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(Under this heading will be published notes sent to the Secretary of the Institute by members or other persons introduced by members.) Mining Engineer. Graduate of Colorado School of Mines, 1912, experienced in coal, lead manganese and limestone mining, wishes execu¬tive position. A-2146. Graduate Mining Engineer.-Discharged, reserve officer, age 32, single, 7 years' experience holding responsible executive positions, in iron, copper, and talc mining. Well recommended. A-4913. Mine Manager, Superintendent or Engineer. Age 41, graduate of Michigan College of Mines; 20 years' experience in responsible positions in connection with large operations; in iron, copper, pyrites, lead and zinc mines; successful in finding and developing orebodies, increasing production, and reducing costs. Desires a position with a future. A-4081. Mining Engineer.-Graduate from Polytechnicum, Stockholm; 14 years' practical experience in Sweden, United States, Belgium, and Spain, in iron-ore development, mining, and milling; thorough knowledge of English, French and Spanish; desires position as superintendent or assistant manager. Good references; member; now in Sweden. A-4914. Research Engineer. Now in Chile on the erection of a 50-ton mill with modern machinery for the treatment of Chilean nitrate. Desires connection from the first of next year; with firm operating in South or Central America. A-4915. Metallurgical Engineer. Junior member, age 26, single, graduate Columbia School of Mines; recently discharged as lieutenant in the heavy artillery. A-4916. General Superintendent. Technical graduate, age 35, desires position over a group of four or five mines or as assistant general superintendent for a large. company. Has had experience in superintending mines, construction work, opening new and abandoned mines, safety and effi-ciency engineering and handling organized labor. At present employed by a coal company in the middle West. A-4917.

Jan 11, 1919

By N. Schapiro, R. J. Gray, G. D. Coe

A petrographic and chemical investigation was conducted to determine the occurrence and distribution of the organic and inorganic forms of sulfur in various size and specific gravity fractions of a high volatile, A-rank, Pittsburgh seam coal. The investigation was conducted to aid in the resolution of the problem of how metallurgical coke of lower sulfur content can be produced from high sulfur coals. The Pittsburgh raw coal contains about 2.4% S in two dominant forms: pyritic and organic. Pyritic sulfur constitutes about 57% of the total sulfur in the raw coal and occurs in macroscopic and microscopic-size particles. A plant cleaning process mechanically separates between 50 and 60% of the pyritic sulfur, mainly the macroscopic particles. The organic sulfur constitutes 41% of the total sulfur in the raw coal and 55% of the sulfur in the washed coal. Thus, organic sulfur is not reduced by physical methods of separation. Organic sulfur occurs in all the coal entities, but in general, increases as the exinoid content of the coal increases. In this study, it was found that carbonizing certain selected low gravity coal fractions containing an average of 0.45% pyritic sulfur and 1.01% organic sulfur produced cokes containing an average of 0.22% pyritic sulfur and 0.91% organic sulfur. However, the organic sulfur in the coke is probably derived in part from the heating of pyrite in the presence of carbon. Thus, the total sulfur in the coal carbonized is the most important factor affecting the sulfur content of the coke produced. Concentration of microscopic pyritic and organic sulfur in the middling-type coal indicates the necessity for rejecting as much of this material as is economically feasible. Most of the sulfur introduced into the blast furnace originates from the coke. Although the sulfur content of the hot metal can be controlled by the addition of flux, the flux used restricts the productivity of the furnace by displacing ore and requires first to be smelted; therefore, low sulfur coke is highly desirable. Since the sulfur content of coke is dependent upon the sulfur content of the coals from which the coke is produced, low sulfur coals are required to produce low sulfur coke. In the western Pennsylvania area, large quantities of good coking coal are available from the Pittsburgh seam, but this coal unfortunately contains relatively large quantities of sulfur. To provide information that might be useful in reducing the sulfur content of this coal in the cleaning process, an investigation was conducted to determine the physical and chemical forms in which this sulfur occurs and with what petrographic components it might be associated. The Pittsburgh seam coal, like most other coals, contains two dominant forms of sulfur: one occurs as the minerals pyrite and/or marcasite and is referred to as pyritic sulfur; the other is combined with the coal substance and is called organic sulfur. Pyritic sulfur is amenable to physical methods of separation, whereas organic sulfur is not. Pyritic sulfur particles must be freed from the surrounding coal if they are to be removed in the washing process. Generally, this requires crushing; the required degree of crushing being a function of the size and distribution of the pyrite. The present investigation was conducted to 1) determine the size, distribution and association of sulfur-bearing minerals in the coal and 2) to determine whether the organic sulfur has a preferential association with specific coal entities. If a preferential association exists, this knowledge may be useful in devising a method for organic sulfur reduction. In addition, a study was made to determine the extent to which pyritic and organic forms of sulfur in the coal contribute to the sulfur in the coke produced from this coal. A representative 3%-ton sample of raw coal was crushed to —3 in. and screened into square-mesh sizes: 3 to 1 in., 1 to % in., % to % in., % in. to 10 mesh, 10 to 35 mesh, and 35 to 200 mesh. Separate samples of the -200-mesh fraction and the all-size composite were also collected. Each size fraction (except the -200 mesh) was fractionated on heavy liquids of the following specific gravities: 1.280, 1.300, 1.325, 1.350, 1.375, 1.400, 1.425, 1.450,

Jan 1, 1963

By J. Douglas Gibson

In Canada, the economic climate for mining is still warm, but a noticeable chill set in last November when the Government published a White Paper on tax reform known as the Carter Report. Moreover, this chill could drop to a freeze injurious to the whole Canadian economy if two of the proposals in the Carter Report are adopted. The offending suggestions call for an end to (1) the depletion allowance and (2) the three-year tax holiday for new mines. Both of these tax incentives have played a major role in the postwar development of the Canadian economy and will, if undisturbed, play an even more important role in the future. The fact that they have worked and worked well is evident from the record. Fruits of an Industrial Beanstalk Excluding fuels, the value of Canadian mineral production was just under $3 billion in 1968-almost nine times as much as in 1946. With fuels included, the figure is $4.25 billion, or almost ten times as much as in 1946. Proportionately, this growth far exceeds that of Canada's manufacturers or of her economy as a whole. Table I traces the overall mineral production growth by principal products. Of particular interest here are petroleum, iron ore, natural gas, sulfur and potash, the combined production of which has grown from little or nil to a point where it now accounts for more than 40% of Canada's mineral output.

Jan 1, 1970

By R. Woodward Moore

A graphical method of analyzing the data obtained from shallow earth-resistivity depth tests is presented. The method is based upon empirical results and has no theoretical basis. The usual apparent resistivity-electrode spacing curve is used together with a cumulative resistivity-electrode spacing curve plotted on the same sheet. The greatly reduced scale required for plotting the cumulative values of resistivity together with the effect of the summation of the individual resistivity values serves to minimize the effect of purely local surface anomalies and inadvertent errors of measurement. The point of intersection of tangents or straight lines drawn to intersect at zones of maximum curvature in the cumulative curve indicates the depth to the underlying material. Numerous figures are presented in which data from published reports and from recent field studies are analyzed and the results compared with actual depths established by borings or with depth values obtained by the use of theoretical methods of analysis. Smoothly rounded curves of apparent resistivity such as are often obtained in the field, and which have been a serious drawback to attempts to analyze the data empirically heretofore, appear to be susceptible to rather accurate analysis by the method described. The method is best suited to analyses involving shallow two-layer formations. It has been applied successfully, however, in analyzing the data obtained from tests made over shallow three-layer formations. As with most empirical methods, its chief advantage is its simplicity and ease of application. There have been published many papers that discuss the interpretation of data obtained from earth-resistivity tests when using the four-terminal method of electrode spacing developed by Wenner.' The majority of these have dealt with theoretical analyses for two-layer and three-layer formations. Some sets of "master curves" have been presented for use in analyzing field data to determine the depth to the first and possibly the second horizon below the earth's surface. Although practically all of these theoretical methods of analysis have appeared to have particular merit and some have been used successfully in practice, they have been found to be of little value where the local conditions surrounding the test failed to conform to those assumed in the theory. In certain fields, particularly in civil engineering, relatively shallow explorations are often involved and geophysical methods of test must compete with the direct methods of exploration ordinarily used. Only when it can be demonstrated that geophysical methods of test can materially reduce the time and cost of a given exploration project will the civil engineer abandon direct methods in favor of the interpretations of geophysical exploration data. Empirical methods of analyzing earth-resistivity data have been used in many instances in the past. Such methods have been employed for a number of years by the Public Roads Administration in research work relative to the application of

Jan 1, 1946

By R. Woodward Moore

A graphical method of analyzing the data obtained from shallow earth-resistivity depth tests is presented. The method is based upon empirical results and has no theoretical basis. The usual apparent resistivity-electrode spacing curve is used together with a cumulative resistivity-electrode spacing curve plotted on the same sheet. The greatly reduced scale required for plotting the cumulative values of resistivity together with the effect of the summation of the individual resistivity values serves to minimize the effect of purely local surface anomalies and inadvertent errors of measurement. The point of intersection of tangents or straight lines drawn to intersect at zones of maximum curvature in the cumulative curve indicates the depth to the underlying material. Numerous figures are presented in which data from published reports and from recent field studies are analyzed and the results compared with actual depths established by borings or with depth values obtained by the use of theoretical methods of analysis. Smoothly rounded curves of apparent resistivity such as are often obtained in the field, and which have been a serious drawback to attempts to analyze the data empirically heretofore, appear to be susceptible to rather accurate analysis by the method described. The method is best suited to analyses involving shallow two-layer formations. It has been applied successfully, however, in analyzing the data obtained from tests made over shallow three-layer formations. As with most empirical methods, its chief advantage is its simplicity and ease of application. There have been published many papers that discuss the interpretation of data obtained from earth-resistivity tests when using the four-terminal method of electrode spacing developed by Wenner.' The majority of these have dealt with theoretical analyses for two-layer and three-layer formations. Some sets of "master curves" have been presented for use in analyzing field data to determine the depth to the first and possibly the second horizon below the earth's surface. Although practically all of these theoretical methods of analysis have appeared to have particular merit and some have been used successfully in practice, they have been found to be of little value where the local conditions surrounding the test failed to conform to those assumed in the theory. In certain fields, particularly in civil engineering, relatively shallow explorations are often involved and geophysical methods of test must compete with the direct methods of exploration ordinarily used. Only when it can be demonstrated that geophysical methods of test can materially reduce the time and cost of a given exploration project will the civil engineer abandon direct methods in favor of the interpretations of geophysical exploration data. Empirical methods of analyzing earth-resistivity data have been used in many instances in the past. Such methods have been employed for a number of years by the Public Roads Administration in research work relative to the application of

Jan 1, 1946

By C. E. Wood, E. P. Barrett, T. L. Joseph

The United States Bureau of Mines has been studying the blastfurnace process for about ten years. An experimental furnace was developed by the Burcau in cooperation with the Minnesota School of Mines Experiment Station, University of Minnesota. Many data have been obtained and published.' Royster, Joseph and Kinney §(48) found that the particle size of ore had an important effect upon the blast-furnace process. Kinne(28) stated: Economy in blast-furnace practice depends largely upon efficient gas-solid contact in the shaft of the furnace. If efficient work is not done in the shaft, the hearth and bosh will not function properly. A condition may be readily imagined where the particles of ore in the shaft are so large that the time entailed in the descent of these materials into the bosh is not sufficient to permit proper reduction and preparation prior to the time the ore enters the bosh of the furnace. Another condition may be pictured where the density of theatock column and the flow of stock is such that the ore will take one course and the gas another. Both of these examples will result in insufficient contact between the gas and the ore. Unreduced ore will reach the hearth, and the gas which has not been efficiently oxidized will reach the stock line. The result is the use of an excess of carbon in the smelting process. It is obvious that fine ore particles occurring in the ore as charged, or formed in the furnace due to heat and mechanical action, place a definite limitation upon the efficiency of the operation. There is also an economic loss of fine material as dust. Effect of Size of Material Kinney reported (p. 83(29)) the reduction of iron oxides between planes at three furnaces as given in Table 1. The Chicago furnace was operated on Lake ores. Distribution of gas was not good and much of the charge passed into the hearth before the iron oxide was reduced. The Holt furnace was operated on coarse ore. Distribution of gas was fairly uni-

Jan 1, 1930

By W. T. Bishop

For many years pine oil has been used extensively as a frother for the flotation of minerals, particularly sulphides, yet the published information available to the average user on its composition, chemical and physical properties, has been rather meager. It is the purpose of this paper to discuss these points and their relationship to the frothing properties of pine oil used in flotation processes. Pine oil, as the name implies, is a liquid obtained from the processing of wood of the longleaf and other southern pines. It is a complex mixture of naturally occurring terpene derivatives, primarily alcohols, and a smaller amount of terpenes, which has found many uses in various industries. Its use as a frother in flotation processes was the first large-scale application in industry and today the mining industry still consumes large quantities of pine oil but the textile and disinfectant industries consume comparable volumes. Much is used in soap manufacture and laundry operations. The surface-active properties of pine oil are in a large degree responsible for this versatility. History The name "Naval Stores" goes back to the days when pine tar and pitch were used to caulk leaky ships and 'Oat their ropes and rigging. Today this term is still used to include not only the oleoresinous products of the pine tree—rosin and turpentine— but other products such as pine oil, pine tar, and the many terpene and resinous compounds obtained by extracting the pine wood or tapping the tree. That part of the industry known as "wood naval stores" dates from about the beginning of this century and today produces a large part of the country's rosin and turpentine by processing pine wood. In addition, all of our natural pine oil is supplied by the wood naval stores industry, as tapping of the live tree gives only rosin and turpentine. This latter phase is known as the "gum naval stores " industry. The first successful commercial operation of the steam and solvent process of the wood naval stores in industry was carried out by Yaryan at Cadillac, Mich., in 1909.1 This operation did not prove profitable, so Yaryan went south to utilize the longleaf pine, and built a plant at Gulfport, Miss.2 Soon after, another plant was built at Brunswick, Ga., which is still in operation, and in 1914 was reported to have processed about 500 tons of wood per day.' In 1921 Hercules Powder Co. acquired the Yaryan interests, at which time the production of pine oil was only 3 to 5 million pounds per year and flotation was the largest customer. As time went on, technological advances were made, other companies entered the field, and the production of pine oil increased many fold. The growth of the industry was especially marked during the past 10 years, and in

Jan 1, 1947

By W. T. Bishop

For many years pine oil has been used extensively as a frother for the flotation of minerals, particularly sulphides, yet the published information available to the average user on its composition, chemical and physical properties, has been rather meager. It is the purpose of this paper to discuss these points and their relationship to the frothing properties of pine oil used in flotation processes. Pine oil, as the name implies, is a liquid obtained from the processing of wood of the longleaf and other southern pines. It is a complex mixture of naturally occurring terpene derivatives, primarily alcohols, and a smaller amount of terpenes, which has found many uses in various industries. Its use as a frother in flotation processes was the first large-scale application in industry and today the mining industry still consumes large quantities of pine oil but the textile and disinfectant industries consume comparable volumes. Much is used in soap manufacture and laundry operations. The surface-active properties of pine oil are in a large degree responsible for this versatility. History The name "Naval Stores" goes back to the days when pine tar and pitch were used to caulk leaky ships and 'Oat their ropes and rigging. Today this term is still used to include not only the oleoresinous products of the pine tree—rosin and turpentine— but other products such as pine oil, pine tar, and the many terpene and resinous compounds obtained by extracting the pine wood or tapping the tree. That part of the industry known as "wood naval stores" dates from about the beginning of this century and today produces a large part of the country's rosin and turpentine by processing pine wood. In addition, all of our natural pine oil is supplied by the wood naval stores industry, as tapping of the live tree gives only rosin and turpentine. This latter phase is known as the "gum naval stores " industry. The first successful commercial operation of the steam and solvent process of the wood naval stores in industry was carried out by Yaryan at Cadillac, Mich., in 1909.1 This operation did not prove profitable, so Yaryan went south to utilize the longleaf pine, and built a plant at Gulfport, Miss.2 Soon after, another plant was built at Brunswick, Ga., which is still in operation, and in 1914 was reported to have processed about 500 tons of wood per day.' In 1921 Hercules Powder Co. acquired the Yaryan interests, at which time the production of pine oil was only 3 to 5 million pounds per year and flotation was the largest customer. As time went on, technological advances were made, other companies entered the field, and the production of pine oil increased many fold. The growth of the industry was especially marked during the past 10 years, and in

Jan 1, 1947

By F. D. Rosenthal, F. J. Dunkerley, G. J. Mills

Activities, free energies, and heats and entropies of mixing of liquid Pb-Zn alloys have been obtained by the electrode-potential method between 400° and 650°C. The large positive deviations observed from Raoult's law are in agreement with the phase diagram, which indicates a wide immiscibility field. A vapor-pressure method was used to extend the activity measurements to 900°C, allowing the maximum of the immiscibility gap to be estimated by thermodynamic calculation. Data on the mono-tectic and eutectic points compare favorably with previously existing work. SEVERAL long-standing methods have been in use for the study of phase diagrams from measurement of the activities of the component metals.' The use of thermodynamic analysis for interpreting equilibria data is comparatively recent, however. Such analysis is usually undertaken by first evaluating the principal thermodynamic functions as, for example, the enthalpy, entropy, and free energy of the alloy constituents. These, in turn, quite often can be correlated with the interatomic potential energies and atomistics of the system, from which a clearer understanding of the causes leading to deviations from ideal behavior is gained. The present study of liquid Pb-Zn alloys is concerned with a determination of these quantities by electrode-potential and vapor-pressure measurements, using these values in calculations involving phase equilibria and to obtain a theoretical insight into an alloy system exhibiting strong positive deviations from ideal metallic solution. A considerable portion of the previously reported work is based on thermal analysis. Supplemented by optical studies of solid alloys, these techniques have revealed the essential nature of the immiscible mixtures that are formed. It is difficult, however, using the phase-

Jan 1, 1959

By T. Sterry Hunt

The deposit of rock-salt which is known to exist along the eastern shore of Lake Huron, in the province of Ontario, has lately been more completely explored than before, by a boring with a diamond drill, put down by Henry Attrill, Esq., of New York City, and the results obtained are so important in every way that I make no apology for presenting them to the Institute of Mining Engineers. I may be permitted to preface an account of this remarkable exploration, and of its results, with a historical sketch of the discovery and development of this salt-region. It was in December, 1865, that a boring was begun near the town of Goderich, in the hope of finding petroleum. In this the adventurers were disappointed, but, after passing through about 800 feet of limestone, they encountered a series of variegated marls, in which, at a, depth of 964 feet from the surface, a bed of rock-salt, 30 feet in thickness, was met with in May, 1866. The boring was carried to a depth of 1010 feet, ending in hard rock, and yielded, by pumping, a very pure saturated brine when examined by me in August of the same year. In the report of the Geological Survey of Canada for 1863-66, published early in 1867, I described this salt-well, with many geological details, and gave an analysis of the brine. In the next three years a considerable number of wells was sunk in and around Goderich, and numerous trials were made in various other parts of the region. Salt was found at Kincardine, thirty miles north-northeast from Goderich, at a depth of about 900 feet, and also at Clinton, thirteen miles southeast, at 1180 feet. Records of these wells, with analyses of the brine from them, were given by myself in a subsequent report of the Geological Survey, 1866-69, published in 1870 (pp. 211-244), together with accounts of various unsuccessful borings in the neighborhood, analyses of the brines from the various wells (including one analysis by Dr. Goessmann), with many details of the salt-manufacture at Goderich, at Syracuse, New York, and at Saginaw, Michigan. The geological character of the region was there discussed at length, and it was shown that the salt here occurs in the Onondaga or Salina formation, which

By D. J. Jr. McAdam

PART I.-OUTLINE OF INVESTIGATION, DESCRIPTION OF METHODS AND MATERIAL Previous Investigation of the Influence of Stress on Corrosion IN 1917 Haigh1 presented evidence that under simultaneous corrosion and cyclic stress metals may fail at lower stresses than if the corrosion is prior to the cyclic stress. In 1926 the author, while investigating the cooling effect of water on the fatigue resistance of metals, found that under these conditions steel specimens fail at stresses far below the endurance limit.2 (By "endurance limit" is here meant the fatigue limit obtained with specimens as free as possible from stress concentration and corrosive influences.) This led to an investigation (at the Naval Engineering Experiment Station, Annapolis, Md.) of the influence of cyclic stress on corrosion. This investigation maybe divided into three parts. The first part was a general survey of the conditions necessary to cause complete failure under corrosion and cyclic stress of relatively high frequency. The entire process by which metals fail under these conditions was-called "corrosion-fatigue." "Corrosion-fatigue limits" for a large number of metals were determined and the relationships of these limits to chemical composition, heat treatment and physical properties were established. The conclusion was reached that corrosion-fatigue is due to the accelerating influence of cyclic stress on corrosion. Results of this part of the investigation were presented in five papers.2-6 The second part of the investigation was a preliminary study of the influence of cyclic stress on corrosion. Each experiment was conducted in two stages. The first was a corrosion stage in which the specimen was corroded under cyclic stress; the second was a fatigue stage, in which the previously corroded specimen was tested (without further corrosion) to determine its fatigue limit. The difference between this fatigue limit and the endurance limit was used as a criterion of the "damage" due to

Jan 1, 1931

By Richard L. Ash, J. H. Kelley, W. H. McCracken, William Bellano, J. D. Morgan, D. R. Mitchell

Rubber-tired shuttle cars are finding increased use as gathering units in under-ground mines. As the name implies, they shuttle back and forth between the loading machine and the section transportation system. In many mines their use has in-creased the efficiency of the loading and gathering operations, resulting in increased output per man employed and decreased costs per ton. A car motivated by cable reel is shown in Fig I, and a car with battery power in Fig 2. A brief chronological account of the development of rubber-tired haulage equip-ment follows: 1936. J. H. Fletcher1 installed his first unit for the Blue Bird Coal Co., Carrier Mills, Illinois. This unit consisted of a battery-powered industrial tractor and a trailer with drop-bottom doors. The coal was transported for short distances to a hopper for discharge into mine cars. 1938. A battery-powered self-contained shut-tle car with rubber-tired wheels was built by the Joy Manufacturing Co. Two units were installed for the Katherine Coal Co., Lumberport, West Virginia. The shuttle car consisted of a materials-receiving body with a conveyor in the bottom to move the coal forward during loading and to unload the coal at the discharge station. 1938. A cable-powered shuttle car with four-wheel drive and four-wheel steer was developed by A. L. Lee. Special wheels mounted on king pins on the car permitted all four wheels to be steered. The cable reel was driven by a torque motor to give the cable proper tension during the payout and uniform tension when rewound on the reel. 1940. A Joy shuttle car equipped with trolley poles and a cable reel was developed to operate on a double trolley-wire system.2 This unit was installed at a potash mine of the International Minerals and Chemicals Corporation at Carlsbad, New Mexico. It is believed to have been the first installation of its kind, and the first of shuttle cars for handling material other than coal. 1941. Truck haulage3 was introduced in the Tri State District by the Eagle-Picher Mining and Smelting Company. Storage battery electric trucks were rebuilt to handle a bottom-dump trailer. 1941—Joy shuttle cars were installed in a mine of the United States Gypsum Company, Oakfield, New York. 1943—Joy shuttle cars were installed in several bauxite mines.4,5 1945—Joy shuttle cars installed in a lime-stone mine. Because of the nature of bituminous coal beds trackless equipment has had its greatest application in bituminous coal mining. Usually a shuttle car is filled by a continuous type of loader. In Fig 3 is shown a continuous machine loading coal into a battery-powered shuttle car, 48-in. coal. However, intermittent types of load-

Jan 1, 1949

J. S. Unger,* Pittsburgh, Pa. (written discussion?).-I heartily agree with the author's suggestion, near the close of the paper, that greater uniformity in the making and use of brick is desirable. The effect of the manner of laying the brick, the mortar or cement used, the necessity of standardizing the shapes, the elimination of irregular or poorly designed brick, and the necessity for uniform operating conditions were pointed out by me some years ago. Many factors influence the quality of firebricks. The following figures obtained from bricks during their making or after completion show the need for greater uniformity in their quality. These results were obtained from regular commercial bricks, shipped to the consumer. In many cases the samples were from the same car load.

Jan 11, 1919

By Herbert Banks Johnson

During the past 10 or 12 years very little information has been made generally available concerning the commercial possibilities of separating materials by means of static electricity; and yet during that same period important improvements have been made in various branches of the science of electricity, which, when taken together, and applied to electrostatic separation, have resulted in important improvements in that art as well. For example, much improvement has been made in high-voltage electrical equipment such as full-wave vacuum-tube rectification and improved mechanical rectification. Great strides have likewise been made in the development of insulators for high-voltage work, not only in the materials used but also in the design of the insulators themselves. Again, in another field, the development of air-conditioning equipment has improved the technique of controlling the surface condition, through drying or humidifying, of the various materials that are passed through the electrostatic separator. In many authoritative publications and textbooks, the electrostatic separation process is declared to require a balance far too sensitive for general commercial application. For example, one publication1 in the past has referred to an unfavorable effect on the process caused by varying atmospheric conditions such as humidity. Some2 have even gone so far as to state that sunlight and shadows may seriously affect the separating efficiency of the process. Such statements may have been true in the early development of the art, when the source of static electricity was derived from a friction disk machine, such as the Wimshurst. The Blake Mosher equipment and the work of Huff in applying motor-generator sets, transformers and mechanical rectification overcame much of this kind of objection to the commercial application of the electrostatic separating process. Another objection made periodically is that it is generally considered necessary to feed the particles into the electrostatic field in a stream that

Jan 1, 1939

By Herbert Banks Johnson

During the past 10 or 12 years very little information has been made generally available concerning the commercial possibilities of separating materials by means of static electricity; and yet during that same period important improvements have been made in various branches of the science of electricity, which, when taken together, and applied to electrostatic separation, have resulted in important improvements in that art as well. For example, much improvement has been made in high-voltage electrical equipment such as full-wave vacuum-tube rectification and improved mechanical rectification. Great strides have likewise been made in the development of insulators for high-voltage work, not only in the materials used but also in the design of the insulators themselves. Again, in another field, the development of air-conditioning equipment has improved the technique of controlling the surface condition, through drying or humidifying, of the various materials that are passed through the electrostatic separator. In many authoritative publications and textbooks, the electrostatic separation process is declared to require a balance far too sensitive for general commercial application. For example, one publication1 in the past has referred to an unfavorable effect on the process caused by varying atmospheric conditions such as humidity. Some2 have even gone so far as to state that sunlight and shadows may seriously affect the separating efficiency of the process. Such statements may have been true in the early development of the art, when the source of static electricity was derived from a friction disk machine, such as the Wimshurst. The Blake Mosher equipment and the work of Huff in applying motor-generator sets, transformers and mechanical rectification overcame much of this kind of objection to the commercial application of the electrostatic separating process. Another objection made periodically is that it is generally considered necessary to feed the particles into the electrostatic field in a stream that

Jan 1, 1939

By Herbert Banks Johnson

DURING the past 10 or 12 years very little information has been made generally available concerning the commercial possibilities of separating materials by means of static electricity; and yet during that same period important improvements have been made in various branches of the science of electricity, which, when taken together, and applied to electrostatic separation, have resulted in important improvements in that art as well. For example, much improvement has been made in high-voltage electrical equipment such as full-wave vacuum-tube rectification and improved mechanical rectification. Great strides have likewise been made in the development of insulators for high-voltage work, not only in the materials used but also in the design of the insulators themselves. Again, in another field, the development of air-conditioning equipment has improved the technique of controlling the surface condition, through drying or humidifying, of the various materials that are passed through the electrostatic separator. In many authoritative publications and textbooks, the electrostatic separation process is declared to require a balance far too sensitive for general commercial application. For example, one publication1 in the past has referred to an unfavorable effect on the process caused by varying atmospheric conditions such as humidity. Some2 have even gone so far as to state that sunlight and shadows may seriously affect the separating efficiency of the process. Such statements may have been true in the early development of the art, when the source of static electricity was derived from a friction disk machine, such as the Wimshurst. The Blake Mosher equipment and the work of Huff in applying motor- generator sets, transformers and mechanical rectification overcame much of this kind of objection to the commercial application of the electrostatic separating process. Another objection made periodically is that it is generally considered necessary to feed the particles into the electrostatic field in a stream that

Jan 1, 1938

By A. M. Gaudin, A. F. Taggart

Flotation of ores is a practical utilization of the energy that resides in the surfaces of solids and liquids. The best known manifestation of this energy is called surface tension; an equally important, though less apparent, phenomenon is adsorption. This paper reviews some of the recent investigations of these phenomena, and gives the results of certain experiments performed by the authors. Surface tension is a manifestation of energy having its seat at the bounding surface between the adjacent phases of a multiphase system. Thus, at the interface between a liquid and a gas, or between two immiscible liquids, or between a solid and a gas or a liquid, there are forces capable of doing work, their magnitude depending on the nature of the adjacent phases and the extent of the bounding area. These surface forces are inappreciable when the ratio of surface to volume of the adjacent phases is small, but they become powerful when this ratio becomes large, as it does when one of the phases is highly dispersed. Froth flotation, which consists in buoying solids heavier than water to the surface of water by means of gas bubbles, utilizes the force of surface tension to attach the solid particles to the gas bubbles and again to maintain the floating mass of bubbles as a more or less persistent froth at the surface of a pulp for a sufficiently long time to allow its removal. It follows from the second law of thermodynamics that the potential energy of a system in equilibrium is a minimum. Therefore a multiphase system, tending toward equilibrium, will arrange itself in such a way that the total energy of the interfaces will be the least possible. This end can be accomplished in two ways: by a change in shape that will reduce the interfacial area; by a change in the nature of the surface layer in

Jan 1, 1923

By A. F. Taggart, A. M. Gaudin

Flotation of ores is a practical utilization of the energy that resides in the surfaces of solids and liquids. The best known manifestation of this energy is called surface tension; an equally important, though less apparent, phenomenon is adsorption. This paper reviews some of the recent investigations of these phenomena, and gives the results of certain experiments performed by the authors. Surface tension is a manifestation of energy having its seat at the bounding surface between the adjacent phases of a multiphase system. Thus, at the interface between a liquid and a gas, or between two immiscible liquids, or between a solid and a gas or a liquid, there are forces capable of doing work, their magnitude depending on the nature of the adjacent phases and the extent of the bounding area. These surface forces are inappreciable when the ratio of surface to volume of the adjacent phases is small, but they become powerful when this ratio becomes large, as it does when one of the phases is highly dispersed. Froth flotation, which consists in buoying solids heavier than water to the surface of water by means of gas bubbles, utilizes the force of surface tension to attach the solid particles to the gas bubbles and again to maintain the floating mass of bubbles as a more or less persistent froth at the surface of a pulp for a sufficiently long time to allow its removal. It follows from the second law of thermodynamics that the potential energy of a system in equilibrium is a minimum. Therefore a multiphase system, tending toward equilibrium, will arrange itself in such a way that the total energy of the interfaces will be the least possible. This end can be accomplished in two ways: by a change in shape that will reduce the interfacial area; by a change in the nature of the surface layer in

Jan 1, 1923

This is a brief account of the history of unit operation in the Salt Creek field, Wyoming, from the time of the agreement to prorate production in March, 1921, to the present. An attempt has been made to evaluate the savings in development and production costs resulting from the unit plans adopted. Summarized, these savings have amounted to $11,650,000. No effort has been made to estimate any increase in ultimate recovery, for it is believed that unit operation can be justified on saving in development and production costs alone. It would require nearly 20,000,000 barrels of additional oil to be produced in order to return the amount saved by not drilling unnecessary wells. Four horizons are affected by unit or near-unit programs, as follows: The principal operator is under contract with six companies to operate 10,400 acres. This includes all of the productive area of the First Wall

Jan 1, 1930

By A. H. Daane, A. S. Wilson

The U-Cr system is of the simple eutectic type with some solid solubility of chromium in r and ß uranium. The eutectic occurs at 20 atomic pet Cr and melts at 859°C. The maximum solubility of chromium in y uranium is 4 atomic pet at the eutectic temperature, and in ß uranium the solubility is estimated to be 1 atomic pet. y-ß and ß-a transformations were found to occur at 737°estimatedt° and 612°C respectively. DURING 1944 and 1945, the U-Cr constitution diagram was studied in this laboratory as a part of a research program on uranium metallurgy in the Manhattan Project, and the work was described in a Manhattan Project report issued in December 1945. This paper is based on that report, which has been declassified. Prior to this study, it had been shown by other Manhattan Project workers that the low Cr-U alloys could be quenched to retain the form of uranium. Experimental The uranium used in this work was massive metal prepared in this laboratory and contained less than 0.1 pct of other elements. The chromium was 200 mesh powder obtained from the A. D. McKay Co. and was found on analysis to be 99.5 pct Cr with 0.3 pct Fe the major impurity. Alloys, weighing 400 to 600 g, were prepared by induction heating the components to 1700°C in slip-cast ZrO, crucibles in a vacuum of 3x103 mm Hg. TO prevent too violent agitation of the melt by the induction field with subsequent crucible breakage and sample loss, the ZrO2 crucible was placed in a graphite crucible, which was surrounded by a layer of powdered carbon insulation 2 to 3 cm thick. Polished vertical sections of the alloys were examined microscopically to confirm their homogeneity. Heating and cooling curves were taken on the alloys by reheating them in ZrO, crucibles to 1200°C and inserting a mullite-protected chromel-alumel thermocouple into the melt by means of a slip seal in the vacuum head of the furnace. A recording potentiometer traced the curves which had a slope of from 3" to 6" per min. Samples of the alloys were prepared for metallo-graphic examination by conventional mechanical polishing techniques followed by an electrolytic polish in an ethylene glycol-phosphoric acid-ethyl alcohol bath. The structure of the alloys was brought out clearly by this procedure so that no further etching was required. Samples for chemical analysis were taken from drillings from the top, center, and bottom sections of the alloys. The uranium was determined by titra-tion with Ce(SO1)2, while the chromium was titrated with FeSO,; the uranium and chromium totaled at least 99.6 pct in all of the alloys prepared. X-ray samples were prepared by filing bulk specimens in a helium-filled glove box and annealing the resulting powder in a zirconium-gettered helium atmosphere. A 114.6 mm diam Debye-Scherrer camera and a Weyland nonsymmetrical self-focusing camera were used with filtered copper radiation to obtain the powder X-ray diffraction data. Results The data obtained in this study have been combined to construct the constitution diagram of the U-Cr system shown in Fig. 1 where the arrests observed in cooling curves are indicated by dots. The liquidus arrest was quite distinct in thermal data taken on alloys in the range 0 to 20 atomic pct Cr. The eutectic arrest was not observed in studies on the 2.5 and 4.5 pct Cr samples but appeared in the 7.5 pct samples, which suggested some solubility of chromium in y uranium. On quenching from 859 °C, the 2.5 pct sample showed but one phase while the 4.5 pct sample contained a small amount of the eutectic along the grain boundaries; see Figs. 2 and 3. From this the maximum solubility of chromium in r uranium has been set at 4 pct. X-ray studies on these samples showed that the r phase was not retained at room temperature by quenching, but in each case a pattern was observed .which has been identified with the ß phase of uranium. Thermal data show the y-ß transformation of uranium lowered to 737°C as a consequence of this solubility. On quenching from the ß range (660°C), precipitation of chromium in the primary uranium is observed in the 2.5 and 4.5 pct Cr samples (see Figs. 4 and 5),

Jan 1, 1956