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By G. Carman Ridland

In conjunction with a geological investigation of the silver-bearing veins at Contact Lake, Northwest Territories, Canada, a survey was made with a Geiger-Miiller counter of the gamma-ray emissions from the rocks in the vicinity of the mine workings. Discontinuous pitchblende veins have been encountered occasionally in the silver-bearing fissures, and the geophysical survey was undertaken with the hope that abnormally high gamma-ray intensities, if detected, might lead to larger and more continuous pitchblende discoveries. Before the instrument was used at Contact Lake, preliminary tests were made, first with laboratory specimens at Princeton University, and later over known pitchblende deposits at the Eldorado property, LaBine Point, N.W.T. The Geiger-Müller counter, as adapted for field use, is described; the technique of transporting and operating the instrument is outlined; and the general precautions to be observed are discussed. The results obtained at Great Bear Lake show that the instrument is capable of detecting not only a pitchblende ore shoot in a shear zone, but also the mildly radioactive "host rock" at a considerable distance from the ore body. Hence, use of the Geiger-Müller counter is urged, not just for the detailed search for an ore body in a shear zone, but for the detection of possible radioactive "host rocks" in large-scale reconnaissance surveys of unexplored regions made by prospectors and members of federal geological survey parties. Location.—Along the rocky eastern shores of Great Bear Lake, in the Northwest Territories of Canada, lies one of the world's great radium-producing areas. The Eldorado mine, owned and operated by the Eldorado Gold Mines, Ltd., is at LaBine Point; while the Contact Lake mine, operated by Bear Exploration and Radium, Ltd. (B.E.A.R.), lies 9 miles to the southeast of LaBine Point and 2 miles south of Echo Bay, an indentation in the eastern shore line of Great Bear Lake. Geology.—The Eldorado company obtains its radium by the mining of the mineral pitchblende, which is found associated with a complex variety of metallic and nonmetallic minerals1 in quartz-carbonate veins occurring in metamorphosed pre-Cambrian sediment aries. Most of the pitchblende is intimately associated with a brown quartz and belongs to an early hydrothermal stage of mineralization during which safflorite-rammelsbergite and minor cobalt-nickel minerals were also deposited. Some pitchblende occurs with a group of minerals belonging to a later stage of mineralization in which the gangue is mainly dolomite and sometimes ferruginous rhodochrosite. Associated with this group are native silver and lead-zinc-copper sulphide minerals. The Contact Lake property owes its existence to the mining of rich, native silver ore shoots, which are

Jan 1, 1946

By G. Carman Ridland

In conjunction with a geological investigation of the silver-bearing veins at Contact Lake, Northwest Territories, Canada, a survey was made with a Geiger-Miiller counter of the gamma-ray emissions from the rocks in the vicinity of the mine workings. Discontinuous pitchblende veins have been encountered occasionally in the silver-bearing fissures, and the geophysical survey was undertaken with the hope that abnormally high gamma-ray intensities, if detected, might lead to larger and more continuous pitchblende discoveries. Before the instrument was used at Contact Lake, preliminary tests were made, first with laboratory specimens at Princeton University, and later over known pitchblende deposits at the Eldorado property, LaBine Point, N.W.T. The Geiger-Müller counter, as adapted for field use, is described; the technique of transporting and operating the instrument is outlined; and the general precautions to be observed are discussed. The results obtained at Great Bear Lake show that the instrument is capable of detecting not only a pitchblende ore shoot in a shear zone, but also the mildly radioactive "host rock" at a considerable distance from the ore body. Hence, use of the Geiger-Müller counter is urged, not just for the detailed search for an ore body in a shear zone, but for the detection of possible radioactive "host rocks" in large-scale reconnaissance surveys of unexplored regions made by prospectors and members of federal geological survey parties. Location.—Along the rocky eastern shores of Great Bear Lake, in the Northwest Territories of Canada, lies one of the world's great radium-producing areas. The Eldorado mine, owned and operated by the Eldorado Gold Mines, Ltd., is at LaBine Point; while the Contact Lake mine, operated by Bear Exploration and Radium, Ltd. (B.E.A.R.), lies 9 miles to the southeast of LaBine Point and 2 miles south of Echo Bay, an indentation in the eastern shore line of Great Bear Lake. Geology.—The Eldorado company obtains its radium by the mining of the mineral pitchblende, which is found associated with a complex variety of metallic and nonmetallic minerals1 in quartz-carbonate veins occurring in metamorphosed pre-Cambrian sediment aries. Most of the pitchblende is intimately associated with a brown quartz and belongs to an early hydrothermal stage of mineralization during which safflorite-rammelsbergite and minor cobalt-nickel minerals were also deposited. Some pitchblende occurs with a group of minerals belonging to a later stage of mineralization in which the gangue is mainly dolomite and sometimes ferruginous rhodochrosite. Associated with this group are native silver and lead-zinc-copper sulphide minerals. The Contact Lake property owes its existence to the mining of rich, native silver ore shoots, which are

Jan 1, 1946

By George Smith

Introduction THAT an oil-land law is the most needed item in the proposed program of mineral-land legislation follows from the fact that Congress has never enacted a law really applicable to petroleum and natural gas. The action of Congress in 1597 in authorizing entry of oil-lands under the placer law, enacted 27 years before for the mining of gold in surface gravels, was plainly only makeshift legislation. Naturally the provisions of this placer law with its requirement of discovery as a prerequisite to location are nothing less than absurd when applied to petroleum deposits hundreds or thousands of feet beneath the surface. Other reasons which render oil-land legislation an urgent necessity arise first from the large acreage of lands believed to be valuable for their deposits of oil and gas and therefore withdrawn by Executive order from all entry pending the enactment of an appropriate law for their disposition-a withdrawal that has been specially ratified by Congress in the case of one State, Utah-and second from the exceptional importance of this resource to the nation, the large industrial worth of petroleum, and indeed its paramount value to the navy, not being suspected 17 years ago when Congress last legislated upon this subject. Mineral land of this type is also well adapted to serve for purposes of illustration in discussing the general principles that demand recognition in legislative reform. Most of the issues involved in the consideration of oil-land legislation are clean-cut, and essential differences of opinion will be seen to be based upon radical divergence in economic theory rather than upon conflicting views concerning unimportant details. For the last five years or more the geologists of the Federal Survey have discussed this subject and prepared memorandums and reports on .the various bills introduced in Congress. Most of the provisions suggested in the present outline have been under consideration at one time or another during that period, and many of the statements which follow can be said to represent the consensus of opinion among those of us who, both in the field and in the office, have given special attention to the public oil-lands.

Jan 6, 1914

By S. F. Shaw

THE Sierra Mojada mining district is situated in western Coahuila, about 8 km. east of the Chihuahua state line, and about one-half way from the northern to the southern extremity of the state. It is at the terminus of the Mexican Northern R. R., 125 km. northeast of Escalón, Chihuahua; also about 240 km. due west of Monclova, Coahuila. The altitude is approximately 1500 m. above sea level. The Sierra Mojada valley is about 10 km. long, from east to west, with a width of 1 to 2 km. It is approached from the east through the Puerto del Oro, where the Mexican Northern R. R. enters the valley; the slope from west to east is gentle. The Sierra Mojada, of which about. 300 m. is an almost vertical wall, bounds the valley on the south side; on the north side, the slope to the crest of Sierra Planchada is more gradual, rising only 200 or 300 m. above the valley. Water is relatively scarce in the district, and there are no running streams. The rainy season, usually beginning at the middle of June, lasts through July, and occasionally into August or September. In some years the rains fail entirely. The slope of the ground is such that nearly all the water immediately runs off. The arroyos along 'the flanks of the mountains are not very deep, but in heavy rains, sometimes approaching cloudbursts, a tremendous volume of water rushes down them, carrying large boulders. A certain amount of seepage collects in the agglomerate, lying below the conglomerate, and is retained in the local fractures. Some shallow wells have been sunk in this agglomerate, and one well over 150 m. deep was sunk on, the Volcan ranch, supplying about 76 1. (20 gal.) per min. A considerable supply of water is collected in large earth reservoirs in and below the town of Esmeralda. In ordinary years this supply will last until January or February, after which the Volcan well has to be depended on until the next rainy season.

Jan 8, 1922

By R. F. Shurtz

This paper relates geostatistical doctrine to classical statistical and mathematical concepts. It is not a contribution to geostatistics; it is a contribution about geostatistics. It uses descriptive and pictorial arguments to assist interested readers in forming an intuitive grasp of the recondite and difficult mathematical issues involved. The method chosen is to cite authoritative literature references from the two fields and trace connections between them. Four broad conclusions appear: first, geostatistics comprises a relabelled subset of concepts detached from classical statistics and mathematics; second, this relabelling artificially isolates geostatistics from the classical fields and restricts its scope; third, the classical fields still have much to offer to the mining industry but will remain fallow unless artifcial communication barriers are removed; and fourth, the unique advantages asserted for geostatistics are neither unique nor necessarily real. These findings should not be regarded as iconoclastic but rather as Pointing the way to a wider and more productive scope for those who evaluate mineral deposits.

Jan 1, 1983

By A. E. Schuetz, A. E. Roswell, W. R. Hibbard

THE drawn wire texture of body-centered cubic iron,' tungsten,' and molybdenum~ as been determined to be a [110] direction parallel to the wire axis. The purpose of this study is to extend the available information on body-centered cubic wire textures to other metals and alloys. Wires were produced using hand wire rolls and dies as given in Table I. In addition, attempts were unsuccessful to draw wires from chromium, vanadium (Vanadium Corp. of America), and tungsten (Cleveland Tungsten Inc.). Although it is known that wires can be made from these materials, suitable techniques were not readily adaptable. Where necessary, wires were polished and etched to form flat ribbons 0.005 to 0.007 in. thick, and transmission X-ray patterns were taken using molybdenum radiation with the specimen tilted 0 degrees from the perpendicular toward the beam to critically cover the wire axis. Analyses were made of (110), (002), and (112) reflection circles. In all cases reflection maxima indicated the texture to be a single [1101 deformation fiber, as illustrated by Fig. 1 for molybdenum. In the case of the hot-worked ß brass, a second texture, [loo], was also found, but this is believed to be the result of recrystallization since it has been reported for re-crystallized molybdenum wires' and it was not present in the cold-drawn ß brass. The difference in drawability between the 51.92 pct Cu ß brass and the 62.5 pct Cu ß brass (containing some grain boundary a due to incomplete quenching) is quite striking, since the latter could be cold worked readily while the former had to be hot worked to avoid cracking. Summary The deformation texture of drawn body-centered cubic wires of ß brass, iron, molybdenum, niobium, and tantalum is essentially a single [110] fiber as predicted by theory.' Acknowledgment The authors wish to thank the suppliers of the metals listed in the text, and the Grant-in-Aid from the Research Fund of the Society of the Sigma Xi and Scientific Research Society of America which made possible the purchase of X-ray equipment.

Jan 1, 1952

By R. G. Ward, John Henderson. R. G. Hudson, G. Derge

Densities of melts of the iron oxide-silica system in contact with solid iron have been measured by the maximum hubble pressure method in the composition range O to 37 wt pct SiOz and the temperature range 1255 to 1410C. The constitution of the melts is discussed and it is postulated that the structure changes from a dislribution of iron ions in an oxygen ion network at pure "FeO" to a distribution. of iron ions in a network of silicate tetrahedra at the orthosilicate composition. JOHN HENDERSON, Junior Member AIME, was formerly with the Metals Research Loborotory, Carnegie Institute of Technology, Pittsburgh, Pa., on leave from Broken Hill Proprietary Co., Ltd., Research Division, Shortland, Australia. R. G. HUDSON, formerly with Metals Research Laboratory, is now with the John Jay Hopkins Loborotory for Pure and Applied Science, General Atomic Division, General Dynamics Corp., LaJolla, Calif. R. G. WARD, was formerly with the Department of Metal lurgical Engineering, Carnegie lnstitute of Technology, while on leave from the Department of Metallurgy, University of Sheffield, England. G. DERGE, Member AIME, is Jones and Laughlin Professor of Metallurgical Engineering, Carnegie lnstitute of Technology. Manuscript submitted January 19, 1961. ISD The system iron oxide-silica is an important one metallurgically because it forms the basis of several complex slag systems in use for industrial smelting and refining processes. In recent years considerable work has been done on liquids of this system but there are still many points of difference among workers using different experimental techniques and theoretical approaches. Phase equilibria/"3 activity,4-6 electrical conductivity,' current efficiency,' transference number,8 viscosity,9 surface tension,'' and density" measurements have all contributed to an understanding of the problem. Measurement of density is one procedure which is directly indicative of liquid structure since any deviation from ideality must be a result of structural interactions. Liquids of the iron oxide-silica system are of special interest because this is one of the few metal oxide-silica systems on which measurements can be carried out conveniently over the entire composition range from pure oxide to silica saturation. This includes the range of high basicity which has received relatively little attention in other systems. Although one investigation of density in this system has previously been undertaken," the results seem of sufficient importance to warrant the independent redeter-mination reported here.

Jan 1, 1962

By P. M. Blair

This paper presents numerical solutions of the equations describing the imbibition of water and the countercurrent flow of oil in porous rocks. The imbibition process is of practical importance in recovering oil from heterogeneous formations and has been studied principally by experimental means. Calculations were made for imbibition of water into both linear and radial systems. Imbibition in the linear systems was allowed to take place through one open, or permeable, face of the porous medium studied. ln the radial system, water was imbibed inward from the outer radius. The effects on rate of imbibition of varying the capillary pressure and relative permeability curves, oil viscosity and the initial water saturation were computed. For each case studied, the rate of water imbibition and the saturation and pressure profiles were calculated as functions of time. The results of these calculations indicate that, for the porous medium studied, the time required to imbibe a fixed volume of water of a certain viscosity is approximately proportional to the square root of the viscosity of the reservoir oil whenever the oil viscosity is greater than the water viscosity. Results are also presented illustrating the effects on rate of imbibition of the other variables studied. INTRODUCTION The process of imbibition, or spontaneous flow of fluids in porous media under the influence of capillary pressure gradients, occurs wherever there exist in permeable rock capillary pressure gradients which are not exactly balanced by opposing pressure gradients (such as those resulting from the influence of gravity). The importance of such capillary movement in the displacement of oil by water or gas was recognized in early investigations and described by Leverett, Lewis and True in 1942.1 Methods advanced by these authors for studying the process using dynamically scaled models were rendered more general and flexible by the research of later workers.2"4 The influence of capillary forces in laboratory water floods has also been discussed by several authors.6 While imbibition plays a very important role in the recovery of oil from normal reservoirs, Brownscombe and Dyes7 pointed out that imbibition might be the dominant displacement process in water flooding reservoirs characterized by drastic variations in permeability, such as in fractured-matrix reservoirs. In water-wet, fractured-matrix reservoirs, water will be imbibed from fractures into the matrix with a countercurrent expulsion of oil into the fractures. If the imbibition occurs at a sufficiently rapid rate, a very successful water flood can result; if the imbibition proceeds slowly the project might not be economically attractive. Scaled-model studies have demonstrated the vital importance of imbibition in secondary recovery in fractured reservoirs. It is therefore important in the evaluation of waterflooding prospects to develop a thorough understanding of the quantitative relationships of the factors which control the rapidity of capillary imbibition. The imbibition process serves reservoir engineers in still another important way by providing a technique for studying the wettability of reservoir core samples. Such experiments are usually conducted by observing the rate of expulsion of oil or water from core samples submerged in the appropriate fluid. Several papers have been 'published on the experimental techniques involved?? Although Handy has recently published a method for calculating capillary pressures from experiments with gas-saturated cores, it has not yet been possible to deduce quantitative information regarding water-oil relative permeability and capillary pressure characteristics of the rock from the experimental results. Thus a technique is needed for studying the quantitative dependence of imbibition rate on oil and water viscosity, initial water saturation, relative permeability-saturation, and capillary pressure-saturation relations. The development of such information, including saturation and pressure profiles by laboratory experiments, would be very difficult. However, recent advances in the applica-

Jan 1, 1965

By Richard Bosustow, Van Dyne Howbert

The Presidio mine of The American Metal Co. is situated in the "Big Bend" region, some 45 miles over state highway south of Marfa, a station on the Southern Pacific R.R. It lies 20 miles by road north of the Mexican border, in semidesert surroundings typical of this general section of the United States and the adjoining part of Mexico. All supplies are hauled in by truck from Marfa under contract. The concentrates and precipitates produced by the mill are carried by the same trucks to Marfa, from whence they are shipped, respectively, to the El Paso and Selby plants. History The mine was discovered about the year 1880 and was soon thereafter taken over for development by some army officers stationed at Fort Davis, Texas. It was later operated by the Presidio Mining Co., which treated the ore in a small pan-amalgamation mill from 1883 until 1913, when a cyanide plant was erected which has been in continuous operation ever since. When the present company, a subsidiary of The American Metal Co., Ltd., took over the mine in April, 1926, the ore-bearing zone had been worked for about 2200 ft. to the east of I the outcrops down the dip of the formation, at which point it is at a I vertical depth of 500 ft. below the surface. Up to that time the mine had produced some 1,150,000 tons of ore averaging about 17 oz. silver. After a development campaign the company started milling again in February, 1927. Since then the production has been approximately 4700 tons per month of ore; of which the yearly average grade has varied from 19.7 to 23.2 oz. silver, $0.20 to $0.50 gold, and 2.0 to 2.5 per cent. lead. No other property in this district has ever produced tonnage of any importance.

Jan 1, 1931

By M. H. Gaskell, D. C. Lindley

Small, steeply inclined reservoirs without natural water drives often are found associated with salt domes or other highly faulted structures. Frequently, only one well may be economically justified in these reservoirs, from which oil is produced by an expanding gas-cap drive or by a dissolved-gas drive. Although a large fraction of the oil upstructure from the well may be recovered during primary depletion, only a small fraction of the downdip oil can be produced because of gravity effects. This downdip oil has been defined as cellar oil991 in contradistinction to "attic oil" which is the oil above the structurally highest well in reservoirs where a natural water drive is present. In this study, two methods of producing cellar oil by water flooding a one-well reservoir were investigated by means of a laboratory model. This model was scaled to represent a prototype reservoir having an area of 30 acres, a permeability of 500 md, and a thickness and dip of 30 ft and 30°, respectively. One method considered, the simultaneous injection of water and production of oil from a single well, would require that the lower portion of the productive interval of a well be completed for water injection and the upper portion for oil production. The other method considered, intermittent injection, would involve alternate injection of water into and production of oil from a single well. Injection of water into the formation would repressure the reservoir, causing gas to go back into solution. Since some of the injected water would flow updip from the well, water injection usually would be followed by a waiting period during which the water could drain from above the wellbore. Production of oil by gravity drainage and gas-cap drive could be initiated when water drainage became sufficiently complete. The amount of water produced along with the oil would naturally depend on how soon after water injection ceased that production was started. This process could be repeated in cycles until oil could no longer be produced economically. Of these two methods, the intermittent injection technique would be simpler to put into operation since it does not require a dual completion. Also, it is probably more generally applicable than the simultaneous injection-production method. It is to be expected that in some reservoirs the rock and fluid properties would be such that practical oil-production rates could not be achieved by the simultaneous technique. However, in reservoirs where the simultaneous method will result in practical rates of oil production, it does have the advantage of permitting immediate, continuous oil production; whereas in the intermittent method, oil production is interrupted by periods of water injection and drainage. It was the objective of this study to determine whether these two methods of cellar oil production are practical for the representative prototype investigated and to evaluate their relative merits. DESIGN OF LABORATORY MODEL SCALING REQUIREMENTS The prototype reservoir and fluids were selected to have the dimensions and physical properties shown in Table 1. The laboratory model was then designed in accordance with well known scaling criteria, as discussed by Croes, et al,2 except for one modification. According to Croes, et al, one requirement of scaling a laboratory model to a reservoir prototype is that both the relative permeabilities and dimensionless capillary pressure be the same functions of water saturation for the model and the prototype. Since unconsolidated sand packs are used in the laboratory model to represent the consolidated porous media of the prototype, it is virtually impossible to satisfy this requirement. Much of the difficulty stems from the fact that unconsolidated sands usually exhibit lower residual oil and connate-water saturations than do reservoir rocks. To satisfy the scaling requirement as nearly as possible, Perkins and Collins' have suggested that the relative permeabilities be re-defined as

By John W. Vanderwilt

THE Climax district is in northeastern Lake County, Colorado, on Fremont Pass (elevation 11,320 ft.) where the continental divide runs east-west joining high peaks of the Mosquito Range with the Sawatch Range, prominent ranges of the central Rocky Mountains. The mining towns of Leadville and Kokomo are thirteen miles to the south and seven miles to the northwest, respectively. Good highways lead to Denver (100 miles) by way of Kokomo, Loveland Pass, and Idaho Springs, and to Colorado Springs by way of Leadville. The ore deposit and mine are about one mile east of Fremont Pass and 600 ft. higher on the southwestern flank of Bartlett Mountain, a peak in the Mosquito Range. The molybdenite deposit lies within the Colorado mineral belt extending across the Rocky Mountains from Jamestown and Boulder to Silverton and Telluride. (See Fig. 1.) Fremont Pass is a broad open divide separating the drainage of the Tenmile River (Pacific) from that of the East Fork of the Arkansas River (Atlantic) ; but the mountains to the east and west are extremely rugged; altitudes in the vicinity vary from 11,000 to 14,000 ft. A conspicuous topographic feature within the district is the Tenmile Amphitheater, which lies east of Climax and

Jan 1, 1946

By W. C. Peters

From the time of its beginning in the mid-19th century, the American barite industry has had its major development in the eastern and central states. Geologic and economic factors serve to maintain Arkansas, Missouri, and the Southern Appalachian states in the lead position. In earlier days, the major markets for barite were in paint, chemical, and glass manufacturing, and the favored deposits were those which were close to eastern industrial areas; furthermore, the eastern deposits were cheaply mined and required little or no beneficiation. In the last few decades, the use of barite as a weighting medium for muds in rotary oil well drilling has caused a great expansion in the industry, but the marketing picture is still centered outside of the western states-now on the Gulf Coast area where high pressures are common in oil wells. Low cost imported barite, readily available on the East Coast and Gulf Coast, has always been a major marketing factor in the industry. The major barite producing state is Arkansas, with the industry centering about the Magnet Cove area. Missouri ranks second, with production mainly from residual deposits. Several Southestern states are actively producing from residual deposits.

Jan 9, 1958

By Haim Chiswik

IN recent years considerable attention has been devoted to the devel-opment of new commercial uses for silver, chiefly because of lowered prices and large stocks of the metal. This has led to increased interest in the phase diagrams of silver alloys. The silver-lead diagram is reported' to be of the simple eutectic type, but no measurements of the solubility of lead in silver have been made. The solubility of silver in lead has been estimated2 from diffusion experiments and resistance measurements to vary with temperature from 0.09 to 0.18 atomic per cent (0.05 to 0.10 weight per cent). Silver-rich silver-lead alloys have recently been recommended as high-strength bearing metals.3 The silver-bismuth diagram is similar.' The solubility of bismuth in silver has been estimated to be about 5.5 weight per cent on the basis of X-ray work.4 Matthiessen5 found a solubility of silver in bismuth from 0.25 to 0.50 per cent by conductivity measurements. Silver and thallium form the same type of diagram,1 with no data on their mutual miscibilities. We have studied the first two of these diagrams by X-ray methods, verifying their main features and determining the solubilities of lead and bismuth in silver at several temperatures. We also determined the solubility of thallium in silver at one temperature. The solubilities of silver in lead and in bismuth were found to be too low to be detectable.

Jan 1, 1940

By W. Rostoker

Single isothermal sections were constructed for the titonium-rich corners of the systems Ti-Fe-O, Ti-Cr-O, and Ti-Ni-0 with a view to locating the shape and disposition of the ternary intermediate-phase fields for the compounds isomorphous with Fe3W3C. IN a previous note,' it was reported that a group of ternary intermediate phases existed which occurred in the general composition range Ti,X,O-Ti&O where X was one of the following elements: copper, nickel, cobalt, iron, or manganese. In two instances, binary intermediate phases occurred (Ti²Cu and Ti²Ni) which appeared to be isomorphous. The X-ray diffraction patterns of the phases could be indexed on a cubic lattice whose cell edge was of the order of 11 kX. Karlsson2 stated that the line extinctions and line intensities indicated that these phases were isomorphous with Fe³W³C and therefore belonged to the space group Oh. This author also noted that no unique phase of this type occurred at the composition Ti,Cr,O. This latter statement was accepted as true at the time the previous technical note was written.' However, work continued along these lines and that reported here has shown that a phase isomorphous with Fe³W³C does exist in the vicinity of the composition Ti³Cr³O but not at or near Ti4 Cr²O. The lattice parameter of this phase was found to be 13.01 kX. Metallographic examination of both as-cast and annealed specimens of these supposed ternary oxide phases disclosed structures which were far from single phase in many instances. It was considered a point of some interest to locate more positively the composition coordinates of the single-phase fields. To this end, single isothermal sections for the systems Ti-Fe-O (1000°C), Ti-Cr-0 (1000°C), and Ti-Ni-0 (900"C) were constructed. Phase relationships were studied by both X-ray diffraction and metallotrra~hic methods. Allovs were prepared as 10 g buttons by melting in a noncon-sumable electrode, water-cooled copper crucible arc-melting furnace using a helium atmosphere. Oxygen was introduced quantitatively by the use of weighed amounts of TiO² or TiO. Iodide titanium and the purest available alloying metals were used. All results are discussed in terms of the nominal composition of the melts. Previous experience with making oxygen-rich alloys had shown that oxygen losses were not significant if a homogeneous melt was produced. Weight-loss measurements were used to check loss in metallics during melting. Anneals were conducted in evacuated Vycor bulbs, and annealing times ranged from 24 hr at 1000 °C to 48 hr at 900°C. To achieve equilibrium in certain sluggish alloys, seven-day anneals were used. Debye-Scherrer powder patterns were taken in a 14 cm diam camera using filtered CuK radiation (K² = 1.541232 kX; K., = 1.53739 kX). Specimens were prepared by crushing and screening previously annealed buttons. In general, the X-ray diffraction results were used to identify the major phases, while the metallographic examinations were more useful in indicating the number of phases present. By the use of the combined results and general fundamental rules governing ternary equilibrium, it was possible to construct isothermal sections in good detail. In some instances where auxiliary lattice-parameter data were available, it was possible to lay down tie lines and to locate more positively corners of three-phase fields. Isothermal Section of the System Ti-Fe-O at 1000°C The binary systems Ti-O³ and Ti-Fe4 have been published. Binary phases, TiO, TiFe, and TiFe2, are likely to be encountered in the titanium-rich corner of the system. The structures are NaCl (Bl), CsCl (B2), and MgZn, (C14) types, respectively. Although preliminary X-ray diffraction studies indicated the presence of a ternary phase in the composition range Ti,Fe,O-TiJ?e,O, metallographic examination of two specimens at these compositions revealed the presence of other phases. Thirty-eight alloys were used to delineate the phase boundaries of the isothermal section illustrated in Fig. 1. The five almost single-phase ter-

Jan 1, 1956

By Eugene C. Robertson

INTRODUCTION A direct proportionality between the observed displacement of a fault and its thickness of breccia and gouge has been proposed recently (Robertson, in press). To validate this finding, an explanation of the mechanics of continuous breccia formation is needed and is offered in this paper. A summary of evidence for the finding will show why an explanation is needed. The correlation between fault displacement [d] and accompanying breccia- plus-gouge thickness [t] seems to be linear and reasonably well established over 6 orders of magnitude, with a range in [d] from 1 mm to 1 km, on a trend of [d/t]= 100, shown in Figure 1. Most of the points are for faults observed underground in mines. The [d] – [t] relation is limited to normal and reverse faults, that have a flat to steep dip and a displacement less than 5 km. It is not applied to large strike-slip and low-angle overthrust faults, whose displacements and breccia thicknesses are widely variable and uncertain. Undisplaced jointed rock is not included in the thickness measurement. A complete description of sources and analysis of the data is given in Robertson (in press). One would intuitively expect that continued movement on a fault would grind up the previously formed breccia and gouge and not produce any more, but the evidence (Fig. 1) indicates otherwise. A physical model to explain continuous formation of gouge and breccia from the wall rocks can be obtained from laboratory experiments on friction.

Jan 1, 1982

By E. L. Swarts

In the course of a program on high-temperature processing and electrowinning of uranium at the Knolls Atomic Power Laboratory,'' it became necessary to give attention to the interaction of molten uranium with graphite. Although it is known3 that a protective interface layer may form, details of this reaction have not been reported. Unfortunately it was impossible to complete the planned experimental program. However, the general problem is considered of sufficient interest to warrant reporting those preliminary results actually obtained. EXPERIMENTAL PROCEDURE Interface carbide layers were formed by melting samples of cleaned uranium metal in small closed graphite crucibles. Equilibrations were conducted in vacuo or in an atmosphere of dry helium at temperatures ranging from 1150" to 1400°C and for periods of from 24 to 240 hr.

Jan 1, 1960

By L. C. Morganroth

From a geological standpoint, but scant attention has been paid to fire-clay beds. Only within the last few years have they been the subject of individual investigation, prior to this time having been considered only in their relation to coal seams. While the relative importance of coal and fire clay is still immeasurably in favor of coal, yet an industry as large as that of fire clay is entitled to a measure of attention. A discussion of the Carboniferous clays is practically a discussion of the clay beds in the Appalachian basin, since more than 90 per cent. of these clays mined are from this region. The clays are confined to the northern end of the basin, or the States of Pennsylvania, Ohio, Kentucky, Maryland and West Virginia, ranking in importance about in the order named. The clay deposits of the Carboniferous period have been divided into two classes; those found in the Pottsville conglomerate series of rocks, ' and all those that are found in the formations above, for the reason that the clay beds above the Pottsville series all resemble each other in properties, composition and appearance, and all are distinctly different from the bed found in the Pottsville formation. The bed of clay found in the latter formation is unique in that flint clay is practically restricted to it. (A variety of flint clay is occasionally found in these upper deposits but this is in such small amounts as to be negligible.) Carboniferous clays occur between stratified rocks; sandstones, limestones, etc., in the same manner as coal veins. They are often accompanied by a coal vein although where the clay is of a workable thickness, the coal is generally too thin to work. The clay beds are sometimes known by the name of the coal seam at which horizon they occur. Clay beds may be from a few inches up to 20 ft. in thickness. They may consist of all soft clay, all flint or both soft and flint. The Carboniferous clay beds of Pennsylvania are the most important of any of the clay beds found in the country, and are among the oldest ones worked. We know more about this clay geologically for the reason

Jan 1, 1916

By B. D. Cullity, A. Freda

It is well known that deformation by cold drawing or swaging produces a kind of preferred orientation called fiber texture in metal wires. Such textures have been extensively studied by means of X-ray diffraction, chiefly by techniques in which the diffracted X-rays are recorded photographically. This paper describes some results obtained with a new method, involving the use of a diffractometer. X-RAY METHOD Since the pole figure of a material having a fiber texture is symmetrical about the fiber axis, there is no need to present the entire pole figure. Instead, texture data can be summarized by means of a curve showing the variation of pole density along any meridian of the pole figure, if the north-south axis of the latter is made parallel to the fiber axis. The position of a pole on the meridian is specified by the angle 9 between the pole and the fiber axis (wire axis). The X-ray method1 used here to measure pole density as a function of 9 actually consists of two methods, referred to as A and B. In method a, X-rays are reflected from the wire surface. Pole densities can be measured by this method from O = 90 deg down to a limiting value which is dependent on the Bragg angle 8 and is typically of the order of 30 to 40 deg. Method B involves diffraction from the wire cross section and covers a range of 0 values from 0 up to an angle sufficient to overlap the measurements made by method A. By a combination of the two methods, a complete pole-density curve can be obtained. However, method A alone, which requires no specimen preparation other than etching, can often reveal enough of the pole-density curve to provide complete information about texture components. Both methods require that the measured diffracted intensities be corrected for changes in absorption and diffracting volume with changes in 9. A11 intensities I reported in this paper are corrected diffracted intensities; they are propor-

Jan 1, 1960

By J. O. Glanville, L. H. Haley

Ice frozen from a dilute chemical solution is mechanically weaker than ice frozen from pure water. This phenomenon is the basis of a practical method for reducing the strength of a mass of frozen coal. If a chemical additive is applied to moist coal prior to its shipment during freezing weather, the resulting frozen coal can be more easily broken than in the absence of the chemical additive. This greatly expedites the unloading and handling of coal during winter. There has been considerable research into the nature and mechanical strength of ice frozen from various solutions. In this paper, literature relating to this process as well as literature relating to the chemical treatment of coal and mineral particulates is reviewed. Some important articles are discussed and speculations made about the nature of the ice-weakening process. A laboratory evaluation of the effects of chemical additives on the mechanical strength of ice and frozen coal has been made. An apparatus designed for this purpose is described, and some results obtained with it are discussed.

Jan 1, 1983

By M. G. Corson

THE iron-silicon alloy series has always been one of the most puzzling among the binary alloys. Examining the well known mechanical properties of the iron-rich alloys only we meet the following situation: The ultimate strength and yield point of alloys worked and annealed under the usual conditions represent nearly a straight line function of the silicon content up to 4.5 per cent. silicon (Fig. 1). Starting at the ultimate strength of 35,000 lb. and at a yield point of 16,000 lb. for pure electrolytic iron, one reaches a maximum strength of 93,000 lb. and a maximum yield point of 74,000 lb. at 4.5 per cent. silicon. This corresponds to an increase in ultimate strength by 13,000 lb. per each per cent. of silicon added and nearly the same rate applies to the yield point. The data mentioned are taken from the investigation by T. D. Yensen,1 and while they do not exactly corroborate the results obtained by earlier investigators, they seem to be the most correct. Plastic properties of the alloys are controlled by a much more complicated relationship. Up to 2.5 per cent. Si, the elongation stays close to 50 per cent. (in 2 in.) and the area reduction amounts to 85 per cent;, a situation that forms the usual feature of all alloys representing strictly solid solutions. The plasticity of the latter is always nearly equal to that of their base metal. Beyond 2.5 per cent. silicon, the situation becomes much more complicated. Yensen observed an enormous drop in elongation and area reduction at about 2.65 per cent. silicon, where the first hardly reaches 10 per cent. and the second is still lower; he found, however, a considerable recovery in plasticity at about 2.8 per cent. Si and up to 4.5 per cent. Si it is represented by 20 per cent. for the elongation and 30 per cent. for area reduction.

Jan 1, 1928