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By T. J. Fabiniak, R. A. Dodd, R. Balow

ALTHOUGH the (111) slip direction in pure bcc metals is well established, the information on operative slip planes is less unambiguously interpreted. So far, (110) {112), and (123) slip planes have been identified, but it is not certain whether glide on (112) and (123) really occurs or if it is composite slip on non-parallel (110) planes. The second of these possibilities is supported by the work of Chen and Maddin on niobium and molybdenum, and a subsequent analysis by these same workers of slip in bcc metals generally.3 The alternative possibility is exemplified by the work of Opinsky and smoluchowsky4 who concluded that slip in Fe-Si crystals can occur on any one of the systems {110}(111), {112}(111), and {123)(111), depending on which system the resolved shear stress is highest. Allen et alS5 also found that glide in ar iron could occur on any of these three systems, the operative system being determined principally by orientation. By an analysis of crystal rotation, slip lines, and X-ray asterism Harris6 concluded that niobium also deforms on these same systems, but if one of these glide planes does not coincide with the plane of maximum resolved shear stress, composite slip on nonparallel (110) planes may occur giving a macroscopic high indices slip plane. Earlier work on iron by Vogel and Brick reached the same conclusion.7 The analysis of slip in bcc metals is made more difficult by the fact that the slip lines may be quite wavy. In fact, the generality of wavy slip lines suggests that screw dislocations slip readily from one plane to another in the (111) zone ("pencil glide") although, as noted, it is not certain whether planes other than (110) really contribute to the slip. If planes of higher indices than {110} do operate, there is a possibility they may do so more readily at higher temperature Argon and Maloof9 observed {100}{211}(111) slip in tungsten single crystals plastically strained at low temperatures, but the results were interpreted in terms of an orientation-dependence rather than temperature-dependence. Therefore, at the present time corroborative evidence for the operation of higher indices slip planes at higher temperatures is lacking. The present results were obtained during the course of an investigation into the effect of cathode and anode surface crystallography on the prebreakdown currents of vacuum insulated devices. In the experiment of particular interest, the 1/8-in.-diam anode and the in.-diam cathode were tungsten crystals (total impurities -230 ppm) with (110) and (100) faces respectively. The faces were electrolytically planed and examined for initial perfection by plastic/carbon replicas and a study of Kikuchi lines in reflection electron diffraction patterns. They were aligned precisely parallel in an insulating holder incorporated into the electron microscope, the measured microscope vacuum being 2 x 10-5 torr, and the electrode spacing 0.01524 cm. The anode structure shown in Fig. 1 was obtained

Jan 1, 1970

By S. B. Christy

The fact that many millions of gold have been extracted by the cyanide process, during the last five or six years, from South African tailings which could not be profitably worked by any other method previously tried upon them, lends a peculiar practical interest to this branch' of metallurgy. Numerous writers have recently made valuable contributions on the process without exhausting the many complexities of the subject. Among the first American writers on the subject in its modern aspect were two former students of the University of California, Mr. Louis Janin, Jr., and Mr. Charles Butters. Young Janin was one of the first to enter this field, and performed much useful experimental work in the early stages of the history of the process. At about the same time, Mr. Charles Butters, who had left California to erect chlorination works for the Robinson mine at Johannesburg, became interested in the cyanide process, and, after getting the chlorination plant in working order, put up, for working the tailings from the Robinson mine, a cyanide plant which achieved the first large-scale success ever made with this process. The papers which Charles Butters, together with John E. Clennell and Edgar Smart, have contributed on the chemistry of the process, were among the first to give any adequate idea of its nature.* Another important contribution to the literature of the subject is the paper of Dr. A. Scheidell, published in 1894 as a " Bulletin of the California State Mining Bureau." This contains an admirable summary of the state of the art at the time of its publication.

Jan 1, 1897

By H. H. Stout

THE high copper price during the war stimulated the capacity to produce far beyond a possible normal consumption. The curves in Fig. 1 show this. The line YZ indicates, what the world production and consumption of primary copper nor-mally would have been, had not the 3 war upset the rhythm of industry. Granting that the maximum world production of 3,150,000,000 lb. in 1917 was obtained by crowding both the equipment and the grade of ore mined, yet in many instances addi-tional capital was invested, upon which the producer will be driven to earn at least a reasonable interest. During the period of deflation, or C liquidation, which we have entered, the consumption of copper will nat-urally be below the normal. Fig. 1 shows the actual consumption ex-pressed-in per cent. of normal : 1919, 96 per cent.; 1920, 94 per cent.; 1921, 70 per cent. The copper industry, consequently, faces: (1) Potential over-production capacity; I (2) Diminished consumption. To deny the existence of these factors would be illogical. To minimize the menace of this potential producing capacity might lead to regret. All past attempts at artificial control have not proved very successful. Obviously the remedy is to increase, if possible, the consumption of copper to a point where these factors cease to be dangerous. In ultimate analysis, this means: Produce an article so cheap and so good that no one can afford to use substitutes. The problem can be solved by: (1) Re-ducing price; (2) Improving product offered.

Jan 11, 1922

By M. A. Mahtab, T. M. Yegulalp

This paper presents the development and application of an approach for clustering fracture orientation data. Data are projected on the surface of the unit upper hemisphere and the clustering approach is applied in three steps: (1) randomness test and identification of dense clusters, (2) estimation of cluster statistics, using Bingham distribution, and (3) rejection of extremal data based on Chauvenet's criterion.

Jan 1, 1982

By John Brown

As a part of a symposium on the relations of structure to ore deposi-tion, in February 1938, the writer presented some tentative opinions derived from his experience with a number of important lead-zinc replace-ment deposits. These ideas were set forth, as a basis for discussion and a stimulus to further inquiry, in a mimeographed leaflet that read as follows: Intimate acquaintance with a number of lead and zinc deposits in metamorphosed limestones seems to indicate the existence of certain common features from which can be established some general principles governing the localization of ore in this type of formation. It is suspected that these principles can be applied, with modifica-tions, to mineralization in unmetamorphosed limestone. In metamorphosed forma-tions, some observed rules are as follows: 1. Bands or masses of pure limestone are very resistant to replacement by ore solutions, and are likely either to contain no ore or to resist replacement until near the end of mineralization. The reason for this apparently is physical, not chemical, since microscopic data indicate that when ore is deposited by far the greater part of it substitutes for carbonate. The chief factor is believed to be a lack of porosity in massive limestone that has undergone flowage and recrystallization. 2. Masses of intensely siliceous or silicated rock are likewise unfavorable ore receptacles. This seems to be accounted for by two factors: (a) chemical unsuit-ability or resistance to replacement, and (b) physical resistance to small-scale brecci-ation, which might facilitate the opening of effective channelways for solutions. Some low-grade ore may occur, however, and also sporadic fracture fillings. 3. The optimum condition for ore reception appears to be found in bands or areas containing carbonate and silicates (or quartz) intimately mingled in something like equal proportions. In this situation movement is likely to result in mixed flowage and fracture, producing a fine-textured porosity that admits solutions freely and provides access to an abundance of replaceable carbonate. Cleavage cracks in some minerals such as diopside are believed to facilitate the penetration of solutions. 4. Certain minerals or assemblages are regarded as favorable impurities in a lime-stone and others as unfavorable. Original quartz, and subsequently developed diopside, and perhaps garnet, are typical favorable pre-ore gangue; in general rather equidimensional, brittle minerals. Tremolite, biotite, and probably wollastonite, are typical unfavorable pre-ore gangue; in general highly elongated and somewhat flexible minerals likely to develop under strong shearing stresses. 5. Tentative opinion is that the ratio of lime and magnesia in a limestone-is of little or no importance.

Jan 1, 1940

By John S. Brown

As a part of a symposium on the relations of structure to ore deposition, in February 1938, the writer presented some tentative opinions derived from his experience with a number of important lead-zinc replacement deposits. These ideas were set forth, as a basis for discussion and a stimulus to further inquiry, in a mimeographed leaflet that read as follows Intimate acquaintance with a number of lead and zinc deposits in metamorphosed limestones seems to indicate the existence of certain common features from which can be established some general principles governing the localization of ore in this type of formation. It is suspected that these principles can be applied, with modifications, to mineralization in unmetamorphosed limestone. In metamorphosed formations, some observed rules are as follows: 1. Bands or masses of pure limestone are very resistant to replacement by ore solutions, and are likely either to contain no ore or to resist replacement until near the end of mineralization. The reason for this apparently is physical, not chemical, since microscopic data indicate that when ore is deposited by far the greater part of it substitutes for carbonate. The chief factor is believed to be a lack of porosity in massive limestone that has undergone flowage and recrystallization. 2. Masses of intensely siliceous or silicated rock are likewise unfavorable ore receptacles. This seems to be accounted for by two factors: (a) chemical unsuitability or resistance to replacement, and (b) physical resistance to small-scale brecciation, which might facilitate the opening of effective channelways for solutions. Some low-grade ore may occur, however, and also sporadic fracture fillings. 3. The optimum condition for ore reception appears to be found in bands or areas containing carbonate and silicates (or quartz) intimately mingled in something like equal proportions. In this situation movement is likely to result in mixed flowage and fracture, producing a fine-textured porosity that admits solutions freely and provides access to an abundance of replaceable carbonate. Cleavage cracks in some minerals such as diopside are believed to facilitate the penetration of solutions. 4. Certain minerals or assemblages are regarded as favorable impurities in a limestone and others as unfavorable. Original quartz, and subsequently developed diopside, and perhaps garnet, are typical favorable pre-ore gangue; in general rather equidimensional, brittle minerals. Tremolite, biotite, and probably wollastonite, are typical unfavorable pre-ore gangue; in general highly elongated and somewhat flexible minerals likely to develop under strong shearing stresses. 5. Tentative opinion is that the ratio of lime and magnesia in a limestone is of little or no importance.

Jan 1, 1940

By J. O. Brittain, E. Lautenschlager

An investigation was conducted on fine grained airon wire to measure the influence of the temperature of deformation on strain aging near room temperature. Specimens were deformed various amounts at 77°, 195°, or 273°K and aged. The strain aging was followed by either internal friction or return of the yield-point measurements. The results show that strain aging occurs in three stages. During the first stage there is small, almost immediate return of the yield point. The solute carbon concentration, as mesured by internal friction, remains constant in stage I but is lower than the concentration in the unstrained condition. In the second stage, the solute concentration decreases while the magnitude of the yield point increases. In the third stage, the solute atoms continue to drain from the solution, the yield point approaches a maximum, and the strain-hardening coefficient and flow curve increase. The kinetics of the strain aging reaction are not the same for the two sets of measurements since the internal friction results lag behind the yield-point measurements. However, the strain-aging kinetics measured at 44° and 64°C showed no effect due to the difference in initial deformation temperature; nor were the strain aging kinetics influenced by low-temperature anneals at 77°, 195°, and 273°K. 1 HE object of this investigation was to measure the effect of initial deformation temperature on the strain aging of a-iron by tensile tests (i.e., return of the yield point) and internal friction methods, to correlate the results of the two measuring methods, and to measure the effect of low-temperature annealing (<273°K) after low-temperature deformation upon strain aging. The experiments were performed on fine-grained a-iron wire containing 0.02 wt pct c.l According to Thomas and Leak,&apos; return of the yield point and internal friction are similar measures of strain aging since both are dependent on solute atoms leaving the solid solution. The decrease in internal friction as a function of aging time is indicative of the removal of solute atoms from the solid solution, while the return of the yield point as a function of the aging time gives the rate of arrival of solute atoms at the dislocations. According to Cottrell and Bilby,3 during aging the solute atoms create an "atmosphere" which locks the dislocations and causes a return of the yield point on subsequent testing. It has been shown that after low-temperature neutron bombardment, a-iron goes through a stage of recovery at low temperatures which can be attributed to the annealing of iron interstitials&apos; and/or vacancies.4 If, after low-temperature deformation, there is an interaction during a low-temperature anneal between mobile point defects and the solute atoms (i.e., carbon atom interaction with vacancy or iron interstitial), it is possible that some solute atoms will be found at defect sites other than dislocations. Such changes in the sinks for the carbon atoms might be expected to alter the strain-aging kinetics sufficiently to be detected by either inter-

Jan 1, 1962

By Arthur Knapp

The practical application of mud-laden fluids in wells has been the subject of many papers.&apos; However, there seems to have been little investigation of what actually happens when mud-laden fluids are applied to a loose porous sand. The assumption is that the fluids penetrate the sands and that there is some plastering action. The degree of penetration and the relation of plastering action to wall stability is not generally known. This paper describes a series of experiments made in an attempt to observe, in laboratory apparatus, the action of mud-laden fluids under conditions simulating those to be found in a well. For the purposes of this discussion all fluids containing solid matter in suspension are mud-laden fluids. Series I: Penetration of the Pores of Uncemented Sands The subject of the penetration of porous formations by water is discussed in detail in Water-Supply Paper No. 67 of the U. S. Geological Survey. No attempt was made to repeat the experiments described therein. The results of the first experiment of this series are given simply to show the capacity of the apparatus used. The conditions in this first experiment were maintained throughout the remainder of this and the second series, except where noted. The experiments of Mills, McCoy, and others on subsurface flows, adjustments, migrations, etc., deal with the oil, water or gas within the porous beds.V he experiments described herein deal with the conditions immediately surrounding the bore hole.

Jan 1, 1923

By Arthur Knapp

The practical application of mud-laden fluids in wells has been the subject of many papers.&apos; However, there seems to have been little investigation of what actually happens when mud-laden fluids are applied to a loose porous sand. The assumption is that the fluids penetrate the sands and that there is some plastering action. The degree of penetration and the relation of plastering action to wall stability is not generally known. This paper describes a series of experiments made in an attempt to observe, in laboratory apparatus, the action of mud-laden fluids under conditions simulating those to be found in a well. For the purposes of this discussion all fluids containing solid matter in suspension are mud-laden fluids. Series I: Penetration of the Pores of Uncemented Sands The subject of the penetration of porous formations by water is discussed in detail in Water-Supply Paper No. 67 of the U. S. Geological Survey. No attempt was made to repeat the experiments described therein. The results of the first experiment of this series are given simply to show the capacity of the apparatus used. The conditions in this first experiment were maintained throughout the remainder of this and the second series, except where noted. The experiments of Mills, McCoy, and others on subsurface flows, adjustments, migrations, etc., deal with the oil, water or gas within the porous beds.V he experiments described herein deal with the conditions immediately surrounding the bore hole.

Jan 1, 1923

By B. B. Zavoico, J. G. H. Crump, P. P. Gregory

West Texas was the scene of greatly increased oil activity during 1937, producing 75,743,000 bb1.l in that year as compared with 61,901,-000 bb1.2 in 1936, an increase of 22.36 per cent. The annual total of wells completed increased from 15863 in 1936 to 28062 in 1937, an increase of 76.92 per cent. Of the total completions in 1937, 2464 were oil wells,2 11 gas wells2 and 331 dry holes.2 The marked increase in the number of oil wells completed in West Texas during 1937 had a substantial effect upon the daily average production per well, which decreased 20.84 per cent from December 1936, when a total of 5310 wells3 produced 5,236,467 bbl.3 for an average of 31.81 bbl. per well per day to December 1937, when 7571 wells2 with a total production of 5,910,257 bb1.2 averaged 25.18 bbl. per well per day. Drilling blocks and checkerboard acreage were being acquired following geophysical work in the northern end of the Permian Basin area, composed of Bailey, Cochran, Hockley, Yoakum and Terry Counties, presaging extension of active development northward. During 1937, at one time 30 geophysical crews were working in West Texas, and an average of 15 to 20 crews was active in this area throughout the year. Discoveries Wasson-Denver Field.—Wasson-Denver field in Gaines and Yoakum Counties was the outstanding field discovery of the year. Production is from porous limestone found at about 5000 ft., and an average well is good for from 300 to 500 bbl. of crude oil per day through 3/4-in. choke. The discovery well was drilled by A. G. Carter and others on the Wasson Ranch, Gaines County, and the field has since been extended into Yoakum County. At the year&apos;s end 21 wells had been completed, producing

Jan 1, 1938

By Charles Catlett

AN examination of the census reports&apos; for 1880, which contain a large number of complete analyses of typical American iron-ores, indicates that the existence of barium sulphate in intimate association with iron-ore is rather unusual. Of 94 analyses reported there, but four show any barium sulphate, and the maximum content amounts to 3.04 per cent. The note of the occurrence of considerable quantities of barite in connection with certain iron-ores found in the Pinar del Rio Province of Cuba may be of interest. These deposits are found near the little village of Francisco, about 25 miles west of the city of Pinar del Rio on the Western Railroad of Havana. The principal ridges are anticlines, and consist of very thick deposits of sandy shales and slates containing a large number of little veins of white quartz which, by the gradual disintegration of the mass of the material, is left covering the surface. This quartz occasionally shows sulphide, but is generally barren of any such indication. At times lenticular masses of a more or less pure limestone were observed in these slates. The shales, which are of light color, are occasionally talcose. The formation would tentatively be classed as the Lower Cambrian, and the heavy ridges of comparatively horizontal limestone found in the anticlinal valleys as the Upper Cambrian. Along the crest of these slaty ridges deposits of iron-ore are found which are apparently in place, and were probably formed by replacement of masses of limestone similar to those noted elsewhere. The ready disintegration of the slates, and the

Jul 1, 1907

By G. Thodos, R. B. Grieves

A method has been developed For predicting the critical temperatures and critical pressures of binary mixtures of carbon dioxide, hydrogen sulfide, nitrogen, hydrogen, carbon monoxide and oxygen with the normal paraffin hydrocarbons. For carbon-dioxide and hydrogen-sulfide systems, relations are presented that take into account the peculiar behavior of mixtures with closely boiling components, such as carbon dioxide-ethane and hydrogen sulfide-propane mixtures which exhibit minimum critical temperature points. For hydrogen, nitrogen and carbon-monoxide systems, the extreme critical behavior caused by wide differences in pure component properties is established In addition, those fixed gas-paraffin systems which resemble paraffin-paraffin systems are also accounted for. For a mixture of known composition, the pure component critical temperatures, critical pressures and normal boiling points are all that are required to determine its critical point. Graphical relations are presented relating Tc and PC , of the mixture to the pure component properties. From the treatment of 12 carbon-dioxide and hydrogen-sulfide systems reported in the literature (74 mixtures), the expected error lor the critical temperature is approximately 1.5 per cent, and for the critical pressure, approximately 2 per cent. From the treatment of six hydrogen, nitrogen and carbon-monoxide systems reported in the literature (30 mixtures), the expected error for both the critical temperature and critical pressure is approximately 2.5 per cent. The relationships, which have been developed with only normal paraffins as the hydrocarbon components, may be extended to those isoparaffins and olefins which fall within the allowable volatility ranges. INTRODUCTION Many of the fixed gases — carbon dioxide, hydrogen sulfide, nitrogen, hydrogen, carbon monoxide and oxygen — occur in natural mixtures with hydrocarbons. Carbon dioxide and hydrogen sulfide are frequent components of the fluids produced from underground petroleum reservoirs. Nitrogen, carbon dioxide and hydrogen sulfide are present in varying quantities in most natural gases and gas-condensate well effluents. Hydrogen mixtures are of considerable interest in many phases of refining processes of petroleum. The determination of the critical temperatures and critical pressures of such mixtures is of value in vapor-liquid equilibrium studies, for the prediction of the characteristics of underground reservoirs, and for reduced-state correlations of PVT, transport and thermodynamic properties. The accurate estimation of the critical point for binary mixtures is an important initial step toward a complete analysis for the establishment of the critical temperatures and pressures of multi-component mixtures. Methods for predicting the critical temperatures and critical pressures of binary hydrocarbon systems have already been presented in the literature.8 It is possible to apply these existing methods to fixed gas-paraffin mixtures, but due to their unusual critical behavior, values calculated deviate considerably from experimental values. For systems containing trace quantities of the fixed gases, these methods are acceptable; however, for systems containing more than 5 mol per cent of the fixed gases, these utterly fail to produce reasonable critical values. Consequently, in this study a method has been developed for handling such binary mixtures over the entire composition range. CARBON-DIOXIDE AND HYDROGEN-SULFIDE SYSTEMS The critical behavior and the vapor pressure behavior of mixtures of carbon dioxide and hydrogen sulfide with paraffinic hydrocarbons may be quite similar or quite dissimilar to that of paraffin-paraffin mixtures, depending on the volatilities of the components involved. The critical temperature and normal boiling point of carbon dioxide are very close to the corresponding values for ethane, while its critical pressure is considerably higher than that of ethane. The normal boiling point of

By J. G. Patchett, R. W. Rausch

Fresh waters and the presence of clay in many Rocky Mountain and West Coast sands require special methods of log analysis. Archie&apos;s saturation equation requires addition of a shale correction term, and the SP equation must also be modified to account for clays. Suitable equations were developed several years ago, but have not been widely used due to the algebraic complexity. A computer-oriented method has now been developed to overcome this problem. The basic shaly sand equations are rearranged in four different ways to permit solution for various sets of available input data. Essential to application of the method is the correction of observed SP values to those that would be observed if the resistivity of the formation waters were exactly interchangeable with the activity. A graphic method for doing this is given. Where conditions require consideration of the effect of clay in the sands, the method presented has been found to improve the accuracy of water-saturation determinations. INTRODUCTION Log interpretation in many Rocky Mountain and West Coast basins is complicated by rapid vertical and lateral changes in water resistivity. Calculation of formation water resistivity from the SP curve becomes difficult in zones that contain clay, since changes in SP deflection may be due to changes in either clay content or water salinity. In hydrocarbon-producing reservoirs, the problem is further complicated because hydrocarbon saturation also reduces the SP.1 A log interpretation system using computers has been developed to provide a solution to this problem, based on equations proposed by de Witte.2 Four different simultaneous solutions of de Witte&apos;s equations have been made. Each solution method uses a different set of input data as independent variables. Thus, a choice of solution method is possible, depending upon the logs run and the availability of other data. Two of the solutions do not require a knowledge of water resistivity. This system is intended to be used primarily in multiple sandstone-shale sequences of low and moderate resistivities where the principal contaminant in the sandstones is clay. However, where sufficient regional data are available, interpretation in single-zone sandstone reservoirs can also be improved by using the method. THEORY AND HISTORY OF SHALY SAND ANALYSIS The log interpretation formula originally proposed by Archie3 in 1941 is applicable only to rock-fluid systems wherein the rock has negligible electrical conductivity. In 1949, Patnode and Wyllie4 showed that if the rock itself can be considered conductive due to the presence of clay, a different calculation approach is necessary. During the following years, this problem was investigated at great length, as was the related problem of the effect of rock conductivity on the SP.5-11 These investigations established functional relationships between SP, resistivity, water saturation and water resistivity for such a formation. Refs. 2 and 12 provide summaries of these studies. Unfortunately, practical use of these relationships required that water resistivity be known independently from the SP. Although log interpretation methods for rock systems containing clay were proposed at that time,&apos; they were not generally accepted for routine use. There are three principal reasons for this. First, in many field situations involving high-salinity water, rock conductivity may be neglected (even if present) without introducing appreciable error. This may be seen by considering the following expression for waier-saturated rock.&apos; 1/R2=1/R1+1/FRn....(1) where 1/R, is conductivity due to clay. As Rw becomes small, I/FRw becomes much greater than 1/R, which may be neglected. Where 1/R, may be neglected, the sandstone is called clean. If the term may not be neglected, the sandstone is termed dirty or shaly. For resistivity purposes, the classification between clean and shaly sands then depends not only upon the conductivity due to shale in the sand, but also upon the resistivity of the associated water (shale is used here to mean surface condition due to disseminated clay). A sand of given conductivity might safely be treated as clean in association with high-salinity water, but would require shaly sand methods if associated with fresher waters. Shaly sand methods are not required in many areas having saline waters; but in Rocky Mountain and West Coast sands having relatively fresh waters (often more than 0.3 ohm-m resistivity at formation conditions), the shaly sand methods are needed. Errors Rw calculations from the SP due to the presence of shale are likewise related to water salinity. In saline water formations drilled with fresh mud, the ratio of mud filtrate resistivity to water resistivity is high, the SP is large and the presence of shale can introduce large errors in water resistivity calculated by the conventional method. When the resistivity ratio is low, the errors are smaller. At zero SP, no error would result from shale. Thus, from the SP viewpoint, a given rock could be shaly if associated with a saline water, and clean in association with a fresh water, which is the opposite of the resistivity-oriented definition above.

By H. Vance

In 1932, as in 1931, the East Texas area outside the Gulf Coast exerted &apos; its influence over the entire petroleum industry. Practically 60 per cent of the oil wells completed in the United States during 1932 were in this area, development being chiefly confined to the East Texas oil field in Upshur, Gregg, Rusk, Smith and Cherokee counties. This East Texas area is geologically an interior salt dome basin, along the western edge of which are located the fault line fields as represented by Mexia and Powell. Production occurs on salt domes in the interior of the basin as represented by Boggy Creek and possibly Van, although no salt has actually been discovered in drilling at Van. Shore line conditions on the east side of this basin along the flanks of the Sabine uplift have been responsible for the East Texas oil field. Many known salt domes in the center of this basin have been tested but as yet have failed to produce oil in commercial quantities. The main producing horizon throughout the area is lowermost upper Cretaceous and is known locally as the Woodbine sand. The East Texas Oil Field Development.—Approximately 6000 producing wells were completed during the year in the East Texas oil field. No accurate estimate of the total initial production of these wells is available because few initial production tests were made as the wells were completed. The writer estimates the average initial production of these completed wells at 2500 bbl. per day while flowing wide open through tubing. Based on this estimate, the total initial production of the wells completed during the year is 15,000,000 barrels. At the close of 1932 there were approximately 9500 completed wells in the East Texas field. Of this number 176 were without pipe line connections. The oil produced from these unconnected wells could be marketed for $0.30 per barrel while the price paid for oil run from the connected wells was $0.75 per barrel.

Jan 1, 1933

By Harrison R. Cooper

Measurement of process material composition with on-line instrumentation has commanded attention of metallurgical plant management as a logical extension of the sampling operation, making possible immediate determination of essential data needed to maintain efficiencies at the highest possible level. The current status of methods employed for online composition analysis of slurries and solid materials is reviewed.

Jan 1, 1984

By J. Gurland

The wmk is concerned with the estimate of the degee of continuity of a particulate phase dispersed in a matrix. The first section is a verieu: of the parameters nzeasurable by quantitative rnetallogvaphy, namely the contact area and, under certain conditions, the number of contacts between particles of one phase. In the second section, the frequency of particle contacts is related to the degee of continuity of a randomly embedded phase orz the basis of the lattice-percolation model of Hamrnersley and others. THE extent of continuity of the constituent phases may greatly influence the structure-sensitive properties of phase mixtures, particularly if the phase properties differ significantly. An example from the literature1 is shown in Fig. 1. The marked decrease of the electrical resistivity of sintered silver-alumina bodies near 25 pct by volume of silver presumably occurs because the more conductive phase changes from a discontinuous to a continuous structure. Other example of electrical- and thermal-conductivity transitions are cited by kingery In view of these observations, a knowledge and understanding of the connectivity of the microstructure may be of considerable practical importance. This study is concerned with one aspect of the genera1 problem, namely the estimate of the degree of continuity of a particulate phase dispersed in an opaque matrix. The first section reviews the parameters measurable on a polished cross section by auantitative metallography, such as the contact area and under certain conditions, the number of contacts between particles of one phase. In the second section, an attempt is made to relate the frequency of particle contacts to the degree of continuity of a randomly embedded phase. For the purpose of this discussion, the aggregate has two constituents: the particulate phase and the matrix. The latter is considered to be homogeneous. The term "particle" is used with the meaning of "grain", i.e., a minute unit of matter which is usually a single crystal of a readily distinguishable substance within the confines of a simply connected boundary. While many of the concepts which are used here to describe the structural variables characterizing the microstructure of phase mixtures are qualitative and ill-defined, they are presented with the intent of stimulating further work of a more general and rigorous nature. I) PARTICLE CONTACT, CONTIGUITY, AND MEAN FREE PATH 1) Measurement of Contiguity. The fraction of the total internal surface of a phase a shared with particles of that same phase in a two-phase mixture of and $ is indicated by the contiguity ratio:3 whereis the area of the interface between o particles, and Sap is the area of the interface between a particles and matrix P, per unit volume of mixture. The contiguity ratio ranges from 0 to 1 as the distribution of the a phase changes from a completely dispersed to a completely agglomerated structure. The interfacial areas may be obtained from simple intercept measurements on a random plane, after Smith and Guttman where and N are the numbers of intercepts between a random line of unit length on a plane of polish and the interparticle and interphase interfaces, respectively. The equations are valid for any distribution of particle sizes and shapes.

Jan 1, 1967

HAVING demonstrated to you above the practice of bringing silver to its ultimate fineness and perfection, it now remains for me to describe how the two kinds of metals that are found in the smelting product that you made from the ores are to be brought to their end: One is copper and the other lead, and perhaps a third is gold, if per-chance the silver that you refined in the cupeling hearth contained any. It would be almost impossible that it should not contain any, because either a little or a lot is almost always found as an admixed substance not only in silver but in. every one of the other metals as well. But in order to continue in sequence, you must suppose that there is some gold and that, of the two materials you have that I mentioned above and told you to save, one is the matte (calling it according to the usage of Germany, * since I do not know a more exact or better word for describing it to you) and the .other is the litharge that you took from the cupeling hearth. In addition, the hearths themselves are saturated and full of lead. If these things should remain in their present condition they would be useless bodies without any perfection. First, taking one of the three said parts, as a material of greater quantity and also as a thing that needs greater labor, and because, being reduced to the point I have told you with smelting and evaporation, it is nearer to its end, I shall tell you what must be done in order to bring it to pure copper. As I have told you, there are two materials on hand, one of which is the matte and the other the litharge. Each at first sight seems a half-burned thing; one has already been finished metal and the other is to be, but in my opinion the matte is nearer to its end than is the litharge because the latter has been dried by the power of the fire and re-formed from another body. Now leaving aside the discussion of this thing, after the matte has been well evaporated and reduced, it is taken and put on a forge. In front of the tuyère a receptacle is made of stones that neither calcine nor melt, or of coals and powdered clay, in the form of a little cradle that is longer than it is wide and not very deep. Its length should be about one and a half

Jan 1, 1942

By David Keys

THE object of this investigation was to determine with a vertical magnetic variometer the extent of the titaniferous ore deposit that occurs not far from Ivry in Terrebonne County, Quebec, about 70 miles north of Montreal. The Ivry mine, on lots 37 and 38 of range V, Beres-ford township, Quebec, is one of the largest and most accessible to transportation of the deposits of ilmenite in Quebec. The ore consists of an aggregate of ilmenite anhedra serving as host for numerous fine plaques of hematite. No magnetite is known from any occurrence near this lot, and in this way the deposit differs from many others that contain a large percentage of magnetite with the ilmenite. The deposit at Ivry thus has much lower magnetic susceptibility than those containing abun-dant magnetite, and a sensitive magnetometer was necessary for the work, although a body of magnetite with ilmenite about a mile from the Ivry mine was successfully prospected with a dip needle. The principal orebody is exposed in a quarry known as the Ivry mine, from which about 16,000 tons of ore have been shipped. Small exposures of ilmenite isolated by drift serve to show the presence at the surface of some of the bodies indicated by the magnetometer,- but most of the hill is covered with glacial till and second growth hardwood. At the lower levels the till gives place to fluvioglacial sands and gravels from which the forest has been cleared. The increasing thickness of the sand and gravel as the hill descends makes the tracing outward of the deposits from the rocky knob of anorthosite a difficult matter. Within the orebodies too, some masses of anorthosite persist, which may account for some local irregularities. Fig. 1 is a photomicrograph, taken by reflected light, of a typical specimen of the ore. The dark patches are hematite and the light parts are ilmenite. No trace of magnetite was found. Fig. 2 is a photo-micrograph of a thin section of the country rock showing the texture of the anorthosite. The mean of four analyses quoted by Robinson1 is: titanium, 19.26 per cent; iron 45:41 per cent.

Jan 1, 1936

By David B. Reger

Exploration for new pools of gas in the Oriskany sand and continued exploitation of areas already known to be productive in that sand were the main features of petroleum activity in West Virginia during 1938. To a considerable extent the exploration program resulted in failure, but the extension of former areas was eminently successful. Throughout the state, in general, less drilling was done than in 1937. According to the West Virginia Department of Mines, only 631 permits to drill were issued, as compared to 1034 in 1937. The account of operations, as reported by trade journals and other sources, shows that 766 wells were drilled, resulting in 131 oil wells with 1609 bbl. of daily production; 484 gas wells with 1,232,216,000 cu. ft. of daily open flow; and 151 dry holes. Several discoveries indicate new pools of oil and gas; and several extensions of old gas pools have been made. In spite of a decreased number of total wells, the figures for new gas and oil are both larger than in 1937. The new oil average is 12.3 bbl. per well per day; the gas average is 2,545,900 cu. ft. per well per day, the ratio of dry holes to completions is 19.71 per cent. No general attempt was made to discover new pools of oil. A continued low price, coupled with reduced takings, combined to make drilling unattractive. The principal oil wells completed, by counties are: Boone, 6; Calhoun, 10; Clay, 7; Gilmer, 5; Kanawha, 5; Lincoln, 7; Pleasants, 13; Ritchie, 32; Roane, 6; Tyler, 7; and Wirt, 14. Production for the year, according to the Oil and Gas Journal, was 3,724,750 barrels. The leading counties in gas, with the number of successful wells in each, are: Boone, 16; Braxton, 13; Cabell, 47; Calhoun, 29; Doddridge, 10; Gilmer, 55; Kanawha, 127; Lincoln, 18; Ritchie, 29; Wayne, 19; and Wetzel, 26. Production for the year is estimated as 150,000,000,000 cubic feet. Pipe-line construction, which was extensive in 1937, was insignificant in 1938. Exploration was not as active as in 1937. Field prices of both oil and gas have severely declined.

Jan 1, 1939

By David B. Reger

Exploration for new pools of gas in the Oriskany sand and continued exploitation of areas already known to be productive in that sand were the main features of petroleum activity in West Virginia during 1938. To a considerable extent the exploration program resulted in failure, but the extension of former areas was eminently successful. Throughout the state, in general, less drilling was done than in 1937. According to the West Virginia Department of Mines, only 631 permits to drill were issued, as compared to 1034 in 1937. The account of operations, as reported by trade journals and other sources, shows that 766 wells were drilled, resulting in 131 oil wells with 1609 bbl. of daily production; 484 gas wells with 1,232,216,000 cu. ft. of daily open flow; and 151 dry holes. Several discoveries indicate new pools of oil and gas; and several extensions of old gas pools have been made. In spite of a decreased number of total wells, the figures for new gas and oil are both larger than in 1937. The new oil average is 12.3 bbl. per well per day; the gas average is 2,545,900 cu. ft. per well per day, the ratio of dry holes to completions is 19.71 per cent. No general attempt was made to discover new pools of oil. A continued low price, coupled with reduced takings, combined to make drilling unattractive. The principal oil wells completed, by counties are: Boone, 6; Calhoun, 10; Clay, 7; Gilmer, 5; Kanawha, 5; Lincoln, 7; Pleasants, 13; Ritchie, 32; Roane, 6; Tyler, 7; and Wirt, 14. Production for the year, according to the Oil and Gas Journal, was 3,724,750 barrels. The leading counties in gas, with the number of successful wells in each, are: Boone, 16; Braxton, 13; Cabell, 47; Calhoun, 29; Doddridge, 10; Gilmer, 55; Kanawha, 127; Lincoln, 18; Ritchie, 29; Wayne, 19; and Wetzel, 26. Production for the year is estimated as 150,000,000,000 cubic feet. Pipe-line construction, which was extensive in 1937, was insignificant in 1938. Exploration was not as active as in 1937. Field prices of both oil and gas have severely declined.

Jan 1, 1939