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By M. E. Hassan, J. C. Calhoun, R. F. Nielson

An apparatus was constructed for the measurement of inter-facial tensions over a range of temperatures and pressures. This apparatus utilized the pendent drop method, and resembles in construction similar apparatus recently described in the literature and in use in some petroleum research laboratories. The interfacial tensions of benzene, propane, n-pentane, n-hexane. n-octane. and iso-octane against water were measured at temperatures ranging from 26" to 82" C and at pressures ranging from 1 to 204 atm. Values of interfacial tensions for the henzene-water system and their variations with temperature and pressure are generally in good agreement with value? of previous investigations. The data in all cases showed a slight decrease of interfacial tension with pressure at constant temperature in the range studied. The effect of pressure became less as the pressure was increased, with an indication of a reversal of the effect at higher pressures. There was a decrease of interfacial tension with temperature at constant pressure in all cases, as would normally be expected. This rate of decrease became greater the higher the temperature. A general equation is presented for the interfacial tensions as a function of presPurp and temperature over the range studied, and the constants calculated for each system. A definite trend was found in the effect of molecular weight on the interfacial tension at a given temperature and pressure, for the homologous series from propane to n-octane. Data for n-decane from the literature fitted well into this trend. INTRODUCTION It has been recognized for many years that surface forces play an active part in the production history of an oil reservoir as well as in determining the amount of unrecoverable oil. The magnitudes of these forces are governed by the values of the interfacial tensions. These vary greatly with composition, pressure, and temperature. The effect of composition is greater than that of pressure and temperature over the ranges normally encountered. In fact, because of the variety of compounds present in a crude, no attempt has yet been made to correlate crude composition with its surface tension or with its interfacial tension against water. The amount of dissolved methane greatly affects the surface properties of an oil, and there are "surface-active" compounds in crudes which have a much greater effect on boundary tensions than do equal amounts of hydrocarbons. The purpose of the present work was partly to contribute data that would eventually be used in correlations applicable

Jan 1, 1953

Discussion of the paper of Robert Franke, presented at the Butte meeting, August, 1913, and printed in Bulletin No. 79, July, 1913, pp. 1201 to 1205. ARTHUR 0. GATES, Lafayette, Ind. (communication to the Secretary*) :-In connection with the comparison of mechanical crushing efficiencies in Tables I and II of Mr. Franke's paper, I wish to suggest a somewhat simpler way of making this' comparison, based upon what the writer has called the "crushing-surface diagram," as published by him in the Engineering and Mining Journal for May 24, 1913. Such a diagram, based on the data given in Table II, is submitted herewith, Fig. 1, cumulative percentages being plotted as abscissas and reciprocals of diameters (theoretical mesh per inch). plotted as ordinates.. Such a diagram averages the diameters without calculation, and areas upon it are proportional to surface produced, and, in accordance with Rittinger's law, to energy spent on crushing alone.

Jan 11, 1913

By N. A. Zeigler, T. D. Yensen

Aging is a term that connotes a slow change in properties under ordinary operating conditions. It can be accelerated by increasing the temperature and by mechanical straining. The magnetic properties of iron and some of its alloys have for many years been known to be subject to such a change. But the cause of the change was not recognized until a few years ago after mechanical age-hardening in non-ferrous alloys of the "duralumin" type had been definitely shown, by means of solid solubility curves, changes in electrical resistance and microanalysis, to be caused by slow precipitation of one or more constituents from the solid solution. The similarity between the solid solubility curves of such alloys (Fig. 1) and those for iron-nitrogen (Fig. 2) and iron-carbon alloys (Fig. 3) below the A1 transformation point suggested at once that magnetic aging of iron might be caused by a similar process; namely, by the slow precipitation of carbon and nitrogen in the form of Fe4N and Fe3C at ordinary temperatures because of a cooling rate that had been too rapid to permit complete precipitation according to equilibrium conditions. This suggestion has since been amply confirmed, particularly by the comprehensive work of Köster1 on the effect of nitrogen and carbon. Typical curves are shown in Fig. 4 for the relationship between aging temperature and coercive force. Previous to the establishment of the precipitation-hardening theory it was thought that the effect of nonmetallic elements like C, N, O, etc., on the magnetic properties of iron was greatest when these elements were retained in solid solution, atomically dispersed throughout the interstitial spaces of the iron lattice2. Based on the theory that magnetic properties are intimately connected with the regularity of the lattice, it now follows quite logically that a greater effect on this regularity may be obtained when the above impurities are precipitated as very fine particles of Fe3C, Fe4N, FeO, etc., more or less uniformly dispersed within the grains. But if this is the case, it follows also that there must exist a relationship between the size

Jan 1, 1935

By N. A. Zeigler, T. D. Yensen

Aging is a term that connotes a slow change in properties under ordinary operating conditions. It can be accelerated by increasing the temperature and by mechanical straining. The magnetic properties of iron and some of its alloys have for many years been known to be subject to such a change. But the cause of the change was not recognized until a few years ago after mechanical age-hardening in non-ferrous alloys of the "duralumin" type had been definitely shown, by means of solid solubility curves, changes in electrical resistance and microanalysis, to be caused by slow precipitation of one or more constituents from the solid solution. The similarity between the solid solubility curves of such alloys (Fig. 1) and those for iron-nitrogen (Fig. 2) and iron-carbon alloys (Fig. 3) below the A1 transformation point suggested at once that magnetic aging of iron might be caused by a similar process; namely, by the slow precipitation of carbon and nitrogen in the form of Fe4N and Fe3C at ordinary temperatures because of a cooling rate that had been too rapid to permit complete precipitation according to equilibrium conditions. This suggestion has since been amply confirmed, particularly by the comprehensive work of Köster1 on the effect of nitrogen and carbon. Typical curves are shown in Fig. 4 for the relationship between aging temperature and coercive force. Previous to the establishment of the precipitation-hardening theory it was thought that the effect of nonmetallic elements like C, N, O, etc., on the magnetic properties of iron was greatest when these elements were retained in solid solution, atomically dispersed throughout the interstitial spaces of the iron lattice2. Based on the theory that magnetic properties are intimately connected with the regularity of the lattice, it now follows quite logically that a greater effect on this regularity may be obtained when the above impurities are precipitated as very fine particles of Fe3C, Fe4N, FeO, etc., more or less uniformly dispersed within the grains. But if this is the case, it follows also that there must exist a relationship between the size

Jan 1, 1935

By W. R. Toeplitz

H. N. Ghenn.*—It has been established that the accuracy obtainable from any precision machine is a function of the wear resistance, maintenance and closeness of fit of the bearings, hence I would like to ask Mr. Toeplitz how these oil-less bearings compare with cast iron or babbitt or similar materials when used on precision machinery. Could these bearings be used, for example, on a grinding machine in which work must be held to a tolerance of plus or minus 0.000025 inch? W. R. TOEPLITZ.—The metal-powder bearings can be held to very close tolerances and are used in place of cast iron and babbitt on precision machinery.

Jan 1, 1945

The U. S. Navy Department has perfected plans for the enrollment and training of considerable numbers of engineering officers. A school for this purpose, the U. S. Navy Steam Engineering School, has been established by the Department at Hoboken, N. J. The school is open to men between the ages of 21 and 40 who meet the physical requirements of the Navy, who are of thorough ability and officer-like character and who have completed the mechanical or electrical engineering course at certain recognized technical schools, or who possess an education and experience adjudged to be an equivalent thereof. Enrollment in the U. Naval Reserve Force of men properly qualified may be made at any Naval enrolling office, notation being made of the applicant's qualifications and desire to be detailed to this school. Applicants will be enrolled as Chief Machinist Mates, and during the course of instruction will draw the pay of this rating, $83 per month, plus $60 per month paid as subsistence. Upon graduation, men will be commissioned as Ensigns in the U. S. Naval Reserve, with a salary of $1700 per year. The duty to which a graduate of this school will be assigned will be that of an engineer officer in the auxiliary service of the Navy. Special provision has been made for the continuance of the school with proper material by a Navy regulation which permits undergraduates of the Freshman, Sophomore, and Junior Classes in recognized engineering schools to enroll in the Naval Reserve Force with the rating of Seaman 2d Class, and continue their courses at the institutions where they have matriculated. Such men will be called into active service after their graduation, and can at that time, if they are qualified to pass an officers' physical examination, apply for admission to the U. S. Navy Steam Engineering School. Men who are registered in the draft, either graduates or undergraduates, may enroll with the proper enrolling officer by securing from their draft board a letter of release, which in all probability can be obtained for this purpose. The aim of this school is not simply to produce engineers, but to produce naval engineering officers in the true sense of the word. The course of instruction covers a period of five months, arranged in four periods.

Jan 10, 1918

The visitors to the October meeting will be given opportunity to visit the coal fields in Illinois, adjacent to St. Louis, the steam-shovel operations near Pittsburgh, Kan., and the Oklahoma oil fields. The coal mines of Illinois, Missouri, Kansas, Oklahoma and Arkansas furnish fuel over all of the central region of the country. Especially at this time, this district is of importance because of the necessity of producing enormous quantities to meet the country's demand. Some of the mines produce as much as 5,500 tons in 8 hr., and. the total output of Illinois, alone, in 1916, was 63,000,000 tons. Visitors may see elaborate underground electric tram systems, large underground machine repair shops, surface plants equipped for rapid loading, and some of the most modern coal-washing installations. The conditions for mining here are somewhat simpler than in the east.

Jan 8, 1917

By C. E. SWANN

NOT long ago an engineering study was made to determine if the time had arrived to lower the head of standing water in abandoned Rock Springs mines Nos. I and 3 of The Union Pacific Coal Co. so that this water would not become a menace to the future operations of adjacent mines or mines developed on seams lower in the coal measures. This survey resulted - in a decision to unwater the No. 1 mine workings and, incidentally, the old No. 3 mine workings by drilling a large-diameter hole from the surface to an opening in No. 1 mine at the sump below 21 entry, provided it was found practical to operate a large-capacity, vertical, deep-well pump under the existing conditions. This would relieve the static bead of 200 ft. of water at the fault that separates Rock Springs mines Nos. 1 and 4, which is the

Jan 1, 1935

By D. Malhotra, R. M. Hoover

The effect of a surfactant, designated Syntex, on the wetting and spreading of hydrocarbon oil on molybdenite surfaces (faces) has been investigated experimentally through measurements of zeta potentials and factorially designed flotation tests. These studies indicate that Syntex has a positive effect in increasing molybdenite recovery in the rougher flotation circuit at the Climax mill. The analysis of experimental data using DLVO theory shows that the controlling factor in determining the magnitude of the repulsive energy barrier preventing oil from wetting and spreading on the molybdenite faces is the MoS2 zeta potential and the vapor oil droplet size. The role of Syntex in this case seems to be related to the decrease and stabilization of MoS2 zeta potential by Syntex adsorption and also to the emulsifying action of Syntex on vapor oil to provide a more favorable oil particle size.

Jan 1, 1976

The co-operation of the members of the Institute is earnestly sought by the Committee on Nominations, recently appointed by the Board of Directors, in its work of formulating a ticket for officers and places falling vacant in the Board of Directors in February, 1916. The Committee must present the official ticket of nominations to the Board of Directors at its October meeting. Members are, therefore, urged to send promptly their nominations for officers and Directors in order that the Committee may have an opportunity to give them full consideration. The officers to be elected at the annual meeting in February, 1916, are: One officer, known as Director and President. Two officers, known as Director and Vice-President. Five officers, known as Director. The officers of the Institute whose terms expire are as follows: President, William L. Saunders (not eligible for re-election). Past President, Charles F. Rand. Vice-Presidents, Thomas H. Leggett, District 0; Fred W. Denton, District 4.

Jan 9, 1915

The co-operation of the. members of the Institute is earnestly sought by the Committee on Nominations, recently appointed by the Board of Directors, in its work of formulating a ticket for officers and places falling vacant in the Board of Directors in February, 1916. The Committee must present the official ticket of nominations to the Board of Directors at its October meeting. Members are, therefore, urged to send promptly their nominations for officers and Directors in order that the Committee may have an opportunity to give, them full consideration. The officers to be elected at the annual meeting in February, 1916, are: One officer, known as Director and President: Two officers, known as Director and Vice-President. Five officers, known as Director. The officers of the Institute whose terms expire are as follows: President, William L. Saunders (not eligible for re-election). Past President, Charles F. Rand. Vice-Presidents, Thomas H. Leggett, District 0; Fred W. Denton, District 4.

Jan 10, 1915

By Reinhardt Thiessen

During the last few years a type of coal called "splint coal" has been brought to the attention of the United States Bureau of Mines, through numerous inquiries concerning its nature. Until recent years it appears to have escaped general notice. The term "splint coal" is of long standing, but was thought to be merely another expression applied by the miner to coal having certain minor characteristics. When closely examined, however, these coals were found to form a marked and distinct type, with distinctive characteristics that cannot be mistaken. Because splint coals produce a hot cheerful flame, possess a clean blocklike nature, and have a high volatile content, they have lately become much valued for domestic, gas-producer and steaming purposes, and have attracted considerable attention. Mattkohle For many years we have heard from the Germans about Mattkohle and Streifenkohle, in contradistinction to Glanzkohle, but have not realized that they were of a different type from the coals with which we were most familiar. This type of coal was first brought to general notice by Muck, in 1881, who gave a good description of it.' Because this coal is often intercalated with thin sheets of brightly shining cod, Schondorff, who was more familiar with the Saar coals, called it Streifernkohle. This term was later used by Muck also. Still later Potoné² used this term exclusively for the whole group in contradistinction to a class called Glanzkohle, and considered these coals to be composed alternately of Humuskohle and Faulkohle or Mattkohle (Pig. 20). Not knowing the nature of the German coals and not realizing that the term Streifenkohle was applied to a distinct class of coal, the terms of its components as used by Potonié and others were translated to "bright Coal" and "dull coal" and applied to the components of our

Jan 1, 1930

By Howard R. Keil

CARLTON mill in the Cripple Creek district, 45 miles southwest of Colorado Springs, Colo., has been in operation for approximately three years, treating the custom sulpho-telluride ores formerly handled by the Golden Cycle mill in Colorado Springs. At the new mill the pyrite-telluride flotation concentrates have been roasted, prior to cyanidation, in a Dorrco FluoSolids reactor, which has proved capable of yielding calcine readily amenable to cyanidation. Incoming ores are crushed at Carlton to 5/8 in. and sampled in 30 to 75-ton lots before the individual lots are mixed in the fine ore bin. The composite ore then goes to the grinding circuit. Classifier overflow from the grinding circuit is treated by flotation to produce a concentrate containing approximately 85 pct of the values in 5 pct of the weight. The flotation concentrate goes to the FluoSolids reactor prior to cyanidation. Cyanide solution values are recovered by zinc dust precipitation. Flotation tailings are thickened and cyanided, the values from this part of the circuit being recovered from solution by activated carbon.

Jan 12, 1954

By K. J. Richards, W. J. Schlitt

A combination of industrial and laboratory data is used to explain the interrelationships between operating parameters and cementation plant performance as measured by copper recovery and iron consumption. The chemical factors considered are the relative concentrations of copper and ferric ions in solution, acid concentration, the possible buffering action of other dissolved salts and solution temperature. The effects of flow conditions, solution oxidation, the presence of metallic copper and retention time are also considered. Based on the various relationships developed, possibilities for plant optimization are discussed.

Jan 1, 1974

By Adrian C. Dorenfeld, John T. Oleksy

Fuel problems of two lesser developed countries (LDC 's) are presented. In particular, the paper reviews cement technology and the fuel-intensive cement industries of the Philippines and South Korea. Based on current financial and cost data, analyses are presented of the proposed substitution of high-sulfur and slow-sulfur American coal in place of fuel oil. The analyses show that economic substitution of coal for oil is not only based on relative prices for coal and oil, as expected, but also to be an inverse function of degree of intensity of energy use, and a direct function of financial incentives such as accelerated depreciation, taxes on the savings made by the use of coal, and cost of capital.

Jan 4, 1979

By Frank Somogyi, Donald H. Gray

Techniques for in-situ dewatering of tailings and slimes include evaporation, decantation, drainage under self weight, drainage by surcharging, and electro-osmosis. A promising technique for increasing drainage efficiency is a vertical, wall-drain system, which can be constructed in an impoundment concurrently with deposition of slurried tailings. The vertical drains, which can be constructed from sand or from the coarse fraction of a tailings stream, greatly speed the rate of consolidation of the fine tailings or slimes. The performance of a wall drain system and the semitidy of consolidation efficiency to certain variables or system parameters are examined. These parameters include the slime deposition rate, ratio of drain to slime permeability, drain width, and drain spacing.

Jan 1, 1979

Rep. William S. Hill (R.- Colo.) will preside over a Congressional hearing investigating the problems of the mining industry to be conducted in Phoenix, Ariz., late in April. Rep. Hill has expressed the desire to hear from the industry itself all possible testimony on the needs of domestic mining and how Congress can help. Rep. John J. Rhodes of Arizona is also expected to attend the hearing. Two new features are incorporated into an SO2 process for treatment of low grade manganese ores disclosed by Chemical Construction Corp. The new approach includes a high temperature autoclaving step and a sintering operation. Data was given for work performed on Cuyuna Range ores.

Jan 4, 1953

By R. A. Wyman

KYANITE schists in the Sudbury area have been generally described by Haw,1 who has also given particular information on preliminary treatment of three large samples from Dryden township, Ontario.2 Kyanite, garnet, biotite, quartz, and feldspar comprise the main ingredients of this ore. Kyanite is the valuable mineral. About 5 ½ tons of -35 +200 mesh product, made by dry rod milling, screening, and separation on the Exolon magnetic separator, were available for treatment by flotation. Magnetic separation had effectively reduced garnet and biotite so that flotation feed consisted essentially of kyanite, quartz, and feldspar, the kyanite content averaging 32 pct and representing about 86 pct of the kyanite in the original ore.

Jan 1, 1958

By A. K. Chakravarti, A. Lihiri, G. G. Sarkar

One primary objective of India's third Five Year Plan is the expansion of coal production. The goal: boost present output of 45 million tons to 95 million tons by 1965--an increase of more than 100 pct!

Jan 7, 1961

By S. Tandanand, Powell. L. R.

The US Bureau of Mines assessed the geological effects on the ratio of maximum subsidence and extraction thickness, known as the subsidence factor, to develop a simple method for predicting the maximum subsidence. The study is restricted to the Northern Appalachian Coal Basin where data were collected from 13 coal mines. A model previously developed to relate the subsidence factor with the lithology and with the width and depth of working panels was used in the assessment. The result shows the possibility of determining maximum subsidence without resorting to a rigorous method.

Jan 1, 1985