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By L. M. Howe, J. Gordon Parr, E. Saarema

THE decreasing solid solubility limit at the titanium-rich end of the Ti-Cu constitutional diagram,' Fig. 1, suggests the possibility that titanium-rich alloys may be age-hardenable. However, results obtained by Holden et al. reproduced in Fig. 2 show that after quenching from 790°C the age-hardening of an alloy containing 1.7 pet Cu is very slight, while a 0.8 pet alloy decreases in hardness, during heat treatment at 400°C. It was believed possible that powder samples of alloys might show different results from the lump samples used by Holden et al., since small particles are often more sensitive to diffusion processes than larger samples. Consequently, a 1.9 pet (by weight) Cu alloy was made by the technique of levitation melting," checked for homogeneity, and filings of 48-65 Tyler screen size were cut from it for aging experiments. The filings were helium-quenched (by a technique described previously)' from 790°C, sealed in vacuo in silica tubes and aged at temperatures of 400°, 450°, and 500°C. Microscopic and X-ray examinations failed to reveal any structural changes during the aging process. This is not too surprising since early stages of precipitation do not usually manifest themselves in ways that are readily detectable by metallographic methods, and the extent of precipitation on overaging a 1.9 pet alloy is very small. However, hardness readings (taken on a Bergs-man micro hardness tester, using a 25 g load applied to a diamond indenter) do show a hardness peak at each aging temperature, Fig. 3. About a dozen readings were taken on each heat treated sample; the highest reading and the lowest reading were ignored and an average taken of the remaining values. In

Jan 1, 1957

By Ralph E. Hartline, Wilfred Tapper

The Strataflow process for locating water entry in producing, wells is now available. This method as now practiced utilizes the fact that fluids of different salinities have different electrical resistivities. By introducing into the well a fluid of a markedly different salinity than that of the fluid being produced, a pronounced resistivity change will occur at the point of entry. By running a Strataflow survey the points of major and minor water entry may be interpreted from changes in the resistivity of fluid in the hole. Strataflow results are obtained with the well operating under almost normal producing conditions, and are a logical primary step in any workover program, having as its purpose shutting off of the water. INTRODUCTION Water production is a serious problem in many producing oil wells. It certainly increases lifting costs and in some cases presents a disposal problem. It often aggravates corrosion problems and can even endanger oil production. With accurate information to guide an effective workover program, many marginal wells could be restored to Profitable Production. The shortcomings of previous meth- ods of water entry location were recognized. The Strataflow process is the result of several years of development and field testing directed toward overcoming these limitations. It represents the continued development of a process reported by Silverman and Brown. The earlier work established the basic soundness of fresh-to-salt water resistivity contrast in delineating zones of water entry, but its application was limited by the difficulty of maintaining static balance of the well during preparation for the test. A more serious deterrent to its use, however. was its unadaptability to existing well logging service equipment and field operating methods. STRATAFLOW PRINCIPLE The general principle of the new method involves, first, conditioning the well by displacing the fluid in the bore of the well adjacent to the zone to be tested by a conditioning fluid which is miscible with the formation fluid. This displacement is carried out without interruption of the well production. The conditioning fluid must have some measurable physical, chemical, nuclear, or electrical property which is distinctive from that of the formation fluid. As the well continues to produce. formation liquid entering the well bore dilutes the conditioning fluid so that zones of entry may be determined by making a log of the property undergoing change. This general principle may be applied to indicate zones of either water or oil entry by suitable selection of conditioning fluid and proper logging equipment. The Strataflow process, as it is currently practiced for water entry location, uses fresh water as the conditioning fluid and depends for its operation upon the marked difference of electrical resistivity between this fresh water and the salty water produced by the formations. If possible. any necessary modifications of the well equipment are made a week or so before the test. The well is then returned to normal production. On the day the test is to be carried out. the conditioning water is landed at the bottom of the well and the test is made without interrupting production except for a brief period required for the conditioning water to consolidate into a continuous column extending to a point well above the test section. With this general description of the process in mind, a more detailed step-by-step description of the process will be clearer. PRELIMINARY PREPARATION OF WELL The Strataflow survey, as it is currently practiced for water entry location, is applicable only to pumping wells. Since the required electrical measurements are made by a special

Jan 1, 1952

By David S. Butts

The high cost of energy has made many solution mining corporations turn from fuel consuming evaporators to solar energy and solar ponds. The generally held concept of a solar pond is an area enclosed by dikes into which brine is pumped, water evaporated by the sun, and the resulting salts scraped from the bottom of the pond. This paper will show that solar ponding is not simple. It is a science involving six main areas. These areas are (1) land conditions, (2) meteorology, (3) fresh water, (4) accessibility, (5) manpower and (6) mineral resources. Each area is discussed to identify important parameters that must be investigated before the viability of a solar pond complex can be established as a mineral recovery step.

Jan 1, 1985

By Walter Scott

THE removal of lead by fire refining methods from copper of electrolytic quality is growing in importance. Particularly is this true of the refining of secondary copper and copper cathodes obtained from electrolytic cells where lead is used as the anode material, as in the electrolysis of ore-leaching solutions and foul electrolyte. When investigating the removal of small amounts of lead from molten copper in a reverberatory furnace during the refining of secondary copper of otherwise electrolytic copper quality,1 it was found necessary first to FIG. 1.-SAMPLING DEVICE. know something about the distribution of the lead throughout the bath. The authors believe that it is not generally known how small amounts of lead as an impurity are distributed in a molten copper bath; that is, whether the lead is concentrated at the bottom or at the top, or whether it occurs more or less uniformly throughout the bath. The data contained in this report may help, therefore, in the development of a satis-factory fire refining method for the removal of this obstinate element from a molten copper bath.

Jan 1, 1930

By Arthur Notman

THE year 1937 started off most hopefully for the metal industry but the prices for nonferrous metals declined after reaching a peak in the first quarter. E. & M. J. average prices for March were: -electrolytic copper f.o.b. refinery for domestic delivery 15.775c., lead 7.19c., and zinc 7.38c. There was the usual talk of shortages and the accompanying peak in the market prices of securities of producing companies. In retrospect it now appears that this was the peak of general security prices as well and of most commodity prices. On Dec. 1 copper was back to 11c., lead to 5c., and zinc to 5.5c. At the same time metal security prices had fallen to less than 40 per cent of their March highs. This has not been a purely domestic phenomenon. Metal prices have followed a similar course in London, in spite of the fact that in all three metals a tariff wall separates the domestic market from the foreign. There is nothing in the record to suggest that planning has so far had any stabilizing effect on prices. It is doubtful whether anybody will he found to claim credit for the planning. Strong evidence supports the conclusion that domestic demand for these and the other metals has been dammed back by the uncertainties confronting those who are considering long term construction commitments. This is particularly true with the public utilities, who are the largest consumers of copper and lead. If the plans were designed to maintain employment rather than to maintain political control of the Government, it would appear that they should be discarded. The course of the steel industry has been followed so closely in the press that no comment is necessary to indicate its similarity.

Jan 1, 1938

Graham Macfarlane, Louisville, Ky. (communication to the Secretary*):—In the paper by S. Whinery under the above caption mention is made of the occurrence of Clinton iron-ore in Kentucky and Tennessee. I believe that this is really a ferruginous limestone in what the Tennessee Geological Survey calls the Fernvale formation. In Davidson and Sumner counties, Tennessee, this occurs at about the horizon stated by Mr. Whinery. The maximum thickness of the deposit is from 10 to 12 ft., but it averages between 6 and 8 ft., lying practically horizontal. The Red River Furnace Co., under my direction, opened a mine in the Fernvale " red rock" near Goodlettsville, Tenn., several years ago. When it was first found we assumed it to be Clinton ore, but the absence of the characteristic Clinton fossiliferous structure and other evidence satisfied us that it is really limestone saturated with iron oxide. I think the very low ratio of SiO2 and Al2o3 to iron content as compared with the usual ratio in the Clinton ore is also evidence in favor of its being the Fernvale. The Tennessee Geological Survey states that at outcrops where this ore has been leached it carries about 44 per cent. of iron; under cover, from 20 to 25 per cent. of iron and from 3 to 6 per cent. of silica, the remainder being chiefly calcium carbonate. Its phosphorus content is irregular and generally rather high for a foundry-iron mixture. Since it is more than self-fluxing, we have at times operated with a mixture of brown hematite and red ore with no limestone.

Jan 1, 1913

S., at Niagara Falls, as an expert chemist. There he was engaged in perfect.ing the various kinds of gases, and while thus employed was gassed several times, which so affected his heart and lungs that he was unable to withstand an attack of the influenza which developed into pneumonia, from which he died at the end of 24 hours. He was a member of St. Luke's Episcopal Church, Lebanon, and belonged to the Ancient Accepted Scottish Rite of Freemasonry, Lebanon Lodge 121, I. 0. 0. F. and Camp 65, P. 0. S. of A. Lieutenant Bernhardt Edward Heine Bernhardt Edward Heine, a lieutenant in the Aviation Service of the U. S. Army, died as the result of a fa1I1 in an aeroplane at Fort Sill, Okla., on Aug. 10, 1918. The accident occurred on Aug. 2, when the machine in which he was flying with Lieutenant Carsons fell from a height of 1500 ft.; Lieutenant Carsons was instantly killed, but Lieutenant Heine died from his injuries a week later. Lieutenant Heine was born at Mount Clemens, Mich., in 1895. After attending the local High School he entered the Michigan College of Mines, and became a Junior Member of the Institute while still a student. He graduated in 1916, with the degree of B. S. In 1914 he served as a transitman for the engineering department of the City of Hancock, Mich. Lieutenant Heine had been in the army since 1916, having been with the 'troops at 'the Mexican border. He had been in the Aviation Section since August, 1917.

Jan 1, 1920

By K. C. Strebig, C. W. Schultz, A. A. Selim

For some time researchers have attempted to in- crease drilling efficiency (and therefore reduce costs) by adding certain chemical agents to the circulating medium. The effect of some organic additives on the diamond drilling of quartzite was recently investigated in the laboratory by personnel of the U. S. Bureau of Mines. In these tests, the penetration rate and bit life were found to increase with the use of additives. In addition, an economic analysis of a hypothetical 1000-ft hole showed that additives can reduce drilling costs by 30%. Wetting Agents Improve Drilling Efficiency Much of the interest in the use of wetting agents to improve drilling efficiency is the result of an observation made by Rehbinder, Shreiner, and Zhigach.1 These investigators postulated that drilling creates a region of increased crack formation directly below the bit and that a circulating medium that wets the rock will also penetrate the micro- cracks of the predestruction zone. Increasing the molecular affiinity (wetting ability) of these circulating media for the surface of the rock helps the deformation and destruction by softening the rock in the zone of increased crack formation. In this manner, the hardness or strength of the rock is decreased as the medium wets the rock in the predestruction zone. This is known as the "Rehbinder effect." Rehbinder's work has prompted many investigators to examine the relationship between the use of additives and the mechanical destruction of rock. Engelmann, Terichow and Selim reported that the maximum penetration of the rock by a diamond point in a solution environment was at the isoelectric point of the mineral and solution interface.2 Improvement in rock breakage with the use of additives was observed by Frangiskos and Smith.3 Joris and McLaren suggest that additives having a lower surface tension than water will also be more efficient in cooling the diamonds.4 Additives help remove fine cuttings from the face of the bit and improve efficiency. The latter two authors also report an improvement in impregnated bit life and penetration rates with the use of soluble oil additives. All of these investigations were initiated in the hope of discovering what economic benefits will accrue with the use of additives.

Jan 10, 1969

By H. C. Spaulding

The rapid increase, during the last few years, in the number and magnitude of applications of electric power-transmission to commer cial uses in this country, has been due principally to three causes: first, the ability and enterprise of those who have been identified with the progress of electrical industries, since electric illumination became an economic fact instead of a laboratory-experiment: sec ondly, the readiness of the American people to adopt new and ad vanced methods as soon as their superiority has been fairly demon strated; and thirdly, tile economy and flexibility of the apparatus employed, when properly designed and constructed, and installed under suitable conditions. Basing our judgment on the world's advance in scientific devel opments during the past century, we may reasonably conclude that in no other country would the pioneeis of electrical invention, whose names have now become household words, have received the prompt and plentiful financial support which has enabled them to inaugurate undertakings of exceptional magnitude, even in this era of tremendous monetary organizations. And, on the other hand, we have seen, in the numerous financial and engineering failures inseparable from such rapid development, the natural results of a too implicit faith in electrical omnipotence. It is not to be wondered at that conservative engineers have been slow to adopt this new and mighty agent in the solution of exten sive problems, and under circumstances where a single failure means not only a greater or less financial sacrifice, but the loss, in a greater or less degree, of professional reputation. Be mechanical engineer, while recognizing the fact that thousands of horse-power are to-day transmitted by electrical means, from sunning the lathe in a dentist's office to the operation of a fifty-ton travelling crane; from passing a cooling draught of air through a

Jan 1, 1891

By Kjell Lidin, Christer Nordström

INTRODUCTION LKAB produces iron ore in several mines in northern Sweden, and has been doing so for nearly 100 years. Total production to date is 600 million tonnes of finished products of various kinds (pellets, lump ore, fines). Close to 400 million tonnes have been produced by sublevel caving. This method has been the company's standard method for more than 20 years. A review of the development of equipment over the past 15 years and an outlook up to about 1990 leads to the following general re- flections concerning probable trends. Trends for all equipment are increasing precision and stricter environmental requirements will necessitate cabs, remote control etc to an increasing extent. Conventional sublevel caving can be broken down into the following unit operations: 1. Planning incl prospecting drilling. 2. Horizontal drilling. 3. Fan drilling. 4. Charging and blasting. 5. Loading and haulage at sublevels. 6. Ore drawing in chutes. 7. Rock reinforcement. 8. Production service. This lecture will deal in brief with each of these unit operations and the trends we are experiencing for them. A number of slides illustrating equipment

Jan 1, 1981

By Carl S. Westerberg

Coal preparation practice and trends follow, among other factors, production trends in any given area. Considering an area the size of a state, some broad predictions may be made after a review of the annual production records. As this paper is concerned with coal cleaning in Utah, data on its production record are pertinent. Table 1 shows the percentage relation of coal production in Utah to the national total as a single figure up to 1935 which includes all recorded production. From 1935 through 1947 these data are presented by years. It is evident from these data that the production of Utah coal is ascending. The reason for this trend is industrial growth in the West resulting in a population shift which accounts for more people than the normal increase would supply together with Utah's relatively fortunate geographical location and its abundance of good-quality coal. Utah is also hopeful of supplying more coal in the future for West Coast power generati0n.l

Jan 1, 1949

By AIME

DURING the Revolutionary War an iron mining industry was born in the Adirondack region of New York State. New York State ores provided the iron from which were forged the links of the chain that, strung across the Hudson River, successfully kept British vessels from ascending. The industry flourished for a while and then became dormant. For the successful prosecution of World War II, the magnetite mines were revived and given considerable aid in the form of government financial support. The complete story appeared in a special issue Of MINING AND METALLURGY published in November 1943. Now, almost four years later, it is interesting to see that these "war babies" were not really such but are well-established enterprises with a bright future. A ten-day trip through the Adirondack region and to St. Lawrence County dispelled all thoughts that mining in northern New York State is a transitory industry. In addition to substan-

Jan 1, 1947

By Carl M. Fellman

LABOR disputes caused considerable turbulence in the coal mining industry during 1946. As an outcome of these disputes, a definitely fundamental change in safety procedure was instituted: establishment of safety regultions for coal mines through the agency of agreements between the miners' union and the agency or agencies operating the coal mines. Although a temporary plan at present, the future will determine the. extent to which it may become permanent. Notwithstanding the turmoil in the industry extending through much of the year, the safety record for the first eleven months of 1946 was the best in the history of the industry for that period. The fatality rate for 1946 is lower than in any other year in the history of coal mining in the United States. This follows a pattern inasmuch as new low coal-mine fatality records were also made in 1945, 1944, and 1943. The five-year period 1942 to 1946 inclusive has a coal-mining fatality rate far lower than any other five-year period in the history of the industry. It is significant that this period exactly coincides with the operation of Federal coal mine inspection which got under way early in 1942.

Jan 1, 1947

By RALPH HAYES SWEETSER

ONE per cent. of ash in a ton of coal has been so little considered that in many circles it has been positively ignored. Even P. T. Barnum had never heard of it, or he would have had one on exhibition alongside the Cardiff Giant and the White Elephant. One per cent. of ash is closely related by both those freaks of Barnum in that it is "stone" and, in its aggregate, it is the greatest "White Elephant" that the American public now supports. Some of you may have paid Mr. Barnum for a look at the "petrified man" (named the Cardiff Giant by the gullible wise men of the early seventies); but it is certain that everyone of you is now paying for the support of the great White Elephant that is being constantly carried by our railroads all over the country-at the public's expense. " One per cent. of ash in a ton of coal" requires 120,000 open-top railroad cars each year to transport this use- less stone giant from its native bed in the coal seams of the bituminous regions to the coal bins of the consuming public.

Jan 1, 1924

By O. C. Wheeler

During 1938, Colombia witnessed greater activity in oil prospecting and development than in any previous year in its history; more wells were drilled, more potential production established, more geological and geophysical work was accomplished, and more leases and concessions were acquired. Many companies, including the Texas, Socony Vacuum, Richmond (subsidiary of the Standard Oil of California), the Shell, and Tropical, contributed to this activity. Probably the most noteworthy development was in connection with the Barco Concession, which forms part of the Maracaibo Basin in eastern Colombia, adjacent to the Venezuelan frontier. There a great deal of preparatory work was accomplished in addition to camp and other construction, 20 producing wells were drilled and work was begun on the construction of a 12-in. pipe line to transport the oil to the port of Covenas, a distance of 260 miles. It is reported {hat 58,000 bbl. daily initial production was established during the year and is awaiting an outlet through this pipe line. Leasing and exploratory operations in Colombia continued active throughout the year; applications were made for concessions covering more than 1,100,000 acres of national lands and, in addition, leases were taken up on large areas of privately owned lands. Under Colombian law

Jan 1, 1939

By O. C. Wheeler

During 1938, Colombia witnessed greater activity in oil prospecting and development than in any previous year in its history; more wells were drilled, more potential production established, more geological and geophysical work was accomplished, and more leases and concessions were acquired. Many companies, including the Texas, Socony Vacuum, Richmond (subsidiary of the Standard Oil of California), the Shell, and Tropical, contributed to this activity. Probably the most noteworthy development was in connection with the Barco Concession, which forms part of the Maracaibo Basin in eastern Colombia, adjacent to the Venezuelan frontier. There a great deal of preparatory work was accomplished in addition to camp and other construction, 20 producing wells were drilled and work was begun on the construction of a 12-in. pipe line to transport the oil to the port of Covenas, a distance of 260 miles. It is reported {hat 58,000 bbl. daily initial production was established during the year and is awaiting an outlet through this pipe line. Leasing and exploratory operations in Colombia continued active throughout the year; applications were made for concessions covering more than 1,100,000 acres of national lands and, in addition, leases were taken up on large areas of privately owned lands. Under Colombian law

Jan 1, 1939

By C. P. Miller

In order to determine the usefulness of geochemical and biogeochemical prospecting for nickel, ten localities representing several types of nickel occurrences were selected as sites from which to collect plant and soil samples. This report covers the investigations in two of the areas. After a brief geologic description of the areas, the author presents details of the experimental tests and resulting data. Conclusions drawn from the studies led to several general guides for further prospecting. In a study of the usefulness of geochemical and biogeochemical prospecting for nickel made about three years ago, approximately ten localities, representing several different types of nickel occurrences, were sampled and about 1500 samples of plant and soil were collected. This report will cover briefly the data and results for two areas, and a summary of guides for prospecting. DESCRIPTION OF AREAS SAMPLED One locality is the Red Flats nickel prospect in Curry County, Ore., about six miles southeast of Goldbeach, and the other is the Little Rocky Creek prospect in Stillwater County, southcentral Montana, just southeast of the Benbow chromite mine. The Oregon area is a lateritic-type nickel deposit formed on a nickel-rich serpentinite peridotite complex, similar to the Josephine intrusion in southwestern Oregon. The Montana area is a nickel prospect in norite, peridotite, and related rocks of the Stillwater igneous complex. The Stillwater complex is a series of layered basic and ultrabasic rocks, with a layer of norite-gabbro at the base and a series of peridotites and gabbros above. The nickel in the Oregon deposit occurs in both the peridotite and the overlying soil. A deep lateritic soil is developed locally on the peridotite and serpentinite and constitutes the ore. The average nickel content of the lateritic soil is less than 1 pct, whereas the nickel content of the weathered peridotite is about 1 to 1.5 pct. The nickel occurs as garnierite (Mg, Fe, Ni, Mn)3 (OH)4 (SiA1)2O5 in the soil and in the olivine and pyroxene in the peridotite where it probably substitutes for Fe2+ or Mg2+ in the silicate lattices. Nickel is found in three distinct ways in the Still-water rocks: 1) it is in the olivine and pyroxene minerals in norite, harzburgite, etc.; 2) it occurs as widely disseminated grains of pentlandite-pyr-rhotite, which tend to be concentrated in the lower norite band; and 3) it occurs as discrete bodies of pentlandite-pyrrhotite and chalcopyrite which are localized in the norite zone, close to the contact with the underlying rocks. The nickel content of the norite is probably less than 1 pct, and the nickel content of the pods and lenses within the norite is about 1 pct. PROSPECTING APPROACH Although the areas are different geologically, the approach in prospecting them is fundamentally the same. The procedure is twofold: 1) a rapid reconnaissance survey to outline an area of high nickel content, and 2) a more detailed survey to outline zones of possible ore grade within the area of high nickel. The possible ore at Red Flats is concentrated in the lateritic soil, whereas at Little Rocky Creek it is in the sulfide pods. Both types are surrounded by an area of relatively high nickel content. CHEMICAL ANALYSIS Chemical analyses of nickel were made by a di-methylglyoxime colorimetric test, similar to the standard test for nickel, utilizing concentrated sul-furic acid for extraction. The lower limit of detection for nickel in soil by the method used was about 10 ppm and for nickel in plants about 5 ppm. The relative deviation was about 25 pct. SOIL PROSPECTING General Statements: A summary of the approximate average parts per million of nickel in soil, as compiled from the literature and from my study, is given in Table I. Selected references are given at the end of the paper. Few of the investigators reported the type of extraction or analysis, so the data given may not be strictly comparable to mine, which were made with a sulfuric acid extraction. Any nickel concentration greater than these average values might be considered anomalous, although each area must be studied in relation to the surrounding rocks. Method of Soil Sampling: The soil samples were taken in a zone from 1 in. to 1 ft below the humus layer, and within a 15-ft radius around a station.

Jan 1, 1961

By George W. Sears

In preparing this symposium, our ambition was to elicit authoritative expression of opinion concerning important selected phases of the industry from men active in it. Responses to requests for contributions were gratifying, especially so in view of the short time available. The generous and cooperative spirit of the industry as a whole is amply evident. Responses were received from the following, who are therefore the true authors of the paper: W. G. Adamson, General Manager of the pershin; Quicksilver Co., Lovelock, Nev.; Dudley Baird, Vice President, Pacific Foundry Co., San Francisco; Walter W. Bradley, State Mineralogist of California; W. D. Burcham, General Manager of the Brewster Quicksilver Consolidated, Terlingua, Tex.; William Forstner, San Francisco; H. W. Gould, of H. W. Gould & Co., San Francisco; Marcus Hulings, General Manager of the Chisos Mining Co., Terlingua, Tex.; Frank J. Katz, Chief Engineer, Division Mineral Statistics, United States Bureau of Mines, Washington, D. C.; Lloyd J. Lathrap, Superintendent, Nevada Quicksilver Mines, Inc., Lovelock, Nev.; W. R. Moorehead, General Manager, New Idria Quicksilver Mings, Inc., Idria, Calif.; F. W. Oakes, Jr., Terlingua, Tex.; C. N. Schuette, San Francisco. Brief Economic History of Quicksilver in the United States Quicksilver ore was first discovered in the United States at what was later the New Almaden mine in California, in the year 1824. Production also began here, but not until 1850, when it was stimulated by the active demand caused by gold-mining operations. Prospecting for quicksilver was active, high-grade ores were found and ample production lowered the price from $100 per flask in 1850 to about half that figure for the greater part of the next 10 years. During the succeeding decade, many new quicksilver mines were found; production increased at a time when the local demand diminished, so that most of the product was exported. The third decade of quicksilver mining in the United States witnessed the development of the pan amalgamation process, particularly in Com-stock silver-mining operations. A suddenly increased demand sent prices soaring, the all-time peak of quicksilver production followed, and the highest price was soon replaced by the lowest one on record. Huge quantities of quicksilver were exported between 1870 and 1880 and exports continued in decreasing measure for three decades to 1910. In

Jan 1, 1930

By H. M. Cyr, T. F. Steele, C. W. Siller

The development of a new metallurgical roasting device is described. It consists of a refractory column into which air is injected at various levels, forming several superimposed fluidized beds with no supporting grates. When pelleted zinc sulphide concentrates are charged, the roasted product needs no further sintering before reduction to metal. WHEN a gas such as air is blown upward with increasing velocities through a loose mass of solid particles, marked changes in the physical behavior of the particles are noted. At first, when the velocity of the gas is insufficient to support any of the solid, the mass constitutes a "fixed bed." As the gas velocity increases until the pressure drop through the bed approaches the effective weight of the bed per unit area, the bed expands until the solid particles are supported by the air rather than by the lower particles. Some vibration of the particles becomes apparent, but little mixing occurs. This condition is called a "quiescent fluid bed." A further increase in gas velocity imparts more separation and more motion to the individual particles until a condition of turbulence is reached. This "turbulent fluid bed" resembles a rapidly boiling liquid with the characteristic highly agitated diffuse surface and many small eruptions of the boiling mass. Different degrees of turbulence can be generated and all produce excellent mixing. The final stage occurs when the gas velocity becomes so great as to create a "dispersed suspension." Here no surface of the mass is defined and the gas carries solid particles out of their original positions. These changing conditions of fluidization have been studied carefully and pertinent nomenclature standardized by a committee of the American Institute of Chemical Engineers.' Many mathematical analyses2-3 have been made of the forces acting in a fluid bed. These analyses are invaluable, especially for the design of column sizes and selection of equipment. However, in a metallurgical process involving solids of many sizes with changing densities, varying temperatures, and changing gas compositions within the bed, calculations based on theory become approximate. Optimum operating conditions then are best determined experimentally. Many applications have been made of the principles of fluid-bed action by mechanical, chemical, and metallurgical engineers. Especially when good con- tact between reacting solids and gases is desired, very effective results are obtained from fluid beds. They permit excellent temperature control and uniformity throughout a mass of solids in fluid action. Heat transfer to walls and any coolers is high, and fast reaction rates are attained because the solid surfaces are continuously swept clean. The main disadvantages of fluid-bed operations are the danger of short-circuiting in a single bed, danger of incipient sintering which stops action, the necessity of avoiding large changes in particle size or density during roasting, and dust losses when particles of the charge are carried out with exit gases. In the metallurgical field the roasting of sulphide ores to form oxides and sulphur dioxide appears to combine several operating conditions which can be achieved to advantage in a fluid bed. Roasting involves a solid-gas reaction where a high reaction rate is necessary for high capacity, where good temperature control is important in order to prevent sintering, where good heat transfer is needed, and where the density of the solids, when changing from sulphides to oxides, is not largely changed. Short-circuiting, however, constitutes a major problem when a single fluid bed is used. Because of the turbulence of the bed, an entering particle may be in the region of the discharge before it is roasted. Hence, to attain a satisfactorily low sulphur in the calcine, a long average residence time with correspondingly low capacity is required. The solution to this difficulty is the use of multiple stages, which in the conventional fluid-bed design requires separate hearths with feed and discharge mechanisms for each stage. A further practical difficulty in fluid-bed roasting of flotation zinc concentrates is their fine particle size which makes a true fluid action without excessive carry-over of dust very difficult to attain, especially when the large air volumes necessary for high capacity are used. A New Design After considerable experimentation in the laboratory and on a semipilot-plant scale, a new method and equipment for roasting were devised which provided a unique solution to these problems. A detailed account of this development appears in the patent literature," and many of the variations of this development reported herein are the subject of

Jan 1, 1955

By L. C. Reese

The ultimate resistance against a rigid cylinder which is moved laterally in a cohesionless soil is a function of the geometry of the cylinder and the properties of the soil. An approximate method is developed for computing this resistance and is tested against results of laboratory experiments. Satisfactory agreement between the method and experiment was obtained. Not only was the ultimate resistance against the cylinder measured, but measurements were made of the shape of the rupture surfaces. These measurements should allow the development of a more rigorous computation procedure. INTRODUCTION A critical aspect in the design of offshore drilling platforms is assuring the stability of the platform during a hurricane. The large horizontal loads from waves and wind make a severe loading condition. Piles are generally employed as the foundation since they can be effective in resisting both horizontal and vertical loads. Spuds are sometimes used with a mat foundation, where the spuds are designed principally to resist horizontal loads and the mat designed principally to resist vertical loads. The research reported in this paper is related to one aspect of the problem of laterally loaded piles or spuds in sand. The complete solution to the problem of the laterally loaded pile in sand would require the prediction of soil resistance against the pile as a function of pile deflection; only the ultimate resistance against short piles is considered in this paper. A considerable amount of additional research will be necessary in order to obtain a complete solution to the problem of the laterally loaded pile in sand; however, the work reported here should be useful as a guide in the performance of some of the additional research. ULTIMATE LATERAL RESISTANCE AGAINST A LONG FALL IN SAND To aid in the understanding of the theory which is developed for a cylinder, the theory for earth pressure against a wall is reviewed. In Fig. l(a), a long wall of height H is shown embedded in soil. Soil resistance will develop as the wall is deflected, and the soil resistance will increase with deflection until some limiting value is reached. In this discussion, and those following, it is assumed that all points on the wall deflect equal amounts. A possible shape of the real curve which relates soil resistance to deflection is shown by the dashed line in Fig. l(b); however, as a means of simplifying the discussion, an idealized curve (shown by the unbroken lines) is drawn. If such a wall as this were furnishing the horizontal support for an offshore structure, the dashed curve in Fig. 1 would be the information needed in performing a foundation analysis, with the idealized curve possibly being an acceptable substitute. For the idealized curve, the soil resistance is linear with deflection for the early portion of the curve such that