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By M. C. Fuerstenau, W. F. Cummins

The flotation response of quartz in the presence of calcium chloride and various fatty acids is presented. Flotation is not effected with lauric acid until calcium laurate is precipitated in solution, while flotation is obtained with the 9, 10, and 11-carbon members before precipitation of the calcium carboxylate. The active species responsible for flotation is suggested to be a basic aqueous complex, e.g. Ca(OH) (RCOO) (aq), and a possible mechanism of adsorption is given. Most of the previous work on activation in non-metallic flotation systems has involved the use of high molecular weight collectors, such as oleic acid or alkyl aryl Sulfonate.1-7 In these studies the levels of addition of collector and activator required for flotation were much above the concentrations necessary for precipitation of the metal-collector salt. In fact, Clemmer, Clemmons, Rampacek, Williams, and Stacy1 have stated, "Our experiments on a variety of materials have demonstrated that the metal salts which react with anionic collecting agents, as soaps and alkyl sulfates, to form relatively insoluble compounds may be employed as activating agents provided an optimum quantity is used at a proper pH." On the other hand, Gaudin and chang8 obtained flotation with additions of barium and lauric acid below the level required for barium lautate precipitation.

Jan 1, 1968

By C. E. Julihn

Technology concerns the ways of doing things; mineral technology the ways of performing operations required for obtaining minerals from the earth and extracting their valuable constituents for man's use. At any particular time, technology is relatively fixed, as everyone tries to adopt the way of doing things that has proved most profitable; but improvements evolve from minor changes here and there, and occasion- ally entirely new methods are discovered. Technologic improvement thus characterizes any long-time view of the mineral industries. Its test lies always in reduction of costs; there is no other incentive for the adoption of new methods. Reduction in cost of producing metal from ore decreases, in turn, the amount of metal that must be obtained from ore in order to pay for its production. An advancing technology thus is characterized by utilization of ores of lower and lower grade. A very important result of this is an increase in the gross quantity of metal obtainable at any price level, since the earth's crust contains vast amounts of very low-grade ores and relatively insignificant amounts of very high-grade ores. Technologic advances have, therefore, been the means of rendering the metals both cheap and abundant. Though concern as to possible exhaustion of the world's ore deposits is warranted, it is conceivable that a transcendent technology of the future might supply metal requirements from what we

Jan 1, 1932

By Caner Zanbak, Erdogan Yüzer, Mahir Vardar, Kemal A. Erguvanli

The Hasancelebi iron deposit in Eastern Turkey is a very low grade (average 20% oxide) magnetite body consisting of 720 million longtons of proven reserve at a 10% cut-off limit. The ore-bearing scapolitic oclcs cover an area of approximately 4300m x 300m, and the thickness of the outcropping deposit exceeds 300m. Prefeasibility project studies revealed that a one degree decrease in a 45° final slope angle of the proposed pit would require excavation of approximately 10 million cubic meters of excess waste material, for a projected pit bottom 300 meters below the valley floor. There- fore, determination of the final slope angles of the open pit was considered to be the most important task in the feasibility analysis of this project. In this investigation, the main emphasis was given to collection, compilation and evaluation of the engineering geological, hydrogeological and rock mechanics data of the highly fractured and weathered rocks. Due to the presence of intense fracturing, the rock wedge analysis method was used for projected 30m-high benches and the circular failure analysis method was used for the stability of the projected final pit slopes. The proposed bench slope angles ranged between 60° and 80°, whereas the projected final slope angles varied between 30° and 48°, depending on the slope heights and groundwater levels.

Jan 1, 1983

By J. D. Miller, A. Cortez, J. Hupka

The separation efficiency of the hot water digestion-flotation technique used for bitumen recovery from various domestic tar sands was evaluated. Bitumen viscosity was found to be the most important tar sand property in determining the success of the bitumen separation. Bitumen viscosity of the tar sand war controlled by changes in digestion temperature and/or changes in diluent (kerosene) addition. Complete and uniform dilution of the bitumen phase was achieved by providing a sufficient presoaking, or penetration time, for a given tar sand type. For all the tar sand samples tested, an excellent correlation was obtained between the coefficient of separation and the bitumen viscosity. To achieve a satisfactory coefficient of separation, it was found that the bitumen viscosity must be reduced below 1.5 Pa.s (16 P) at the temperature of digestion. This was the case regardless of the tar sand type, grade, or origin.

Jan 1, 1984

By H. Martyn Chance

I have been induced to present this paper to the Institute because I have been unable to find any publication containing a disctission of this subject. In some of our technical schools and colleges the student is required to construct or copy (generally the latter) a number of profile sections as part of his routine work; but little attention is given to the methods of projecting observed dips and exposures upon the section line, and still less to the method of constructing the under (or above) ground curves. As a result of this lack of instruction every engineer or geologist is compelled to invent for himself a system, or copy the style of others. Geological profile sections have frequently been used to determine underground structure from data obtained at the surface, but the experience of engineers in the anthracite coal-fields has shown that they are to be relied upon only in exceptional instances. The possibility of indicating underground curvatures from dipangles observed at the surface has been found to be limited to a mere approximation of the larger flexures, As a means of predicting the depth and shape of minor rolls, they have been found most unsatisfactory. In the anthracite coal-fields the hypothecated

Jan 1, 1881

By N. R. Tipman, G. E. Agar, L. Paré

The flotation chemistry of the commercial INCO matte separation process was investigated. The slow cooling of Bessemer converter matte forms discrete phases of Cu2S and Ni3S2 and a Cu-Ni alloy. After magnetically removing the alloy, the Cu2S and Ni3S2 are separated by flotation at pH 12.4 (saturated lime) using diphenyl guanidine (DPG) as both collector and frother. DPG has been used exclusively in this flotation process because of its unusual selectivity for copper minerals. The surface product resulting from chemisorption of DPG onto theCu2S was identified as the double salt CU(DPG)2SO4.CU(DPG)2(OH)2. The adsorption followed Langmuir behaviour up to a monolayer coverage. In the absence of DPG, the rapid adsorption of oxygen by Cu2S in flotation pulps was observed. The surface product was identified as the insoluble basic copper sulfate CuS04.3Cu(0H)2 with the production of sulfate ion. In the presence of DPG, the oxidation reaction appears to be suppressed. The frothing properties of DPG and commercial frothers were compared. DPG is not a powerful frother. Batch flotation tests confirmed that DPG is a highly selective collector when compared to most sulfhydryl collectors.

Jan 1, 1976

By Frank E. Briber

In the years ahead, the industrial minerals producer will face several major challenges. Not only will he have to market increasing quantities of his product economically, but he will have to do so from lower grade deposits that are farther away from the marketplace. At the same time, he will have to comply with more regulations controlling the handling and disposal of waste products and get along with relatively less available labor than he has at present. Accordingly, industrial minerals developments of the next 30 years will be directed primarily toward helping the producer meet these challenges. There will be greater raw materials usage, new processes, new marketing practices affecting plant location, size and complexity, and maximum automation-all aimed at producing more materials at lower cost. Processes To Make the Most of Materials In future processes for industrial minerals, there will be great emphasis on more or total use of the initial raw materials or plant feed stock. This approach will result in the application of more and more concentration methods to the treatment of industrial minerals-both conventional processes and new ones that might be developed in conjunction with pyro-processing. High-intensity and electrostatic separation are certainly two areas which will see greater use in the field.

Jan 6, 1969

By Alfred Heggem

IT is the purpose of this article to describe methods recently introduced into the oil and natural gas industry to safeguard the lives of the workmen and to protect property from destruction. Only such drilling methods are described as pertain directly to the operations necessary to maintain the well under complete control at all times. Wells Formerly Drilled Without Controlling Equipment It may seem incredible that practically all wells, until recently, were drilled without the provision of any means for control. To drill a hole into a boiler carrying high-pressure steam without first providing means to control the escape of steam would be unthinkable, yet in oil fields wells are drilled into a gas or oil formation with a possible pressure of 300 to 1,800 lb. per square inch and a daily flow of 20,000,000 to 80,000,000 cu. ft. of gas or 1,000 to 15,000 bbl. of oil per day. Some wells have produced in excess of 100,000 bbl. of oil per day, but these are exceptional cases. In addition to the loss of product, one must consider the great danger attendant upon the promiscuous liberation of such an amount of explosive and inflammable substance.

Jan 1, 1916

By P. A. Tucker, T. B. Rhinehammer, D. E. Etter, J. E. Selle

The Ce-Cu phase diagram was investigated by differential thermal analysis and rnetallography. Two congruent melting compounds, CeCu2 (817°C) and CeCua (938°C), and three incongruent cornpounds, CeCu (516°C), CeCu, (796°C), and CeCu, CERIUM and copper have been suggested as possible diluents in a liquid-plutonium fueled reactor. As part of the determination of the Ce-Cu-Pu ternary phase diagram, a review Of the Ce-Cu system (798°C), are present in this system. Eutectics exist at 28 at. pct Cu (424°C), 74 at. pct Cu (756°C), and 91 at. pct Cu (876°C). The purity of the cerium used has an important effect on the results obtained by differential thermal analysis. was considered necessary. Previous work by Hanaman was conducted with relatively impure metal: 96.7 pct Ce with 2.5 pct other rare earths and 0.5 pct Fe as major impurities. The metal had a melting point of 715°C as compared to the melting point for pure cerium of 804°C as reported by Spedding and Daane.2 Results presented in this work were obtained primarily by differential thermal analysis (DTA) and metallographic examination of slow-cooled or quenched samples.

Jan 1, 1964

By Pierre de P. Ricketts

Having had occasion while in Europe during the past summer to visit some of the foreign mints and assay offices connected with the same, I thought a brief description of the general process of coining employed, and such items connected with assaying as were new, might prove interesting to the Institute. The principal foreign mints are: the Royal Mint, London; and the mints in Paris, Brussels, Utrecht, Berlin, Vienna, Copenhagen, St. Petersburg, Stockholm, Madrid, Milan, Rome, and Constantinople. My time only permitted my visiting a few of the principal and largest given in the list, and for a description of the remainder I am indebted to the kindness of Mr. James M. Napier, who in company with the deputy master, and chemist of the Royal Mint, made a complete inspection of all the European Mints in 1870.

By Joseph R. Crump, Francois Ville, Frank M. Tiller

Several simplifications have been accepted in filtration theory during the past fifty years in an effort to avoid apparently intractable mathematical problems. In effect, these simplifications ignored the variation in average cake porosity and average filtration resistance with variation in pressure drop or with time. This study examines the traditional approach and shows that, in many cases, it cannot give correct design guidance. Using a set of dimensionless parameters because of the large number of significant variables, a revised theory is developed which does not require that porosity and resistance values be set constant. Graphs developed in the traditional approach (e.g., dt/dv versus v or t/v versus V) have substantial curvature near the ordinate; but this curvature is frequently ignored in theory and is easily missed in experiments. The revised theory allows more accurate design calculations, especially for compressible cakes.

Jan 1, 1980

By I. Havenaar

Various methods have been proposed in the literature to calculate the pressure losses in drill-pipe and bit-nozzles, i.e., those parts of the mud-circuit where the largest pressure-losses occur. Very few data, however, are available to check the validity of these proposals. Presented in this paper are the results of pumping experiments with clay-water drilling fluids of different specific gravities and different laminar flow-properties (differential viscosity and Bingham yield value), using pipes of different diameters. In addition, a series of measurements on bit-nozzles is discussed. Two main conclusions may be drawn from this work for the flow through pipes. 1. In the laminar flow region pressure losses can be calculated from the differential viscosity and Bingham yield value of the mud. 2. In the turbulent flow region pressure losses can be calculated with good approximation from a viscosity term which is determined by the volume fraction of the dispersed phase. Calculations making use of laminar flow properties may lead to erroneous results. The effect of temperature on the pressure losses in the case of turbulent flow can be calculated from the change in viscosity of the dispersing medium, i.e., water. The main conclusions determined for the flow through bit-nozzles are that for flow conditions prevailing in the field, the pressure-drops in bit-nozzles are independent of the laminar flow properties of the mud. They are solely determined by the density of the mud and the geometry of the nozzle. INTRODUCTION The last decades have witnessed a steady increase in the depth of oil wells. This is illustrated by the increase in the drilling depth record in the USA from 8,046 ft in 1927 to 21,482 ft in 1953. This increasing depth, together with the experience that high rates of mud circulation and high fluid velocities in the bit-nozzles enhance the rate of drilling, has emphasized the importance of selecting suitable mud-pumps when starting the drilling of a deep borehole. For such a selection it is necessary to be able to calculate the pumping pressures necessary to obtain the required circulation rates. The main part of the pressure-losses in the mud circuit occur in the drill pipe and the bit-nozzles. Various methods have been proposed in the literature to calculate the pressure-losses in the drill pipe1,2,3,4. These methods do not all lead to the same results, and at the time this investigation was started insufficient basic data were available to check their validity. Moreover, to our knowledge, no data are available at all on the effect, if any, of the flow-properties of the mud on the pressure-losses in bit-nozzles.

Jan 1, 1955

By F. L. Fayers, J. W. Sheldon

It has been a matter of concern to the petroleum industry to determine what effect the capillary term has on saturation profiles, since these profiles determine ultimate economic oil recovery. In their original solution of the non-capillary two-phase flow problem, Buckley and Leverett&apos; showed that solutions of the two-phase flow equations became multiple-valued in saturation. Since it is physically unrealistic for saturation to have more than one value at a given position, Buckley and Leverett resolved this difficulty by introducing a saturation discontinuity or "shock". They evaluated the strength and position of the shock from material balance considerations. Recently Sheldon, Zondek and Cardwell&apos; have demonstrated that the method of characteristics can be used to solve this and related problems. Owing to capillarity it is physically unlikely that saturation shocks occur in an oil reservoir. Buckley and Leverett suggested that the effects of interfacial tensions should be included in the fluid flow equations, if the solutions are to give continuous single-valued saturation distributions. An analogy to this problem is encountered in the theory of wpersonic compressible flow where the introduction of the viscous term eliminates shock behavior. However, the mathematical form of the capillary term in the porous medium fluid flow equations differs from the viscosity term in the Navier-Stokes equation. This paper demons~rates that capillarity does eliminate the triple-valued behavior and indicates the magnitude of capillary and gravity effects on the saturation profile for a variety of systems. DERIVATION OF LAGRANGIAN AND EULERIAN FORMS OF THE DISPLACEMENT EQUATION The equations representing capillary, two-phase flow are given by applying Darcy&apos;s law and a material balance condition for each phase. The familiar Darcy and material balance equations are as follows. ^U*^0......<3, ^^r=°......c« S is the saturation of the water phase, and B the inclination of the porous medium. Pressures in the oil and water phases differ by the capillary pressure associated with the interfacial tensions, P.-P.=pAS)..........(5) where p, is determined experimentally. The porous medium is said to be oil-wet if P, > Po and water-wet if P, < Po. If the fluids are incompressible and the total volumetric flow rate, q, is constant, then v, f v,, = q...........(6) By eliminating P.. /»,, and v, from Eqs. 1, 2, 5 and 6 it follows that It is convenient to normalize the variables in the problem after the manner of Handy and Hadley% so that Eqs. 3 and 7 become where j,, = —, the fractional flow of water; (F, is a capillary pressure normalizing constant.) Substitution of Eq. 9 into Eq. 8 gives In this partial differential equation for an initial value

By J. E. Burke, Y. G. Shiau

SEVERAL attempts have been made to account for the fact that grains in a fully recrystallized metal will coarsen on annealing Two fundamentally different hypotheses have been advanced; with several variations of each. One school considers that the cause of grain growth is the surface energy of the grain boundary The theory of Jeffries1 that grain size and grain size contrast control growth is an example The second school considers the primary cause to be a difference in the lattice energy on either side of the grain boundary The more perfect grains are considered to grow at the expense of their less perfect neighbors, with a decrease in free energy, and a consequent increase in the stability of the system. Burgers2 presents the case for the strain or lattice imperfection theory of grain growth quite completely The latter theory is attractive, since there is no doubt that differences in lattice energy or lattice perfection can cause grain boundary migration A recrystallization nucleus grows for this reason as was beautifully demonstrated by van Arkel and Ploos van Amstel3 Although it is generally stated that grain growth does not precede recrystallization, several workers4,5 have shown that small strains may induce a single crystal in an aggregate to grow, or at least may cause some&apos; grain boundary migration The origin and nature of the imperfections that are considered to be responsible for normal grain growth have never been clearly described, but it is generally agreed that they are a consequence of the difficulty of atomic reorientation in the solid state, and that they do not seriously differ from the type of imperfection that-can be introduced by mechanical deformation An object of the present work was to determine whether the introduction of mechanical deformation would cause grain growth in a specimen which would not otherwise show it under the conditions used It was also planned to determine the effect of such deformation the rate of growth in a specimen which would show - growth in the unstrained condition Recently Maddigan and Blank6 have indicated that slightly strained specimens of alpha brass can undergo considerable growth prior to recrystallization if annealed at low temperatures French7 has reported that at deformations less than 17 pct it is very difficult to detect the beginning of recrystallization in the same material. It was therefore planned to broaden this work to include a complete study of the microscopic behavior of alpha brass under conditions of temperature, time, grain size and deformation such that recrystallization would not occur or would occur to only a small extent EXPERIMENTAL PROCEDURE The brass was prepared by melting cathode copper and commercially pure zinc

Jan 1, 1947

By W. B. Watson

IN the USSR considerable technical improvements have been made in hydraulic methods of mining coal. In New Zealand coal mining by these methods is still comparatively crude. The Russian techniques are closely studied in New Zealand, and this description is based mainly on translations of technical articles. Fundamentally the methods in both countries are the same-chief developments in the USSR are the use of high pressure water jets, capable of winning all but the hardest coal without prior blasting, and hydraulic pipeline transportation where the gradient is unsuitable for flume transport.

Jan 4, 1958

By C. M. Romanowitz, H. A. Sawin

PLACER dredging as we know it today, especially gold dredging, is an industry about 40 years old, dating from the beginning of this century, when a few mining men in California saw the possibilities in adapting earlier dredging methods to California placer fields in and immediately adjacent to streams. At first it was thought that dredges must be operated in existing stream beds, but experience soon pointed the way to dredging alluvial deposits of old stream beds, operating on landlocked dredging ponds. Within the first five or six years of modern dredging, experience was gained so rapidly that dredges to dig 60 ft. below water level were designed and built. This depth was believed by many operators to be the maximum at which successful dredging could be carried on. Alluvial deposits of gold, suitable for dredging, were readily handled by equipment available and developed early in the industry&apos;s history. Much of the gravel was easily dug and if deposits were cemented, contained large boulders, or for some other reason could not be handled by a dredge, the ground was abandoned in favor of other deposits that could be handled easily. Many failures, adversely affecting the dredging industry, resulted from attempts at that time to extend the scope of placer dredging with equipment not suited to the formation being dredged. Dredging ground suited to early equipment was exhausted eventually, but many supposedly undredgeable alluvial fields containing gold in commercial quantities were found and became known to dredgemen. Improved equipment was needed to work deposits known to exist at great depths or associated with unusual obstructions. Operating companies looked to dredge manufacturers and metallurgists, particularly manganese-steel foundries, for improved designs and materials. Experience developed in California has spread throughout the world, and dredges of improved types have been adapted to the mining of platinum and tin as well as gold. Space will not permit a description of all the improvements in dredging since the early days, but a few of the recent developments are worthy of note, because they make possible the dredging of placer deposits of great depth, those having hard, irregular bedrock or containing large boulders in great quantities, and compacted or cemented gravel deposits. DEEP DREDGING At Hammonton, Calif., Yuba Consolidated Gold Fields has, within the past two years, built its dredge No. 20. The company has operated continuously in that field since 1904, digging successively at maximum depths of 60 ft., 8o ft., 112 ft., and now 124 ft. below water level. The first dredges were equipped with buckets of 6 and 7 ½ -cu- ft. capacity; six dredges operating in the field today have 18-cu. ft. buckets, digging now 65 to 124 ft. below water level. Some ground near Hammonton has been dug for the third time, owing to the devel-

Jan 1, 1941

By L. W. Casteel

This is a story of progress through research, invention and innovation-progress that made a small mine in Missouri into a large and prosperous corporation. The St. Joseph Lead Co. was founded in Borne Terre, Missouri, in 1864. At that time, the mine consisted of a narrow trench eight feet deep; the mill was a hand-operated jig; and the smelter, a charcoal oven with a sloping hearth. During the first year, production was suspended for two months because of an invasion by the Confederate army. There have been few interruptions since that time.

Jan 7, 1964

By Steven T. Mitchell

The introduction of Vertical Crater Retreat (VCR) Stoping at the Homestake Mine in Lead, SD, constitutes a major advance in Homestake Mining Company&apos;s efforts to improve productivity and reduce costs through under- ground mine mechanization. The work to date indicates that Vertical Crater Retreat Stoping is one of the safest methods of underground hardrock mining today, and is competitive with all other forms of stoping in terms of cost and productivity. Homestake anticipates that VCR stoping will account for approximately 35% of the total mine production in 1981.

Jan 1, 1981

By Baxter C. Madden

Stress corrosion is defined and certain examples are illustrated. A number of test methods, to determine the resistance of materials to stress corrosion, are being developed at Wright Field. The criterion as to the validity of a method is stated. Three types of specimens and the method of stressing each type are described. Five different corrosive conditions are set forth. The results of tests to date, although too few for any general conclusions to be arrived at, are presented. The program for the continuation of the investigation is indicated. A bibliography is included. The development of the method of loading a cantilever-type specimen, so that a nearly constant stress at a large deflection may be realized, is presented as Appendix I.

Jan 1, 1945

By Alfred G. Heggem

It is the purpose of this article to describe methods recently introduced into the oil and natural gas industry to safeguard the lives of the workmen and to protect property from destruction. Only such drilling methods are described as pertain directly to the operations necessary to maintain the well under complete control at all times. Wells Formerly Drilled Without Controlling Equipment It may seem incredible that practically all wells, until rkcently, were drilled without the provision of any means for control. To drill a hole into a boiler carrying high-pressure steam without first providing means to control the escape of steam would be unthinkable, yet in oil fields wells are drilled into a gas or oil formation with a possible pressure of 300 to 1,800 lb. per square inch and a daily flow of 20,000,000 to 80,000,000 cu. ft. of gas or 1,000 to 15,000 bbl. of oil per day. Some wells have produced in excess of 100,000 bbl. of oil per day, but these are exceptional cases. In addition to the loss of product, one must consider the great danger attendant upon the promiscuous liberation of such an amount of explosive and inflammable substance. Introduction of Metal Casing for Deep Drilling The introduction of metal casing to secure a permanent and impervious wall in a well made the drilling of deep wells possible and removed many of the original problems encountered in well drilling, but it did not insure the control of the well. To obtain the full value of the casing it was essential that a pressure-tight joint be made between the wall of the well and the lower end of the casing. Many materials in various forms were used, including cotton, hemp, stable refuse, oats, rice, cloth, leather, cork, rubber, lead, clay and cement, resulting, after a slow process of evolution, in the general adoption of two types of bottom fittings for

Jan 1, 1916