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Freeman, the English historian, said that he had learned from Macaulay "never to be afraid of using the same word or name over and over again if by that means anything could be added to clearness or force. Macaulay never goes. on, like some writers, talking about ' the former ' and 'the latter ', 'he ', 'she ', 'it), and 'they’, through clause after clause, while his reader has to look back to see which of several persons it is that is so darkly referred to". He might have learned also from Macaulay that a preposition makes a feeble ending for a serious statement. How often do you hear 'the former' and 'the latter' in conversation? Good conversation is a guide not to be disdained. When you must use 'the latter ', do not confuse it with 'the last '. Cheap labor, cheap fuel, and cheap transport are essential, the latter [last] being particularly important in base-metal mining. The apparatus may be used to determine such gases as hydrogen sulphide, chlorine, oxides of nitrogen and some others, as well as sulphur dioxide. In the case of the latter two, etc. The two last mentioned are "sulphur dioxide" and "some others". He should have stated which two, and he should have avoided that wretched phrase "in the case of ". Pinning may be partly prevented by use of chalk, oil, or turpentine. The latter [last] is beat. "Partly prevented" is a poor phrase. 'Prevented' is a word that does not lend itself readily to modification. He means ' checked ' or 'corrected '. These steps are necessary to produce the gas, crude oil, and ammonia, the latter [last] of which is in solution in the water obtained along with the oil.

Jan 1, 1931

By Kiyoshi Azuma, Hiroshi Kametani

Dissolution of a ferric oxide in acid solution is divided into two different types In the accelerated type dissolution proceeds in three stages 1) an inittal reaction during which the dissolved amount of oxide is nearly proportional to the cube root of time ; 2) an accelerated reaction: and 3) a final stage during which dissolution approaches completion. This course of dissolution gives an S-shaped curve in the above sequence OH a log weight percent of dissolved oxide against log time graph. In the parabolic type dissolution proceeds in four stages: first and second stages similar to those of the accelerated type; 3) parabolic-rate dissolution during which the dissolved amount of oxide is nearly proportional to the square root of time: and 4) a final stage. The effect of the kind of acid, the temperature of solution, and the concentration of acid was investigated. The results are discussed and a rate equation is proposed. AN attempt has been made to obtain some information on dissolution of a ferric oxide in various acid solutions. In view of hydrometallurgical processes the dissolution of ferric oxide is of less importance than that of zinc oxide or copper oxide in general. One of a few processes which intend to dissolve ferric oxide is an elimination of iron impurity from acid-insoluble materials. However, most leaching processes of oxide ores and cinders are accompanied with more or less dissolution of iron. According to Pryor and Evans1 the rate of dissolution of a ferric oxide in various acids decreased in the order of hydrofluoric acid > hydrochloric acid > sulfuric acid > perchloric acid. This order was in accord with the order of decrease of the complexing affinity of the anion for ferric ion,

Jan 1, 1964

By A. M. Gaudin

UNTIL recently little attention has been paid to the effect of particle size on flotation. This has been especially true of material finer than 200 mesh.1 Particles of different sizes must behave differently in a flotation circuit; increased information along this line would be of practical use as well as of theoretical interest. The object of this study has been to determine what effect particle size has on floatability. The problem has been approached in two ways. One method consisted in a study of samples of the final products of several mills. These samples were sized and each size-product was analyzed for its important constituents. Bakelite briquettes2 of some of the products were made and studied under the microscope. This investigation is being continued, with particular reference to quantitative microscopic analysis of intermediate products of flotation plants. M In the other method of study, mixtures of pure minerals were ground to different degrees of fineness and floated. The products were then sized and analyzed. A study of the behavior of mixtures of pure sized minerals would have been illuminating, but after trial it was considered impractical on account of the tediousness of the large amount of elutriation required and the fact that the mineral particles would oxidize while being sized, preparatory to flotation. Broadly speaking, the following conclusions have been reached: 1. Results obtained by the two methods of study are in agreement. 2. The usual notion about the relative ease of flotation of very fine particles does not agree with the facts: 3. There is a time sequence of flotation with regard to particle size, the medium coarse particles floating first. 4. No successful method of floating extremely fine pulps has been found. 5. Recovery is optimum in a certain well-defined size range. 6. Selection is optimum in another well-defined size range.

Jan 1, 1931

By A. N. Winchell

In connection with law suits between mining companies at Bingham, Utah, a few years ago, the writer made petrographic studies of more than 1400 rock and mineral samples in thin sections, and also careful studies of their field relations. In petrographic studies, even when an area is studied intensively, attention is commonly centered very largely on the unusual features of special interest, so that the relative abundance of rock types (or minerals or textures) can only be determined by a study of map areas outlined largely by field methods, and cannot be based directly on microscopic work. It is very uncommon, and usually impossible, to take samples at regular short intervals along and across formations. It is precisely because such methods were used at Ringham that the work presents a rare opportunity for determining, on a microscopic basis, the relative abundance of rock types and the continuity of gradations between rock types. At the same time, a study was made of the alteration of sediments under the influence of igneous intrusions, with results that are believed to be of interest and importance. • Sandstone-limestone Gradation The sedimentary rocks of the Bingham district are chiefly sandstones, with some beds of limestone, all now lying with their strike nearly east and their dip nearly north at an angle of about 30°, near the surface. The limestone beds are remarkably irregular in thickness in some places, but usually change very slowly in composition along the strike. However, the most interesting results are obtained from a study of a section across the beds at right angles to the strike. In some places, such sections show the usual alternation of pure sandstone with nearly pure limestone, in the simple manner assumed in most geological discussions.

Jan 1, 1924

By W. Hurst

The authors of this paper, in substituting values in a material balance equation associated with a gas reserve and a water drive, cannot find sustainment of what the gas in place should be; therefore, their conclusion is that this type of problem dealing with gas reservoirs is insoluble. They have introduced the word, "cybernetics," based on the work of Norbert Wiener, that further extends this line of reasoning, namely, to the effect that the system is a "black box", and that the gas reservoir and aquifer can take on infinite aspects 'based upon their past performance, to quote the authors. The inference is that this black box is an unknown. which permits in computer programming to subscribe as many variables as possible to observe by adjustment of one to another those combinations of conditions that fit field behavior. This may satisfy those in this discipline whose dedication is to programming, but to the others this is a comparison to the rationalization of the combinational results of the throwing of dice—a probability procedure. In reservoir engineering we are more direct. We learn from the examination of individual we'll and field data exactly what is in this black box. I now come to the impasse that has confronted these authors in their machine calculations. In this I have reproduced from their own production data (Tables 1 and 2 of their paper) pressure vs cumulative gas produced. shown as Figs. D-1 through D-5. A perusal of any of these five plots, for the corresponding fields in the Po Valley, shows the straight-line relation of pressure vs gas produced, evidencing pressure depletion. The point I make is that in their fundamental production data, there is no variance from a straight line that can support a water drive.

The problems associated with the processing of the Tilden ore are very much representative of the problems encountered in plants processing fine grained magnetic and nonmagnetic iron ores. I would like to comment on some of the problems mentioned in Dr. Nummela'spaper and add to his list of research opportunities in the processing of iron ores. Grinding, the most important step in the processing of fine grained iron ores, is synonymous with liberation. One grinds to separate discrete grains of minerals from the gangue. By convention- al grinding in tumbling mills, mostly random size reduction is achieved with relatively little preferential liberation of minerals. Not only are discrete particles broken that should not be broken, but damage is done to the mineral surfaces. The combination of over- grinding and surface damage shows up in lower recovery figures and higher grinding costs. What is obviously needed is a better comminution process that is more discriminating and that would permit liberating mineral particles at the coarsest possible size with a minimum production of fines. Laboratory attempts at such preferential grinding have been quite successful, but technological difficulties have unfortunately prevented its use. Impact grinding is a good example of a new comminution process that has not been accepted because of equipment problems. Either these problems have to be solved or new comminution systems have to be developed to reduce grinding costs and improve liberation. In his paper Dr. Nummela mentions the change in the primary mill throughput that occurs during the winter months. Seasonal changes in the operation of the grinding circuit and other unit operations have been observed in many plants, and many explanations for this phenomenon have been advanced. The fact is that we do not fully

Jan 1, 1979

By D. W. Fuerstenau

THE object of this article is to point out the experimental relationship which exists among contact angle, adsorption density, zeta potential, and flotation rate data. In each of the experiments discussed in this article, the surface properties of quartz, as a function of pH, were measured in solutions to which constant quantities of dodecylammonium acetate were added. Morrow1 and deBruyn2 worked with solutions containing 4.08x10-5 moles per liter, whereas Fuerstenau3 and Seele worked with solutions containing exactly 4x10 moles per liter, but this difference is not significant. The pH of the solutions was regulated with HCI or NaOH in all cases. In each case, the addition of collector was constant, but the concentration of dodecylammonium ions decreased because of the formation of dodecylamine at higher pH values2 Contact Angles: Gaudin and Morrow1 presented data for the contact angle of quartz in solutions containing 4.08x10-5 moles of dodecylammonium acetate per liter between pH 2 and pH 10.15. Using the same captive bubble techniques, the writer measured contact angles on quartz in solutions containing 4x10-5 moles of dodecylammonium acetate per liter at pH values ranging from 9.9 to 13.2. Both sets of data are presented in Fig. 1, in which the contact angle in degrees is plotted as a function of the pH of the solution. From pH 2 to about 8, the contact angle increases slightly with increased pH, but further increase in pH causes a sharp rise in the contact angle to a maximum of about 80º. At pH values above 11.6, the contact angle drops sharply, reaching zero by pH 12.6.

Jan 12, 1957

By J. W. Pugh, Sam Leber

Single crystals of tungsten were made and deformed in tension at 3000°C. The slip traces so formed on these crystals were analysed to determine the apparent slip system. Results indicate that deformation occurs in the<III> direction on planes of maximum shear stress. This determination agrees with the early work of Taylor and Elam on other body-centered cubic crystals at lout temperatures. SLIP in face-centered cubic and hexagonal close-packed metals has consistently manifested itself in straight traces which indicate that glide takes place on planes of highest atomic density and in directions of closest packing. The slip traces observed on body-centered cubic metals are, on the other hand, frequently branched and wavy, and indicate that while glide takes place in the direction of closest packing, it does not necessarily choose the plane of highest density. The early work of Taylor and Elam1 4 indicated that glide took place in the close-packed direction on planes close to those defined by the maximum shear stress. Subsequent investigations have tried to rationalize these observations in terms of an elementary process on the close-packed planes (110). For example, Elam5 and Grenin~er&apos; have suggested alternate glide on nonparallel (110) planes with the observed result that the summation of these glides results in a trace which defines some plane other than{110). Madden and chen7 have recently reviewed the phenomenological and theoretical aspects of noncrystallographic slip. More recently Koehler&apos; has presented a model of dislocation propagation which permits another rationalization. He indicated that dislocation loops are transferred from one glide plane to another by double cross-slip of screw segments. It is reasonable to assume that, on the average, such transfers may result in a trace which approaches the plane of maximum shear stress. The work described in this paper will show that

Jan 1, 1961

By J. A. Eisele

The Bureau of Mines has played an important role in the revival of precious-metal mining underway in the Western United States. During the past 30 years, many techniques used by industry to recover gold and silver were pioneered and developed by the Bureau of Mines. In 1952, technology was developed to strip gold from granular activated carbon and allow the carbon to be reused. In 1969, the heap leaching concept was applied to low-grade gold and silver ores and mine wastes. Heap leaching in conjunction with carbon adsorption-desorption permits very low value material to be economically processed. In 1970, an oxidation treatment based on hypochlorite was developed to increase the recovery of gold from carbonaceous gold ores by cyanidation. In the early 19501s, attempts were made to employ carbon-in-pulp technology to recover gold from ores, but the fixed price of gold and increasing operational costs made the process unprofitable. The Bureau of Mines and Homestake Mining Co. jointly operated a carbon-in-pulp pilot plant, and the technology was used in full-scale production at the Homestake Mine in 1972. In 1973, a pressure stripping method, which decreased the time needed for the stripping step, was developed to desorb gold and silver from carbon. An alcohol desorption method, developed in 1976, also decreased the carbon stripping time. These stripping methods are in commercial use. In 1979, an agglomeration pretreatment was developed that permitted clayey precious metal ores to be heap-leached. Agglomeration-heap leaching technology is being used by at least 30 operations, several of them major gold and silver mines. Almost all precious-metal-mining companies use at least one of the above techniques in production facilities.

Jan 1, 1984

The notion prevails that writing is a knack, that the skilful use of the pen is a gift of nature. This is an error. Dogberry may be responsible for it; he said: "To be a well-informed man is the gift of fortune, but to write and read comes by nature". Because Dogberry said it, we may be sure that Shakespeare thought otherwise. Ability of any sort may be partly innate, but my own observation and experience lead me to conclude that most of the easy writers have become so by constant practice. As I recall the names of men successful with the pen, I remember that most of them have written a great deal and have taken particular pains to improve their style. The suggestion that proficiency in the difficult art is a happy accident provokes a sardonic smile. The larger part of the great writing in our literature is the result of persistent effort. An easy fluency has been the undoing of many; their flamboyant and fantastic scribbling has proved as perishable as froth. This criticism applies to technical writing also; in order that a technical description or discussion may hold the interest of the reader, at least long enough to cause him to read it to the end, the writing must be done carefully and systematically; otherwise it will fail in its purpose of conveying information. Clearness is absolutely essential. "It is not enough to use language that may be understood; it is necessary to use language that must be understood."* The purpose of writing, at least of that which is meant to be read by others, is not only to express ideas but to communicate them. Lack of perspicuity may prove as bad as

Jan 1, 1931

By James Finlay

(New York Meeting, February, 1913) AT first blush one is tempted to say that iron-mines are like any other mines, and that principles governing mining-property in general will apply to them. But there are certain considerations which seem to repay reflection. Gold and copper are more or less independent of transportation. The proof of this is that those metals are profitably mined and shipped from the remotest corners of the earth. Their value is determined by the cost of production on the ground. This is quite true of gold, not quite so true of copper, not at all true of iron. If New York were a fishing-village and Chicago&apos; a swamp, Calumet & Hecla might still be a bonanza. The main element of its value is the 60 lb. of fine copper per ton which it produced for years. But the Mesabi Range is absolutely dependent upon the industrial activity in the United States. Iron-manufacture in Europe would give it no value whatever. If Chicago and New York had a population of Peruvians or Hindus, the Hull-Rust mine would be as worthless a bit of landscape as any tundra in Alaska. I have discussed these facts more or less casually and dimly in my book on the cost of mining and in my report to the Tax Commissioners of Michigan1 I shall try here to bring them out in more detail. I have already referred to some differences in the problem of mining as between the more precious metals, e.g., gold, and the less precious and more abundant minerals, like iron and coal; but it is interesting to note that the literature of the eco-

Jan 3, 1913

By Frederic P. Dewey

It is common to blame irregular assay results upon volatilization and much has been written upon the subject, but there is no real evidence that, in a properly conducted assay, the loss of either gold or silver by volatilization is sufficient to affect appreciably the result, even when arsenic or antimony may be present. Bulk assays of flue dust from assay muffles have been published, but the data given are totally insufficient to even approximate the volatilization from a single assay; and such figures as we have indicate the volatilization to be extremely small. Diligent search in the literature and wide inquiry among assayers and instructors have failed to produce a single case where the litharge volatilized in making an assay has been collected and assayed for gold and silver. Having attempted to do this, with most indifferent success, I am not surprised that this has not been done. While various textbooks give volatilization as a cause of loss in cupella-tion, it may safely be said that in the rare cases where this volatilization is sufficient to affect appreciably the result it is due to excessive temperature. Percy&apos; says "The loss of silver by volatilization during cupellation is very slight (unless the temperature has been much too high), and may be disregarded." This statement is repeated by the Beringers2 and Smith,3 who includes gold with silver. Mitchell4 says the litharge fume rarely contains over one ten-thousandth of silver. Campredon5 ays that at a proper temperature no silver is lost by volatilization. Primarily, excessive temperature may be due to too high general temperature in the muffle; but it may often be due to temperature localized within the bead by oxidation of the metals and this may be influenced by other causes than the general temperature. I have shown an ex-

Jan 1, 1921

By C. H. G. Bushell, James E. Lawver, William Barbarowicz

Proper use of automatic controls in the process industries is a combination of art and science. Although many phases of automatic control theory can be expressed by precise mathematical relationships, the final control arrangement usually requires considerable effort by trial and error before the optimum control circuit is found. The failure of flotation operators to recognize that control circuits require study and plant experimentation before satisfactory operation occurs has led to a popular misconception that flotation plants simply do not lend themselves to automation. This widespread belief has been overcome to some degree in recent years by the numerous installations of automatic controls that have paid their way by increasing profits in terms of increased recoveries, lowered costs, or higher grade concentrates. WHY CONTROL ? Any form of automation must be justified in terms of ultimate return on in- vestment by improving quality, by increasing plant throughput, or by reducing the total operating costs. Generally speaking, automatic controls rarely re- place a mill operator. They assist the operator in holding important variables within predetermined limits. Large tonnage operations usually can justify a great deal of automation because an increase in one or two units of recovery results in enormous savings compared to the capital and operating costs of controls. DETERMINATION OF CONTROL The first questions in considering plant automation are: 1) What variables must be controlled? 2) What are the optimum levels of the variables? The optimum operating conditions for any process are those which maximize profits. Many of the variables active in flotation processing can be determined by experimentation in the laboratory or pilot plant 10. Although laboratory experiments can pinpoint variables, the true optimum conditions existing at plant level usually must be determined by plant scale experiments. In recent years, the concepts of detailed experimental designs in the laboratory, followed by plant experiments, have reached the stage of maturity where

Jan 1, 1962

By Waldemar Lindgren

No one would maintain that all ore deposits or all deposits of useful minerals have been formed by the same processes. Generally they have originated by special processes of concentration but these may be of many different kinds. Some deposits have their origin in chemical or biochemical processes of concentration in rivers, lakes or seas, others, developed on land by, means of chemical reactions of surface waters on various forms of rocks. Certain insoluble substances remained behind; others were dissolved and precipitated in favorable places. This action -proceeded in the realm of the oxidizing surface waters or in the deeper zones to which the waters from the surface could find their way. Examples of the latter kind may be found in the extensive copper and vanadium deposits of some sedimentary beds or in the lead and zinc deposits of certain broad limestone strata. In these instances the evidence for any other mode of origin would seem to be very weak indeed.1 Nor does it seem possible to deny that circulating waters may form deposits of the more common metals along fissures after having dissolved many constituents from paths traversed. Another very large class has been formed by magnetic processes of concentration. The last 40 years have been a period of intense activity in. the investigation and description of a vast number of deposits; all modern methods have been employed and the result is an accumulation of data, difficult or impossible to master. It has been a period similar to that in petrography. The generalizations, the able deductions have lagged behind. Evidently several geologists have become weary of this "infinite detail" and a mistrust of the microscope seems to have. arisen. Although this feeling of being swamped in microscopic detail is a painful experience, nevertheless only through the detail in combination with

Jan 6, 1926

The Committee submits the following report: The General Committee met in the Treasury Building at Washington on Oct. 6 and 7, 1919. At the first meeting, Cornelius P. Kelley was appointed chairman, and Paul Armitage, secretary of the Committee. Subcommittees were appointed on Invested Capital, on Mine Valuation, and on Depletion and Depreciation. These subcommittees were directed to meet separately and to report on Oct. 7 to the General Committee. On Oct. 7, the reports of these committees were submitted to the General Committee and on motion were received and referred to the Executive Committee for its information to be used as it deemed wise. A motion was carried that the Executive Committee be constituted a permanent committee to continue the work of the Committee, with full power to add to and increase its membership; that as thus increased it should constitute a permanent organization to act and cooperate with the Treasury Department in matters of mining taxation under the Federal Income and Excess Profits Tax Laws. Thereafter the Executive Committee met and formed a permanent committee as follows: Cornelius F. Kelley, chairman, 42 Broadway, New York City. J. L. Darnell, Office of the Commissioner of Internal Revenue, Washington, D. C. J. Parke Channing, 61 Broadway, New York City. Walter Douglas, 99 John St. New York City. R. V. Norris, 542 Second National Bank Bldg., Wilkes-Barre, Pa. J. E. Spurr, care of Engineering & Mining Journal, 10th Ave. and 36th St., New York City. W. G. Swart, 808 Selwood Bldg., Duluth, Minn. J. P. Finley, 45 Cedar St., New York City. W. A. Williams, Bartlesville, Okla. F. S. Peabody, care of Peabody Coal Co., McCormick Building, Chicago, Ill. Matthew C. Fleming, 71 Broadway, New York City. H. B. Fernald, 54 Wall St., New York City.

Jan 1, 1923

The Committee submits the following report: The General Committee met in the Treasury Building at Washington on Oct. 6 and 7, 1919. At the first meeting, Cornelius P. Kelley was appointed chairman, and Paul Armitage, secretary of the Committee. Subcommittees were appointed on Invested Capital, on Mine Valuation, and on Depletion and Depreciation. These subcommittees were directed to meet separately and to report on Oct. 7 to the General Committee. On Oct. 7, the reports of these committees were submitted to the General Committee and on motion were received and referred to the Executive Committee for its information to be used as it deemed wise. A motion was carried that the Executive Committee be constituted a permanent committee to continue the work of the Committee, with full power to add to and increase its membership; that as thus increased it should constitute a permanent organization to act and cooperate with the Treasury Department in matters of mining taxation under the Federal Income and Excess Profits Tax Laws. Thereafter the Executive Committee met and formed a permanent committee as follows: Cornelius F. Kelley, chairman, 42 Broadway, New York City. J. L. Darnell, Office of the Commissioner of Internal Revenue, Washington, D. C. J. Parke Channing, 61 Broadway, New York City. Walter Douglas, 99 John St. New York City. R. V. Norris, 542 Second National Bank Bldg., Wilkes-Barre, Pa. J. E. Spurr, care of Engineering & Mining Journal, 10th Ave. and 36th St., New York City. W. G. Swart, 808 Selwood Bldg., Duluth, Minn. J. P. Finley, 45 Cedar St., New York City. W. A. Williams, Bartlesville, Okla. F. S. Peabody, care of Peabody Coal Co., McCormick Building, Chicago, Ill. Matthew C. Fleming, 71 Broadway, New York City. H. B. Fernald, 54 Wall St., New York City.

Jan 1, 1923

By John M. Cummings, Warren. Harry V.

THE Geology Department of the University of British Columbia has undertaken the task of examining the ores from as many as possible of the gold mines of British Columbia. The object of this work is two- fold. First, it is known that detailed mineralographic studies are useful in attacking ore-dressing problems, and these studies are intended to be helpful to mill operators. Second, it is hoped that mineralogical and mineralographical studies will prove useful adjuncts to those of lithology and structure in throwing more light on problems related to the origin of the deposits. The paper shows that gold, for all practical purposes, is not present in an ore mineral in solid solution nor as a eutectic with any mineral; if the latter were true the gold particles would be distributed equally throughout that mineral. The gold occurs either as native gold or as a gold-silver telluride and is not distributed regularly through any mineral or minerals. The relationship between the gold or gold-bearing telluride and the associated minerals affords a means of classification that is not only simple but also appears to be directly related to the geological nature of the deposit, which may be summarized as follows: 1. Disseminated Gold Type.-Precious minerals in extremely small grains, which are distributed without regard to grain size, fractures or grain boundaries: (1) Hedley variety-gold in native form; (2) Surf Point variety-gold predominantly as telluride. 2. Veining Gold Type.-Precious minerals in grains of various sizes, which occur mainly along fractures and grain boundaries: (1) Cariboo gold quartz-goldin native form. (2) Waneta variety-gold as telluride. Application Te Ore Dressing These mineralographic studies have proved to be of value to mill operators, and future studies of a similar nature should prove increasingly useful because every year provides a further opportunity to correlate

Jan 1, 1937

BETWEEN the third and twentieth days of November, 1903, six intensely interesting letters were mailed from Santiago, Chile, addressed to "Mr. William Braden, Consulting Mining Engineer, 71 Broadway, New York City." The subject of these communications, referred to as the "Rancagua mines," was a copper property situated in the high. Andes; and the writer was Marco Chiapponi, an Italian mining engineer. Many a letter has been written about potential mines and prospects, good and bad, situated in all parts of the world; but few of them combine the shrewdness, sincerity, naïveté, and salesmanship that appear in these fascinating letters by Chiapponi. In 1894, Mr. Braden, as a young man twenty-three years old, had gone to Santiago to look after the erection and operation of some mining machinery that was to be exhibited at the International Mining Exposition. Not the least important of his purposes was to get acquainted at first hand with the mines and mining men of Chile, which ranked at the time (as it does today) second to the United States as a copper-producing country. It happened that a dispute arose regarding charges for certain construction work done in connection with young Braden&apos;s exhibit. Finally, arbitration was agreed upon and the Chilean exposition officials proposed Se[n]or Marco Chiapponi as a fair-minded neutral to decide the question. This he did in a manner satisfactory to both sides, and subsequently he and Mr. Braden became good friends. Nine years later Braden wrote to Chiapponi inquiring as to certain matters connected with the Corocoro copper mines in Bolivia. It was to this letter that Chiapponi refers in his letter of November 3, from which the following are some extracts,

Jan 1, 1933

By J. L. Bray

LEAD has often been suggested as a protective coating for iron and steel. Such a protective coating should possess: (1) good adhesion, (2) durability, (3) ease of application, (4) freedom from pinholes, (5) good appearance and (6) low cost, but, unfortunately, lead coatings so far produced do not have all of these characteristics. Because of the necessity of carrying out the coating process cheaply, and because lead solutions have poor plating characteristics, most of the efforts have been directed toward the hot-dipping process rather than electroplating. The hot-clipping processes using lead have not been successful chiefly because of the lack of adherence between iron and lead. In any coating process involving iron a bond can be obtained only by the formation of an intermetallic compound, the formation of a solid solution, or mechanical means. Lead forms with iron two immiscible liquid solu-tions, and in the solid state no intermetallic compounds or solutions. It is necessary, therefore, to employ some other element or elements as a binding agent. Tin may be used as in terneplate, or copper in the form of a thin film of electrolytically deposited metal to which the lead will adhere. Because of its physical and chemical properties, lead as a coating medium would undoubtedly be limited in its use to sheet and wire and then only when the article is not subject to abrasion or wear. A very large tonnage of these products are being used under such conditions and a successful lead-coating process should be a valuable contribution to the science. Two other difficulties stand in the way of successful lead coating-that of poor appearance of the weathered surface and the tendency of the lead to form pinholes during solidification. Since lead is commonly accepted as cathodic to iron, these exposed areas are ones of accelerated corrosion.

Jan 1, 1937

By L. H. Reiss, J. Groult, L. Montadert

Many fields, where the reservoir is composed of sandy layers, show great complexity because of the lack of continuity which results from a particular type of seditnentation. This complexity may be a factor of prime importance in studying reservoir drainage, especially in the displacement of oil by water or gas. This paper describes work done to study this heterogeneity and its influence in the exploitation of the fields of the lower Devonian sandy shale in the Fort Polignac Basin in Algeria. Two lines of research were followed. 1. On the border of the hasin, a detailed sedimentological study established rules for the distribution of the sandy zones, which furnished hypotheses necessary for devising a geologic model of the reservoir. A certain number of sandy zones were recognized and characterized by their sedimentation. 2. In the interior of the basin, production logs deterrnined the productivity profile. Study of these point data led to a description of the distribution of oil and gas phases in the reservoir so that the continuity of different zones between the wells could be deduced. These techniques were applied to the study of the lower Devonian sandy shale reservoir of Zarzaitine. The sedimentological study guiding the correlation work, with the aid of the conventional static data (logs and cores), led to the establishment of a useful geologic model of the reservoir. Production logs, thanks to the contribution of dynamic elements, permitted corrobora-tion of the model. In particular, the logs confirmed separation, as proposed by the sedimenfological study, of two comparable sandy groups by revealing the continuity of a thin impermeable layer, invisible on conventional logs. INTRODUCTION The heterogeneity of sandstone reservoirs considerably influences the distribution of fluids, as well as their displacement in the reservoir. Rational development of a field and maximum recovery of hydrocarbons are closely tied to an exact and precise knowledge of the intern architecture. We will try to show how it is possible I refine the knowledge of the reservoir by seeking qui different and varied sources of information. Productic geology, the group of techniques which leads to idei concerning reservoir architecture and its geometric descris tion, furnishes the framework of this undertaking. Of these techniques. those used so far are qui varied. Descriptive as well as quantitative, the technique partake as much of classical geology as of reservo science. They include (1) geologic studies of the enti basin, especially a stratigraphic and sedimentologic study of the reservoir member at its outcrop, detail1 observations of cores taken from wells and, finall oriented cores; (2) interpretation of geophysical dat (3) interpretation of electric logs, nuclear and sonic lo and dipmeters: (4) petrophysical study of the reserve on samples taken from wells; (5) reservoir dynamics (stu of the production history and, in particular, interpretati of production logs); and (6) analysis of the fluids a thermodynamic studies. This incomplete list could also include (1) study the migration of the fluids, (2) geochemistry (chemi characterization of the oils), (3) regional hydrodynamii and (4) injection and detection of tracers. If most of these techniques are classic, attention i nevertheless be called to applying two of the techniql in conjunction: the study of the reservoir member its outcrop and the study of dynamic distribution fluid phases in the reservoir through use of product logs, used in the study of the sandy shale reservoirs the lower Devonian of the Fort Polignac Basin, Alge in particular, their application to the study of the 2 zaitine field where they have led to a new and satisfact model of the reservoir will be described. THE ZARZAITlNE FIELD Situated in the interior of the Fort Polignac 8 about 150 kilometers (km) north of the lower Devol outcrop, the Zarzaitine Devonian oil field was discovc On Ian. 28, 19&apos;&apos; (Figs. 1 and l8). It is in the fern a monocline truncated by two perpendicular fault: great throw, with a downthrown section to the north\: Erosion at the top of the structure has caused one of it to disappear. It is a reservoir with a gas cap an m coefficient on the order of 1:5, open to the aql On the northeast, with the oil zone covering an Of 106 sq km and with initial oil reserves of 222 mi

Jan 1, 1967