producing high-antiknock blending naphthas from refinery gases progressed at an accelerated rate in refineries affording sufficient raw gas to make the use of the process profitable. The total productive capacity of polymerization units built and contracted for in the United States is now about 25,000 bbl., equivalent to the gasoline production from approximately 55,000 bbl. of crude oil a day. Octane Fuels Also utilizing refinery gases—the butylene fractions in particular—the plants for manufacture of iso-octane increased in number to such an extent that the combined capacities will enable the air forces of the United States shortly to go entirely to the use of 100-octane fuel, indications being that the Army will reach that position in 1938, with the Navy not far behind. Commercial air-lines are expected to take advantage of the greater power of high-antiknock fuels to gain the increased power and increased pay loads possible with their use. Work done on producing fuels with octanes beyond the 100 point has recently been reported, and their production can be expected, although at high cost, when the economics of the situation justifies and engines capable of utilizing them efficiently are available. In the field of motor fuels, important work was reported to the A.P.I. at its annual meeting, on the effect of altitude on antiknock requirements

Jan 1, 1938

By Frederick Burbridge

The Morning silver-lead-zinc mine of the Federal Mining & Smelting Co. is about 'two miles northwest of Mullan, Ida. The lode is a metasomatic fissure vein. The orebody is approximately 2000 ft. long within the bounds of the property and varies in width from knife edge stringers to 50 ft. It has been developed to a depth of 3600 ft. and stands nearly vertical in Revett quartzite, which .strikes north 65" west. The high-grade veins and lenses are generally mixed with waste (siderite, quartz, and quartzite). The average grade of ore to sorting plant in 1921 was 4 oz. silver per ton, 8.6 per cent. lead, and 4.1 per cent. zinc. Wall rock stands only a short time without timbering. The minimum angle of gravity flow is 45". The ratio of waste sorted out to ore is 6 per cent. No gases are generated underground and temperature has no influence on mining operations. Fresh air is forced down the air raise and up the main shaft. Drifting and Stoping Main drifts 12 ft. wide and 13 ft. high are driven every 200 ft. (vertically) and are connected by raises 125 ft. apart. These raises consist of three compartments (chute, tramway, and timber slide) and are for the purpose of ventilation, access, and hoisting supplies to stopes. Ground is stoped between raises. Chutes are placed every 25 ft. for drawing off ore broken in stopes. Waste for filling is obtained from waste raises off the stope in walls or waste is dumped from the level above down the chute compartment of raises, which is bulkheaded so that waste can be drawn off at any floor as required. Timbering Posts and caps for square sets (varying in diameter from 6 to 24 in.) are cut to length in a sawmill on the surface. No preseratives are used. Timber is taken on a flat car along drifts to a raise nearest the working place and hoisted as required. Practically no timber is salvaged for

Jan 1, 1925

By W. T. Jr. Thom

IN PREVIOUS classifications of coal, it has been customary to regard moisture eliminated from coal samples between 20° and 100° C. as extraneous matter, rather than as a constituent part of the coal. It seems, however, that the physical character and use properties of the low-rank coals are directly related to the amount of such moisture present, and recent chemical work has shown1 that such coals contain unstable groupings which decompose between 20° C. and temperatures somewhat above 100° C., with the splitting off of moisture. According to this view, the moisture eliminated from air-dried coal below boiling point is similar in all essential respects to moisture eliminated above 100° C., and is produced by analogous reactions; and inasmuch as the moisture given off above 100° C. has always been treated as a constituent of the volatile matter of coal, it would seem that consistent usage would include as a part of the volatile matter all moisture present as an essential component of the coal as it occurs in nature. As a matter of experience, it seems clear that the general physical and chemical characteristics of the low-rank coals are largely determined by or related to the moisture, whether chemically or physically combined, present in air-dried coal; it is also demonstrable by trial that the low-rank coals cannot be satisfactorily classified on a purely chemical basis by using the moisture free form of analysis. The low-rank coals of the western United States include numerous well-defined types, many of which were referred to in a classification proposed by Ashley,2 in which the physical and use properties of the coals were made the primary basis for their systematic grouping. When testing this classification by replotting analyses of these type coals according to the Seyler scheme of classification,3 a satisfactory parallelism between use properties and chemical constitution of the dry coal was found among

Jan 5, 1925

By D. A. Rice, M. C. Fuerstenau

Flotation data indicate that sulfonate and amine adsorb physically on manganese oxide; oleate also adsorbs physically if the zero point of charge is sufficiently high. Chemisorption of oleate occurs on pyrolusite between pH 8 and 9, and possible mechan- isms of collector adsorption involving metal ion hydrolysis are discussed. The flotation characteristics of most metal oxides1-15 have been examined with standard collectors such as fatty acids and sulfonates. From these studies it would appear as though electrical phenomena are important when shorte r-chained collectors are involved. For example, Iwasaki, Cooke, and Choi9 have shown that dodecyl amine and dodecyl sulfate float iron oxide above and below the zero point of charge, respectively. In another system, D.W. Fuerstenau and Modi10 have shown that dodecyl sulfate, dodecyl

Jan 1, 1969

NEW MEMBERS The following list comprises the names of those persons who became members during the period Sept. 10, 1916, to Oct. 10, 1916. BLOOMFIELD, EDWIN CHARLES, Min. Engr., 1012 Standard Bank Bldg., Vancouver, B. C., Canada. BRINGS, HENRY, Min. and Met. Engr., Chief Engr., and Geol., Mollet-Mesrine, 1212 Mills Bldg., El Paso, Texas. CHASE, MARCH F., Vice-Pres., Commercial Acid Co., 1906 Boatmens Bank Bldg., St. Louis, Mo. CUMMINGS, ALVIN M., Asst. Mine Supt., Witherbee, Sherman & Co., Inc., Mineville, Essex Co., N. Y. DOUGLASS, GEORGE M., Genl. Safety Inspector, Amer. Smelt. & Ref. Co. 120 Broadway, New Fork, N. Y. EMRICH, CLARENCE T., Chief Chemist, Old Dominion Copper Min. & Smelt. Co., Box 1163, Globe, Ariz. GARDANIER, SUTTER ALBERT, Assayer, Mgr., Douglas Assay Co., Douglas, Cochise Co., Ariz.

Jan 10, 1916

By J. D. Kalasky

Continuous mining has revolutionized the coal industry but intensified the problems of earlier mechanization. From the installation of the first miner, it was recognized that face ventilation would be one of these problems. To establish an efficient work cycle for the equipment being used, conventional mechanized mining provides four or more development faces. Continuous mining, relying on a single machine, requires only one face, although more than one can be driven alternately by the same machine. In gaseous areas mined by the older methods, the intermittent rate of exposure allows time for the face to bleed off or be cleared, and the width obtained with conventional units makes it possible to hang a brattice line almost to the face. Continuous mining increases the ventilation hazards; there is no margin of time, and very limited space. For all practical purposes, continuous miners available today can be grouped into two major types, rippers and borers. The two can be further classified, respectively, as flexible and rigid. Both types have been in operation in U. S. coal mines for the past five to ten years in a number of seams, under various conditions ranging from slightly gaseous to very gaseous. Common methods of face ventilation utilizing jute or plastic brattice material for line curtains, stoppings, and checks have so far met with success. Air volumes to operating sections are greater than for conventional mining, and specific instructions have been given to section crews stressing the precautions needed in dealing with a steady rate of gas emission and the importance of maintaining reasonably air-tight brattice to direct a good steady flow toward the face at all times. Operators of continuous miners, as well as the foreman on each section, are equipped with an approved safety lamp for gas testing. When the miner is in steady operation, tests for gas at the face are made at 15 to 30-min intervals, depending on the

Jan 1, 1960

By W. T. Thom

In previous classifications of coal, it has been customary to regard moisture eliminated from coal samples between 20 and 100 C. as extraneous matter, rather than as a constituent part of the coal. It seems, however, that the physical character and use properties of the low-rank coals are directly related to the amount of such moisture present, and recent chemical work has shown' that such coals contain unstable groupings which decompose between 20 C. and temperatures somewhat above 100" C., with the splitting off of moisture. According to this view, the moisture eliminated from air-dried coal below boiling point is similar in all essential respects to moisture eliminated above 100" C., and is produced by analogous reactions; and inasmuch as the moisture given off above 100" C. has always been treated as a constituent of the volatile matter of coal, it would seem that consistent usage would include as a part of the volatile matter all moisture present as an essential component of the coal as it occurs in nature. As a matter of experience, it seems clear that the general physical and chemical characteristics of the low-rank coals are largely determined by or related to the moisture, whether chemically or physically combined, present in air-dried coal; it is also demonstrable by trial that the low-rank coals cannot be satisfactorily classified on a purely chemical basis by using the moisture free form of analysis. The low-rank coals of the western United States include numerous well-defined types, many of which were referred to in a classification proposed by Ashley,2 in which the physical and use properties of the coals were made the primary basis for their systematic grouping. When testing this classification by replotting analyses of these type coals according to the Seyler scheme of classification,3 a satisfactory parallelism between use properties and chemical constitution of the dry coal was found among

Jan 1, 1925