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By W. C. Winegard, C. J. Simpson, C. J. Beingessner

VARIOUS organic compounds, such as borneol, carbon tetr a bromide, and hexachloroethane, solidify as transparent plastics with a fcc structure. Each of these substances undergoes a solid-state transformation from the plastic phase to a brittle phase at temperatures slightly above 20°C. Since it was known that these plastic crystals solidified like metals,1 it was decided to investigate the possibility that solid-state grain growth would occur in the same way as it does in metals. Two-dimensional grain growth in thin films of plastic organic compounds has been studied with the aid of cinemicrophotography. Samples varying in thickness between 250 and 1000 @ were prepared by subliming a thin layer of the compound onto a microscope slide plate which was then covered with a second slide plate.

Jan 1, 1968

By James E. Hoffmann, John A. Bonucci, Peter D. Parker

A hydrometallurgical process has been developed for the recovery of high-purity silver from sulfated residues. The process eliminates the high temperature operations ordinarily associated with silver recovery and refining. The crux of the process is a metathetical leach which maintains the sulfate ion concentration at a level which both allows silver nitrate to be freely soluble and simultaneously depresses the solubility of lead nitrate. The subsequent hydrolytic purification of the silver nitrate solution, the recovery of high-purity silver by electrowinning in a diaphragm cell, and the final product purity are discussed.

Jan 1, 1981

By R. W. H. Atcherson

BLAST-FURNACE flue dust is one of the most troublesome operating factors in the iron and steel industry. It is usually involved in all the unpleasant phases of blast-furnace operations. It adds to our aggravations until we are willing to spend large sums of money to keep it out of our stoves and boilers acid more money to handle it again and again on one scheme or another to induce the furnaces to retain it without bad after effects. Several successful operators claim that it is useless to recharge raw flue dust because the furnace would never have blown it out if it had been suitable material for blast-furnace consumption. Most of us who have made persistent efforts to return raw flue dust to the furnaces have decided that it is very often false economy to do so. Yet some remarkable results have been attained at the Ohio Works of the Carnegie Steel Co. through recharging raw dust. The plant comprises six modern blast furnaces. Up to 1909, about 300,000 tons of flue dust had accumulated in stock piles. During the last 10 years, there have been recharged into these furnaces all of the flue dust recovered from the furnace operations, the entire stock pile of flue dust, and nearly 80,000 tons of dust shipped from other furnaces of the Carnegie Steel Co. The results obtained are shown in Table 1.

Jan 2, 1920

By R. W. H. Acherson

Blast-furnace flue dust is one of the most troublesome operating factors in the iron and steel industry. It is usually involved in all the unpleasant phases of blast-furnace operations. It adds to our aggravations until we are willing to spend large sums of money to keep it out of our stoves and boilers and more money to handle it again and again on one scheme or another to induce the furnaces to retain it without bad after effects. Several successful operators claim that it is useless to recharge raw flue dust because the furnace would never have blown it out if it had been suitable material for blast-furnace consumption. Most of us who have made persistent efforts to return raw flue dust to the furnaces have decided that it is very often false economy to do so. Yet some remarkable results have been attained at the Ohio Works of the Carnegie Steel Co. through recharging raw dust. The plant comprises six modern blast furnaces. Up to 1909, about 300,000 tons of flue dust had accumulated in stock piles. During the last 10 years, there have been recharged into these furnaces all of the flue dust recovered from the furnace operations, the entire stock pile of Rue dust, and nearly 80,000 tons of dust shipped from other furnaces of the Carnegie Steel Co. The results obtained arc. shown in Table 1.

Jan 1, 1922

By R. W. H. Acherson

Blast-furnace flue dust is one of the most troublesome operating factors in the iron and steel industry. It is usually involved in all the unpleasant phases of blast-furnace operations. It adds to our aggravations until we are willing to spend large sums of money to keep it out of our stoves and boilers and more money to handle it again and again on one scheme or another to induce the furnaces to retain it without bad after effects. Several successful operators claim that it is useless to recharge raw flue dust because the furnace would never have blown it out if it had been suitable material for blast-furnace consumption. Most of us who have made persistent efforts to return raw flue dust to the furnaces have decided that it is very often false economy to do so. Yet some remarkable results have been attained at the Ohio Works of the Carnegie Steel Co. through recharging raw dust. The plant comprises six modern blast furnaces. Up to 1909, about 300,000 tons of flue dust had accumulated in stock piles. During the last 10 years, there have been recharged into these furnaces all of the flue dust recovered from the furnace operations, the entire stock pile of Rue dust, and nearly 80,000 tons of dust shipped from other furnaces of the Carnegie Steel Co. The results obtained arc. shown in Table 1.

Jan 1, 1922

By Thomas H. Clagett

ThE Pocahontas coal field comprises the area in Tazewell County, Va. and Mcrcer and McDowell counties, W. Va., in which Nos. 3 and 4, Pocahontas seams of bituminous coal are mined. It is a mountainous region with ridges rising 300 to 1000 ft. (91 to 305 111.) above the very narrow valleys and, except for some poorly kept farms along the tops of the ridges and the area occupied by the mining and coking plants and villages, is wooded throughout. First shipments were made from Pocahontas in 1883. There are now about 100 mines, 95 per cent. of which are drift mines. At the end of 1920, approximately 298,000,000 gross tons of coal had been produced and 35,000 acres of coal mined. No. 3 seam is from 4 to 10 ft. (1.2 to 3 m.) thick, but the change is gradual and the thickness fairly uniform in any particular locality. It has a streak of bone, about 2 in. (5 cm.) thick, to which the coal adheres on both sides. In parts of the field this bone is replaced by hard slate, usually from 2 to 4 in. thick. The seam has a slate or fireclay bottom and a draw-slate top. No. 4 seam is from 65 to 80 ft. (19.8 to 24 m.) above No. 3 seam, and of minable section only in the western part of the field. It is from 3 to 8 ft. thick and has two streaks of bone, cach from 1 to 2 in. thick. It has a fireclay or slate bottom and is overlaid by from 4 to 24 in. of a laminated coal and slate, locally termed "black rash," which is separated from the coal seam by about 3 in. of slate. This "black rash" averages about 2.5 per cent. ash, but contains some clean coal. The coal in both seams is quite soft. Cleavage sufficieiltly well defined to exert an influence on the mining is rare. Overlying strata arc slates, shales, and sandstones, the sandstones predominating, extending from 30 to 1000 ft. above No. 3 seam. The strata directly above the draw slate of No. 3 seam, or "black rash" of No. 4 seam, and up to the first sandstone are usually slates or shales, about 10 ft. thick over the.

Jan 1, 1923

By Thomas H. Clagett

ThE Pocahontas coal field comprises the area in Tazewell County, Va. and Mcrcer and McDowell counties, W. Va., in which Nos. 3 and 4, Pocahontas seams of bituminous coal are mined. It is a mountainous region with ridges rising 300 to 1000 ft. (91 to 305 111.) above the very narrow valleys and, except for some poorly kept farms along the tops of the ridges and the area occupied by the mining and coking plants and villages, is wooded throughout. First shipments were made from Pocahontas in 1883. There are now about 100 mines, 95 per cent. of which are drift mines. At the end of 1920, approximately 298,000,000 gross tons of coal had been produced and 35,000 acres of coal mined. No. 3 seam is from 4 to 10 ft. (1.2 to 3 m.) thick, but the change is gradual and the thickness fairly uniform in any particular locality. It has a streak of bone, about 2 in. (5 cm.) thick, to which the coal adheres on both sides. In parts of the field this bone is replaced by hard slate, usually from 2 to 4 in. thick. The seam has a slate or fireclay bottom and a draw-slate top. No. 4 seam is from 65 to 80 ft. (19.8 to 24 m.) above No. 3 seam, and of minable section only in the western part of the field. It is from 3 to 8 ft. thick and has two streaks of bone, cach from 1 to 2 in. thick. It has a fireclay or slate bottom and is overlaid by from 4 to 24 in. of a laminated coal and slate, locally termed "black rash," which is separated from the coal seam by about 3 in. of slate. This "black rash" averages about 2.5 per cent. ash, but contains some clean coal. The coal in both seams is quite soft. Cleavage sufficieiltly well defined to exert an influence on the mining is rare. Overlying strata arc slates, shales, and sandstones, the sandstones predominating, extending from 30 to 1000 ft. above No. 3 seam. The strata directly above the draw slate of No. 3 seam, or "black rash" of No. 4 seam, and up to the first sandstone are usually slates or shales, about 10 ft. thick over the.

Jan 1, 1923

By Thomas Clagett

THE Pocahontas coal field comprises the area in Tazewell County, Va., and Mercer and McDowell Counties, W. Va., in which Nos. 3 and 4 Pocahontas seams of bituminous coal are mined. It is a mountainous region with ridges rising 300 to 1000 ft. (91 to 305m.) above the very narrow valleys and, except for some poorly kept farms along the tops of the ridges and the area occupied by the mining and coking plants and villages, is wooded throughout. First shipments were made from Pocahontas in 1883. There are now, about 100 mines, 95 per cent. of which are drift mines. At the end of 1920, approximately 298,000,000 gross tons of coal had been produced and 35,000 acres of coal mined. No. 3 seam is from 4 to 10 ft. (1.2 to 3 m.) thick, but the change is gradual and the thickness fairly uniform in any particular locality. It has a streak of bone, about 2 in. (5 cm.) thick, io which the coal adheres on both sides. In parts of the field this bone is replaced by hard slate, usually from 2 to 4 in. thick. The seam has a slate or fireclay bottom and a draw-slate top. No. 4 seam is from 65 to 80 ft. (19.8 to 24 m.) above No. 3 seam, and of minable section only in the western part of the field. It is from 3 to 8 ft. thick and has two streaks off bone, each from 1 to 2 in. thick. It has a fireclay or slate bottom and is overlaid by from 4 to 24 in. of a laminated coal and slate, locally termed "black rash," which is separated from the coal seam by about 3 in. of slate. This "black rash" averages about 25 per cent. ash, but contains some clean coal. The coal in both seams is quite soft. Cleavage sufficiently well defined to exert an influence on the mining is rare. Overlying strata are slates, shales, and sandstones, the sandstones predominating, extending from .30 to 1000 ft. above No. 3 seam. The strata directly above the. draw slate of No. 3 seam, or "black rash" of No., 4 seam, and up to the first sandstone are usually slates or shales, about 10 ft. thick over the

Jan 5, 1922

Meeting of Nov. 20, 1914.-Charles F. Rand was unanimously elected as the representative of the Institute on the John Fritz Medal Board of Award. E. Gybbon. Spilsbury was unanimously elected to succeed himself in January, 1915, on the Library Board of the United Engineering Society. . The President appointed Messrs. Walter Douglas, Charles E. Mills, and L. D. Ricketts as delegates to the seventeenth National Convention of the American Mining Congress, Phoenix, Ariz., Dec. 7 to 11, 1914. It was voted that the sum of $857.61, or so much of it as may be necessary, be advanced to the Land Fund from the general funds of the Institute, in anticipation of the collection of unpaid installments of subscriptions to the Land Fund; and that the Treasurer be instructed to pay to Andrew Carnegie at the present. time the sum of $2,500 on account of the Land Fund indebtedness.

Jan 1, 1915

By B. Meddings

The technology involved in the Sherritt process for the recovery of nickel and cobalt from sulphide concentrates and mattes is presented in a manner which emphasises the chemistry of the process. The hydrometallurgical process takes advantage of the differing stabilities of the various oxy-acids of sulphur from thionates through thiosulphates to sulphate. Some separations are based upon stability differences, some upon kinetic differences and some upon valence state differences and similarities The engineering and economic factors involved in hydrometallurgy are not discussed in either detail or depth.

Jan 1, 1981

By K. A. Natarajan, I. Iwasaki

The meaning and the utility of redox potential (Eh) measurements in sulfide flotation systems are examined. Since some preliminary plant Eh and laboratory flotation data were available, experiments were made to establish the pH range at which a platinum electrode might be used for such measurements without much difficulty in aerated systems. Triangular wave voltammetry was used to study the surface conditions of the electrode immersed in pyrrhotite suspensions at different pH. The measured Eh both at the plant and the laboratory is interpreted in terms of the experimental water-oxygen line.

Jan 1, 1974

B. F. TILLSON,* Franklin Furnace, N. J.-I would like to ask Major Yerkes if he will not give us more examples of the tests than are contained in the printed pamphlet. It would be of great interest to study them more carefully. ROBERT M. YERKES, Washington, D. C.-The reason for not reproducing the methods in any public print is that it lessens their value and necessitates the preparation of new test materials. BRADLEY STOUGHTON, New York, N. Y.-I hope that this matter will be of so much interest to the members of the Institute that the Directors will decide to appoint a committee which can bring further results of this practice before us. I understand that Columbia University, at least in some departments, has already adopted the B and A tests and is using them. I understand that some industries have considered seriously the question of grading their employees in accordance with

Jan 4, 1919

By H. I. Smith

CONTENTS [PAGE Problems of Mining and Processing Mineral Aggregates (TP 1649, by NATHAN C. ROCKWOOD, Min. Tech., Nov. 1943. Discussion by H. I. SMITH, IRVING WARNER and the author) t Mica in War (TP 1749, by RUSSELL G. WAYLAND, Min. Tech., July 1944. Discussion by H. S. SPENCE) 3 Three Roofing-granule Plants in Pennsylvania (TP 1787, by RICHARD M. FOOSE, Min. Tech., Jan. 1945. Discussion by H. I. SMITH)5 Methods of Prospecting and Mining Optical Calcite in Montana (TP 1896, by E. W. NEWMAN, Min. Tech., Nov. 1945. Discussion by W. C. STOLL and FRANK C. ARMSTRONG, and the Glass Sand and a Glass Industry in Puerto Rico (TP 1939, by HOWARD A. MEYERHOFF and J. EARL FRAZIER, Min. Tech., Nov. 1945. Discussion by A. M. SHORT, the author and PHILIP The "Bonanza" Mica Operation of Purdy Mica Mines, Limited, Mattawsn Township, Ontario (TP 2154, by HUGH S. SPENCE, Min. Tech., March 1947. Author's supplement and discussion by JOHN A. BAKER, E. J. LINTNER, and the author) 7 Process for Manufacture of Dead-burned Magnesite and Precipitated Calcium Carbonate from Dolomite (TP 2155, by ROBERT D. PIKE, Min. Tech., March 1947. Discussion by 0. C. RALSTON and the author) 9] Problems of Mining and Processing Mineral Aggregates H. I. SMITH*-Mr. Rockwood has presented a very interesting paper on problems of the mineral aggregate industry in meeting specification requirements, which apparently are ever decreasing in tolerance. May I call attention to a method of mineral separation that may be of value in separating the flat aggregate particles from the more angular ones and possibly the soft particles from the hard. The method is the old Pardee spiral coal separator, extensively used many years ago in the anthracite region for separating rock and bone from anthracite coal.1 The success of the process depends on the relative coefficient of friction of the aggregate particles to be separated rather than on their relative specific gravity. The flat and the soft particles normally will slide more slowly and stay on the inner spiral until they reach the delivery spout at the bottom whereas the round and the angular pieces will work to the outer edge and fall off into a spiral of larger diameter. The capacity of the separator is increased materially by having three inner spirals, with a separate feed for each, on which the particles travel more slowly, and one outer spiral from which the more rapidly traveling pieces slide to the bottom. IRVING WARNER*-I have long been convinced that much of the equipment and methods developed for mineral dressing might be advantageously employed in the mineral aggregates industry, and more particularly in the production of sand and gravel. The two industries are not well acquainted with each other or their problems. They have separate trade publications. The difficulty with the situation is that there are few large sand and gravel plants and few provided with technical services in their own organization or by retainer. This does not refer to engineering organizations but rather to improvement of plant technic in processing.

Jan 1, 1947

By K. A. Natarajan, I. Iwasaki

The effect of poisoning on the behavior of platinum electrodes in redox potential measurements in metallurgical systems was studied in the presence of such inorganic surfactants as cyanide and sulfide and such organic surfactants as dodecylammonium acetate, trimethyldodecylammonium chloride, potassium ethyl xanthate, and potassium diethyl dithiophosphate (Aerofloat®). These chemical species represent, more or less, typical constituents encountered in leaching, flotation, and sewage treatment systems. Triangular wave voltammetry was used as the experimental technique to study the nature of poisoned surfaces. Among the species studied hydrogen sulfide and dodecylamine were found to form a resistant surface film affecting charge transfer. Platinum electrodes appeared to have a weaker tendency to adsorb sulfide species in alkaline pH ranges, while cyanide, xanthate, and dithiophosphate affected the normal electrode behavior differently. Possible methods of reactivation of a poisoned electrode by mechanical cleaning are suggested.

Jan 1, 1974

By John A. Wolfe, James A. Niederjohn

Applications of mathematical statistics to the field of exploration are still relatively new. There are two primary reasons why little has been published in this field. First, if one discovers an effective technique for exploration, he does not like to disclose it. Second, the geologist needs to work closely with a mathematical statistician, and the communications barrier between the disciplines is formidable. The authors, one a geologist and the other a statistician, were interested in the economic benefit which appeared to be possible in the inter-disciplinary area they call "geostatistics."

Jan 11, 1962

By John M. Warde, Eileen P. Burke

ORES of manganese and chrome have a high order of strategic importance, both metals are basic to the metallurgy and usefulness of steel, the fabric on which our economy rests. Looking beyond the current recession and short range picture of oversupply in these ores, this review attempts to answer the following questions regarding the longterm outlook for these key commodities: By 1970, what will be the probable demand here and abroad, what are future supply prospects, and what effect is the USSR likely to have on the world market? (See summary forecast on facing page.)

Jan 8, 1958

By J. H. Wilhelm, Y. Naide

Continuous thickeners can be sized from previous experience, continuous pilot-scale test results, or batch settling tests. It is relatively simple to size full-scale thickeners when previous experience or pilot-scale operating data are available. But batch testing is often the only realistic method for sizing thickeners due to time restrictions, budget limitations, and availability of sample material. Many authors have, therefore, suggested means of running batch tests and analyzing the resulting data. Fundamental thickening theory began with the work of Coe and Clevenger (1916). In order to determine the size of the thickener settling area, they proposed that a series of batch settling tests be run at various initial concentrations. The solids handling capacity at each concentration can then be determined and the lowest capacity (maximum area requirements) used to size the thickener. Kynch (1952) developed a mathematical analysis in which the relationship between solids concentration and settling rate can be obtained from a single batch settling curve. Talmage and Fitch (1955), Yoshioka

Jan 1, 1982

By S. J. Swainson

"It appears to me that the chief progress in milling operations in America have been made in the steady improvement of existing practice through both higher extractions and increased efficiencies of operations rather than by the development of new processes. The recent rapid development of sink-float, or heavy-medium separation, however, is an exception, and is becoming increasingly used to permit the economic treatment of certain low-grade ores that otherwise could not profitably be mined. The use of spirals and of small cyclones, both of which employ the principle of centrifugal force, show promise of increasing adoption through their application and efficiency in special cases." So did our distinguished colleague, O. A. E. Jackson, consulting metallurgist for the Union Corporation and president of the Chemical, Metallurgical and Mining Society of South Africa, summarize his impressions of a recent tour which he made of various metallurgical and milling plants in North America. I believe that all mineral dressers will agree with Dr. Jackson's concise conclusions.

Jan 1, 1950

Executive ARTHUR S DWIGHT, Chairman B THAYER CHARLES F RAND P MATHEWSON J V W REYNDERS Membership WILLIAM H BASSETT, Chairman W Y WESTERVELT Vice-chairman P MATHEWSON H G MOULTON F T RUBIDGE Finance WALTER H ALDRIDGE, Chairman GEORGE D BARRON GALEN H CLEVENGER

Jan 1, 1923

By L. R. Gremillion, G. H. McClellan

Chemical and mineralogical data on 25 apatitic phosphate ores of diverse origins from commerical deposits around the world were widely variable. From 14 to 18 chemical constituents of each sample were determined, and each sample contained four to ten mineral phases. Altogether there were 34 different mineral phases, many of which occurred in only one sample. Samples contained varieties of francolites, fluorapatites, and mixed hydroxyfluorapatites. The apatite compositions calculated from chemical data showed that certain types of substitutions were characteristic of different apatite varieties, but every variety had some degree of substitution of (CO3)2- for (PO4)3-, and the P205 contents of the apatites ranged from 35.1 %for a North Carolina apatite to 41.9% for a Missouri apatite. In a concentrate with a grade of 32% P2O5, the North Carolina sample should contain about 8.7% gangue and the Missouri sample about 23.7% gangue. To optimize the digestion process of a phosphate ore, it is necessary to consider the dissolution behaviors of different mineral phases during acidulation and their possible effects on chemical properties of a fertilizer intermediate. In the production of wet-process acids or superphosphates, acidulation of certain minerals may cause foaming and formation of sludge, filtration, corrosion, and handling problems.

Jan 1, 1982