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By G. R. Speich

A cellular precipitation reaction in which cells consisting of an Ni3Ti (DO24) phase and austenite are formed has been studied in an austenitic Fe-30 Ni-6 Ti alloy. The variation of the growth rate and interlamellar spacing of the Ni3Ti cells with temperature has been determined m the range 400" to 975°C; the interlamellar spacing is proportional to the degree of undercooling; the growth rate can be expressed by an equation of the form G = K?T)2 exp(-Q/RT). The habit of the Ni3Ti lamellae is (001)Ni3Ti (111)y;[010]Ni3T2 [010]y. An almost perfectly coherent interface is formed between Ni3Ti lamellae with this orientation rela -tionship and the intervening austenite. This first Ni3Ti cellular product is subsequently consumed by a second cellular reaction of much coarser spacing. CELLULAR precipitation reactions have been studied in copper-base,1,2 Au-Ni,3 pb-sn,4 and iron-base ferritic5,6 solid solutions, and this mode of precipitation has been treated theoretically by smith," Turnbull,8,9 cahn,10 and more recently by bohm.11 In the case of substitutional austenitic iron-base alloys little or no data are available, Cellular precipitation reactions are well known in austenitic nickel-base alloys12,13 but usually these reactions do not proceed to completion because of general precipitation occurring in the matrix, and they have not been studied in detail. Precipitation from an austenitic Fe-30 Ni-6 Ti alloy was studied as part of a larger investigation of the mechanisms of precipitation from substitutional iron-base alloys. This alloy, austenitic at high temperatures, decomposes at lower temperatures by a double cellular precipitation reaction. The first decomposition product consists of alternate lamellae of an Ni3Ti(DO24) phase and austenite. The reaction proceeds to completion, consuming all of the original austenite. This first cellular product is subsequently consumed by a second cellular reaction of much coarser spacing. The first cellular reaction was studied in detail by light and electron microscopy, hardness measurements, and by X-ray and electron diffraction. Interlamellar spacings and growth rates were measured during isothermal aging in the range 400" to 975°C. The orientation relationship between the Ni3Ti and austenite lamellae was determined and indicates that an almost perfectly coherent interface exists between the two phases. This first Ni3Ti cellular reaction is of particular interest because it occurs over such a wide temperature interval. This allows cellular growth rates and interlamellar spacing data to be obtained for much larger degrees of undercooling than reported hitherto. MATERIALS AND EXPERIMENTAL PROCEDURE The Fe-30 Ni-6 Ti alloy was prepared from electrolytic iron, Mond nickel shot, and sponge-purity titanium* by vacuum melting in a zirconia crucible

Jan 1, 1963

By C. W. Mallett

The distribution and properties of interseam and overburden rocks in coal mines is largely controlled by conditions at the time of their original deposition. Within the developed areas of the Bowen Basin, depositional environments range from fluvial through upper and lower detaic, to marginal marine and intertidal facies. Each environment has a characteristic association of lithologies with specific range of properties, and each lithology has a characteristic geometry. Fragmentation problems are associated with ancient sand channel systems, where the difficulties encountered depend on the dimension and shape of channels, their continuity, orientation to mining face and associated sediment bodies formed as levees or interdistributary muds. Stability problems in spoil, pit floor and highwalls are usually associated with mudstones which contain swelling clays derived from the original Permian volcanic source. This clay problem is aggravated by deep Tertiary weathering. Case studies are presented of detailed analyses and prediction of geomechanical properties on a mine site scale. These are used in investigating or forecasting fragmentation and stability hazards. The studies incorporate detailed field mapping, bore log data and computer data processing. They allow the development of detailed depositional models for specific interseam intervals within mines. As areas of depositional environment are identified they allow the construction of maps of similar mining conditions and the determination of the most suitable mining techniques.

Jan 1, 1983

By D. D. Dunkin

Sandstone has been prepared for glassmaking purposes, and marketed from the White River Valley in Arkansas at Guion, Izard County, since about 1910—soon after the completion of the White River Branch of the Missouri Pacific R. R. Co. Until 1921, operations were somewhat spasmodic and ended in many failures. In that year a plant was built by the Silica Products Co., Inc., and since that time the operation has been continuous and steady. The land is held under leases, covering about 30 square miles of the best sandstone adjacent to the railroad. Most of the product is shipped to glassmakers. Geology The St. Peter sandstone is rather widely distributed in north central Arkansas and is exposed most prominently in outcrops along the slopes of the White River Valley and its tributarirs that form the division between the Boston Mountains to the south and the Salem Plateau of the Ozarks to the north. It is of Ordovician age and is generally underlaid by Cotter dolomite and capped by Plattin limestone, except in the vicinity of Bellefonte and Everton. At those places, it is a massive cross-bedded, laminated, saccharoidal sandstone; underlying it is the Everton limestone and overlying it, the Joachim magnesium limestone The sandstone at Everton contains numerous phosphatic pebbles and inclusions of sandy limestone. The irregularity of cross-section, the evidence of sorting action and the phosphatic pebbles appear to be indications of secondary deposition The St. Peter sandstone occurs as a massive formation in the picturesque bluffs along the White River Valley from near the eastern escarprnent of the uplift northwestmard into the Ozarks. The exposure shows a series of gentle anticlinal and synclinal folds. The greatest thickness is at the southeastern end, where it is over 100 ft. in many places. It thins out to the north and west and then to isolated and scattered deposits which cap the ridges and mountains of the Ozarks.

Jan 1, 1928

By H. A. Schwartz, Wolfram Ruff

The spheroidal form of the temper carbon nodules in malleable cast iron and of the graphite mottles of "mottled" cast iron suggests that in both all the graphite in a given mottle or nodule grew from a single center of crystallization or nucleus. $ There is, however, a distinct metallo-graphic difference between the mottle and the nodule; the area of mother metal impoverished in combined carbon by the crystallization of graphite in a mottle is practically coextensive with the ramifications of the graphite, while the impoverished zone of metal corresponding to a given nodule is always larger, and usually much larger, than the approximately spherical mass of graphite crystals forming the nodules. Furthermore, the mottle probably is formed during freezing and the nodule almost always at a considerably lower temperature. Assuming that the nodules or mottles can be used as a measure of the existing nuclei (capable of germination) we propose to record certain observations as to the graphitizing reaction in the light of the number and habits of growth of these nuclei. The present authors, in cooperation with others'-', have reported upon various cognate aspects of the problem. The fact that temper carbon is a mass of flakes and not a solid granule has become well recognized since the introduction of an improved polishing technique8, 9, 10 for cast iron. The problem of deriving from the circular planar intercepts of a mass of spheres of varying sizes their number and size distribution in space has also been satisfactorily solved12, 13 Growth of Nuclei in White Cast Iron It has already been shown1, 3 that the progress of graphitization with time is usual1y consistent with the assumption that nodules grow in size

Jan 1, 1936

By Wolfram Ruff, H. A. Schwartz

The spheroidal form of the temper carbon nodules in malleable cast iron and of the graphite mottles of "mottled" cast iron suggests that in both all the graphite in a given mottle or nodule grew from a single center of crystallization or nucleus. $ There is, however, a distinct metallo-graphic difference between the mottle and the nodule; the area of mother metal impoverished in combined carbon by the crystallization of graphite in a mottle is practically coextensive with the ramifications of the graphite, while the impoverished zone of metal corresponding to a given nodule is always larger, and usually much larger, than the approximately spherical mass of graphite crystals forming the nodules. Furthermore, the mottle probably is formed during freezing and the nodule almost always at a considerably lower temperature. Assuming that the nodules or mottles can be used as a measure of the existing nuclei (capable of germination) we propose to record certain observations as to the graphitizing reaction in the light of the number and habits of growth of these nuclei. The present authors, in cooperation with others'-', have reported upon various cognate aspects of the problem. The fact that temper carbon is a mass of flakes and not a solid granule has become well recognized since the introduction of an improved polishing technique8, 9, 10 for cast iron. The problem of deriving from the circular planar intercepts of a mass of spheres of varying sizes their number and size distribution in space has also been satisfactorily solved12, 13 Growth of Nuclei in White Cast Iron It has already been shown1, 3 that the progress of graphitization with time is usual1y consistent with the assumption that nodules grow in size

Jan 1, 1936

By Gerhard Derge

THE introductory paper1 of this series described the potential behavior of tin in sodium carbonate and bicarbonate solutions whose pH ranged from 8.4 to 11.2 and demonstrated that significant and reproducible results could be obtained by proper attention to experimental technique. In examining the corrosion of tin under such conditions, it is desirable to know the effects of anions, aside from carbonate, that are likely to be present in commercial materials packaged in tin. Therefore, in this paper the potential behavior of tin in carbonate solutions to which sodium fluoride, chloride, bromide, iodide, sulphate, nitrate, monobasic phos-phate, dichromate, perborate and acetate have been added will be described. For most of the additions, solutions containing 0.001 and 0.01 .moles of the added material were studied. The experimental procedure was exactly the same as that described in the first paper; the pH of the electrolyte was controlled by adjusting the ratio of carbonate to bicar-bonate as follows: pH 0.1 M NaHCO3 8.4 2 parts 0.1 M NaHCO3, 1 part 0.1 M Na2CO3 9.5 1 part 0.1 M NaHCO3, 2 parts 0.1 M Na2CO3 10.0 0.1 M Na2CO3 11.2 The reagents used were all of C.P. grade. The anions studied may be divided into three groups: (1) anions that had little or no effect upon the potential curves-sulphate, nitrate, and acetate; (2) those that helped to prevent corrosion at low pH only-fluoride, chloride, bromide, and iodide; (3) those that helped to prevent corrosion at high pH also-phosphate, perborate, and chromate.

Jan 1, 1939

By L. P. Bayvel

The method of spectral transparency was investigated. A device for measuring particle sizes based on this method was developed, tested and applied. The device affords measurements of particle size distribution in the range from 0.1 to 4 µm. It proved possible to measure sizes not only of spherical particles but also of non- spherical ones. The spectral range in which it is necessary to determine transparency for particle size measurements was found.

Jan 1, 1980

By John S. Brown

As a part of a symposium on the relations of structure to ore deposition, in February 1938, the writer presented some tentative opinions derived from his experience with a number of important lead-zinc replacement deposits. These ideas were set forth, as a basis for discussion and a stimulus to further inquiry, in a mimeographed leaflet that read as follows: Intimate acquaintance with a number of lead and zinc deposits in metamorphosed limestones seems to indicate the existence of certain common features from which can be established some general principles governing the localization of ore in this type of formation. It is suspected that these principles can be applied, with modifications, to mineralization in unmetamorphosed limestone. In metamorphosed formations, some observed rules are as follows: 1. Bands or masses of pure limestone are very resistant to replacement by ore solutions, and are likely either to contain no ore or to resist replacement until near the end of mineralization. The reason for this apparently is physical, not chemical, since microscopic data indicate that when ore is deposited by far the greater part of it substitutes for carbonate. The chief factor is believed to be a lack of porosity in massive limestone that has undergone flowage and recrystallization. 2. Masses of intensely siliceous or silicated rock are likewise unfavorable ore receptacles. This seems to be accounted for by two factors: (a) chemical unsuit-ability or resistance to replacement, and (b) physical resistance to small-scale brecci-ation, which might faeilitate the opening of effective channelways for solutions. Some low-grade ore may occur, however, and also sporadic fracture fillings. 3. The optimum condition for ore reception appears to be found in bands or areas containing carbonate and silicates (or quartz) intimately mingled in something like equal proportions. In this situation movement is likely to result in mixed flowage and fracture, producing a finc-textured porosity that admits solutions freely and provides access to an abundance of replaceable carbonate. Cleavage cracks in some minerals such as diopside are believed to facilitate the penetration of solutions. 4. Certain minerals or assemblages are regarded as favorable impurities in a limestone and others as unfavorable. Original quartz, and subsequently developed diopside, and perhaps garnet, are typical favorable pre-ore gangue; in general rather equidimensional, brittle minerals. Tremolite, biotite, and probably wollastonite, are typical unfavorable pre-ore gangue; in general highly elongated and somewhat flexible minerals likely to develop under strong shearing stresses. 5. Tentative opinion is that the ratio of lime and magnesia in a limestone is of little or no importance.

Jan 1, 1941

By John S. Brown

As a part of a symposium on the relations of structure to ore deposition, in February 1938, the writer presented some tentative opinions derived from his experience with a number of important lead-zinc replacement deposits. These ideas were set forth, as a basis for discussion and a stimulus to further inquiry, in a mimeographed leaflet that read as follows: Intimate acquaintance with a number of lead and zinc deposits in metamorphosed limestones seems to indicate the existence of certain common features from which can be established some general principles governing the localization of ore in this type of formation. It is suspected that these principles can be applied, with modifications, to mineralization in unmetamorphosed limestone. In metamorphosed formations, some observed rules are as follows: 1. Bands or masses of pure limestone are very resistant to replacement by ore solutions, and are likely either to contain no ore or to resist replacement until near the end of mineralization. The reason for this apparently is physical, not chemical, since microscopic data indicate that when ore is deposited by far the greater part of it substitutes for carbonate. The chief factor is believed to be a lack of porosity in massive limestone that has undergone flowage and recrystallization. 2. Masses of intensely siliceous or silicated rock are likewise unfavorable ore receptacles. This seems to be accounted for by two factors: (a) chemical unsuit-ability or resistance to replacement, and (b) physical resistance to small-scale brecci-ation, which might faeilitate the opening of effective channelways for solutions. Some low-grade ore may occur, however, and also sporadic fracture fillings. 3. The optimum condition for ore reception appears to be found in bands or areas containing carbonate and silicates (or quartz) intimately mingled in something like equal proportions. In this situation movement is likely to result in mixed flowage and fracture, producing a finc-textured porosity that admits solutions freely and provides access to an abundance of replaceable carbonate. Cleavage cracks in some minerals such as diopside are believed to facilitate the penetration of solutions. 4. Certain minerals or assemblages are regarded as favorable impurities in a limestone and others as unfavorable. Original quartz, and subsequently developed diopside, and perhaps garnet, are typical favorable pre-ore gangue; in general rather equidimensional, brittle minerals. Tremolite, biotite, and probably wollastonite, are typical unfavorable pre-ore gangue; in general highly elongated and somewhat flexible minerals likely to develop under strong shearing stresses. 5. Tentative opinion is that the ratio of lime and magnesia in a limestone is of little or no importance.

Jan 1, 1941

By William C. Overstreet, Paul K. Theobald, Jesse W. Whitlow

Monazite placers in a region of the Carolinas explored in 1951-1954 by the USGS are estimated to contain at least 53,000 short tons of thorium and 4600 short tons of uranium. None of these deposits is being mined. The 5200-sq mile area investigated extends northeast along the western Piedmont from the Savannah River in South Carolina to the Catawba River in North Carolina. Much of the region is 700 to 1100 ft above sea level. Gentle hills and broad interfluves give a local relief of 100 to 200 ft. This increases to 1700 ft at the west margin of the area where the east flank of the Blue Ridge is approached in South Carolina and the South Mts. are entered in North Carolina.

Jan 7, 1959

By W. B. Coleman

Considerable discussion on the effect of iron and steel scrap in blastfurnace burdens was presented in the January, 1927, issue of Mining and Metallurgy. Therein the question is asked as to what causes the difference in physical properties of pig irons where the chemical analyses are practically the same. This point no doubt has been noticed by a number of furnace operators, but several years ago very little thought was given to it. The foundries purchased pig iron, had it analyzed and found it to be within their specification. The castings made from this iron at times would be satisfactory and at other times hardness and shrinkage would occur. Since the iron was chemically correct the foundries generally were at a loss as to what to do. They changed their method of melting in the cupola and in some cases this corrected the trouble. In some instances the foundry would continue eliminating a brand of iron until the castings produced were satisfactory. Through this process of elimination they would finally arrive at the conclusion that a certain brand of iron was causing the trouble. During the course of this elimination minor changes might have been made in the melting and in the end satisfactory castings were secured without discovering any definite reason for the trouble. Frequently the foundries blamed the manufacturer of the pig iron although the seat of the trouble was in their own method of melting. I have in mind one foundry in particular that was using three brands of pig iron for producing their castings and their losses were rather high. Three entirely new brands of iron were substituted in the charge and still the losses continued. Even after using six brands of pig iron the management felt that the pig iron was the cause. The difficulties encountered in the melting of iron in the cupola, over the past several years, reflect in a great many cases on the operation of the cupola. At different times certain brands of iron were unsuitable for producing a certain class of castings, but at the same time one could see no reason why the iron should be considered abnormal. Irons from furnaces where production and low cost are the main factors that are being used in foundries produce in most cases harder cast-

Jan 1, 1927

By Myrick N. Bolles

The concentration of gold and silver in mattes low in copper, and the subsequent separation and recovery of either or both of these metals, is a question the satisfactory solution of which has long vexed metallurgists. It covers a broad and important department of metallurgical science and brings in its train a series of attendant problems continuing from the initial operations of concentration to the final recovery of " values."

Jan 1, 1905

By R. G. Ward, John Henderson

It has been shown1 that the observed density1-' of liquid iron silicates in contact with solid iron depends upon whether nitrogen or argon is used to protect the experimental system from oxidation. These densities have been measured by the maximum bubble-pressure method, in five different labora-

Jan 1, 1965

By Frank M. Brewster

The handling of congealing oils and paraffin is a serious problem in the Appalachian fields, particularly because the small amount of oil produced per well makes the removing of paraffin a very costly operation per barrel. Few operators realize or have any means of knowing just how much production is lost on account of paraffin depositing over the face of the sand and plugging the pores of the sand; but where paraffin has been removed the production increases indicate that this loss has been considerable. Many operators believe that paraffining is confined to the tubing and pumping equipment, but it is evident that the most serious damage occurs on the face of the sand and a short distance back in the pores. This paper is an attempt to disseminate information on methods and processes in use in the Eastern fields for combatting losses of production and operating difficulties caused by deposition of paraffin in the pores, on the walls, on the tubing and on other pumping equipment. Mills1 covers this subject so thoroughly that excerpts, abstracts and quotations from his work have been used freely in this paper. Nature oF Paraffin Mills states: "The so-called paraffin that collects in oil wells, and in the pores of the producing sands immediately around the wells, is generally made up of amorphous wax or uncracked paraffin, asphalt, or other gummy hydrocarbons mixed with more or less water, oil and inorganic silt. Some of the samples of this paraffin collected from oil wells in different fields and examined by the Bureau of Mines contains as much as 20 per cent. by weight of water and inorganic silt, whereas other samples are composed entirely of waxy hydrocarbons and oil. The inorganic silt accompanying this 'paraffin' is mostly fine sand, clayey materials, common salt and finely disseminated precipitates of calcium and magnesium carbonates. Sulfates of calcium, barium and strontium are less common constituents of paraffin.

Jan 1, 1928

By Morris Muskat

A general theory has been developed for the effect of permeability stratification on the efficiency of the gas-injection phase of cycling operations. It has been applied to three special types of permeability variation; namely, exponential, probability, and linear. In the case of the exponential permeability distribution the effect of areal pattern sweep efficiency was also taken into account. The exponential permeability distribution can be characterized by the ratio of the maximum to minimum permeability, which has been termed the stratification constant. Curves were calculated for the variation in total wet gas recovery and total gas throughflow, to give that recovery to various abandonment limits of the wet gas content in the produced gas, as a function of the stratification constant. The cumulative wet gas recovery decreases monotonically as the stratification constant increases and is generally higher at the lower values of the wet gas content abandonment limits. The total gas throughflow first rises to a maximum as the stratification increases, and then ultimately declines. The effect of the areal sweep pattern efficiency is relatively minor as compared to that of the stratification constant, except in the region of low values of the latter where the formation is substantially uniform. The probability distribution can be characterized by a "variation" parameter varying from o to I as the formation changes from strict uniformity to extreme variability. The curves of total wet gas recovery and total gas throughflow to different abandonment limits of wet gas content versus the variation parameter have the same general characteristics as for the exponential permeability distribution. In the linear permeability distribution the ratio of maximum to minimum permeability also serves as a stratification constant index defining the distribution. The curves of total wet gas recovery and gas throughflow to fixed abandonment limits versus the stratification constant are similar to those for the exponential permeability distribution. However, for the higher values of the stratification constant the recoveries and throughflows do not asymptotically fall to o as in the latter, but approach constant values determined by the abandonment limit of wet gas content in the produced gas. Introduction It is becoming generally recognized that one of the most important factors determining the economic feasibility of cycling operations is the areal continuity and permeability distribution of the producing formation. While the effects of areal variations in permeability, porosity, thickness, and well pattern on the sweep efficiency can be evaluated by electrical model studies,' those due to permeability stratification require separate treatment. Several studies have been reported2,3 on the' influence of permeability variations on the wet gas recovery by cycling. In these, however, discontinuous permeability variations either have been assumed explicitly, or the analysis has been carried through as if they were discontinuous. While, in fact, the actual permeability profiles will undoubtedly be discontinuous, recent develop-

Jan 1, 1949

By C. S. Matthews, H. C. Lefkovits

The performance of depletion-type reservoirs at the stage in which the gas is at such low pressure that gravity is essentially the sole driving force has been investigated both theoretically and by use of scaled models. A simple theory is developed which completely explains the scaled model experiments. It also agrees with some field data. When the range of production rates to be considered is less than 25, the theory predicts that the production rate decline curve for homogeneous reservoirs in which there is a free surface will be of the hyperbolic type with n = 2: The theory gives a physical significance to the parameter y. INTRODUCTION This investigation was undertaken to determine a method for prediction of performance of reservoirs where gravity is the sole driving agent. Depletion-type reservoirs fall into this category after the pressure has fallen to some low value. Some examples of this type are found at Healdton ('Oklahoma), Oklahoma City (Oklahoma), Midway-Sunset (California), and East Coalinga (California). Generally the production rate per unit thickness is quite low in such reservoirs, with the conse- quence that this stage is sometimes called the stripper stage. However, per well production rates may be of the order of 50 B/D because of the considerable sand thickness open in some of the reservoirs. In the past, predictions of behavior of such reservoirs have been based on empirical extrapolation of the rate of production to the economic limit. Difficulties arise when new wells are drilled in the field or when production is artificially curtailed, since in such cases the decline rate of individual wells or leases changes and no clear trend can be detected. It was hoped that the present study would lead to improved methods for evaluation of such reservoirs. The study was initiated by building a scaled model for a particular field and by running a number of experiments on this model. Later a simple theory was developed which explained the laboratory results completely. The theory led, as shown below, to a hyperbolic-type decline equation which had been used previously' in a completely empirical manner. THEORY The General Case The problem to be treated here is the following: We are given a homogeneous cylindrical porous reservoir with exterior radius r, wellbore radius r., and height h,, containing, from the bottom up to a height hit oil, some gas, and interstitial water (see Fig. 1 A). The portion of the reservoir between K, and h, is filled with gas at low pressure, with residual oil, and with interstitial water. If at a time t = 0, the level of the oil in the wellbore is lowered to a height h,, what is the production rate from the reservoir at a time to The configuration within the reservoir at some instant

Jan 1, 1957

By Jerry M. Thornton, Richard W. Cannon, Don C. Rotherham

This paper attempts to show the role of induced polarization (IP) and resistivity surveys in the discovery of the ore bodies of Gibraltar Mines Ltd. (N.P.L.) and the importance of conducting large enough surveys to properly evaluate the results. The first IP survey was conducted in the area in 1963. This survey was extended and other IP surveys were added to it for the next seven years. The data from these surveys was finally combined to produce four large scale plan maps of resistivity and percent frequency effect (PFE) results (N = 1 and 3). A halo-type anomalous zone 6000 ft wide and 14,000 ft long was thus outlined in the PFE maps. The four ore bodies of Gibraltar Mines were found to occur along the inside rim of this IP halo.

Jan 1, 1973

THE total crude production from the Dutch East Indies, and the British Protectorates of Sarawak and Brunei for 1932 is given in the following table: BARRELS BARRELS (42 GAL.) (42 GAL.) North Sumatra 4,226,935 Ceram 326,207 South Sumatra 13,956,157 Sarawak 2,739,650 Java 3,845,568 Brunei 1,322,725 Dutch Borneo (main island) . 9,406,733 Dutch Borneo (Island of Tara- kan) 6,579,184 Total 42,403,159 Production, which had shown a rapid increase from 1921 to 1929, has since been reduced. Exploitation drilling in the majority of the larger fields was suspended and existing production kept within predetermined limits by beaning. Most of the smaller fields were shut down entirely. The depth of producing levels varies widely in the different fields. Shallow fields with drilling depths to 500 meters (1650 ft.) are still numer-ous as well as those with depths between 500 and 1000 m. (3300 ft.). A few of the newer fields reach greater drilling depths. up to 1600 m. (5250 ft.). The deepest exploration well drilled to date (Djambi field, South Sumatra) reached a depth of 2332 m. (7650 ft.) before abandon-ment in March, 1930. The specific gravities of the various crude oils produced range between 0.65 (86.2° A.P.I.) and 0.95 (17.5° A.P.I.). The lighter crudes have a high gasoline content and fuel oils are derived from the heavier crudes, which usually are rich in paraffin.

Jan 1, 1933

By A. G. Weber, K. H. Coats, M. H. Terhune, R. L. Nielsen

Two computer-oriented techniques for simulating the three-dimensional flow behavior of two fluid phases in petroleum reservoirs were developed. Under the first technique the flow equations are solved to model three-dimensional flow in a reservoir. The second technique was developed for modeling flow in three-dimensional media that have sufficiently high permeability in the vertical direction so that vertical flow is not seriously restricted. Since this latter technique is a modified two-dimensional meal analysis, suitably structured three-dimensional reservoirs can be simulated at considerably lower computational expenses than is required using the three-dimensional analysis. A quantitative criterion is provided for determining when vertical communication is good enough to permit use of the modified two-dimensional areal analysis. The equations solved by both techniques treat both fluids as compressible, and, for gas-oil applications, provide for the evolution of dissolved gas. Accounted for are the effects of relative permeability, capillary pressure and gravity in addition to reservoir geomety and rock heterogeneity. Calculations are compared with laboratory waterflood data to indicate the validity of the analyses. Other results were calculated with both techniques which show the equivalence of the two solutions for reservoirs satisfying the vertical communication criterion. INTRODUCTION Obtaining the maximum profits from oil and gas reservoirs during all stages of depletion is the fundamental charge to the reservoir engineering profession. In recent years much quantitative assistance in evaluating field development programs has been provided by computerized techniques for predicting reservoir flow behavior. Because of the spatially distributed and dynamic nature of producing operations, automatic optimization procedures, such as those now in use for planning refining operations, are not now available for planning reservoir development. However, present mathematical simulation techniques do furnish powerful means for making case studies to help in planning primary recovery operations and in selecting and timing supplemental recovery operations. A number of methods have been reported which simulate the flow of one, two or three fluid phases within porous media of one or two effective spatial dimensions>-4 However, applying computer analyses to actual reservoirs have been limited mostly to two-dimensional areal or cross-sectional flow studies for two immiscible reservoir fluids. To obtain a three-dimensional picture of reservoir performance using such two-dimensional techniques, it has been necessary to interpret the calculations by combining somehow the results from essentially independent areal and cross-sectional studies. To the authors' knowledge, the only other three-dimensional computational procedure, in addition to those presented here, was developed by Peaceman and Rachford8 to simulate the behavior of a laboratory waterflood. Two computational techniques which may be used to simulate three-dimensional flow of two fluid phases are described in this paper. The first method, called the "three-dimensional analysis", employs a fully three-dimensional mathematical model that treats simultaneously both the areal and cross-sectional aspects of reservoir flow. The second method, called the vertical equilibrium (VE) analysis", is applicable

By H. E. Cline, D. F. Stein

A fine lamellar structure with interlamellar spacings ranging from 0.I to 3.7 was Woduced by high-speed directional solidification and used to study the interaction of dislocations with an array of bimetallic bound-am.es. The tensile flow properties were measured at elevated temperatures and the results interpreted in terms of an image force model. As the width of the plates decreases the strength increases according to a Hall-Petch relation, suggesting pile -ups. Considerable strengthening was also observed at elevated temperatures. In recent years composites containing a strong but brittle phase and a ductile but weak phase have been studied extensively in the search for a high-strength material with adequate ductility.' However, the strength of these composites has been limited to a volumetric average of the strengths of the component phases. In this paper we will show that a composite made by directional solidification of a Cu-Ag eutectic has strength properties that substantially exceed the strength of either of the metals in the composite, and an explanation for this increased strength will be presented. The Cu-Ag eutectic is a near ideal material to study for several reasons. The eutectic structure is made up of alternate plates of silver-rich and copper-rich phases with the same crystal structure.2'3 In addition, the mechanical and elastic properties of silver4 and copper5 are known over a wide range of temperatures and the eutectic microstructure is stable to nearly the melting point.6'7 Therefore, the properties of the eu-tectic are readily comparable to various theories involving the mechanical properties of copper and silver. The experiments consisted of producing directionally solidified Ag-Cu eutectic material, determining the structure and performing tensile tests at different temperatures and strain rates. EXPERIMENTAL A) Solidification and structure. A cylindrical ingot 2.2 cm in diam and 15 cm long was prepared from 99.999 pct pure materials and cast in argon. The ingot was placed in an alumina crucible and was direc-tionally solidified at 7 x 10"4 cm per sec in a Bridg-man apparatus in argon. Metallographic examination at both ends and along the length of the ingot showed a uniform structure that consisted of fine alternate plates of silver- and copper-rich phases. The plates were aligned parallel to the growth direction, as shown in the longitudinal section, Fig. 1, and were in small randomly oriented domains of parallel plates as viewed in a transverse section, Fig. 2. Four smaller ingots 0.175 in. in diam were solidified at speeds of 2Xlo-', 4.4 xlo-', 4.4 x 10-3, and4.4x10-4 cm per sec to produce a range of lamellar spacings. Replica electron micrographs were taken to resolve the individual plates as shown in Fig. 3. The copper-and silver-rich plates in the larger ingot were about

Jan 1, 1970