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By W. V. Vietti, W. A. Oberlin

Crude petroleum produced in the Texas Panhandle oil field is both an asphalt and a paraffin-base oil and is further characterized by being a high-gravity crude with an extremely high cold test,. An eight-well composite of Panhandle crude showed the following characteristics: Gravity, 36.6° A. P. I. Viscosity: 61 sec. Saybolt at 100° F. 170 sec. Saybolt at 75° F. 1560 sec. Saybolt at 50° F. (stirring) Cold Test, 60° F. Distillation Test: Per Cent. Per Cent. Gasoline........................ 28.8 Wax........................... 19.2 Kerosene........................ 4.8 Asphalt........................ 13 .0 Gas oil......................... 30.7 Sulfur1......................... 0.8 Fuel oil......................... 34.7 Subsurface Conditions The original pressure in the formation in the Panhandle field closely approximated 420 Ib. gage or 435 Ib. absolute pressure. Temperatures taken indicate that the formation temperatures do not exceed 90° F. The temperatures in Table I are typical measurements taken on one lease. * A contribrition from the research department of the Marland Refining Co. of Oklahoma and the production engineering department of the Marland Oil Co. of Texas. 1 Smith [Analysis of Panhandle and Rig Lake Crudes. U. S. Bur. Mines, Circular No. 6014 (December, 1926)] found an average sulfur content of 0.6 per cent.

Jan 1, 1928

By John Devine

DURING the past few years the Bureau of Mines has been studying hydrogen-sulfide corrosion in the petroleum and natural-gas industries. Early work was confined to investigating the various practical, or operat-ing, factors that control the corrosion reaction when ordinary mild steel is being attacked. In that work it was shown that, if the optimum operating conditions1 are obtainable, . gas containing hydrogen sulfide can be handled at ordinary temperatures without serious corrosion resulting. However, frequently "sour" gas must be handled under other than optimum operating conditions, and combating corrosion then becomes a problem to be considered more during the construction of a system than during its subsequent operation. That is, where economi-cally practicable in such cases the designer will seek to substitute for mild steel other steels or ferrous metals more resistant to corrosion by hydro-gen sulfide. The comparative resistance of various commercial steels and alloy steels to corrosion by hydrogen sulfide at elevated temperatures has been reported systematically by previous investigators,2 but similar information for corrosion at ordinary temperatures is available only from scattered sources, representing different methods of testing. As the value of comparative corrosion tests depends largely upon the use of a

Jan 1, 1934

By M. L. Fuller

The fundamental mechanism of the deformation of zinc has been thoroughly described by several prominent investigators, particularly Mark, Polanyi, and Schmid,1 Mathewson and Phillips,2 and Schmid and Wassermann.3 The deformation of zinc occurs primarily through slip along basal planes (00.11, and secondarily through twinning on pyramidal planes of the form (10.2). In addition to these basic studies on single crystals, there have been a number of determinations4,5 of preferred orientations developed in rolled, polycrystalline zinc. In no case, to our knowledge, has there been described the development of oriented structures in zinc as a result of a systematic series of rolling treatments. The work included in the present paper shows the changes in orientation produced in a zinc alloy by successively increasing degrees of cold-rolling reduction. This alloy has the same crystal form, hexagonal close-packed, as zinc, but its susceptibility to hardening for a given degree of working is much greater because of its higher recrystal-lization temperature. Experimental Procedure Composition of the Alloy and Rolling Treatment The alloy used in this investigation consisted of zinc of 99.9 per cent purity to which 1 per cent of copper and 0.01 per cent of magnesium had been added.

Jan 1, 1934

By D. L. Albright, R. W. Kraft

A technique is described whereby the study of crystal perfection through the use of conventional X-ray rockite curves is extended to three dimerzsions. Specinzens of unidirectionally solidified eutec-tic alloy which consist of a nearly perfect parallel arrangement of alternating Platelets of Al and CuAl2, but which contain lamellar faults have been analyzed by this technique in conjunction with X-ray microscopy. Analysis of the data has shown that some rotational symmetry about the growth direction occurs, that small groups of lamellae between faults diffract as a unit, and that the misorientation caused by a fault is on the order of a degree of arc. A eutectic-grain can be defined as that portion of a eutectic specimen in which the crystallographic orientation of each phase AND the microscopic or met-allographic orientation of the phase particles have fixed angular relationships one to another. Eutectic-grains of the A1-CuA12 eutectic, which is a normal lamellar eutectic, have been grown by unidirectional solidification and identified as such.1-3 To a first approximation, a eutectic-grain in this system consists of two interpenetrating single crystals which are related to each other and to the lamellae themselves as follows:

Jan 1, 1962

By Norman C. Britz, Mortimer P. Buck

THIS PAPER DEALS WITH the practices used at the Huntington, Nest Virginia works of The International Nickel Company, Inc., in hot and cold rolling nickel and high-nickel alloys. The practical metallurgical aspects are discussed and a brief description of equipment given. The alloys covered may he divided into three main groups. based on their major constituents: 1. Nickel alloys, 2. Nickel-copper alloys. 3. Nickel-chromium alloys. The nominal compositions of the various alloys which are produced in most common mill forms are given in Table 1. Nickel, a commercially pure grade of nickel containing about 0.05 pct carbon as' the chief alloying element, is produced in all common Mill forms. "L" Nickel is commercially pure nickel in which the carbon content is held as low as possible, usually less than 0.01 pct. This grade of nickel is used chiefly for spinning and for special high temperature applications where its low carbon content enhances its corrosion resistance. "D" Nickel contains 4.5 pct manganese to provide improved resistance to sulphur embrittlement at elevated temperatures. "Z" Nickel is an age hardening grade of nickel containing carbon, aluminum, and silicon as the age hardening elements. This alloy combines the cor-

Jan 1, 1948

By B. H. Bergstrom, Will Mitchell, T. G. Kirkland, C. L. Sollenberger

SEVERAL constructive and fundamental studies have been made in the analysis of data obtained from experiments carried on with batch ball and rod mills. The operating characteristics of ball milling in small continuous circuits have also been appraised. It is from these analyses that some of the theories of comminution have been developed. Relatively few studies of continuous rod milling have added significantly to the fundamental concepts, because seldom have they yielded sufficiently consistent results. Perhaps they have been too limited in their scope. Careful control of the variables in batch grinding is simple compared with that encountered in a continuous operation. This factor alone has discouraged many investigators. Occasionally results of systematic changes made in industrial rod mill circuits have been published, but usually the data are sketchy and are restricted because -of the unwieldiness of the equipment used. The work, in general, has not been comprehensive; nevertheless it has provided empirical relationships that have bridged the gap between postulate and practice so that by proper manipulation of formulae, a mill designer can anticipate mill size and power requirements.1-3 Although operating variables of a small continuous mill are not so easy to control as with the batch mill, with present day devices, and with careful experimental work, consistent results can be obtained.

Jan 10, 1954

By W. M. Peirce

ON May 16, 1871, twenty-two men met in Wilkes-Barre, Pennsylvania, and founded the American Institute of Mining Engineers.* If we could transport ourselves back to that year and survey the state of science and technology in general, and, in particular, the field of our immediate interest-nonferrous metals-we would feel a justifiable pride in what had been accomplished up to that time. These accomplishments in the metal field were at the moment in the process of documentation by an Englishman, J. A. Phillips, in a new 700-page edition of his book to be published in 1874 under the title of "Elements of Metallurgy." True, looking over his shoulder, we would smile to read that "all metals are capable of assuming a crystalline form under favorable conditions," and that tensile testing is done "by adding weights to a firmly suspended wire until it fractures," and we would find only three pages on aluminum and none on magnesium. We would, however, find an astonishing wealth of detailed knowledge on iron and steel and the then common nonferrous metals and alloys such as brass and bronze. But if we possessed a little prophetic vision as we directed our attention to the short period that had elapsed since the close of the Civil War, we

Jan 1, 1947

By A. J. Fenn

Long experience with underground mining inspired the unusual idea of using an underground crusher-conveyor system as a substitute for surface haulage at the Cananea open-pit copper mine in Sonora, Mexico. Now implemented and working well, the system has born out the expectations of its originator, Cia. Minera de Cananea S.A. de C.V., that it would effect substantial cuts in the high cost of haulage. The Cananea deposit is a large, low-grade orebody above the mined-out Colorada pipe which was once one of the largest high-grade underground deposits in the district. Present facilities at the pit consist of: (1) A large open-pit mine capable of moving 80,000 tons of material per day with a shovel-truck, underground crusher and belt conveyor haulage system. (2) A 25,000-tpd concentrator equipped for four stages of crushing, rod mill-ball mill grinding with cyclone classification, and flotation in conventional machines. (3) A dump leaching process producing 1 million lb of copper per month in a tin-can scrap precipitation plant. (4) A two-reverberatory, six-converter smelter which can make 140 tons of blister copper per day. (5) A well-integrated contingent of supporting departments running the gauntlet from housing to power generation.

Jan 3, 1969

By J. Charles Miller

THE expansion of facilities for rapid transportation of perishables by train, truck and airplane has necessitated consideration of refrigerants of a minimum weight and volume per pound of cooling and has stimulated the use of solid carbon dioxide commercially. The gas probably has not had wide application in the past in air-cooling equipment for mines, theaters or buildings, owing to its thermodynamic properties, as will be deduced from examination of Table 2. However, consumption of the liquid in carbonating beverages remains a dominant factor. In addition to these uses, carbon dioxide is employed to a limited degree as an explo-sive in the liquid form, as a freezing agent in plumbing, in laboratories for low-temperature work, and in the manufacture of golf balls. SOURCES The principal sources of the gas at present are coke ovens, lime kilns, breweries and other fermentation plants, all of which are within easy reach of markets. Natural sources, however, have not received the consideration they merit, mainly because of their isolation. It is asserted by some manufacturers that the carbon dioxide gas produced from wells is unsatisfactory because it often contains impurities that are difficult to remove, while that produced as a byproduct is much purer or contains impurities that are easier to remove.

Jan 1, 1936

By H. S. Chiang, S. S. Peng

INTRODUCTION Underground coal mining disturbs the original in-situ conditions which induces a series of strata activities and results in creating "mine pressures," the source of all ground control problems. Adoption of self advancing powered supports in modern longwall mining adds a new dimension to ground control problems and thus research. Roof stability, in general, refers to the integrity and stability of the immediate roof which is measured by the maximum exposed area and time duration without support. There are many factors that con- tribute to roof stability problems. In addition to mining height, rock property and stratum components and caving angle of the immediate roof, characteristics of joints and fissures and their degrees of development, faults and underground water, the operational techniques also play a very important role. This paper summarizes these operational techniques and methods of controlling stable and unstable roof. CLASSIFICATION OF THE IMMEDIATE ROOF There are many ways of classifying the roof (1). For practical purpose, the immediate roof in this paper is divided into three groups, i.e. unstable. medium stable and stable. Unstable Immediate Roof It has the following features (1) It consists of weak or soft carbonaceous shale, black shale, clay shale and well-jointed or fractures sandy shale

Jan 1, 1983

By Andrew Hyslop

In our never ending search for new and better ways of underground mining, we find that transportation has had its share of new ideas in the past few years. The old and still effective method of track haulage has had some competition from rubber-tired cars and belt conveyors, each of which has its own safety hazards which demand close scrutiny in any safety study. The use of shuttle cars, in particular, has introduced clearance hazards caused by the absence of the more or less positive guides formed by the rails of a track sys- tem; likewise the requirement of greater clearance tends to increase roof hazards which we all know to be great enough with the best of methods. However, the subject of transportation hazards is too broad to be covered entirely in one paper, so I will confine myself to track methods which carry the preponderance of underground tonnage. I am quite sure that to this group it is an evident fact that haulage accidents are of major importance. However, to stress the point, it may be well to look at a few figures. Safety statistics can be quite boring and often are subject to question as to mathematical accuracy because of different

Jan 1, 1949

By Thomas F. Torries, George H. K. Schenck

Crushed and broken stone is used directly in construction as an aggregate and accounts for about half the value and two-fifths of the quantity of natural aggregates consumed in the United States. Sand and gravel provide most of the balance of aggregates except for some lightweight materials such as pumice and expanded shale. Conditions necessary for production of crushed stone from a deposit are : 1) Quality-should pass rigid specifications for strength and durability. 2) Cost-low average total delivered cost. Construction aggregates are hard, essentially inert materials suitable for being formed into a stable mass either (1) by the addition of cementing or binding materials that produce a concrete or (2) by compaction or by natural weight to produce a road base or foundation. Aggregates usually provide about 80 to 100% of the material volume of the construction masses in which they are used. The construction industry utilizes as aggregates about 70% of all crushed stone produced in the United States according to statistics provided by the U.S. Bureau of Mines (USBM) , [Table 1], using definitions as shown below. Nonconstruction uses of crushed stone, [Table 2], are included elsewhere in Industrial Minerals and Rocks because such uses require the special physical or chemical characteristics which are discussed in those chapters.

Jan 1, 1975

Discussion of the paper of J. E. Johnson, Jr., The Effect of High Carbon on the Quality of Charcoal-Iron, presented at the Cleveland meeting, October, 1912, and printed in Bulletin. No. 74, February, 1913, pp. 173 to °14, and of the paper of Albert Sauveur, Notes on Cast-Iron, presented at the New York meeting, February, 1013, and printed in Bulletin No. 75, March, 1913, pp. 503 to 524. CHAIRMAN. JOHN BIRKINBINE :-Just 20 years ago I had the pleasure, when I retired from the Presidency of the Institute, of introducing my successor, and this afternoon it is my pleasure to ask my good friend Dr. Howe to open this discussion. PROFESSOR HENRY M. HOWE, New York, N. Y. :-This paper of Mr. Sauveur's is extremely interesting. It is one of those papers that one wishes to read in the quiet of one's study, where it can be read with great profit. There are many points which he makes which I think are of very great value, in particular as to the importance of getting fine ;grained graphite by a relatively rapid cooling, combined with a high percentage of silicon. That theory would seem to be very promising; how far it has actually been carried out very likely Dr. Moldenke can. tell us.

Jan 5, 1913

By Andrew Hyslop

IN our never ending search for new and better ways of underground mining, we find that transportation has had its share of new ideas in the past few years. The old and still effective method of track haulage has had some competition from rubber tired cars and belt conveyors, each of which has its own safety hazards which demand close scrutiny in any safety study. The use of shuttle cars, in particular, has introduced clearance hazards caused by the absence of the more or less positive guides formed by the rails of a track sys¬tem; likewise the requirement of greater clearance tends to increase roof hazards which we all know to be great enough with the best of methods. However, the subject of transportation hazards is too broad to be covered entirely in one paper, so I will confine myself to track methods which carry the preponderance of underground tonnage. I am quite sure that to this group it is an evident fact that haulage accidents are of major importance. However, to stress the point, it may be well to look at a few figures. Safety statistics can be quite boring and often are subject to question as to mathematical accuracy because of different

Jan 1, 1948

By M. K. Foster

Ten horizontal retort zinc blocks of a modified Hegeler design are in operation at Nueva Rosita, Coahuila, Mexico, and produce approximately 170 t of spelter daily, or 62 000 t/year. A block consists of two furnaces of 448 retorts each, making 8960 retorts as the plant complement. Each furnace block is fired with natural gas and air maintaining the combustion mixture in the furnace always slightly reducing. No attempt to recover energy through waste heat boilers is made. The spelter moves to market by rail and truck either in palletized bundles weighing approximately 1060 kg, as loose slabs weighing 26.5 kg each, or as 1088 kg ingots. At present 46% of the metal is exported and 54% is consumed domestically in Mexico. The present day trend toward equalized or alloyed spelter, as well as special shaped castings results in sales of 35% of the entire plant's production. Sulfuric acid is also produced by the Contact Process using vanadium pentoxide as the catalyst. The plant is basically a Monsanto contact system, producing approximately 68 t of 100% sulfuric acid daily. Both 98.5% sulfuric acid and 20% oleum are available. All of the acid made is consumed in Mexico. Shipments are made in 26,900 dm3 tank cars.

Jan 1, 1970

By J. Greenspan

The anisotropy of fracture and slip, that is, the brittleness and ductility of the beryllium single crystal, is characteristic also of po1ycrystalline beryllium in which the grains are oriented in a preferred manner. Beryllium with grain orientations resulting from hot working either unidirectionally or bidirectionally is ductile or brittle in directions given by the anisotropy and orientation of the grains. Textures developed from various hot-working sequences are given, and tensile results are correlated with textures. Not only texture, but fine grain size is necessary for obtaining high tensile elongation. Ultimate tensile strength and elongation are both correlated with grain diameter. Of particular interest is the case in which unusually high tensile elongations of 30 to 40 pct are obtained when basal planes are oriented to carry THE beryllium crystal (of nominal purity) is probably unique among metals with respect to its unusually acute anisotropy of slip and fracture. While extensive slip can occur on the system (1010) [ll20] starting at about 19,000 psi, the (0001) plane is particularly vulnerable to fracture at 4500 psi or less. Fracture occurs also on the (11zo) plane at about 26,000 psi.1"3 Further, there seems to be no other slip System which contributes significantly to

Jan 1, 1960

By K. S. Seljesater

SINCE the development of dispersion-hardenable lead-antimony alloys1 in the laboratories of the Western Electric Co., Inc., studies have been made of the effect of various third constituents on these alloys.2 This paper covers a study of the effect of small amounts of arsenic. This element is important since it occurs as an impurity in many commercial antimonial leads and the results obtained are particularly interesting as indicating a class of addition agents which exert a stabilizing effect on dispersion-hardened alloys. EXPERIMENTAL In order to-study the effect ,of increasing amounts of arsenic, a series of alloys were made up containing 1 per cent. antimony, and arsenic varying from 0. to 0.10 per cent., the balance Doe Run lead (99.997 per FIG. 1..-CHANGE OF MICRO-BRINELL HARDNESS WITH TIME OF 1 PER CENT. LEAD-ANTIMONY ALLOY. cent. lead). The alloys were cast into bars 1 ½ in. wide by ¾ in. thick and cold-rolled to about 1/8 in. thickness. Three samples of each composition were annealed 1 hr. at 225° C. and quenched in water. One set was aged at room temperature, one at 50° C., and the third at 100° C., the

Jan 1, 1929

By J. T. Richards

ELASTIC constants, including E-modulus, G-modulus, Poisson's ratio, and compressibility, are affected by temperature, but not necessarily to the same degree nor in the same direction. Theoretical expressions relating the temperature coefficients for the various elastic constants have been introduced by Gruneisen. In considering the thermoelastic characteristics

Jan 1, 1955

By Fred N. Kissell, Maurice Deul

When coal is broken during mining, some of the methane trapped in the coal is released. Some recent investigations by the U.S. Bureau of Mines have shown that this methane released by breakage is only a small proportion of the total methane emission into the working section.

Jan 1, 1975

By E. J. Freeh, W. E. Horst, R. C. Kellner

A technique useful in the important area of process-model building is described. The procedure is illustrated in the development of a mathematical model to describe the unsteady-state process of batch ball-mill grinding. The influence of certain assumptions relative to model structure are quantitatively evaluated and reviewed.

Jan 1, 1969