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By Ray W. Arms

The combination wet and dry coal-cleaning process is not an attempt at a compromise between the wets and the drys nor is its merit confined entirely to the limitation of moisture in the smaller sizes. It is more correctly, and more broadly, an application of the sized-coal cleaning principle adapting itself in an ideal fashion to present day multiple-size preparation practice. The purpose of this paper, therefore, is to call attention to the broader significance of the term "combination wet and dry process" and to mention some of the factors that govern its application. In the narrow sense, when considered apart from the sized-coal cleaning principle, the combination process finds its justification chiefly in the ability to limit the moisture in cleaned coal. Larger sizes of coal offer less superficial area compared with their bulk for the attraction of moisture films. They drain more readily in bins or railroad cars, having more interstitial space for the free flow of water. Therefore, they neither attract nor hold objectionable moisture percentages. In fact, there is so keen a demand for certain washed sizes containing some moisture that hygroscopic salts such as calcium chloride are applied to attract and retain it. When coal deliveries are made on a guaranteed moisture percentage the coarser sizes may be washed and mixed back with the fines without adding greatly to the original moisture but the fines must be dry cleaned or dried to control moisture. Thus in all respects moisture in the coarser sizes is less objectionable than in the fines. The implication of this statement, that moisture is always more or less objectionable, is true. It is safe to say that if dry-cleaning apparatus could be perfected to a point at which its technical results, cost and other aspects would be equal to wet washing, water would no longer be used. As it is, we find that good technical results are more difficult to obtain by dry cleaning than by water. Obviously the use of air tables for coarse coal is not ideal, for it involves the attempt to stratify material in a thin bed on a table surface when the load is only one particle deep. Furthermore, the various air cleaning tables on large sizes require a large volume of air for separation, more power to operate, more dust-collecting apparatus and involve more coal breakage.

Jan 1, 1931

By Rossiter W. Raymond

It is scarcely necessary to augment or amend the "Appreciation" of Dr. Douglas, from the pen of Dr. Albert A. Ledoux, which appeared in January, 1916, in Bulletin No. 109 of the Institute. The author of that admirable summary enjoyed the great privilege of expressing while Dr. Douglas was yet among us (though already marked for death) the love and esteem with which we all regarded him. But now that his earthly life has ended, the historian must still be the eulogist. No line need be added or deleted in the portrait of him already drawn; it has only to be accepted now as a true likeness, and hung in the gallery of the immortals, illuminated by the crowning glory of another world. James Douglas was born at Quebec, Canada, November 4, 1837. His father, James Douglas, was a distinguished physician and surgeon, known in many lands, especially in the Orient, and famous in his own country for his philanthropy as well as his skill, having established and directed for many years the first retreat for the insane in the Dominion. of Canada. One of the latest literary labors of the son was the editing and publishing of his father's journal and reminiscences—a fascinating volume, the review of which, though a tempting task, I must here forego. Nearly fifty years ago, I had the great pleasure of spending an hour with the elder Douglas, who guided me through his collection of Egyptian and Asiatic treasures. I might almost say souvenirs; so many of them were connected with personal experiences and exalted personages. The veteran's memory had already begun to fail with age, but his vivacity and imagination glowed all the more brightly; and his reminiscences of travel and adventure were embroidered with Oriental magnificence. I felt, after that hour, as if I had visited a stately, half-ruined edifice, overgrown with vines and flowers. The father's genius, adventurous spirit and generous philanthropy descended to his versatile, yet practical son. Like other men of such temperament, James Douglas tried many things before circumstances beyond his own control forced him into the line of his principal lifework. At the age of 18, he was sent to the University of Edinburgh, where he studied for two years. Returning to Canada, he entered Queen's University, at Kingston, Ontario, where he was graduated as Bachelor of Arts in 1858. Subsequently he studied medicine at Lava1 University, Quebec;

Jan 1, 1919

By Rossiter Raymond

IT is scarcely necessary to augment or amend the "Appreciation" of Dr. Douglas, from the pen of Dr. Albert A. Ledoux, which appeared in January, 1916, in Bulletin -No. -109 of the Institute. The author of that admirable summary enjoyed the great privilege of expressing while Dr. Douglas was yet among us (though already marked for death) the love and esteem with which we all regarded him. But now that his earthly life has ended, the historian must still be the eulogist. No line need be added or deleted in the portrait of him already drawn; it has only to be accepted now as a true likeness, and hung in the gallery of the immortals, illuminated' by the crowning glory of another world. . James Douglas was born at Quebec, Canada, November 4, 18:37. His father, James Douglas, was a distinguished physician and surgeon, known in many lands, especially in the Orient, and famous in his own country for his philanthropy as well as his skill, having established and directed for many years the first retreat for the insane in the Dominion of Canada. One of the latest literary labors of the son was the editing and publishing of his father's journal and reminiscences-a fascinating volume, the review of which, though a tempting task, I must here forego. Nearly fifty years ago, I had the great pleasure of spending an hour with the elder. Douglas, who guided me through his collection of Egyptian and Asiatic treasures. I might almost say souvenirs; so many of them were connected with personal experiences and exalted personages. The veteran's memory had already begun to fail with age, but his vivacity and imagination glowed all the, more brightly; and his reminiscences of travel and adventure were embroidered with Oriental magnificence. I felt, after that hour, as if I had visited a stately, half-ruined edifice, overgrown with vines and flowers. The father's genius, adventurous spirit and generous philanthropy descended to his versatile, yet practical son. Like other men of such temperament, James Douglas tried many things before circumstances beyond his own control forced him into the line of his, principal lifework. At the age of 18, he was sent to the University of Edinburgh, where he studied for two years. Returning to Canada,, he entered Queen's University, at Kingston, Ontario, where he was graduated as Bachelor of Arts in 1858. Subsequently he studied medicine at Laval University, Quebec;

Jan 9, 1918

By Eugene P. Pfleider

Research indicates that the cube diamond is a superior stone for drill bits. It can be oriented to combine a long cutting edge with structural strength and high resistance to wear. Test bits set with preferred orientation give double the bit life at astoundingly low diamond loss in comparison to oriented octahedral diamonds. A PROGRAM of research on the orientation of diamonds in drill bits has been under way for several years at both the United States Bureau of Mines Experimental Mine at Mount Weather, Va., and the School of Mines and Metallurgy of the University of Minnesota. Reports on past work done both in the laboratory and the field are available in the technical press.1,3,4 The results of such drilling, done under comparable conditions, show that bits having diamonds oriented in a direction that combines structural strength and greatest hardness not only can advance somewhat faster than random set bits but can do this with a unit diamond loss of 50 pct or less. Several bit manufacturers have initiated the training of diamond setters in the principles of orientation on the basis of the above-mentioned research results. The basic information on the crystallography and hardness variation of the diamond was presented in an earlier paper,' which pointed out that the diamond is several hundred times harder along certain directions and certain faces than on others. The same article discussed the drilling results obtained with a group of nine bits having octahedron diamonds set with on-point, positive (gouge) rake, and negative (drag) rake orientations. The testing of oriented cube diamonds is an extension of this research program, employing the same procedures and equipment (Hy Mac hydraulic drill unit, EXT diamond core bits, St. Cloud Pink granite) as previously described. This current work covers the test experience of seven bits set with cube diamonds running approximately 10 stones per carat. The individual stones were near perfect cubic form; hence it was simple to orient them in any desired direction. The cube is a comparatively rare crystal form of the diamond, although considerable numbers are produced from the Congo. It is understood that most of the cube diamonds are retained in Africa, where they are either used locally for diamond bit manufacture or ground up to make powder. They have been considered to be an inferior stone for drilling purposes.

Jan 1, 1954

By David White

While a country is small and its coal fields are not many, it may be possible to classify its coals on some basis that avoids both overlap and inconsistency, and that may be satisfactory to the particular country, such as geographic distribution or geologic age, or regional uses. In the adjoining country, however, the coals may differ more or less; broad areas may have escaped the erasure of transition zones by erosion, and the stages of alteration of the coals may lead to a classification different from and even incompatible with that of the other country. Such classifications, developed primarily along national lines, are essentially opportunistic. Further, many even of the "use" terms that have been in more common employment with a degree of international application have lost their significance and value, due to changes in industrial methods and urban life. When the number of coal fields is large and the classification is designed to cover the coals of many countries, the groups or divisions into which the coals are integrated are found to verge one into another; and, though the main divisions may be so naturally composed and oriented that they are relatively distinct and readily separated as entities or units when taken by themselves, the sequence, through classes, groups, and subdivisions, is so complete that we find transition zones through which boundaries must be arbitrarily drawn with minute technical definition. This situation, which is conspicuously illustrated in the United States, is due to the progressive evolution of all coals, irrespective of geologic age, from peats to successively higher ranks, which, if the progressive alteration goes far enough, ends with graphite. This evolution is now firmly established and its complete acceptance is but a matter of time. A classification of all coals in all coal fields can not escape this fact and must take into account all the stages in the transformation of the fuel from rank to rank through division to division, and through group to group. The plan here outlined aims at a natural classification of coals based on their evolution from peats to graphite. As in other classifications, the differentiation of the various groups and divisions takes account of changes resulting from the progressive losses of moisture and .of oxygen of constitution; the relative conservation of carbon; the progressive increase in fixed carbon (inverse to the loss of volatile matter) in

Jan 1, 1930

By M. H. Richman, E. S. Meieran

An analytical method is presented which enables the electron diffraction patterns from a twinned region to be indexed. The method has only been applied to (112) twins in bcc lattices, but can easily be adapted to other types of twinned lattices. Calculations of all twin spots, including those superimposed on matrix spots, is made possible by this method. SINCE the advent of transmission electron microscopy, the analysis of selected-area electron diffraction patterns has become very important in the interpretation of electron micrographs. Frequently, as in the case of some martensites, twinned areas are observed and give rise to complex diffraction patterns, which so far can be analyzed only for the simplest orientations of the thin foil specimen with respect to the electron beam. In order to simplify the analysis of twin patterns of more complex orientations, an analytical method was devised which is capable of predicting the positions of all reflections from both matrix and twin regions for all possible foil orientations. Although the method has only been applied to the case of bcc metals twinned about a (112) plane, it is equally applicable to other Bravais lattices. This method has been successfully applied to selected-area electron diffraction patterns of Fe-Ni and Fe-Ni-C martensites and drawn tungsten wire. PROCEDURE Imagine the reciprocal lattice corresponding to a bcc material, with each point hkl representing the crystallographic plane (hkl). Since the extinction conditions require that for this lattice, only reflections where h + k + 1 = even integer are allowed, the three dimensional reciprocal lattice is actually fcc. Since in real space twinned regions and matrix regions are mirrored across a (112) plane, the twinned reciprocal lattice is derived from the matrix reciprocal lattice by a rotation of 180 deg about a (112) direction. While it is possible to calculate how a point hkl will shift under a twinning transformation to a new point htktlt using only the reciprocal lattice based on the orthonormal vectors [100], [010], and [001], the calculations are greatly simplified if a new orthonormal coordinate system containing the twin axis is introduced. The twinning operation then becomes a simple rotation of 180 deg about a principal coordinate axis (in this case the twinning axis), and a retransformation back to the original reciprocal space will give the position htktIt of the twinned reflection.

Jan 1, 1963

By F. G. Miller

The washabilities of typical bituminous coals are discussed in an effort to illustrate the importance of determining, by a complete washability study, the sulfur forms and their distribution in a coal. This study will then show the extent to which the sulfur can be removed. It should be emphasized that each potential application requires a thorough study because of the varying amounts of sulfur in different coals. It is not the intent of this paper to show the best results that flotation can produce, but rather to illustrate the potential of this process and point out the importance of improved flotation techniques where sulfur reduction is involved. It is generally accepted that sulfur exists in coal in three forms: (1) pyritic, (2) organic, and (3) sulfate sulfur. Sulfate sulfur usually makes up less than 1% of the total sulfur content. Pyritic and organic sulfur make up almost all of the total sulfur content, occur in varying amounts in different coals, and can vary greatly in coal of the same seam. Pyritic sulfurs of 20% to 80% of the total sulfur have been reported. Other authors have shown that it is not possible to remove the organic sulfur without chemically altering the coal. Chapman and ones' state: "Organic sulfur, unlike pyritic sulfur does not exist as discrete particles, but is intimately associated with the coal structure, and as such it is not possible to remove it or reduce its concentration by physical means." Any success in removing sulfur has come about by removing pyritic sulfur by physical means; therefore, removal of sulfur in the pyritic form is the subject of this investigation. The extent to which any impurities can be removed from a particular coal can be determined by a washability study. Outside of crushing coal to finer sizes or chemically altering the coal, there are no known methods of changing this inherent washability characteristic. The efficiency of various methods used to remove impurities can be determined by comparison of results produced at a yield to the results as shown by a washability study. In recent years heavy media processes have proven their ability to wash plus 28 mesh coal and nearly produce results shown to be theoretically possible by the washability study. Therefore, it is the objective of this paper to show various methods of treating the finer fractions of the coal, in the hope of developing

Jan 1, 1964

By I. H. Pratt

The results of a study on the preparation of thin-film capacitor structures are discussed. The dietectric source material was quartz which was sputtered and deposited onto aluminum electrodes and counter-electroded to complete the metal-oxide-metal structures. This configuration was utilized to evaluate the dielectric, the device characteristics, and related process parameters. The effect of gas sputtering pressure, magnetic field strength, source-to-substrate distance, and power density on the rate of deposition is shown. Increased film thickness uniformity over a 3 by 3 in. area by optimum substrate positioning is indicated. Dielectric constant, dissipation factor, dielectric breakdown strength, insulation resistance, heat treatment, capacitance, and dissipation over the range 400 Hz to 5 MHz are reported. In the fabrication of silicon-integrated circuits, silicon dioxide has found use as a material suitable as a diffusion mask, for surface passivation of the silicon, and for protection of conductive films used for interconnections. Its use as a dielectric for thin-film capacitors in film hybrid circuits has been limited, to a degree, for lack of a compatible processing technique and because of its relatively low dielectric constant. With the recent advent of practical metal-oxide-semiconductor (MOS) field effect devices, the material is now being used to insulate the gate electrode from the conducting channel in the silicon. In this latter application, more stringent requirements have been imposed on .the oxide. A comprehensive resume of the use of silicon dioxide in integrated silicon device technology has been compiled including oxide film and bulk properties, method of oxide formations, and their applications.' A relatively new process to deposit SiO, and other dieIectrics is by rf sputtering, and the purpose of this paper is to describe the behavior of capacitors fabricated with a dielectric which has been sputtered from a quartz target and to indicate the relative effect of several of the process parameters on the film deposition. Work on rf sputtering of SiO2 and other dielectrics has been reported utilizing a triode type of sputtering system as described herein or a diode self-sustained glow discharge system. 2-8 SPUTTERING The process occurs during an electrical discharge in a gas plasma which provides the ions for acceleration to the target to produce the desired sputtering. The necessary plasma can be generated by a dc glow discharge through application of a high potential between two electrodes at approximately 2 to 10 x 10-2

Jan 1, 1969

By Pieter W. Greeff, Graeme W. Mitchell

INTRODUCTION This paper describes the underground environmental planning parameters developed for Pancontinental Mining Limited's Jabiluka uranium deposit. The deposit is located 230 km east of Darwin in the Alligator Rivers region of the Northern Territory, Australia. The deposit is situated within land subject to an Aboriginal land claim, adjacent to a National Park and within a proposed extension to that National Park, as well as being close to a long- established Aboriginal reserve. In addition, being the first large underground uranium mine planned in Australia, the environmental considerations, both on surface and underground are considerable. Pancontinental is committed to the highest practicable standard of environmental management in the operation of the mine. In addition, Government regulations and requirements are particularly stringent by world standards. The underground environmental problems are discussed later in the paper with emphasis placed upon radiation aspects, both gamma and radon daughters, and dust. Consideration has also been given to heat and humidity due to the location of the deposit in a sub-tropical region 12° south of the equator. The paper explains how these environmental factors influence the design and selection of stoping methods. GEOLOGY AND ORE RESERVES The Jabiluka Two orebody is completely overlain by flat-bedded Kombolgie Sandstone with a thin layer of surficial colluvial sands. The orebody occurs in an east-west striking folded succession of Lower Proterozoic metasedimentary rocks of the Cahill Formation. Uraninite and pitchblende constitute essentially all the uranium mineralisation and are contained in the four lithological series, as shown in Fig. 1. - ,Upper Graphite Series - Main Mine Series - Lower Mine Series 1 - Lower Mine Series 2 The succession at Jabiluka has been folded and forms an east-south-east striking, asymmetric syncline-anticline which dips south and plunges to the east. A major fault bisects Jabiluka Tw8 having a north-south trend and dipping about 80 to the west. A near vertical tourmaline granitic pegmatite dyke up to 30 m in thickness has intruded the Jabiluka Two orebody at the western end. Current drilled ore reserves for Jabiluka Two are 52.0 million tonnes at 0.39% U308. Included in these reserves are 1.1 million tonnes of gold ore at 10.7 g/tonne. A large proportion of the orebody can be mined in thick sections (over 80% of tonnage) either as single sections or by bulking a number of thin sections which are close together.

Jan 1, 1981

By W. H. Young, P. D. Torrey

The Eastern fields comprise a distinct geological and geographical unit, located in the northern part of the Appalachian geosynclinal prov-ince. In this area are the fields of New York, producing from rocks of Devonian, Silurian and Ordovician age; the fields of western Pennsylvania, where oil and gas occur chiefly in rocks of Mississippian and Devonian age; the fields of eastern Ohio, where oil and gas are obtained from rocks of Pennsylvanian, Mississippian and Silurian age; and the fields of West Virginia, where oil and gas are produced from rocks of Pennsylvanian, Mississippian and Devonian age. Many of these fields are of great antiquity in comparison to the age of the producing areas in a greater part of this country, and consequently in most instances it is impossible to obtain accurate historical statistics. In addition, the records of many of the more recently discovered fields are either unobtainable or are not sufficiently reliable to justify their incorporation in a review of this character. Rather than overemphasize certain fields and areas, where complete records are available, when there are many other fields of equal importance for which statistical data are not available, the authors have made a tabulation of development that does not take into consideration past operations and production. The records utilized in preparing this paper were derived largely from the scout reports of several of the larger companies, which generously made them available to the authors. These were independently tabulated by counties and townships, in order to eliminate as far as possible duplications and, excepting the Clinton fields of Ohio, where many of the smaller wells have not been individually reported, they represent the most accurate information available. Market conditions in both the oil and gas industry were far from favorable during 1932 and in consequence there was a total decline in drilling in the Eastern States, which is 22 per cent less than the number of completions in the preceding year. This decline was not constant over the entire area, as is shown in Table 1. The oil fields of both New York and western Pennsylvania were the scene of renewed drilling activity, which was largely restricted to the water-flooding operations in the Bradford and Allegany fields. Practically no new operations were started, but a certain number of new wells

Jan 1, 1933

By G. V. Raymor, James T. Waber, I. Rex Harris

The lattice parameters of a series of fcc alloys of cerium and thorium were measured at 93 " and 298OK. Lattice parameters were also estimated for 171OK. Substantial deviations, y, from Vegard's law were observed. Although y was negative at the two higher temperatures, it was positive and large at the lowest temperature. A variety of models, which have been proposed in the past, were considered, and the calculated values of y were compared with the observed values. The best agreement was achieved with values computed with Friedel's equation. THE purpose of this investigation was to determine the effect of temperature on the lattice parameter and on deviations from Vegard's law of Ce-Th alloys. A large negative deviation from Vegard's law was first observed independently by Weiner, Freeth, and Raynor' and Van vucht2 in the room-temperature lattice parameters of Ce-Th alloys that form a continuous series of solid solutions. This observation was confirmed by Evans and Raynor. The allotropy of unalloyed cerium was reviewed recently by Gschneidner, Elliott, and McDonald. In two subsequent papers,5" these authors reported the influence of various alloying additions on the y= transformation, which occurs below room temperature. Although other rare earths tend to stabilize the double-hexagonal phase, thorium, plutonium, and scandium as solutes tend to stabilize the normal fcc phase. With addition of sufficient thorium as a solute, there is evidence that the formation of is suppressed and it becomes possible to pass continuously with decreasing temperature from the room-temperature phase to the fcc a phase. Thus there is a closed loop which is similar in many ways to the y loop well-known in ferrous alloys. A closed field also occurs in the pressure-temperature "equilibrium" diagram of unalloyed cerium. Because of interest in the effect of thorium additions and their influence on the a and phases, lattice-parameter measurements were made at low temperatures on the fcc phase for a series of alloys ranging from 10 to 90 at. pct Th. The results obtained at three temperatures are shown in Fig. 1. Evans and Raynors analyzed the deviations from Vegard's law in Ce-Th alloys in terms of changes in the occupancy of the 4f electron level in cerium,

Jan 1, 1964

By J. H. McCormick

This plant, near Marysville, Mont., was planned to treat the ore from the Piegan and Gloster mines, the latter being one of the early and famous producers of the Marysville district. When the mill was closed in 1888, treatment consisted of stamp milling, followed by pans and settlers for pan amalgamation. The extraction was evidently poor, because, a few years later, thousands of tons of tailings were re-treated by the ranchers in the valley below the mill, by the then new cyanide process, and gave a handsome profit. In 1914, the present owners, after laboratory tests and an experimental mill run, decided upon the following treatment: crushing to 40 mesh in cyanide solution, concentration, amalgamation, classification, and cyani-dation of sands by leaching, and of slime by agitation and decantation in charges. The ore averaged about $7 per ton, gold and silver, the ratio of weight being 1 oz. gold to 7.56 oz. silver. The ratio of gold and silver in tailings was 1 oz. Au to 36.6 oz. Ag; the quartz was sharp and sandy, however finely ground, and rather difficult to slime. The mechanical equipment was a No. 5 Symons gyratory crusher; three 10-ft. Lane slow-speed Chilean mills; one Wilfley roughing and one finishing table; one submerged-type Akins classifier; five 26 by 10-ft. fir leaching tanks; one 24 by 7-ft. Dorr thickener; four 14 by 16-ft. Dorr agitators; four 6-compartment double-row zinc-boxes having compartments 18 in. wide, 18 in. deep, and 34 in. long; Johnson zinc lathe; acid and vacuum filter tanks for treating precipitate; roasting furnace; and Case tilting No. 275 crucible furnace for melting precipitate. The mill is driven by electric power supplied by the Montana Power Co. at the following rates, per kw.-hr.: 200 to 300 hp., 0.68 c.; 300 to 500 hp., 0.61 c.; 500 to 750 hp., 0.55 c.; plus $1 per month per installed motor horsepower. The plant as above described was operated from May, 1915, to the end of the year, when an additional Dorr thickener and a 12 by 12-ft. Portland revolving filter were added, increasing the nominal capacity of 100 tons per 24 hr., but not the percentage of extraction. The combined treatment, at a cost of $1.48 per ton, saved 90 per cent. of the gold arid

Jan 1, 1919

By C. W. Stratford

[During the last few years, the necessity for development work has been generally recognized by executives throughout the oil industry, resulting in greatly accelerated progress and the adoption of many noteworthy improvements in refining methods and equipment. Several years ago, the Associated Oil Co. decided to improve distillation methods with the object of reducing refining costs. This extremely interesting work was entrusted to the writer, and W. S. James, now Chief of Research for Studebaker Corpn. of America, was selected as the principal collaborator. The latter contributed much during his two years with the Associated Oil Co., to the development work that has followed. The writer extends to the Associated Oil Co. his appreciation for permission to disclose the details of distilling equipment. In petroleum refining the principal requisites of good economics are the separation of high-priced distillates from those of lower price; maxi-mum yield of any desired distillate; lowest capital investment in refining equipment; lowest cost of operation and maintenance, and the best adaptability and flexibility of the same refinery equipment for handling crudes of widely varying characteristics. The first two items mentioned, separation and yields of distillates are determined by efficiency of fractionating equipment,. Discussion in this paper is chiefly concerned with oil-heating equipment, combustion and furl economy. It has long been well known that velocity plays a very important part in all heat transfer systems. Any betterment in specific transfer. rates in such systems must. always involve velocity. Realizing this fact, IV decided to adopt as a basic principle, the employment of energy to impart velocity required for high transfer rates through a heating diaphragm, and our method of modernizing obsolete shell stills is founded on this principle. Mechanical energy is usually cheap and its rational rspcntliture is returned in the form of greatly increased heat transfer rates, on both oil and gas sides of the sheet. Certainly there is nothing new in this principle, the only novelty being that of our peculiar method of application On the oil side (Fig. I) use is made of a centrifugal pump to jet the oil against the heated sheet thereby creating a high velocity sheet flow over the entire fired area. Such a pump is one of the most efficient machines, so far developed, for moving fluids. 'I'he oil, under pressure impinging

Jan 1, 1928

By E. W. Mehal, R. W. Haisty, D. W. Show

The next generation of integrated circuits will probably include circuits constructed in and of GaAs. The existence of both semi-insulating and semiconducting forms of GaAs is the fact which will bring this about. In this paper we discuss the uses and limitations of semi-insulating GaAs for integrated-circuit applications. The two main areas considered are the electrical isolation that can be achieved between components on a semi-insulating substrate and the characteristics of p-n junctions in contact with semi-insulating GclAs. A process basic to attaining integrated circuits in GaAs to fully utilize the insulating properties of the substrate is selective epitaxial deposition. This process involves the deposition of a SiO2 layer onto a The trend in integrated circuits is towards the use of high-resistivity substrates or regions to achieve component isolation. The use of SiO, layers in the oxide isolation methods and the use of sapphire substrates are examples of this idea. GaAs is also a polished surface of a GaAs substrate, etching out selected area of the SiO, film to expose a GaAs surface, and deposition only onto the exposed GaAs surface. By using this process , islands of semiconducting GaAs are deposited onto a semi-insulating GnAs substrate, the islands being electrically isolated from one another by the substrate. The deposition of both p- and n-type semiconducting GaAs can be carried out in this nzanner to form p-n junctions in the island areas. This process can also be used to produce a planav structure by deposition of GctAs through a SiO, mask into holes etched into the GaAs substrate. This Putterned Epitaxial Technology (PET) is described. very promising material for use in future integrated circuits because of the existence of both semi-in-sulating and semiconducting forms. Active devices can be fabricated in the semiconducting material, and these individual components can then be electrically isolated from one another by using semi-insulating GaAs as the substrate. Epitaxial semi-insulating GaAs can also be produced thus making three-dimensional monolithic integrated circuits feasible.' This paper describes the research aimed at developing the methods for producing both two- and three-dimensional integrated circuits in GaAs, and examines some of the properties of semi-insulating GaAs as they relate to these integrated circuits.

Jan 1, 1967

By L. C. Snider

All important industries have certain basic principles in common which govern them and give them a family resemblance. In addition, each industry has a certain individuality due to some principle or principles which govern, or are accepted as governing, that industry and which is not effective in others. The customs and practices of an industry depend on these basic principles much as the corollaries follow a proposition in geometry. After the proposition is proved or is accepted as proved, the corollaries are seen to be true almost without additional evidence or proof. In many cases, the corollaries are more important in practical affairs than the proposition on which they depend. By continued application the corollaries may come to be accepted as law and the fact that their truth depends on the correctness of the fundamental proposition is forgotten or ignored. If it is discovered that an error was made in demonstrating the proposition and that the proposition is untrue, the corollaries are, in most cases at least, equally untrue. Considerable time may be required, however, to realize the fact that the corollaries have failed, particularly if they have been embodied in custom and law. For example, in the business of government the proposition that women are intellectually inferior to men was formerly considered, by most men at least, to be duly proved if not axiomatic. This propositiot was never embodied in law, but its corollaries—that the rights of the wife in property and even in her own children were inferior to the rights of the husband, and that women had no place in governmental affairs—were duly incorporated in law or so completely approved by custom that they had the effect of law. Developments of the past few decades have proved, to the satisfaction of the majority, that woman's intellectual inferiority to man had not been satisfactorily demonstrated, and that the proposition that she was inferior, although accepted for many generations, was untrue. It was not so great a shock to men to discover that this proposition was wrong as it was to find out that its corollaries were also untrue and that the laws embodying them were not good laws and were subject to repeal. The adjustments which give women equal rights with men

Jan 1, 1932

By Edward P. Chapman

In the Leadville district toward the close of the "intermediate mesothermal period" of mineralization, there occurred a stage of ore deposition marked by a rather complex mineral association. As bismuth minerals formed in many places during this period, it is here called the "bismuth stage" for convenience of description. The minerals so far identified with this stage, listed roughly in the order of prominence, are: chalco-pyrite; several varieties of galena, differing slightly from one another in their small contents of silver, bismuth and tellurium; altaite; hessite; galenobismutite; alaskaite; aikinite; gold; tennantite; argentite; and perhaps sphalerite and arsenopyrite. With the exception of gold, the age relations of these minerals are difficult to determine. As shown in their descriptions, they all appear contemporaneous and hypogene. Gold may be in part contemporaneous, but most of it is distinctly later. Where minerals of this stage occur so that they can be mined alone, as at the Tucson mine, they constitute high-grade ore. Elsewhere their presence in small amounts has served to increase greatly the value of what otherwise would be low-grade pyritic or zinc-lead sulphide ore. The distribution of the bismuth ores corresponds closely to the distribution of gold ores, though not so general. It seems probable that most of the old in the district was deposited during the "bismuth stage." These ores occur relatively near the supposed centers of mineralization in Breece and Printer Roy Hills or deep down along the Tucson-Maid fault, which is one of the well recognized channels of mineralization in the Iron Hill and Graham Park areas. Consideration of the high-grade nature of this mineralization and the fact that it appears to be found relatively close to the source of mineralization suggests that prospecting along some of the known channels, even deeper than they have yet been prospected, may offer hope of commercial success. Introduction The Leadville district has been studied sinee 1880, and numerous detailed geologic descriptions of it are available in print; so also are more or less complete summaries of the mineral paragenesis, representing what was known at various periods up to 1927, the year of publication of Professional Paper 148.V lie writer has been engaged as consulting geologist at Leadville since the year 1926, and has been able to examine various types of Leadville ores throughout this period. Inasmuch as

Jan 1, 1941

By Samuel S. Wyer

1. The following is an abridgment of a recent report made by the author, covering an investigation of: (A) The necessary use of natural-gas compressors; (B) The effect of gas compressors on natural-gas field operating conditions in Ohio, with special reference to the working pressure relations of gas wells of one company discharging by natural rock-pressure flow without compressors, and adjacent wells of other companies, discharging into intake lines to gas-compressing stations. Tests were made at 107 different places in the counties of fairfield, Licking and Knox, Ohio, which required 7,000 miles of automobile driving, and consumed 6 months' time. 2. A proper conception of the necessary use and effect of natural-gas compressors in natural-gas production necessitates a clear understanding of certain fundamental definitions and judicial doctrines, which are given herein. 3. Gas is a fluid composed of a large number of molecules which are vehicles of energy continually in motion, and havingan inherent tendency to get farther and farther apart. The range of motion of the molecules is limited only by the volume of the closed containing vessel in which they constantly move to and fro. The most distinguishing characteristic of gas is its universal property of completely filling an inclosed space. 4. Gas pressure is the result of the combined efforts of all the moving molecules in the mass trying to get farther and farther apart, that is, a mass of gas inclosed in a vessel expands and fills it, and being restrained from further expansion, it exercises a pressure against the walls of the vessel. This pressure is the same in all directions on equal areas of surface, as shown in Fig. 1. With a given mass of gas, any increase in volume of containing vessel will give the molecules more range of motion, * The public's interest in the age and magnitude of the art of gas compressing and development of the law relating to the use of grs compressors in natural gas production is discussed in the preceding paper. Development of the Law Relating to the use of Gas Compressors in Natural Gas Production; see also Is It Feasible to Make Common Carriers of Natural Gas Transmission Lines, vol. xlviii, 471 to 480 (1914). Consulting Engineer.

Jan 1, 1916

By A. G. Buyers, J. Chilton, W. E. McKee

STUDIES in the high-temperature separations chemistry of thorium-uranium fuels are complicated by the corrosive nature of these molten metal systems at 1700°C. Separations research pointed toward the removal of fission products from irradiated alloys has included a frozen salt-bed technique which minimizes container reaction with molten metal. The procedure consists of high-frequency induction melting of the metal sample which is supported by a vertical column of unmelted salt. The molten alloy melts its immediate salt environment and as it slowly falls down through the column, many of the fission-product poisons are transferred into the fused salt environment. The molten salt-metal zone is encompassed at all times by unmelted salt, preventing container contact. EXPERIMENTAL Experimental methods were separated into three parts: salt-bed preparation, melting, and analytical evaluation. A) Bed Preparation—The procedure for casting calcium-fluoride briquettes was to compress the powdered salt at 5,000 to 10,000 psi and place this compact in a graphite crucible. This assembly was inserted into a vacuum system and surrounded by an alumina crucible as well as molybdenum, tantalum, or stainless-steel foil thermal-radiation shields. The pressure was reduced and the crucible heated under vacuum to about 800°C with the fore pump operating. Argon was then admitted to about 0.8 atm and heating continued until the CaF2 had melted 5 min at the melting point seemed satisfactory). Apparatus used included a 1-in. graphite crucible with 1/8-in. walls, 1-in. ID in a 2-in. induction coil, and a 6-kw Ajax high-frequency converter. B) Melting—Calcium-fluoride briquettes, 1 in. in diam and 1/2 to 1 in. thick, were prepared and vertically stacked to obtain the desired column length. An irradiated alloy sample (nut = 10") was placed on top of the salt column and the assembly was connected to the vacuum system. After evacuation of 5 to 10 , purified argon was admitted and the system flushed twice. The final argon pressure was about 0.8 atm. The sample was heated by induction at a power of about 6.5 kw. It then melted its way down through the salt and freely dropped into a small alumina crucible. The molten metal is followed during its downward course by the induction coil which is mounted upon a power-driven machine-threaded shaft. Experimental conditions used in the foregoing work

Jan 1, 1960

By Edward P. Chapman

In the Leadville district toward the close of the "intermediate mesothermal period" of mineralization, there occurred a stage of ore deposition marked by a rather complex mineral association. As bismuth minerals formed in many places during this period, it is here called the "bismuth stage" for convenience of description. The minerals so far identified with this stage, listed roughly in the order of prominence, are: chalco-pyrite; several varieties of galena, differing slightly from one another in their small contents of silver, bismuth and tellurium; altaite; hessite; galenobismutite; alaskaite; aikinite; gold; tennantite; argentite; and perhaps sphalerite and arsenopyrite. With the exception of gold, the age relations of these minerals are difficult to determine. As shown in their descriptions, they all appear contemporaneous and hypogene. Gold may be in part contemporaneous, but most of it is distinctly later. Where minerals of this stage occur so that they can be mined alone, as at the Tucson mine, they constitute high-grade ore. Elsewhere their presence in small amounts has served to increase greatly the value of what otherwise would be low-grade pyritic or zinc-lead sulphide ore. The distribution of the bismuth ores corresponds closely to the distribution of gold ores, though not so general. It seems probable that most of the old in the district was deposited during the "bismuth stage." These ores occur relatively near the supposed centers of mineralization in Breece and Printer Roy Hills or deep down along the Tucson-Maid fault, which is one of the well recognized channels of mineralization in the Iron Hill and Graham Park areas. Consideration of the high-grade nature of this mineralization and the fact that it appears to be found relatively close to the source of mineralization suggests that prospecting along some of the known channels, even deeper than they have yet been prospected, may offer hope of commercial success. Introduction The Leadville district has been studied sinee 1880, and numerous detailed geologic descriptions of it are available in print; so also are more or less complete summaries of the mineral paragenesis, representing what was known at various periods up to 1927, the year of publication of Professional Paper 148.V lie writer has been engaged as consulting geologist at Leadville since the year 1926, and has been able to examine various types of Leadville ores throughout this period. Inasmuch as

Jan 1, 1941

By R. B. Gordon, D. A. Koss

Ultrasonic-atlenuation changes due to the formation of free dislocations have been observed during tensile tests of magnesium and LiF single crystals and samples of polycrystalline Results on the LiF and samples are similar: A preyield attenzration increase is observed which, however, be-corlzes smaller as the magnitude of the drop in load al yielding increases. This indicates that the yield point observed in these materials is due to dislovation rather than dislocation unpinning and that the initial density ' free dislocations must be low if the yield point is to be sharp,. Tests on the magnesium ere conducted at both 27" and 200C. Magnesium has the unusual property that the yield drop is larger at the higher test temperature and is accomplished by a decrease in attenuation. The latter is due principally to the temprovary pinning of detained dislocations by highly solute atoms. After strain aging., a stress as low as 0.3 bur suffices to unpin dislocations; microstrain measuements of sufficient sensitivity should. reveal plastic flow at stress levels this low IN another paper,' we describe the technique of simultaneously observing ultrasonic-attenuation changes and plastic microstrain during deformation of spher-oidized carbon steels. Changes of ultrasonic attenuation indicate damping effects caused by the oscillation of long, freely moving dislocation segments. Simultaneous microstrain measurements are used to indicate total dislocation motion. The dislocation-damping observations are most useful in the study of the early stages of deformation where the dislocation density is low and the plastic strain is small and relatively difficult to measure. Particularly interesting results are found in materials which display sharp yield points. Observations of these phenomena are reported here for three materials: single-crystal LiF and magnesium, and poly crystalline molybdenum. EXPERIMENTS Dislocation-damping effects were observed by measuring changes in acoustic attenuation with the ultrasonic-pulse method. The end faces of each of the specimens were ground flat and parallel and a quartz 10 Mc per sec, x-cut transducer was attached to one face. The bonding agents used were: a) "Nonaq" stopcock grease with magnesium, b) beeswax with LiF, and c) salol with molybdenum. With the LiF, the best acoustic signals were obtained at 45 and 50 Mc per sec; all other measurements reported are at 10 MC per sec. The Sperry Ultrasonic Attenuation Comparator2 was used to measure attenuation changes. In the

Jan 1, 1967