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Henry D. Hibbard, Plainfield, N J. (communication to the Secretary*):—This very interesting history is a valuable addition to our knowledge of the basic process and its introduction to this country. In addition to the attempts noted in the paper which were made here to establish the basic Bessemer process, and the experiment with the Siemens-Martin process at the Otis works, there were others made with the latter-named process at about the same date, all of which failed or, at least, were discontinued. The first attempt which survived was that of Carnegie,

Jan 1, 1911

By N. S. Kenny, A. A. Burr

THE purpose of this note is to present evidence that vacancies, which have been produced by quenching from a high temperature, alter the rate of strain-hardening of an hep single crystal. The majority of investigations of the effects of quenched-in vacancies on the yield stress of metals have been made using fee samples in the form of thin wires. However, there is an inherent disadvantage in using such wires to study the effects of vacancies on the rate of strain-hardening of metals because fee wires begin stage II slip either immediately upon yielding or very shortly thereafter. When stage II slip occurs, very rapid strain hardening also occurs, masking the effects of vacancies on the rate of hardening. In this investigation single crystals of magnesium hep were studied since magnesium has only one slip plane at low temperatures and has, therefore, an extensive easy glide region. In addition, the effect of both static and dynamic recovery on the rate of hardening were eliminated by testing in liquid nitrogen. Both forms of recovery occur in hep metals by dislocation climb, which is a diffusion controlled mechanism and is negligible at liquid nitrogen temperatures. Finally, the dependence of the strain-hardening rate on the crystal orientation was eliminated by using the equations of Schmid and Boas.' Variations in the strain-hardening rate could, therefore, be attributed to the presence of vacancies. Single crystals in the form of rods approximately 5 mm in diam and 6 cm long were grown by a modified Bridgman technique from commercial high-purity magnesium (99.97 pet) supplied by the Dow Chemical

Jan 1, 1962

By B. M. O Harra, George M. Fowler, R.E. Illidge

The Tri-State district comprises an area of about 2000 square miles in southwestern Missouri, southeastern Kansas, and north- eastern Oklahoma. The part that is in and contiguous to Missouri is still sometimes designated as the Joplin district (Fig. I). Early Operations Mining operations in what is now the Tri-State district date from about 1848 and have been continuous to the present. Apparently the first discoveries of ore were made about the same time near the present sites of Joplin, Oronogo, and Granby. Lead minerals were found at grass roots, probably in shattered rock in shallow excavations, then these minerals were followed in shear zones to deeper horizons. The mining of zinc followed. Before 1874, zinc ore was worthless and discarded as waste. According to published records, the total production of lead to that date was 49,000 tons of metal from 70,000 tons of concentrates. Production The a.ggregate ore production from the Tri-State district was recorded at intervals

Jan 1, 1943

By George M. Fowler, B. M. O Harra, R. E. Illidge

The Tri-State district comprises an area of about 2000 square miles in southwestern Missouri, southeastern Kansas, and north- eastern Oklahoma. The part that is in and contiguous to Missouri is still sometimes designated as the Joplin district (Fig. I). Early Operations Mining operations in what is now the Tri-State district date from about 1848 and have been continuous to the present. Apparently the first discoveries of ore were made about the same time near the present sites of Joplin, Oronogo, and Granby. Lead minerals were found at grass roots, probably in shattered rock in shallow excavations, then these minerals were followed in shear zones to deeper horizons. The mining of zinc followed. Before 1874, zinc ore was worthless and discarded as waste. According to published records, the total production of lead to that date was 49,000 tons of metal from 70,000 tons of concentrates. Production The a.ggregate ore production from the Tri-State district was recorded at intervals

Jan 1, 1943

FRANK N. SPELLER,? Pittsburgh,. Pa.-Mr. -Hayward's paper again draws attention to the fact that copper in steel is not the enemy that a good many of us it one time thought it was. He shows clearly that steel with over 0.75 per cent. of copper is as dependable, under the :conditions which he describes, as the same steel without copper. I might add that you-can weld copper-steel- satisfactorily up to that point; in fact, we have succeeded in welding pipe by the lap weld process up to 1 per cent. copper. Notwithstanding the date that have been presented on the effects of copper on the physical properties and corrosion of steel, a maximum copper limitation is still found in many specifications. In some cases the limit is extremely low, such as below 0.05 .or 0.03: per cent., or thereabout. That is a relic of days gone by, and I think the practice should be discouraged. E. F. CONE, New York; N. Y.-Not so many years ago steel-casting makers were very particular as to the amount of copper that existed in the pig iron that they used. They would not use copper-bearing pig iron unless mixed with non-copper iron. I do not know what the practice now is in the particular foundry where I was metallurgist at one time,

Jan 4, 1918

EDWARD B. GRUBB, Burlington, N. J.: In connection with the discussion relative to the effect of vibration upon the molecular structure of wrought-iron, I would like to call your attention to the following extracts from a work by William

Jan 1, 1897

By R. N. Stevens

Any consideration of the errors involved in determination of ?gb by previous workers should discuss their experimental methods in terms of the appropriate theoretical equation; this the authors have not done in a number of cases. To facilitate the present

Jan 1, 1969

By Paul H. Lu

Methods and results of measuring three basic parameters for ground stability control, ground pressure, strata movement, and geomechanical properties of mine rock are presented in this paper. It is found that these parameters can be measured in situ by simple and practical techniques with nonsophisticated and inexpensive instruments. Specifically, a drillhole dilation technique employing a cylindrical hydraulic borehole pressure cell (CPC) was used to determine the modulus of rigidity. Premining ground pressures were determined by pressure convergence tests with a combination of one CPC and two pre-encapsulated flat hydraulic borehole pressure cells (BPC) installed in a single drillhole. Abutment pressures and pillar loading were monitored with BPC's. Differential strata movements and bed separations were measured with self-recording 10-anchor-point extensometers. Roof-to-floor convergence was measured with self-recording convergence meters. Some applications of these in-situ-determined parameters to mine design and ground stability control are also discussed.

Jan 1, 1984

By J. D. Lubahn

Prior tests by Dorn, where the strain rate in a tensile test was suddenly changed, have shown a small, but definite rate-history effect to exist. If this effect is neglected in the calculation of creep behavior from tensile results, an error should occur. This paper shows that this error is smaller than experimental scattering, and may be neglected. DORN1 has found a small but definite rate-history effect in the aluminum alloy 250 at liquid-nitrogen temperature using tensile tests with an abrupt rate change. Such an effect is to be expected from pre-viously known2-6 temperature-history effects, together with general experience that effects produced by changing the strain rate a large amount are simi-

Jan 1, 1959

By J. L. Lytton, T. E. Tietz

UNALLOYED arc-cast molybdenum sheet is typically supplied in the cold-rolled and stress-relieved condition, hereinafter denoted CRSR. Such processing eliminates the yield-point phe-

Jan 1, 1964

By John H. Hollomon

In a recent paper,' a very early suggestion by Ludwik2 concerning the nature of the mechanical behavior of metals has becn reexamined and extended. In essence it was suggested that there exists, at least under certain conditions, a mechanical equation of state; that the stress required for flow depends upon the instantaneous values of the strain, strain rate, and temperature, and not upon their past values. It is proposed that under these circumstances thc stress does not depend upon past history of these variables, but is like the temperature of a gas that depends only upon the instantaneous values of the pressure and volume. This notion has not been applied to present-day studies of metals, though it is especially applicable to the study of creep. It is the purpose of this paper to analyze the significance and possible range of applicability of this idea and to determine how it influences the accepted ideas concerning creep. Stress-strain Relations It is wcll known that the stress-strain curves of metals are influenced by both train rate and temperature. For a fixed strain rate and temperature there is associated with each metal a stress-strain curve. If either the strain rate or temperature is changed a new stress-strain curve will be characteristic (Fig. I). A much more genera1 relation between the effects of these variables is possible, however. Consider the stress-strain curves of Fig. I determined at

Jan 1, 1947

By John H. Hollomon

In a recent paper,' a very early suggestion by Ludwik2 concerning the nature of the mechanical behavior of metals has becn reexamined and extended. In essence it was suggested that there exists, at least under certain conditions, a mechanical equation of state; that the stress required for flow depends upon the instantaneous values of the strain, strain rate, and temperature, and not upon their past values. It is proposed that under these circumstances thc stress does not depend upon past history of these variables, but is like the temperature of a gas that depends only upon the instantaneous values of the pressure and volume. This notion has not been applied to present-day studies of metals, though it is especially applicable to the study of creep. It is the purpose of this paper to analyze the significance and possible range of applicability of this idea and to determine how it influences the accepted ideas concerning creep. Stress-strain Relations It is wcll known that the stress-strain curves of metals are influenced by both train rate and temperature. For a fixed strain rate and temperature there is associated with each metal a stress-strain curve. If either the strain rate or temperature is changed a new stress-strain curve will be characteristic (Fig. I). A much more genera1 relation between the effects of these variables is possible, however. Consider the stress-strain curves of Fig. I determined at

Jan 1, 1947

By Edna A. Dancy

Jan 1, 1965

By L. C. Uren, J. Domerco

That the diameter of a well through the oil-producing formation has an important influence on its rate of production is a principle accepted by many petroleum technologists. Knowledge of this principle extends back at least to the time when Slichter and King1 confirmed it in a study of the dynamics of flow of water through porous strata into wells. More recently, the senior author2 and his associates3 have produced qualitative experimental data confirming the principle as applied to drainage of expanding oil and gas mixtures, and suggesting that wells of large diameter, or wells having cavities about them within the reservoir rock, enjoy a material advantage in competition with wells of ordinary diameter. Apparently, however, no one has produced experimental data designed to indicate quantitatively the advantages that wells of large diameter possess in comparison with wells of normal diameter producing under comparable conditions. This paper reviews some preliminary experimental results of this kind, together with some conclusions and speculations based thereon, which further emphasize the importance of well diameter as a factor in determining the efficiency of oil recovery. Theoretical Aspects of Radial Flow of Fluids into Wells It is well understood that in a reservoir rock of uniform thickness and permeability oil and gas flow toward the wells along radial lines. The cross-section of the reservoir rock through which the fluids must move becomes ever smaller as the wall of the well is approached. The velocity of flow must therefore correspondingly increase, an effect that is accentuated by the rapid increase in volume of the fluid due to release

Jan 1, 1935

By Edward Saibel

The various theories that have been advanced to explain or predict the conditions under which a metal fractures may be divided into two categories: First, there are the macroscopic theories generally used in engineering practice. These are empirical in nature and limited in application. For example, the maximum normal stress criterion, which is quite satisfactory for a mild steel in simple tension at atmospheric pressure,' no longer suffices when this steel is pulled under hydrostatic pressure.2 In all of these empirical theories, the critical condition characteristic of the material and of the loading conditions must be obtained experimentally. Secondly, there are the theories based on interatomic forces,3'4 or on the energy required to form new surfaces.5,6 These have all dealt with the theoretical evaluation of the tensile stress necessary to bring about rupture in a purely brittle manner; that is, without plastic flow preceding fracture. All of these attempts have led to values of the tensile strength of crystals or of polycrystalline bodies that are 100 to 1000 times higher than observed values. On this account, it has been thought necessary by some investigators to conceive of a microcrack structure or distribution of flaws throughout the specimen such that the resulting stress concentrations provide the factor necessary to bring about agree- ment between calculation and experiment. It has been pointed out by several observers' that this point of view is highly unrealistic, in that the weakening effect of these flaws or microstructures must be very uniform from specimen to specimen, since the fracture stresses found for various specimens of the same material tested under similar conditions are so nearly constant. Furthermore, since calculations based on atomic forces or atomic energy are for purely brittle fracture, a condition probably never satisfied in tests, agreement is hardly to be expected. Thermodynamic Theory of Fürth In order to resolve this apparent discrepancy between the theoretical cohesive strengths and the observed fracture strengths, Fürth8 advanced a thermodynamic theory of the tensile strength of isotropic bodies based on work of Born relating to the melting of crystals. Assuming an isotropic material free from imperfections and flaws, behaving elastically up to the breaking point, and assuming a connection between rupture and the melting phenomenon, Fürth obtains an expression for the rupture stress a, in the form where Q is the melting energy per unit mass, p is the density, and is Poisson's ratio. Furth compares fracture stresses computed from Eq I with the fracture stresses of metals as given in the Landolt-Bernstein Tables (1927) and in the Hand-

Jan 1, 1947

By Edward Saibel

The various theories that have been advanced to explain or predict the conditions under which a metal fractures may be divided into two categories: First, there are the macroscopic theories generally used in engineering practice. These are empirical in nature and limited in application. For example, the maximum normal stress criterion, which is quite satisfactory for a mild steel in simple tension at atmospheric pressure,' no longer suffices when this steel is pulled under hydrostatic pressure.2 In all of these empirical theories, the critical condition characteristic of the material and of the loading conditions must be obtained experimentally. Secondly, there are the theories based on interatomic forces,3'4 or on the energy required to form new surfaces.5,6 These have all dealt with the theoretical evaluation of the tensile stress necessary to bring about rupture in a purely brittle manner; that is, without plastic flow preceding fracture. All of these attempts have led to values of the tensile strength of crystals or of polycrystalline bodies that are 100 to 1000 times higher than observed values. On this account, it has been thought necessary by some investigators to conceive of a microcrack structure or distribution of flaws throughout the specimen such that the resulting stress concentrations provide the factor necessary to bring about agree- ment between calculation and experiment. It has been pointed out by several observers' that this point of view is highly unrealistic, in that the weakening effect of these flaws or microstructures must be very uniform from specimen to specimen, since the fracture stresses found for various specimens of the same material tested under similar conditions are so nearly constant. Furthermore, since calculations based on atomic forces or atomic energy are for purely brittle fracture, a condition probably never satisfied in tests, agreement is hardly to be expected. Thermodynamic Theory of Fürth In order to resolve this apparent discrepancy between the theoretical cohesive strengths and the observed fracture strengths, Fürth8 advanced a thermodynamic theory of the tensile strength of isotropic bodies based on work of Born relating to the melting of crystals. Assuming an isotropic material free from imperfections and flaws, behaving elastically up to the breaking point, and assuming a connection between rupture and the melting phenomenon, Fürth obtains an expression for the rupture stress a, in the form where Q is the melting energy per unit mass, p is the density, and is Poisson's ratio. Furth compares fracture stresses computed from Eq I with the fracture stresses of metals as given in the Landolt-Bernstein Tables (1927) and in the Hand-

Jan 1, 1947

By J. C. Prof. Smock

(Read at the Philadelphia Meeting, February, 1878.) THE fire-clays of New Jersey belong in two geological ages, the cretaceous and quaternary, or post-tertiary. Three very small deposits of plastic clays have been discovered within the limits of the Archoean rocks. These are not refractory and of little importance, excepting in a geological consideration. They have resulted from a decomposition of the feldspars of the rock in situ, and they have been classified as inferior kaolins.

Jan 1, 1878

By L. C. Graton, Joseph Murdoch

I. Introduction......................... 26 1. The Relations of Scale in Geologic Work........ 26 2. General Characteristics of Copper Sulphide Ores..... 29 3. Scope of Present Study................. 31 11. Description of the Important Minerals............ 36 1. Pyrite....................... 36 2. Pyrrhotite....................... 41 3. Chalcopyrite...................... 41 4. Bornite........................ 40 5. Covellite....................... 50 6. Chalcocite....................... 52 7. Enargite...................... 59 8. Tetrahedrite and Tennantite.............. 61 III. Conclusions.......................... 62 I. Introduction. The Relations of Scale in Geologic Work. Many features of human accomplishment rest upon the possibility of representing natural objects on a scale of different magnitude from the actual one. Most drawings, for example, are of very different scale from that of the object depicted, and indeed are useful mainly 011 this account. More important than the question of mere convenience, however, is that of meeting the physical limitations of vision.' Thus, a mural

Jan 1, 1914

By D. N. Stevens, D. N. Bloom, M. A. Klugman

This paper represents a portion of a larger study concerning dispersion of major, minor and trace elements in wall-rock about orebodies in part of the Colorado Mineral Belt. This phase of the work pertains to the Mg/Ca ratio variations in wall-rock adjacent to orebodies in two mines, one in the Horseshoe Mining District (Hilltop mine), and the other in the Alma Mining District (Phillips mine). The two districts lie adjacent to one another, the Horseshoe District on the south and the Alma District on the north, and are commonly referred to as one, the Alma-Horseshoe Mining District. The Alma-Horseshoe Mining District is located 80 miles southwest of Denver, Colo., (Fig. 1) in Park County, on the eastern slope of the Mosquito range. The area is typified by rugged relief with altitudes of from 10,500 to 14,000 ft. The Horseshoe District is separated from the Lead-ville Mining District by the crest of the Mosquito range, with the Leadville District to the west. The Alma-Horseshoe District has been considered as peripherial to the Leadville District, and has not received the detailed attention that the Leadville District has. These two mines were selected for this study because of their ease of access; the attitude of the workings and the drill holes to the known mineralization; the similarity of the mineralization; and because the mineralization occurs in carbonates in both mines but are of different ages. In the Hilltop mine mineralization is confined to the Leadville dolomite (Mis-issippian) and is principally lead with subordinate zinc and silver. In the Phillips mine the mineralization occurs in the Peerless dolomite and shale (Cambrian) and in the Manitou dolomite (Ordovician) and is principally zinc with subordinate lead, silver,

Jan 1, 1964

By Walter Harvey Weed

The Republic of Mexico is traversed by many mountain ranges, and presents a great diversity of climates, soils and geographical features, yet its grander geographic provinces are few and peculiarly well defined. The Gulf plain, the Cen tral plateau, the Sierra Madre, and the lowland or Tierra Cali ente of the western coast are the main features of the geogra phy of the Republic, and in the northern half these provinces are particularly well defined. The Sierra Madre separates the Republic into eastern and western parts, and from the City of Mexico north to the Texas line presents an almost impassable barrier to east and west travel. On the north, the first wagon road pass from east to west is at El Paso del Norte, the site of the Texan city of El Paso. Southward for many hundreds of miles the Sierra Madre, traversed by well-worn trails, over which all travel from the west coast to the interior must pass, is a stupendous barrier to social and commercial intercourse. The Sierra Madre is commonly described as a range or con geries of mountain ranges. In fact, it is, in Chihuahua at least, a great plateau, fringed by mountains on the east, trenched by deep canons in its center, and bordered by a wild and rugged complex of mountains carved out of the plateau on the west. Professional duties took me across this region from Parral westward to the Gulf of California via Guadalupe y Calvo. As it includes some of the great ore-deposits of Mexico, and its geological features have never, so far as I am aware, been described, I have prepared a diagrammatic section made from my observations on a horseback trip across the Sierra, and added such notes as seem to be of general interest.

Jan 1, 1902