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By Michael A. Farrugia, Marcel Michaud

Remoteness of western Canadian coals has always been a barrier to the use of Canadian coals domestically. However, the world energy crunch, increased mining costs, stricter environmental controls, labor shortages, etc., are such that by 1980 a shortfall from traditional U.S. sources will prevail. Of necessity, Canada must then bring western coals east, requiring major new transportation initiatives. CN, CP Rail and Neptune Terminals are proceeding jointly with the design of a $30 million, fully automated, coal terminal at Thunder Bay. This element forms part of a $400 million integral transportation system to open new lines, improve trackage, acquire rolling stock and ships, for an initial capacity of 3 million tpy.

Jan 1, 1977

By Olin G. Bell

At the beginning of the year 1935 the older fields in Southwest Texas, and particularly those discovered during 1934, had been practically delimited and only normal development continued. As a result, operations in this area were somewhat slowed down. Shortly after the first of the year, however, activity in the area was greatly accelerated, due largely to the fact that the Loma Novio field, discovered during the last few days of 1934, indicated the presence of a new productive trend east of and parallel to the Government Wells field and also indicated the presence of a new productive horizon, the Loma Novio sand, approximately 100 ft. lower than the Government Wells sand zone. Other discoveries during the year greatly augmented the activity in the district. During the year there were 651 oil wells, 53 gas wells and 275 dry holes drilled in this area during the year. Most of the operations were in the Government Wells, Cole, Loma Novio, Seven Sisters and Lopez fields. New Fields Four new fields were discovered during 1935 as follows: Seven Sisters and Piedra de Lumbre in Duval County; Loma Alto in McMullen County; and Lopez in Webb County. Seven Sisters Field.—The Seven Sisters field, opened in May, was the direct result of a systematic search for new productive areas northeast of the Loma Novio field. The first producer, Harvey & Henderson NO. 1 Chernosky, survey 226, was completed in the Labbe (Chernosky) sand at 2220 ft. However, the second producer, Santa Clara Oil Co. No. 1 Welder in survey 385, drilled about one mile south of the discovery well, failed to find production in the Labbé sand and was carried on down and completed in the Government Wells sand at 2473 ft. with an initial production of 20 bbl. of oil per hour. These two discoveries, in the Labbé and Government Wells sand, started an active leasing and drilling campaign in this part of Duval County and drilling operations continued especially active throughout the remainder of the year.

Jan 1, 1936

By Olin G. Bell

At the beginning of the year 1935 the older fields in Southwest Texas, and particularly those discovered during 1934, had been practically delimited and only normal development continued. As a result, operations in this area were somewhat slowed down. Shortly after the first of the year, however, activity in the area was greatly accelerated, due largely to the fact that the Loma Novio field, discovered during the last few days of 1934, indicated the presence of a new productive trend east of and parallel to the Government Wells field and also indicated the presence of a new productive horizon, the Loma Novio sand, approximately 100 ft. lower than the Government Wells sand zone. Other discoveries during the year greatly augmented the activity in the district. During the year there were 651 oil wells, 53 gas wells and 275 dry holes drilled in this area during the year. Most of the operations were in the Government Wells, Cole, Loma Novio, Seven Sisters and Lopez fields. New Fields Four new fields were discovered during 1935 as follows: Seven Sisters and Piedra de Lumbre in Duval County; Loma Alto in McMullen County; and Lopez in Webb County. Seven Sisters Field.—The Seven Sisters field, opened in May, was the direct result of a systematic search for new productive areas northeast of the Loma Novio field. The first producer, Harvey & Henderson NO. 1 Chernosky, survey 226, was completed in the Labbe (Chernosky) sand at 2220 ft. However, the second producer, Santa Clara Oil Co. No. 1 Welder in survey 385, drilled about one mile south of the discovery well, failed to find production in the Labbé sand and was carried on down and completed in the Government Wells sand at 2473 ft. with an initial production of 20 bbl. of oil per hour. These two discoveries, in the Labbé and Government Wells sand, started an active leasing and drilling campaign in this part of Duval County and drilling operations continued especially active throughout the remainder of the year.

Jan 1, 1936

By J. B. Rather

The use of sulfuric acid in refining illuminating oils antedates the beginning of the petroleum industry in America by many years. It was used as early as 1792 by Tower in refining "coal oil" in the British Isles, and by 1860 there were 53 refineries in the United States manufacturing "coal oil," most of them using sulfuric acid as a refining agent. Following the completion of the Drake well in 1859, many of the "coal oil" refiners began to use petroleum for manufacturing illuminating oil, and their methods and equipment were adapted so far as possible to this new raw material. The value of sulfuric acid in refining L'coal oil" having been established, this reagent was immediately tried and found to be satisfactory in refining petroleum. Notwithstanding the tremendous advances in petroleum technology since that time, sulfuric acid remains today the most valuable and most widely used means for refining petroleum products. Early Methods of Disposal of Acid Sludge With the almost immediate expansion of the petrolrum industry came the problem of disposing of the acid sludge produced in the refining operations. While in 1859, the year of the discovery of the Drake well, a patent was granted for sludge separation and separated acid concrntration, most of the earlier refiners, and rnany of their successors, felt that separation and recovery of spent acid was uneconomical. Accordingly, many of then) disposed of the sludge in any way that seemed expedient nt the time. It was huricd in the refinery grounds, harged and tlurnped at sea, run into neighboring streams, or dumped into sewers. Some optimists carted it to open pits in the hope that it would eithcr sink into the ground or evaporate. Not so many years ago, the superintendent of nn eastern refinery, who was using the open-pit method of disposal, lost, a sludge cart, with horse attached, in such a pit. The horse was recovred almost immediately, but its availability for further use was reduced to zero by the loss of its hair.

Jan 1, 1928

By B. M. Loring, W. H. Baer, G. M. Carlton

It is a well known fact that age-hardening alloys remain in a supersaturated, or partially supersaturated, condition only for limited periods of time at temperatures below the solvus. In order to develop optimum properties by subjecting the quenched alloy to precipitation or age-hardening treatment at a specified temperature, it is necessary that the cooling rate be sufficiently high to maintain the required degree of supersaturation of the solid solution. In practical applications the size and shape of the specimens obviously have considerable influence on the rate of cooling and there is need for more information on the effects of various rates of cooling. Cooling rates of quenched aluminum alloys generally have been established by the type of quenching medium, the temperature of the medium and the dimensions of the specimen. Except for the work of Roth3 little quantitative information is available on the measurement of cooling rates of aluminum alloys and the significance of the influence of various cooling rates upon the mechanical properties. The purpose of the present investigation was to study the use of the Jominy test for aluminum alloys (Table I). The material for this investigation consisted of extruded rods 1 1/4 to 136 in. in diam. The chemical compositions were as follows: The modified L-type Jominy specimen with dimensions shown in Fig I was selected as the most convenient means for obtaining a wide range of cooling rates. The standard Jominy specimen was not satisfactory because its cooling rate was not sufficiently high. The four flat surfaces machined at right angles along the length of the L-type specimen to a depth of 0.015 in. facilitated the hardness measurements. The specimens were machined from the extruded stock with no intermediate forging. New specimens were used for each aging experiment. The specimens were given solution treatments of 2 hr duration at recommended temperatures in a Hoskins furnace (Table 2). The temperature of the furnace was maintained constant to 3°C. No protective atmosphere was necessary because the thin film of oxide that formed on the surface of the specimens had no effect on the hardness measurements. AT

Jan 1, 1949

By Wilbur Nelson

THE year 1924 showed even less drilling in Kentucky and Tennessee than the preceding year. The operators in this section, however, are anxious to resume development work and are only waiting for a higher market for crude oil before starting such a program. In Kentucky, during 1924, 1605 wells were completed, the combined initial daily production of these wells being 25,599 bbl. Of the total number of wells drilled 1176 were oil wells, 61 gas wells, and 368 were dry holes. The average initial production of the oil wells was 21.8 bbl. per well. In Tennessee, 28 wells having an initial daily production of 1199 bbl. were completed during 1924. Of these, 3 were oil wells, 6 were gas wells, and 19 were dry holes. The initial production of the three oil wells was 400 bbl. Of the total number of wells drilled in Kentucky in 1924, 73 per cent. came in as producing wells; and of those drilled in Tennessee, 10 ½ per cent. came in as producing wells and 20 per cent. as gas wells. In Tennessee, during 1924, wildcatting dropped off considerably and only about one-half as many wells were drilled as in the preceding year; in Kentucky, on the other hand, there was only a slight curtailment in drilling, there being 1943 wells drilled in 1923 as against 1605 in 1924.

Jan 3, 1925

By G. W. Mao, A. M. Gaudin, D. W. Fuerstenau

Activation of sphalerite with copper salts has long been thought of as a chemical reaction of the following form: ZnS + Cu++ [=] CuS + Zn++ [ 1 ] Early experimentation1-3 showed that the reaction seemed to be stopped by the coating of insoluble copper sulfide, but since the analytical methods were crude, it was only surmised that the reaction could proceed by diffusion. Probably the most conclusive evidence for reaction (Eq. 1) was obtained by Cooke,4 who found a stoichiometric replacement of Zn++ by Cu" after 50 days' reaction at about 100°C. Cooke also found the sphalerite to be covered with a rather thick coating of covellite, which in¬dicates that activation is a continuing replacement of Zn++ by Cu" rather than diffusion of Cu" throughout the sphalerite lattice. However, the occurrence of diffusion at high temperatures has been observed.5,6

Jan 4, 1959

By B. A. Joyce, R. W. Bicknell, R. J. Bennett, P. J. Etter

Epitaxial layers of silicon have been grown on single-crystal quartz and alumina by two types of chemical reaction the hydrogen reduction of trichlorosilane and b) the pyrolysis of silane. These reaction systems are described. The cqsfallography of the two systems, as determined by electron and X-ray diffraction, is discussed, and epitaxial mechanisms suggested. The electrical behavior is briefly considered, and the design and properties of field-evert devices fabricated in the epilaxial material are also discussed. RECENT work carried out in these laboratories" has shown that it is possible to obtain epitaxial deposits of silicon on single-crystal quartz and alumina. The purpose of this paper is to describe the method of preparation of these layers using both the hydrogen reduction of trichlorosilane and the pyroly-sis of silane, to compare the crystallographic behavior of films on the two substrates, and to present some initial results of the electrical behavior of silicon layers on alumina. The structural study has been carried out using electron and X-ray diffraction and electron microscopy. The electrical assessment has been made in terms of conductivity and mobility determinations by the van der pauw3 technique, and by measurements on metal-oxide-semiconductor assemblies. 1) FILM PREPARATION Both quartz and alumina substrates, approximately 1 sq cm in area and 0.4 mm thick. were prepared from slices cut parallel to within a few degrees of (11.0), (10.0), and (00.1), and polished mechanically down to about 0.3 p diamond grade. Chemical polishing of alumina slices, using phosphoric acid at elevated temperatures, has also been used; epitaxial silicon layers have been grown on these substrates, but the process is not entirely reliable, possibly because the large strain present in the Verneuil-grown alumina crystal affects the chemically prepared surface. The two reaction systems are fairly conventional and are described briefly below. a) Trichlorosilane-Hydrogen System. The apparatus is shown schematically in Fig. 1. The substrate was heated by induction, with a fused-quartz encapsulated graphite hemicylinder as susceptor. The procedure for carrying out a deposition was to heat the substrate to reaction temperature in a stream of

Jan 1, 1965

By William C. Aitkenhead, John A. Jaekel

Uranium deposits in the Spokane Indian Reservation, as well as those around Mt. Spokane, are essentially low grade, much of the ore containing less than 0.2 pct U808. The Mining Experiment Station of the Division of Industrial Research, State College of Washington, has been engaged in intensive research on the amenability of these low grade ores to froth flotation. The results: successful flotation of autinite, chief mineral constituent. At the outset of this work the goal was a concentrate of 1 pct U308 with a 90 pct recovery from ores containing less than 0.2 pct U3O8. Most of the work has been done on argillite ore from the Midnight mine on the Spokane Indian Reservation. The goal has not been attained using this ore, but samples of the granite ore from Mt. Spokane yielded successful results. For example, a concentrate containing 11.2 pct U308 was produced from a Mt. Spokane high grade ore containing 1.27 pct U3O8 with a recovery of 97.8 pct. Another Mt. Spokane ore yielded a concentrate of 5.0 pct U3O8 from an ore containing 0.13 pct U3O8, with a recovery of 85 pct. This same ore gave a recovery of 93.5 pct when the grade of concentrate was reduced to 2.0 pct.

Jan 1, 1959

By Benjamin Smith Lyman

It has seemed that it might be a highly useful contribution to the study of structural geology to assemble, in as compact a form and on as large a scale as practicable, a great number of

Jan 1, 1896

By W. C. Winegard, C. J. Simpson, C. J. Beingessner

VARIOUS organic compounds, such as borneol, carbon tetr a bromide, and hexachloroethane, solidify as transparent plastics with a fcc structure. Each of these substances undergoes a solid-state transformation from the plastic phase to a brittle phase at temperatures slightly above 20°C. Since it was known that these plastic crystals solidified like metals,1 it was decided to investigate the possibility that solid-state grain growth would occur in the same way as it does in metals. Two-dimensional grain growth in thin films of plastic organic compounds has been studied with the aid of cinemicrophotography. Samples varying in thickness between 250 and 1000 @ were prepared by subliming a thin layer of the compound onto a microscope slide plate which was then covered with a second slide plate.

Jan 1, 1968

By Gilbert L. Eggert

The effects of reactor irradiation on age hardening in a Cu-2 wt pct Be alloy have been investigated in two neutron-energy ranges. During some of the irradiations, specimens were exposed to high-energy fission neutrons which passed through a boron-10 shield; during other bombardments, the boron-10 was omitted and specimens were irradiated in a reactor thermal column, or the fuel configuration was modified to increase the thermal-neutron flux at a location in the core. Differences in length, X-ray diffraction angle, and hardness indicated that low-energy neutron irradiation made a small contribution to changes in the measured properties. The influence of defects generated by knock-om with less than the Brinkman critical energy or by prompt (n,y) recoil is suggested as the cause of this effect. EXPERIMENTS designed to test the effects of reactor irradiation on the properties of age-hardening alloys have to the present time employed fluxes un-differentiated according to neutron energy. Billing-ton and Siegell in 1950 were the first to perform such an experiment and to compare the results with those obtained by thermal aging. These authors concluded that precipitation in a Cu-2 wt pct Be alloy was not enhanced by the radiation. However, 4 years later, Murray and Taylor,2 working with specimens of the same Cu-2 wt pct Be alloy, reported that an increase in density, hardness, and resistivity which followed reactor irradiation resembled changes associated with thermal aging at about 100°C. (It should be noted that these authors reported that higher aging temperatures caused a decrease in resistivity.) cupp3 reported hardness results similar to those of Murray and Taylor. Koppenaal4 showed that irradiation-enhanced precipitation and irradiation defect hardening were not simply additive but that they acted separately in an irradiated alloy. Kernohan et a1.,5 working with Ni-Be, offered evidence that beryllium was removed from solid solution by reactor irradiation and suggested that the mechanism was one of increased diffusion through the use of vacancies in the structure. piercy6 also found that more precipitate particles were formed by fission-neutron irradiation of a Cu-Co alloy which contained a small amount of particles before irradiation. He proposed that the additional particles were caused by an appreciable amount of diffusion during the final cooling of displacement spikes. The retrogression of extant precipitate particles found by Murray and Taylor2 and Boltax7 as well as piercy6 indicated that nuclei were dissolved within a high-energy spike region and, upon resolidification of the perturbed volume, new nuclei precipitate and grow by enhanced diffusion. Bleiberg et al.' and Konobeevski et al.' explained phase changes obtained by irradiating fissionable alloys in terms of retrogression and re-precipitation in regions of high-energy spikes. Parsons and Balluffi10 used electron microscopy to verify that crystallization did indeed occur in displacement spikes which were formed in amorphous germanium by fast-neutron irradiation. The concept that low-energy neutron irradiation might cause structure-sensitive property changes in semiconductors by atomic recoil associated with the (n, y) reaction was first proposed by Schweinler" and walker." This thesis was tested by Cleland and crawford" and found to be valid. Coltman et al.14 exposed a variety of pure metals to thermal-neutron irradiation at cryogenic temperatures and attributed the resulting resistivity changes to the action of defects created by (n, y) recoil. The present work was undertaken to extend the concepts of Schweinler," walker," and Coltman et al.I4 to the case of an age-hardening alloy and to determine whether or not the action of defects produced by thermal-neutron irradiation would en-hance age hardening. EXPERIMENTAL PROCEDURE Omeea West Reactor Irradiations.* Thermal-

Jan 1, 1965

By F. N. Kissell, R. A. Jankowski

The US Bureau of Mines, in close cooperation with the mining industry, has recently established several improved face ventilation techniques for longwall mining systems. These include coursing the primary face intake from tailgate to headgate, installing curtains at the intake end of the longwall face, and identifying improved techniques for measuring face ventilation parameters on longwall sections. Applying these techniques throughout the mining industry should reduce the health hazard associated with excessive exposure to respirable dust.

Jan 1, 1984

By A. J. Phillips, C. G. Grant, Wm. B. Price

Admiralty nickel is a new corrosion-resisting and heat-resisting white metal alloy composed of 70 per cent. copper, 29 per cent. nickel and 1 per cent. tin. It has been given the trade name "Adnic." In 1924, Wm. B. Price' described this alloy and its successful use as a diaphragm metal. The physical properties of Adnic at ordinary and elevated temperatures were given in Mining & Metallury.~ A patent3 was granted on Adnic, April 28, 1925. Work was first started on this alloy during December, 1921. An investigation of the patent situation in this country and abroad, and also a search of the literature, did not reveal any work on the ternary diagram, copper-nickel-tin; and the only wrought copper-nickel-tin alloy found was that known as "Newloy," composed of copper, 64 per cent.; nickel, 35 per cent.; tin, 1 per cent. This was being manufactured and sold by Wm. Gallimorr & Sons, Ltd., Sheffield, England, for unplated spoon and fork stock, and first came to our attention in January, 1922. The preliminary work in connection with the development of Adnic was started by casting four binary copper-nickel alloys of the compositions shown in Table 1. Various a~ilounts of tin were added to each of these mixtures, to produce the series of ternary copper-nickel-tin alloys also given in Table 1. A 200-gm. sample of each of these was cast by iiielting in a clay graphite crucible and allowing the melt to slowly cool with the furnace. A longitudinal section from each of thcsc castings was polished and etched for examination. The castings were not homogenrous solid solutions, but showed the usual cored structure associated with cast alloys. Howcvrr, frorn an exarrlination of these sections we roughly determined

By J. A. MacLellan, John C. Bowling, J. R. Davenport, G. M. Ellis

Six months out of the year the cold is always there, and it seems to be waiting for someone to make a mistake. The simplest things can shut down a multi-million dollar plant besieged with -40°F temperatures and a 40 mph wind. It takes only one man-door improperly latched to feeze up all the pumps on the bottom floor. Someone can poke a one inch hole in an outside wall in July and six months later, the whole plant is flooded because the main water line just froze up and burst. Some important things must be remembered in plant design for cold and remote areas. For one thing, everything in these areas is more expensive due to long and difficult supply lines. Fuel is expensive and would be a major cost item even if it were not expensive, due to the extended periods of low temperatures. Building volumes should therefore be kept to an acceptable minimum. Service areas, on the other hand, must be adequate, because maintenance generally has to be conducted inside in a heated area. Supply vehicles, for instance, have to get completely inside the building to unload. If you try to unload a supply vehicle with the door open at -50°F, you won't be able to find the vehicle for fog and if you take more than 5 minutes half the water lines in the plant will freeze UP.

Jan 1, 1972

By A. J. Phillips, C. G. Grant, Wm. B. Price

ADMIRALTY nickel is a new corrosion-resisting and heat-resisting white metal alloy composed of 70 per cent. copper, 29 per cent. nickel and 1 per cent. tin. It has been given the trade name "Adnic." In 1924, Wm. B. Price1 described this alloy and its successful use as a diaphragm metal. The physical properties of Adnic at ordinary and elevated temperatures were given in Mining & Metallury.2 A patent3 was granted on Adnic, April 28, 1925. Work was first started on this alloy during December, 1921. An investigation of the patent situation in this country and abroad, and also a search of the literature, did not reveal any work on the ternary diagram, copper-nickel-tin; and the only wrought copper-nickel-tin alloy found was that known as "Newloy," composed of copper, 64 per cent.; nickel, 35 per cent.; tin, 1 per cent. This was being manufactured and sold by Wm. Gallimore & Sons, Ltd., Sheffield, England, for unplated spoon and fork stock, and first came to our attention in January, 1922. The preliminary work in connection with the development of Adnic was started by casting four binary copper-nickel alloys of the compositions shown in Table 1. Various amounts of tin were added to each of these mixtures, to produce the series of ternary copper-nickel-tin alloys also given in Table 1. A 200-gm. sample of each of these was cast by melting in a clay graphite crucible and allowing the melt to slowly cool with the furnace. A longitudinal section from each of these castings was polished and etched for examination. The castings were not homogeneous solid solutions, but showed the usual cored structure associated with cast alloys. However, from an examination of these sections we roughly determined

Jan 1, 1928

By E. M. Cox, A. S. Skapski, N. H. Nachtrieb, M. C. Bachelder

D. T. ROGERS*—The conclusions drawn in this paper have important practical significance to the steelmaker and the metallurgist if, in practice, it is demonstrated that metallic copper in the charge will pick up sulphur from the furnace atmosphere and thus increase the sulphur content of the bath. The problem of residual copper arising out of increasing copper in the scrap available to the industry is, in itself, a matter of concern to the steel maker. If, in addition to the often detrimental effects of high residual copper upon the physical properties of some important steel grades, there is to be a complication of the sulphur problem, then we have a set of conditions that bodes no good for the open hearth melter and the open hearth metallurgist. M. B. BEVER*— Investigations of gas-metal equilibria continue to be of interest, especially as new possibilities for improving experimental techniques emerge. Higher purity of reacting substances, better refractories, improved methods of temperature control and an increased awareness of the pitfalls of high-temperature equilibrium work are

Jan 1, 1950

By J. R. Morison, M. P. O’Brein, J. W. Johnson, S. A. Schaaf

The force exerted by unbroken surface waves on a cylindrical object, such as a pile, which extends from the bottom upward above the wave crest, is made up of two components, namely: 1. A drag force proportional to the square of the velocity which may be represented by a drag coefficient having substantially the same value as for steady flow, and 2. A virtual mass force proportional to the horizontal component of the accelerative force exerted on the mass of water displaced by the pile. These relationships follow directly from wave theory and have been confirmed by measurements in the Fluid Mechanics Laboratory of the University of California, Berkeley. The maximum force exerted by breakers or incipient breakers is impulsive in nature, reaching a value much greater than that produced by unbroken waves but enduring for only a short time interval. This impulsive force represents the ultimate development of the accelerative force and is produced by the steep wave front and large horizontal acceleration at the front of a breaker. This impulsive force greatly exceed. the drag force computed from the particle velocities of the breaker. The reader is cautioned that these preliminary results are applicable only to single piles without bracing and are likely to be modified somewhat where multiple piles are driven, one within the influence of the other or where multiple piles are connected by submerged bracing. This paper is essentially a preliminary report submitted at this time because of the current importance of wave forces in the design of offshore structures. An extended series of additional experiments is planned for the near future. Theoretical Relationships For the sake of simplicity of treatment, the theory will be developed from the equations for waves of small amplitude. The horizontal displacement of a water particle is described by the equation 2p cosh — (d + z) H L 2pt X =----------------------sin ----- . , (1) 2 2pD T sinh------ L The horizontal component of the orbital velocity is obtained by differentiation with respect to time as 2p cosh — (d + z) pH L 2pt u = ------------------- cos— .... (2) sinh- L The acceleration of the water particles at any position is obtained by again differentiating with respect to time as 2p cosh — (d + z) 9 u -2vH L 2pt -----=----------------------------sin ----- . . (3) 3 t T2 2pd T sinh------ L where H = wave height — ft L = wave length — ft d = still water depth — ft z = depth below the still water measured negatively downward — ft. T = wave period — sec t = time — sec The force exerted on a differential section, dz, in length is pD2 s u pD 1 dF= [CM (p/4) st + Cn/2 u2] dz • • (4) where D = pile diameter — ft p = water mass density — slugs/ft3 C, = coefficient of mass C,, = coefficient of drag Substituting for a s u/s t arid u2 from Eqs. (3) and (2), the force per unit length at any position z is dF p2 pD H2 &apos; / = — [- fM sin ? ± fD cos2 ? ] . . . (5) dz 2T2 fM D fD 2pt Cm = pA/H:CD = A2;? = T [+ cos2 ? for 0 < ? < p/2 cosh— (d+z) 3p L — < o < 2p Sin L -cos2 ? for p/2 <? <3p/2 The sin 9 term (inertia) i- negative for 0 < 0 < p and positive for p < ? < 2p. Values of A and A&apos; appear in Fig. 1

Jan 1, 1950

By L. W. Kempf

DURING the recent development of aluminum alloys for free-cutting screw-machine rod, it became desirable to know something of the solubility of lead and bismuth in liquid aluminum and in some aluminum alloys. The literature is not particularly helpful in supplying this information. These portions, therefore, of the constitutional relationships of aluminum-ismuth and aluminum-lead alloys were investigated by thermal analysis and by chemical analysis of samples taken from aluminum-rich melts in equilibrium with precipitated lead or bismuth. The solubility of lead and bismuth in some liquid aluminum-copper alloys was also investi-gated. Some consideration was also given to the solubility of these elements in solid aluminum. Among the earliest investigators of the aluminum-lead and aluminum-bismuth systems was Wright,1 who reported that melts of aluminum and lead formed two layers indicating limited liquid solubility. Under his conditions, the aluminum-rich layer was reported to contain 1.91 per cent Pb and the lead-rich layer, 0.07 per cent Al. Subsequently, Pecheau2 found that in aluminum-rich alloy melts with more than 10 per cent Pb three layers were distinguishable. He reported that the middle layer contained from 3 to 10 per cent Pb. He also found that the melting point of aluminum appeared to be lowered slightly by the addition of lead. Gwyer3 investigated these alloys and found evidence of a slight lowering of the freezing point of aluminum by the addition of either lead or bismuth. He found no evidence of solid solubility in either case and made no attempt to determine the liquidus curves. Hansen and Blumen-thal4 reported that the addition of lead distinctly lowered the solidifica-tion point of aluminum. They also found that bismuth lowered the melting point of aluminum. Guillet5 reported almost complete mutual immiscibility for the aluminum-bismuth alloys in the liquid state. Bohner6 examined the effect of various concentrations of lead and bis-muth on the electrical conductivity of aluminum. He found decreases in conductivity on annealing at 500° C. as compared with the conductivity of the same alloys on annealing at 300° C.

Jan 1, 1938

By Mario L. Villa

During 1938, oil activities in the Argentine Republic showed a favorable balance due to the increase in crude-oil production, the incorpora- tion of new producing areas and the discovery of deeper productive horizons. Drilling was as follows:

Jan 1, 1939