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By H. J. Schwellenbach, J. J. Strohl

This paper relates the results obtained by decreasing the size of feed to a rod mill screen circuit. As would be expected, added production was gained and a finer grind with no tonnage loss was made possible. THE MacIntyre mill of the National Lead Co. has four parallel sections in which magnetic and gravity separations are made. Ore from a 5000-ton bin is fed by Hardinge constant weight feeders to a 6x12-ft open-end Marcy rod mill in each section. Rod mill discharge is bucket elevated to two 4x10-ft Tyrock screens whose oversize is returned to the rod mill. Screen undersize is pumped to Crockett separators for magnetite removal, and the Crockett tailings are sized and tabled to make an ilmenite concentrate. Minus 200-mesh material, overflowed by the Crockett and Dorrco sizers is thickened, de-slimed, and concentrated by flotation.' By 1948, the development of a successful slime flotation process and numerous improvements in the gravity circuit of the mill had increased the capacity of the available concentrating equipment. At the same time, improvements in the operating techniques of the dry crushing plant and improved feeding of the crusher by the mining department had appreciably increased the production rate per operating hour in that plant. Therefore, it was decided to take advantage of the added crusher capacity to produce a finer rod mill feed and in that way increase grinding capacity. At approximately the same time, finer screens were installed in the rod mill circuits to give finer grind and thus improve liberation of the magnetite and ilmenite from the gangue and from one another. Prior to the first part of 1948, a 3/4-in. limiting screen was used for sizing rod mill feed. The first reduction in crushing plant screen size was to 1/2 in. With this screen, the circulating load in the tertiary crushing circuit was too high and plant capacity dropped below a practical hourly rate. A 9/16-in.-sq opening screen, installed next, proved satisfac-

Jan 1, 1951

By O. R. Wagner, R. O. Leach

Immiscible displacement tests were performed in a consolidated sandstone core over the interfacial tension range from less thdn 0.01 to 5 dynes/cm to better define how interfacial tension (IFTJ reduction can lead to increased oil recovery. Data obtained were displacement efficiency at breakthbrough vs IFT for both drainage and imbibition conditions. These tests simulate water flooding under oil-wet and water-wet conditions, respectively. Results of the study have shown that displacement efficiency under both oil-wet and water-wet conditions can be markedly improved by a sufficient reduction in IFT. In the particular porous media used and for the low pressure gradients employed, the IFT must be reduced to a value less than about 0.07 dynes/cm to achieve increased recovery at the time of breakthrough of the injected phase. Below 0.07 dynes /cm, further small reductions in IFT result in large increases in displacement efficiency. Observed increases in recovery were obtained at pressure gradients which are well below those which can exist in the interwell area of a reservoir under water flood. The effect of pressure gradient on recovery is discussed. INTRODUCTION A residual oil saturation remains in rock which has been water flooded because, under usual reservoir conditions, the driving force which can be generated is inadequate to expel oil trapped by capillary forces. Since these capillary forces can be reduced by reducing the IFT a frequently studied method of increasing oil recovery has been the use of surfactants to reduce the water-oil interfacial tension. Mungan l observed improved recovery in both water-wet and oil-wet systems at 1.1 dyne /cm IFT, finding that the amount of improvement was greater in oil-wet systems. Moore and Blum,2 working with visual flow cell micro-models, con- cluded that recovery cannot be improved in water-wet systems by injecting surfactant solutions. They calculated that, for a pressure gadient of 1 psi/ft in their model, the IFT must be reduced to 0.03 dynes/cm to release oil trapped under water-wet conditions. Berkeley et al.3 indicated that, at representative field flooding rates, the IFT must be reduced to 0.001 dyne/cm to improve recovery, Thus, there is a wide variation of opinion about the IFT levels needed to improve recovery under field conditions. These previous investigators all have used as their experimental method the addition of surfactants to the injected water. The use of surfactant solutions to reduce IFT creates two experimental problems: (1) the loss of surfactant through adsorption on reservoir rock can obscure the true IFT value which exists at the displacement front, and (2) at very low values of IFT emulsifica-tion of oil and water commonly occurs. It is difficult, therefore, to determine whether the increased recovery is caused by IFT reduction as such, or is instead caused by emulsification. Also the properties of the available surfactants limit the IFT range which can be studied. In the present study the purpose is to better define how interfacial tension reduction can lead to increased oil recovery. A matter of great interest is the amount of recovery improvement potentially achievable in this way. The study was made using very low pressure gradients which was well within the range achievable by water flooding in the interwell region of petroleum reservoirs. A unique experimental approach was chosen to avoid adsorption and emulsification problems, and to allow convenient control of IFT. The fluid phases used were the equilibrium vapor and liquid phases of the methane-n-pentane system. The interfacial tension level was varied by changing the equilibrium pressure of the methane-pentane system over the range from 1,200 psia to near the critical pressure (2,420 psia). All tests were performed at a controlled temperature of 100F. The IFT-vs-pressure relationship for the methane-pentane system was based on the data of Stegemeier and Hough,6 and on new data obtained in this study. With this experimental approach it has been possible to study displacement at lower values of IFT than have been previously investigated.

Jan 1, 1967

By E. S. Fisher

GRAIN coarsening implies a discontinuous type of grain growth during which a few grains in a fine grained recrystallized matrix grow to large grain sizes at the expense of the matrix. Studies of this phenomenon in various metals1,2 indicate that grain coarsening may result when continuous grain growth in a fine grained matrix is inhibited by either a dispersion of very fine inclusions or by a strong texture. In the former case a period of annealing time exists prior to grain coarsening during which grain growth inhibition is gradually de- creased by dissolution or coalescence of the dispersed inclusions. This mechanism can be made to occur in uranium during anneals at high a phase temperatures. ' A study of some of the factors influencing the kinetics of grain coarsening and the coarse grain sizes in a uranium has led to a method for preparing a uranium single crystals. Previously such single crystals containing considerable substructure were prepared at this laboratory by a phase change method, similar to that described by Cahn.3 Attempts to prepare more perfect single crystals by strain-anneal techniques were unsuccessful. Cahn3- as reported his attempts to apply such techniques to uranium. He proposed that the failure of strain-anneal techniques is basically due to the many twins which

Jan 1, 1958

By A. M. Gaudin, C. S. Chang

Adsorption was measured for barium ion and laurate radical, using radioactively marked agents, over wide range of concentrations. Laurate adsorbed in absence of barium fails to float. With barium, flotation-effective laurate coating needs not exceed 5 pct of monolayer. Barium adsorption then is several fold larger. No barium laurate coating is obtained. IN general, fatty acids or their alkali salts do not cause clean quartz to float. However, the presence of multivalent ions, such as the alkaline-earth metal ions and heavy-metal ions, can activate quartz and thus make it respond to soap flotation. The mechanism of activation and soap flotation of quartz has been studied.'-' The problem was attacked by making flotation tests rather than by careful adsorption measurements on suspensions of ground quartz in solutions containing the activator and the collector. Attempts have been made to determine the adsorption of barium ion and calcium ion on quartz. The results have only qualitative value as the analytical methods were not adequately precise. Artificial radioactivity and progress in radioactivity detection have introduced a new analytical tool, which can have a sensitivity several orders of magnitude greater than that of other methods."-" In the experimental work described in this paper the radioactive tracers, barium 140 and carbon 14, were employed. Lauric acid was synthesized, having a radioactive carbon atom and was used with Ba" to study the adsorption of barium and laurate ions from aqueous solution on ground quartz. Flotation tests, using the vacuum flotation technique,' were run in conjunction with the adsorption experiments. The object of this investigation was to understand better the reaction mechanism of barium activation and soap flotation of quartz. Methods and Materials Quartz Sample Preparation: Lumps of hand-picked quartz, washed free of stains, were reduced in size to —20 mesh in laboratory crushers. The product was boiled in concentrated hydrochloric acid to remove the abraded iron. The cleaned product then was ground dry in a laboratory porcelain mill, using siliceous pebbles, to pass through a 200 mesh screen. The ground product was deslimed by sedimentation at 37 microns. This —200 mesh +400 mesh material was subjected again to boiling with concentrated hydrochloric acid, followed by washing with distilled water and further desliming. The cycle was repeated until no trace of iron could be detected in the wash liquor. During the final washing, the pH of the wash water was checked to insure the complete removal of the acid from the mineral. The quartz then was rinsed with conductivity water. The resulting product was dried in a drying oven and stored in mason jars. The impurities (spectrographic) were as follows: Al, 0.01 to 0.001 pct; Li, Mg, Mn, Na, each less than 0.001 pct; Fe and Cu not detected. The specific surface of the quartz sample was determined by the krypton gas adsorption method.' The average of two measurements was 881 sq cm per g. The calculated specific surface for 37/74-micron quartz particles, using a surface factor of 1.96; is 900 sq cm per g. This is in good agreement with the measured value of 881 sq cm per g. Beta-Counting Method: The radioactive isotope of barium used in the experimental work was barium 140. It has a sufficiently long half-life, 12.8 days, emits high-energy beta particles (up to 1.0

Jan 1, 1953

By A. M. Gaudin, C. S. Chang

Adsorption was measured for barium ion and laurate radical, using radioactively marked agents, over wide range of concentrations. Laurate adsorbed in absence of barium fails to float. With barium, flotation-effective laurate coating needs not exceed 5 pct of monolayer. Barium adsorption then is several fold larger. No barium laurate coating is obtained. IN general, fatty acids or their alkali salts do not cause clean quartz to float. However, the presence of multivalent ions, such as the alkaline-earth metal ions and heavy-metal ions, can activate quartz and thus make it respond to soap flotation. The mechanism of activation and soap flotation of quartz has been studied.'-' The problem was attacked by making flotation tests rather than by careful adsorption measurements on suspensions of ground quartz in solutions containing the activator and the collector. Attempts have been made to determine the adsorption of barium ion and calcium ion on quartz. The results have only qualitative value as the analytical methods were not adequately precise. Artificial radioactivity and progress in radioactivity detection have introduced a new analytical tool, which can have a sensitivity several orders of magnitude greater than that of other methods."-" In the experimental work described in this paper the radioactive tracers, barium 140 and carbon 14, were employed. Lauric acid was synthesized, having a radioactive carbon atom and was used with Ba" to study the adsorption of barium and laurate ions from aqueous solution on ground quartz. Flotation tests, using the vacuum flotation technique,' were run in conjunction with the adsorption experiments. The object of this investigation was to understand better the reaction mechanism of barium activation and soap flotation of quartz. Methods and Materials Quartz Sample Preparation: Lumps of hand-picked quartz, washed free of stains, were reduced in size to —20 mesh in laboratory crushers. The product was boiled in concentrated hydrochloric acid to remove the abraded iron. The cleaned product then was ground dry in a laboratory porcelain mill, using siliceous pebbles, to pass through a 200 mesh screen. The ground product was deslimed by sedimentation at 37 microns. This —200 mesh +400 mesh material was subjected again to boiling with concentrated hydrochloric acid, followed by washing with distilled water and further desliming. The cycle was repeated until no trace of iron could be detected in the wash liquor. During the final washing, the pH of the wash water was checked to insure the complete removal of the acid from the mineral. The quartz then was rinsed with conductivity water. The resulting product was dried in a drying oven and stored in mason jars. The impurities (spectrographic) were as follows: Al, 0.01 to 0.001 pct; Li, Mg, Mn, Na, each less than 0.001 pct; Fe and Cu not detected. The specific surface of the quartz sample was determined by the krypton gas adsorption method.' The average of two measurements was 881 sq cm per g. The calculated specific surface for 37/74-micron quartz particles, using a surface factor of 1.96; is 900 sq cm per g. This is in good agreement with the measured value of 881 sq cm per g. Beta-Counting Method: The radioactive isotope of barium used in the experimental work was barium 140. It has a sufficiently long half-life, 12.8 days, emits high-energy beta particles (up to 1.0

Jan 1, 1953

By H. E. Strauss

The short-time tensile-strength test, while it has not attained the practical importance of the creep test at elevated temperatures, has the advantage of being rapid and is satisfactory for determining relatire strengths. For platinum and its alloys, which frequently are used at high temperatures under ill-defined conditions, the short-time test provides useful data that aid in the selection of the most promising alloy for each use. Measurements have been made upon 13 alloys, using wire 0.0031 in. in diameter, the choice of alloys and of wire size being determined by the requirements of a practical problem. Later the measurements were extended to higher temperatures by the use of heavier wire, 0.010 in. in diameter. Apparatus The use of fine wire made the necessary equipment very simple, since no effort was made to measure the elongation. A small platinum-wound horizontal furnace was used, 1/2 in. in internal diameter by 1 ft. long, with the wire threaded through it. The wire, clamped at one end while the other ran over a ball-bearing pulley, of a total length of 29 in., was loaded directly by running sea sand into an attached basket, making the rate of loading and not of elongation constant. The sand flowed from a funnel, under a head of 3 in., into the basket 3 in. below the orifice, at the rate of 170 grams per minute. Pulley friction and bending resistance of the wire as well as the force of impact of the sand could be neglected, being 3 grams and 0.5 grams, respectively. Furnace temperature was uniform within ±5° C. over a length of 3 in., although a drift with time occurred, the largest amount being 20" C. No provision was necessary for a controlled atmosphere. In making the measurements, the furnace was brought to equilibrium before being used, and the temperature was measured with a platinum platinum-10 per cent rhodium thermocouple and a high-resistance pyrometer before and after all the tests at one temperature. The wire sample, after being threaded through the furnace and attached to the

Jan 1, 1940

By H. E. Strauss

The short-time tensile-strength test, while it has not attained the practical importance of the creep test at elevated temperatures, has the advantage of being rapid and is satisfactory for determining relatire strengths. For platinum and its alloys, which frequently are used at high temperatures under ill-defined conditions, the short-time test provides useful data that aid in the selection of the most promising alloy for each use. Measurements have been made upon 13 alloys, using wire 0.0031 in. in diameter, the choice of alloys and of wire size being determined by the requirements of a practical problem. Later the measurements were extended to higher temperatures by the use of heavier wire, 0.010 in. in diameter. Apparatus The use of fine wire made the necessary equipment very simple, since no effort was made to measure the elongation. A small platinum-wound horizontal furnace was used, 1/2 in. in internal diameter by 1 ft. long, with the wire threaded through it. The wire, clamped at one end while the other ran over a ball-bearing pulley, of a total length of 29 in., was loaded directly by running sea sand into an attached basket, making the rate of loading and not of elongation constant. The sand flowed from a funnel, under a head of 3 in., into the basket 3 in. below the orifice, at the rate of 170 grams per minute. Pulley friction and bending resistance of the wire as well as the force of impact of the sand could be neglected, being 3 grams and 0.5 grams, respectively. Furnace temperature was uniform within ±5° C. over a length of 3 in., although a drift with time occurred, the largest amount being 20" C. No provision was necessary for a controlled atmosphere. In making the measurements, the furnace was brought to equilibrium before being used, and the temperature was measured with a platinum platinum-10 per cent rhodium thermocouple and a high-resistance pyrometer before and after all the tests at one temperature. The wire sample, after being threaded through the furnace and attached to the

Jan 1, 1940

By AIME AIME

JOHN LIVERMORE CHRISTIE belongs to that group of metallurgists who entered the industrial field during World War I and have been responsible for many of the important metallurgical developments since that time. He was born in Montclair, N. J., on Jan. 31, 1894. After graduating from Montclair High School he attended Sheffield Scientific School, Yale University, received his Ph.B. degree in chemistry in 1915 and that same year was employed by the Bridgeport Brass Co. in its laboratory. Among his first duties was the return to Sheffield Scientific School for two years of graduate work in metallography under C. H. Mathewson; receiving his M.S. degree in 1917. Thus we see him becoming one of that group of eminent physical metallurgists who, with Dr. Mathewson's teaching as a foundation, have done outstanding work in metallurgy.

Jan 1, 1945

By William P. Blake

The occurrence and distribution of phosphorus is one of the most important questions with which the steel-maker has to do. Large sums are invested in processes for the removal of this element from ores before they come to the blast-furnace, and much greater sums in freeing the pig-iron from it. Mechanical engineers are becoming more and more critical of the amount of total phosphorus left in structural steel, the tendency being to require that it be reduced to the lowest possible figure. The old maximum of 0.1 per cent. is now considered much too high for first-class structural steel, and demands for 0.03 to 0.01 per cent. are by no means unheard of. The first to speak, in a scientific way, of the harmful effect of phosphorus on iron and steel appears to have been Meyer, who, in 1781, made mention of what we now term "cold-shortness," ascribing it to the presence of this metalloid, but not suggesting any remedy. It is, however, doubtful if a clear idea of this subject was possessed by the scientific world until after the invention of the pneumatic or Bessemer process, in 1855-56. One of the chief obstacles in the way of this renowned metallurgist,—one, indeed, the removal of which was the sine qua non of success,—was the phosphorus in the iron blown. The effect of the phosphorus does not seem to have been apprehended until many and costly experiments had been made, and then the required minimum percentage of it in the iron was secured only by the use of low-phosphorus ores. It was not until '1879-80 that practical success was reached, by the Thomas process, in the actual removal of the phosphorus from the iron. We now know something of the effect of the total amount of phosphorus on iron and steel, but very little as to the effect of the condition of the phosphorus. The state of combination in which

Jan 1, 1893

By C. S. Simons

Manufacturers of filtering, thickening or clarifying equipment, have been active in developing machines to meet increasingly rigid operator requirements, and the innovations resulting from this effort are moving into commercial applications. In general, the results of these applications are reported to be good. Little has been reported on progress in theory. The growing insistence on the part of pollution control agencies that waste water discharged into streams contain less and less suspended solids is being felt by a broad cross section of industry. A new clarifier, based on the often rediscovered fact that suspended solids settle more rapidly in inclined channels, is being marketed by Neptune MicroFLOC of Corvallis, Ore. This unit employs modules of inclined tubes, mounted in the upper zone of the clarifier, which carry the water flow. These were developed for light solids, such as those encountered in domestic water treatment and in paper mill waste water. In these applications, flow rates up to about three times those permissible in conventional clarifiers are reported to give comparable overflow turbidity. By combining these units with mixed media filters, high clarity may be obtained with minimum capital. Use of such units in the metallurgical industry, particularly where water reuse or effluent quality is important, should grow.

Jan 1, 1970

By Walter Kauenhowen

Germany's crude oil production during 1935 totaled 3,007,711 bbl., an increase of 36.6 per cent over the 2,202,214 bbl. produced in 1934. The Nienhagen-Haenigsen field furnished 77 per cent of the total 1935 production. Cumulative production figures for Germany's two most important oil fields, Wietze and Nienhagen, show that during the period from 1872 to the close of 1935 the Wietze field produced 13,325,536 bbl. and the Nienhagen field 9,340,870 bbl. Table 1 gives statistics of German production since 1928, arranged both by fields and by oil provinces. Fig. 1 demonstrates the production of the various German fields since 1890. New Fields Discovered During 1935 five new fields came into production. The first of these, the Moelme-Hoheneggelsen field near Hanover, was opened up in April. This region has been sporadically drilled for oil since 1882, but not until 1935 was production on a commercial scale obtained. The oil comes from Mesozoic sandstones on the flanks of a shallow salt plug. Also during April, oil was found in commercial quantities in the Rhine valley at Forst, near Bruchsal. Tertiary and Mesozoic sandstones cut by faults of the Rhine Graben form the reservoir structures in this area. In July a wildcat well drilled on the Fallstein structure, a broad Triassic anticline near Halberstadt, came in as a producer from Permian (Zechstein) dolomite. In September commercial oil mas found at Gifhorn, near Braunschweig, in Wealden sandstones associated with a shallow, geophysically discovered salt plug. During the same month production was obtained at Heide, in Holstein, from the Permian Rotlie-gendes formation, in a structural high on which oil seepages have been known for years. Drilling Activities Published information indicates that during 1935 drilling totaled 574,000 ft., as compared with 436,000 ft. in 1934; 233,000 ft. in 1933 and 151,000 ft. in 1932. The German Government is subsidizing wildcat

Jan 1, 1936

By Walter Kauenhowen

Germany's crude oil production during 1935 totaled 3,007,711 bbl., an increase of 36.6 per cent over the 2,202,214 bbl. produced in 1934. The Nienhagen-Haenigsen field furnished 77 per cent of the total 1935 production. Cumulative production figures for Germany's two most important oil fields, Wietze and Nienhagen, show that during the period from 1872 to the close of 1935 the Wietze field produced 13,325,536 bbl. and the Nienhagen field 9,340,870 bbl. Table 1 gives statistics of German production since 1928, arranged both by fields and by oil provinces. Fig. 1 demonstrates the production of the various German fields since 1890. New Fields Discovered During 1935 five new fields came into production. The first of these, the Moelme-Hoheneggelsen field near Hanover, was opened up in April. This region has been sporadically drilled for oil since 1882, but not until 1935 was production on a commercial scale obtained. The oil comes from Mesozoic sandstones on the flanks of a shallow salt plug. Also during April, oil was found in commercial quantities in the Rhine valley at Forst, near Bruchsal. Tertiary and Mesozoic sandstones cut by faults of the Rhine Graben form the reservoir structures in this area. In July a wildcat well drilled on the Fallstein structure, a broad Triassic anticline near Halberstadt, came in as a producer from Permian (Zechstein) dolomite. In September commercial oil mas found at Gifhorn, near Braunschweig, in Wealden sandstones associated with a shallow, geophysically discovered salt plug. During the same month production was obtained at Heide, in Holstein, from the Permian Rotlie-gendes formation, in a structural high on which oil seepages have been known for years. Drilling Activities Published information indicates that during 1935 drilling totaled 574,000 ft., as compared with 436,000 ft. in 1934; 233,000 ft. in 1933 and 151,000 ft. in 1932. The German Government is subsidizing wildcat

Jan 1, 1936

By R. T. Hukki

This paper presents a series of equations for mechanical ball wear, relating parameters of ball size, mill speed, and mill diameter. The fundamental equation, Eq. 12, presented here is introduced to correlate these basic parameters and thus define and clarify the concept of ball wear. This equation is offered as a general rule, which may be modified to apply to individual problems of grinding. BALL wear as observed in grinding installations is the combined result of mechanical wear and corrosion. Corrosion should be a linear function of the ball surface available. Ball corrosion, however, has been studied so little that its effect, although of great importance, cannot be included in the analyses given here. In a separate paper' it is shown that 1 n = 0.7663 np----=— rpm [1] vD P = c, np D kw [2] T=c²(np)n De tph [3] In these equations n — actual mill speed, rpm np = calculated percentage critical speed D = ID of mill in feet P = power required to operate a mill, kw T = capacity of a mill, tph C¹ and c² - appropriate constants in = exponent of numerical value of 1 5 m 1.5 Exponent m is the slope of a straight line on logarithmic paper relating mill speed (on the abscissa) and mill capacity (on the ordinate). It is generally accepted, although not sharply defined, that ball wear in mills running at low (cascading) speeds is a function of the ball surface available. Accordingly, the wear of a single ball may be considered to be a homogeneous, linear function of its surface and of the distance traveled. Thus dw = f¹(d2) . f2(ds) [4] where dw is the wear of a single ball in time dt, d the diameter of the average ball in ball charge, and ds the distance traveled by the ball in time dt. Indicating that ds - a D n dt, the wear of the average ball in time dt becomes dw = f¹(d2) . f2(Dn dt) 1 --- f¹ (d1) f² (D c3 np-----— dt) \/D = c,d² n, D dt The rate of wear of the average ball is given by dw/dt. dw/dt = c, d² np D lb per hr [5] The weight of the ball charge per unit of mill length is a function of D The number of balls of size d in the ball charge is = f³(D2)/f4(d³). The rate of wear of the total ball charge equals the number of balls times rate of wear of the average ball. Thus rate of total ball wear = — . (dw/dt) w. c, . (l/d) . n,, D lb per hr [6] which is the equation of ball wear in low speed mills. In a mill running at a low speed, grinding is the result of rubbing action within the ball mass and between the ball mass and mill liners. When the speed of the mill is gradually increased toward the critical, the impacting effect of freely falling balls becomes increasingly prominent in comparison with the rubbing action. Reduction of ore takes place partly by rubbing, partly by impact. The share of the freely falling balls in the reduction of ore reaches its practical maximum at a speed somewhat less than the critical; at that speed grinding by rubbing has decreased to a low value. It may be reasonable to think that size reduction by freely falling balls should reach its theoretical maximum at the critical speed, if the fall of the balls were not hindered by the shell of the mill beyond the top point; grinding by rubbing would cease at the critical speed. As a first approximation, wear of freely falling balls may be considered to be a homogeneous, linear function of the force at which they strike pieces of rock and other balls at the toe of the ball charge. The force equals mass times acceleration. The mass of a ball is a function of d3 and its acceleration is a function of the peripheral speed of the mill. The wear of a single ball of size d representing the average ball in a ball charge will therefore be w¹ = f3(F) = f (d3) f7 (v). [7] Indicating that v = D n, and n = c³ np 1/vD, Eq. 7 becomes W1 = cn d3 np Do.5 lb per hr. [8] Total wear of the ball charge equals number of balls times the wear of the average ball. Number of

Jan 1, 1955

By Hsun Hu

The formation of annealing textures in high-purity silver, from the various rolling textures obtanled in the course of texture transition, was studied. It was found that from a brass-type rolling texture the recrystallization texture is mainly (120) [211] type, which is quite different from the recrystallization texture of brass. From a predominantly copper-type rolling texture, the reclystallization texture is mainly (100) [001]. The recrystallization texture of silver- varies also with the degree of purity. In each case, however, the reorientation can be expressed as [Ill] rotations of 30° to 40°, which is consistent with the oriented growth theory of the formation of annealing textures. ThE recrystallization textures of rolled silver were studied long ago by Glocker and co-workers (1924-27) and were reported to be (113) [iil] upon annealing at low temperatures.1 Since that time, no further study of the recrystallization textures of silver, particularly with the modern techniques of quantitative texture determinations, has been reported in the literature. In a previous study2y3 it was found that the rolling texture of high-purity silver (99.999 +pct pure) is changed gradually from the common silver- or brass-type to the copper-type by raising the temperature of rolling from 0" to 200°C. The formation of annealing textures from the various rolling textures in the same material is, therefore, of considerable interest. The present paper constitutes the results of such a study. MATERIAL AND METHOD Specimens were taken from the same strips of high-purity silver* that were used previously for

Jan 1, 1962

By Norman B. Pilling

Practical limitations to the usefulness of silicon steels are the hardness and brittleness silicon imparts to iron, making iron-silicon alloys of more than 8 per cent. silicon content unusable except where castings can be employed. In the use of commercial silicon steel, in thin rolled sheets, as in transformer construction, when the silicon content exceeds 4.2 per cent. the sheet is too brittle for satisfactory shaping by punching or similar operations. When such a brittle steel is sheared, it frequently breaks along a haphazard path in advance of the cutting tool. In Fig. 1 is shown a slightly enlarged view of the sheared edge of a 14-mil enameled sheet of nominally 4 per cent. silicon steel. In 5 in. along the sheared edge, only 44 per cent. was actually cut; the rest was torn, with the path of fracture varying widely from the path of travel between the shears. This is probably an extreme case of such brittle-ness, but a shearing or punching test is not necessary to reveal brittle-ness of this order; narrow strips will break when bent between the fingers. In Fig. 2, the proportion of actual cut edge is greater, but secondary fractures branch off at about 30" from the line of shearing in advance of the cut. Deprived of the support of adjacent parts of the sheet, the tips of the angles are bent out of the plane of the sheet by the shears, leaving a peculiar flared effect, like the set of the teeth on a saw. An end-on

Jan 1, 1923

By Norman B. Pilling

Practical limitations to the usefulness of silicon steels are the hardness and brittleness silicon imparts to iron, making iron-silicon alloys of more than 8 per cent. silicon content unusable except where castings can be employed. In the use of commercial silicon steel, in thin rolled sheets, as in transformer construction, when the silicon content exceeds 4.2 per cent. the sheet is too brittle for satisfactory shaping by punching or similar operations. When such a brittle steel is sheared, it frequently breaks along a haphazard path in advance of the cutting tool. In Fig. 1 is shown a slightly enlarged view of the sheared edge of a 14-mil enameled sheet of nominally 4 per cent. silicon steel. In 5 in. along the sheared edge, only 44 per cent. was actually cut; the rest was torn, with the path of fracture varying widely from the path of travel between the shears. This is probably an extreme case of such brittle-ness, but a shearing or punching test is not necessary to reveal brittle-ness of this order; narrow strips will break when bent between the fingers. In Fig. 2, the proportion of actual cut edge is greater, but secondary fractures branch off at about 30" from the line of shearing in advance of the cut. Deprived of the support of adjacent parts of the sheet, the tips of the angles are bent out of the plane of the sheet by the shears, leaving a peculiar flared effect, like the set of the teeth on a saw. An end-on

Jan 1, 1923

By John H. Bell

R. B. T. KILIANI, New York, N. Y.-I wish to present some figures based upon actual observation extending over a few months time which seem to prove the author's conclusions. It is a comparison of two machines operating on the same ore, in the same plant, one taking the undersize of ½ -in. screen and the other taking the undersize of 8-mesh. Each of the machines was first operated as a pebble mill, with flint pebbles, in open circuit, then with metal pebbles in open circuit and, finally with metal pebbles in closed circuit. For the first case, the percentage of oversize on 48-mesh, Tyler screen, in the discharge, varied, in the mill taking ½ -in- feed, from 37.2 to 19.9 per cent. The second mill, taking the 8-mesh feed, had a variation in oversize on 48-mesh, from 36.8 per cent: to 0.5 per cent.; so it is seen there is considerable variation in these figures. I have computed the tons per kilowatt-day reduced through 48-mesh for each machine under each one of these conditions, giving 6 sets of figures. The first of these I called 1.0 and determined the ratio of the others to this.. In the snipe way, I figured the relative mechanical efficiency according to Kick's law, using' the figures given by Mr. Taggart in his paper, for ordinal numbers of the Tyler screens. I have also figured the efficiency in mesh-tons per horsepower according to Gates' method by plotting the screen analyses of feed and product and multiplying the area by a constant dependent on the scale used. The commercial efficiency of tons per kilowatt-day reduced through 48-mesh checks very closely with the efficiency by Rittinger's law, within 1 per cent. except in one case. By Kick's law, the efficiency checks fairly closely, within about 5 per cent., with the commercial efficiency of the mill grinding feed, but when we start to grind a finer, 8-mesh material, and especially grinding very fine; with a

Jan 4, 1917

By Donald O. Rausch, Robert H. Merrill

12.1 -1. Introduction. Problems concerning slopes in soils and rock generally arise in connection with road cuts and open pit mines. The angle at which a slope will safely stand is of major economic importance to both the road designer and the open pit operator. Stable slopes in soils and rock are evaluated through two fundamental approaches, namely, soil mechanics and rock mechanics. The approach selected to make this evaluation depends upon the material in the slope. For the purposes of this chapter, only slopes totally in soil or totally in rock are considered. By definition, soils are unconsolidated accumulations of solid materials produced by mechanical and chemical disintegration of rocks or the accumulation of sediments (28); rock is defined as the hard, compact, natural materials composing the crust of the earth (10). The basic factors affecting slopes in soil or rock are similar, although rock strengths are orders of magnitude greater than soil strengths. In general, the strength of large masses of soil depends upon the texture of the soil, the particle size, cohesion, and resistance to tensile and shear stress; the strength of large masses of rock depends upon the strength of the rock and the defects, such as faults, fractures or joints, that intersect the rock. Further, some of the defects in rock are cemented or uncemented, and may be filled with materials that are strong or weak compared to the rock. In slopes of either soils or rock, the stability is presumed to be a function of the slope height, slope angle, the size of the excavation, and the stresses imposed on the soil or rock by tectonic and/or gravity forces, earthquakes, or other static or dynamic forces. In addition, both soil and rock slopes are affected by static and dynamic water pressures in the pores of soils or permeable rocks or in the defects in the rock behind the slope. Visual observations of slope failures also indicate that both soil and rock can deteriorate with time, and this deterioration may be caused primarily by weathering (27).

Jan 1, 1968

By L. W. Holm

Laboratory flooding experiments on linear flow systerns indicated that high oil displacement, approaching that obtained from completely miscible solvents, can be attained by injecting a small slug of carbon dioxide into a reservoir and driving it with plain or carbonated water. Data are presented in this paper which show the results of laboratory work designed to evaluate this oil recovery process, particularly at reservoir temperatures above 100°F and in the pressure range of 600 to 2,600 psi. Under these conditions CO2 exists as a dense single-phase fluid. It was found that a bank, rich in light hydrocarbons, was formed at the leading edge of the CO? slug during floods on long cores. Formation of this bank is probably due to a selective extraction by the C02 and, it is believed, partially accounts for the attractively high oil recoveries. In crddition to the efficient displacernerlt of oil from the pores of the rock by this process, the favorable rnobility ratio related to a C0 2-water flood also contributes to high oil recovery. A further advantage of this process is noted on limestone and dolomite rock, in that the CO1 reacts with the porous medium increasing its permeability. Flooding experiments were conducted on sandstone and vugular dolomite models. The results of this experimental work show the effect on oil recovery of type of porous medium, pore geometry, flooding length, and flooding pressure. The porosity of the cores and rilodels varied from 16 to 21 per cent and their pern~eabilities ranged from 100 to 200 md. A reconstituted West Texas reservoir oil, a West Texas stock tank oil, an East Texas stock tank oil and Soltrol were used to represent reservoir oils in this study. Oil recoveries ranging from 60 to 80 per cent of the original oil in place in these cores were obtained by CO2,-carbonated water floods at pressures between 900 and 1,800 psi, compared with conventional solution gas drive and water-flood recoveries of 30 to 45 per cent on the same cores. Oil recoveries greater than 80 per cent resulted frorn f1oods at pressures above about 1.800 psi. There high recoveries were noted from both the sandstone and the irregular Porosity carbonate cores. In all floods, additional oil was recovered by a solutiorr gas drive resulting from blowdown following the flood. Oil recoveries of 6 to 15 per cent of the original oil in place were obtained during this blowdown period. This additional recovery was found to be a function of oil remaining after the flood, decreasing with decreasing oil saturation. It was also noted that highest oil recoveries by blowdown were obtained when carborlated water rather than plain water followed the CO, slug. INTRODUCTION Miscible phase or solvent flooding processes, which are designed to increase oil recovery -from petroleum reservoirs, involve the injection of small quantities of a petroleum solvent into the reservoir, followed by an inexpensive scavenging fluid which is miscible with the solvent. Essentially complete displacement of oil from the pores of reservoir rock has been obtained by this technique. CO,, although not completely miscible with most reservoir oils at moderate pressures, is highly soluble in these oils at pressures above about 700 psi; there is appreciable swelling and reduction in the viscosity of oil when CO, is dissolved in it. Therefore, CO, could be expected to perform similarly to other oil solvents as a displacing agent. CO, is also highly soluble in water at elevated pressures, so water should be a satisfactory material to drive a slug of CO, through an oil-bearing reservoir. A favorable mobility ratio would be obtained through the reduction in viscosity of the oil and the use of water as a final displacing agent. A number of investigations of the use of CO, to improve oil recovery have been reported in the literature.2,3,4,5,6 These studies, however, have been conducted on uniform porosity sandstone at relatively low temperatures and pressures. The behavior of CO1 as a flooding agent at temperatures above its critical temperature could not be predicted adequately from these studies, particularly for the case of non-homogeneous rock. The purpose of this work was to evaluate the oil recovery efficiency of a process involving the injection of a CO2 slug followed by carbonated water, at reservoir temperatures above 100°F and in the pressure range of 600 to 2,600 psi, and to compare this process with conventional water flooding. The investigations were primarily designed to provide information on the efficiency of the process in irregular porosity carbonate rock. The effects of flooding path length, the presence of free gas, the type of oil to be recovered, and the amount of solvent required were also determined. The essential results of static phase behavior studies and experimen-

By Lyndon L. Foley

The proper spacing of oil wells is a problem of vital importance to the oil industry. Conservation demands a maximum recovery, while economic considerations attach primary importance to profitable extraction of oil. Formulas have been evolved,1-4 which attempt to solve the spacing problem mathematically, using reservoir characteristics as factors. Comparisons have been made of fields producing from supposedly similar sands, which have been drilled to varying densitiesl5,6 and also of different leases in the same field. 5-8 Intermediate wells have been drilled in old, depleted fields to test the efficiency of drainage by the original operation.9-11 Intermediate wells have been drilled also to obtain cores of the depleted sand for analysis, from which to learn the degree of efficiency of extraction. The problem is being attacked by many students, and along several different lines. Unfortunately, the fields now depleted were produced generally without restriction, and conclusions drawn from them may not apply to fields operated under restricted production. Reservoir conditions in a restricted field, especially reservoir pressures and pressure gradients within the reservoir, are quite different from those in a field produced to capacity. Many people have held the idea that the closer the spacing, the greater the recovery. This general statement is not always true, as other factors than well spacing enter into the recovery problem. Cutler,5 who has been quoted frequently by advocates of close spacing, limited his conclusions to gas-drive fields, and to the particular fields and spac-ings that he investigated. Hill and Sutton7 analyzed four tracts in the Powell field; the tract most closely drilled had the third largest recovery per acre-foot, and the tract with the widest spacing had the second largest recovery per acre-foot. A search of the references to well spacing in the publications of the U. S. Bureau of Mines5,13-19 discloses repeated condemnations of the wastefulness of the practice of town-lot drilling.

Jan 1, 1938