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By J. E. Strassner

Oilfield emulsions are stabilized primarily by film-forming asphaltenes and resins containing organic acids and bases. Adding inorganic acids and bases radically changes the physical properties of these films and their emulsion-stabilizing properties. Interfacial films show one of three different physical characteristics when retracted in pendent drop tests. These compressed films have rigid, soap-type or minimum film properties depending on the quantity of asphaltenes and resins in the crude oil and on the pH and composition of the brine. There exists for each crude oil-brine system an optimum pH range over which the adsorbed film exhibits minimum contracted filtn properties. In this range, intmfacial tension is high — frequently near its maximum value — indicating the absence of highly surface-active specier; crude oil-brine emulsions generally show minimum stability; and surfactant requirements for breaking these emulsions are significantly reduced — sometimes no surfactant is needed. About two-thirds of the world's crude oil is produced as emulsions that must be treated (demulsified) to be marketed.' Approximately three-fourths of all domestic crude oil produced must be treated. The percentage of crude requiring treatment increases as fields become older and more water is produced. Demulsification most frequently is attained through use of surfactants, heat and electric treaters. It is estimated that over 75 percent of all oilfield emulsions are broken by chemicals generally containing alkylene oxide condensates. Although acids and bases are known to affect emulsion stability:-' they rarely are used in the oil field except in batch treatment of the most severe emulsions. Nevertheless, pH adjustment by using acids or bases in demulsification has some advantages over other methods. Mainly, it is cheaper. Acids and bases frequently are cheaper to use than surfactants, or can appreciably reduce the amount of surfactant required for demulsification. Secondary advantages are that less oil is lost by emulsi-fication into the aqueous phase, and that less corrosion is encountered when the optimum pH is basic. Limitations to the use of pH include (1) use in brines containing high concentrations of reactive ions, (2) closer supervision for pH control than is required for surfactants and (3) need for corrosion protection when the optimum pH is sufficiently acidic. These factors indicate that the economics of pH con trol in demulsification will be maximized when relatively large treating facilities are needed, when relatively large surfactant concentrations are required to break an emulsion, when a relatively low concentration of the aqueous phase is emulsified in the oil and when the emulsified aqueous phase contains relatively low concentrations of reactive ions. Because there are no broad guide lines for using pH control in breaking oillield emulsions (and because the limited guides available are highly specific and frequently contradictory), this paper will attempt to clarify the principles involved in using acids and bases to break emulsions. These principles also should be useful in refinery separations and in other oilfield applications where stable or unstable petroleum emulsions are involved. Principles of Emulsion Stability Oilfield emulsions generally occur as water droplets dispersed in oil (w/o) and occasionally as oil droplets in water (o/w). These emulsion droplets are usually in the 0.1- to 10-micron range. However, more coarsely dispersed water droplets frequently are present in the emulsion. Pure hydrocarbons and water will not form stable emulsii except in extreme dilutions where the large distance brtween droplets inhibits coalescence. An emulsion breaks because interfacial tension acts to minimize the surface area of the dispersed drops by coalescence. However, emulsions can be stablized for long periods of time by the presence of a third phase that adsorbs at the oil-water interface and inhibits coalescence of the dispersed phase."' Emulsions generally are stabilized by (1) repulsive charges on the surfaces of the dispersed phase and (2) adsorbed films that, being preferentially wetted by the continuous phase, act as a physical barrier to inhibit contact between the dispersed droplets. Both these factors generally are important in stabilizing and in breaking o/w emulsions. However, repulsive charges are less effective in stabilizing w/o emulsions which generally are stabilized by adsorbed films.V or this reason the nature and importance of these films at oil-water interfaces were examined closely; as will be shown, pH changes were found to affect the films significantly, and this work led to laboratory tests of pH- adjustment in emulsion breaking. This paper will present evidence to show that emulsions are stabilized primarily by films that form around droplets

Jan 1, 1969

By A. Taylor, S. Leber

WHEN studies of deformation texture, lattice stress, and crystal orientation are made, it is frequently required to know the interplanar angles and subsequently to embody the results of the investigation in a stereographic projection. Tables of

Jan 1, 1955

By Carel Robinson

THE little coal mine at Otsego, in the Winding Gulf field of southern West Virginia was dying. In the history of coal mining thousands of mines have been successful at first, but usually a change occurred and profits ceased. Often be change was so gradual and extended over such a length of time that the fundamental causes did not stand out in sharp relief and their significance was not realized. Studies often reveal that the cause for failure was in the arteries that connect the producing places with the mine entrance. Profits continued so long as the working places were close to the tipple and while the thrill of newness aid ease of access resulted in effective supervision from day to day. The air- way and haulageway, the wire line and manway, may have been sufficient when the distance from the entrance was a few hundred feet, but were inadequate when this was extended for thousands of feet.

Jan 1, 1937

By Albert J. Phillips

The effect of impurities on the flowsheet in the smelting and refining circuits for copper, lead and zinc is reviewed and the interflow of by-poduct metals from copper, lead and zinc plants is pointed out. The principal points of separation of all impurities in the circuits are indicated and the additional steps added to these circuits in order to effect impurity separation me shown. In this day and age, when difficult metallurgy is mentioned, one thinks of the extraction of more refractory or possibly the alkaline earth or rare-earth metals. It is true that the extraction of metals having a high affinity for oxygen and deleterious solubility for that element in the liquid metal, affords some of the most difficult extractive metallurgy problems. When this is coupled with an affinity for hydrogen, nitrogen, and carbon a devious approach is required that sometimes rivals the complexity of the metallurgy with which this paper deals. However, in all such cases the aim is for a simple

Jan 1, 1962

By HARRISON W. CRAVER

LIBRARIES are universally recognized as essential to modern civilization. In a world that gets most of its learning through the printed word, storehouses of print are a vital necessity. In this regard engineering differs in no way from the other learned professions, but until recent times the library needs of engineers have received rather scant attention. When the engineering profession was more of an art and less of a science than it is today, when each problem was solved more through the results of experience than by applying scientific principles, literature was less helpful. The engineer of today, however, is aware that his activities rest upon a scientific foundation and consequently comprehensive books dealing with more limited fields are now being published. Another difficulty for the operating engineer in the past was that the published works on engineering were written chiefly for use as college texts. A third obstacle to the development of engineering libraries has been the lack of librarians with experience in engineering.

Jan 1, 1938

By AIME AIME

T HE year 1920 will be a memorable one in the history of the world's coal supply. The prices reached were the highest of modern times, and as usually happens at such a time, the quality of the output deteriorated. In the last two years of the war, the world's output had risen close to the pre-war level. After the armistice, however, the cessation of munitions manufacture and the delay in resumption of normal business curtailed the demand for coal. Industrial disputes both in Europe and America closed many mines late in 1919 and further reduced the supply. Thus when in 1920 the world set its face to work again and industrial activity was resumed where resumption was possible, consumers' reserves of fuel proved insufficient and an almost universal feeling of apprehension over the coal supply swept around the world. The reasons for this alarm-lately a thing of the past-become clear when the world's production in 1920 is cast up.

Jan 1, 1921

By R. W. Diamond

Low-grade ores can be designated by two main classifications: (1) simple low-grade ores, and (2) complex low-grade ores. As a rule the first type has a relatively small metal content, although low- grade iron ores contain a rather high percentage of metal. As the simple type is the one that is ordinarily in mind when the term "low-grade ore" is used, the paper will be devoted mainly to ores in this general category. Cheap treatment is the prime requirement in utilizing low-grade ores of the simple type, although in some cases the value of nonmetallic by-products, such as limestone for fer- tilizer and silica for flux, allows a little more lati- tude than in the usual situation. When the costs are divided under the three headings-mining, milling, and smelting-it is apparent that the last group will not constitute an important factor as a rule because the high concentrating ratio makes the smelting cost per ton of ore fairly low.

Jan 1, 1949

The regulations governing the filing of claims under the War Minerals Relief Act have been amended so as to allow claimants to file a brief with the questionnaire. It has been decided that hearings will be conducted by the War Minerals Relief Commission when good reason for such action can he shown. When justified, the Commission will conduct the hearing at a point easy of access from the mining district concerned. Applications for relief are beginning to reach the Commission in considerable volume. Thirty claims have been filed in such condition as has permitted of their formal filing with the Commission. Many others have been returned with instructions as to the information required and the procedure it is necessary to follow.' An effort was made to induce the Secretary of the Interior to open a Pacific Coast branch office of the War Minerals Relief Commission; this he has declined to do, claiming that it is impracticable to divide the work.

Jan 5, 1919

By H. Rush Spedden

When Robert H. Richards wrote Ore Dressing, the famous four-volume work published in the first decade of this century, the ore dresser was still largely concerned, with the mechanical treatment of ores. Since then, however, economics have transformed him into a mineral processing engineer who must increasingly deal with closely integrated facilities designed to produce a commodity for manufacturing. Moreover, this change will grow marked as the complex low- grade ores of the future make it ever more necessary for him not only to use the best combination of pyrometallurgical, hydrometallurgical and physical separation processes, but also to integrate these processes at the mine site. Nor are economic pressures the only ones propelling the processing engineer into a new era. The ecology drive has thrown him into a new situation in which his economic base is radically altered, and it could well precipitate as drastic a revolution in his technology as that which took place when flotation was developed.

Jan 1, 1971

W. H. PORTH, New York, N.Y.-I would like to ask what effect segregation of lead would have upon the corrosion of sheet zinc; also what effect would abnormal percentages of iron have upon the ductility of Sheet zinc? One of our difficulties seemed to be that the cells, when standing on the shelf, corroded. We have attributed this to local action in the zinc sheet. We would like to know whether the segregation of, these impurities in this sheet zinc will have any effect on the local action occur-ring in sheet zinc. Lately we have had difficulty in punching some sheet zinc, in that the sheets split in the die. The section that split seemed to have an abnormallly high percentage of cadmium and iron; would that cause it to become brittle? C. H. MATHEWSON.-Iron is one of the most unwelcome impurities when high ductility is the principal requirement in rolled zinc. High

Jan 12, 1919

JOHN H . NELSON,*Worcester, Mass.-In reply to the question "Is there any final information in regard to the relation between the temperature or the rate of cooling of a piece of heat-treated steel from the drawing temperature, and the so-called notch toughness?" I might say that we have conducted a large series of tests in the study of impacts on chrome-nickel and carbon steels and have gone into the subject of quenching from drawing temperature quite thoroughly but have found that one cannot lay down any definite rule or law with respect to the effect of quenching from the drawing heat. We conducted experiments on the effect of cooling by quenching in water, cooling in air, and burying the coupon in lime. Steels that have practically no impact value when air cooled may show very marked results when they are quenched in water, depending on the temperature at which the drawing is done.

Jan 6, 1919

By E. A. Sondreal, P. H. Tufte

Flue gas desulfurization when burning western U.S. coals can be expected to be easier to achieve and less costly than when burning higher sulfur eastern and central coals. However, western coals cannot generally be burned in compliance with federal and state new source emission standards without some degree of control. Western coals and lignite represent about 20% of total U.S. recoverable reserves with 90% of that strip minable, and their production is predicted to increase from the 60 million tons mined in 1973 to 300 million tons in 1985. Most will be used for electric power generation, where low sulfur content is a paramount concern. Western coals are predominantly below 1% sulfur; low compared with typical values of 2 and 3% for eastern and central coals. Coal cleaning for removal of sulfur is not commercially practiced on Western coals, which typically contain half organic and half pyritic sulfur. A fraction of the pyrite sulfur could possibly be removed, but the

Jan 1, 1976

PHILIP L. GILL, New York, N. Y. (written discussion*).There is one feature of the fire-refining of electrolytic copper which I believe should be mentioned when the relation of oxygen content to the "pitch" or "set" of refined copper is under discussion; that is, the segregation of impurities. Variation of "pitch" or "set" is frequently noted in castings of different shapes, cast at the same time from the same furnace, though the oxygen content remains identical. For instance, it is possible to cast two wire-bars in the same shaped molds from the same ladleful of copper, the one 2 in. thick showing a good level set, the other, 4 in. thick, being overpoled. Also, when two bars are cast of the same weight and at the same time from the same furnace, one bar in a copper mold at the proper temperature, the other in a mold that has been allowed to get overheated, the bar in the hot mold will show

Jan 8, 1918

By Robert H. Richards, E. E. Bugbee

Friends often ask how accurate the work of our little stamp mill is, or express the opinion that a little mill cannot do good work. As a reply we would like to place on record the results of a few tests. There are two periods of work in our laboratory; the fall term, when the class collectively goes through all our chief laboratory-processes, and the spring term, when the students work up their theses, each electing some one process or investigation and devoting himself wholly, or almost wholly, to that. Some of the tests, the results of which are recorded in this paper, were made in the fall term; the preparation of the apparatus, the sampling and the assaying being done largely by assistants, with the aid of the students. Others were made in the spring term as thesis-work, and the results are due wholly to. the students. The complete " tree " of our process is patterned after the-

Jan 1, 1904

Q: This is December 1960 and Jafet Lindeberg and myself are sitting around the tape recorder. Jafet, who discovered the gold in Nome, Alaska, in 1898, is going to tell the story of the discovery and of his life up there-a period of some 25 years. Now. Jafet, let's start this off well back of that-start it of1 when you were in Norway and, briefly, tell about when you were born and where you were born, anti so on. Lindeberg: My home in Norway was Varanger in Northern Norway. I was born and raised there and our industry was lumbering, cutting cordwood out of birch, sawing lumber with water power, fishing and dairy work. Q: Did you have anything to do with reindeer? Lindeberg: I never had anything to do with reindeer. But reindeer were raised in the nearby county, called Kautokeino, and they used to come to the coast in the summer, but we had nothing to do with the industry.

Jan 7, 1964

By Raphael D. Schilz, Michael F. Dunn, Edward D. Thimons, Francis S. Kendorski

During a mine fire or other emergency, it may be desirable to reverse the air flow in order to provide an escapeway or to control a fire. Also, in colder areas, the air flow may be reversed to prevent ice build-ups. When reversing main mine fans, the operator usually does not know what operating characteristics of flow and pressure to expect. Laboratory testing of vane axial main mine fans has been completed in order to establish forward and reverse performance characteristics under controlled conditions, with the results presented here. Preliminary tests under field conditions have also been conducted. The data obtained suggest that reverse performance characteristics are dependent upon the blade angle and the hub to tip ratio. There is also evidence that reverse performance can he predicted for a family of blade angles in a given hub to tip ratio. In general, the air quantity delivered by the fan is 30% to 60% less in reverse than when operating in the normal forward mode.

Jan 1, 1982

By P. R. Sperry

In an investigation of the decomposition of the solid solution in a cold worked high-purity aluminum alloy containing 7 pct Mg, aged at temperatures from 30o to 82°C, the nucleating sites at the earliest stages of precipitation were observed to be of two types. Nucleation occurred at the high angle grain boundaries both when the alloy was initially cold worked and when solution annealed. Nucleation also occurred at certain unique deformation markings which began to appear in abundance at approximately 30 pct reduction in thickness by cold rolling. These deformation markings were identified as deformation (kink) bands rather than as the usually assumed "slip planes." Zn material that was cold rolled 15 pct, only the grain boundary Fig. 2—A1-7 pct Mg alloy, cold worked 60 pct and heated at 230° C for 5 min. Etched with Perryman's reagent. X500. Reduced approximately 25 pct for reproduction. (a) Bright field illumination, precipitate deeply pitted. (b) Phase contrast, showing slip markings.

Jan 1, 1962

By W. J. Travers

SEVERAL new procedures for completing oil wells have been developed in recent years. Each method when used where properly applicable promises to be a definite aid to operators in lowering development or operating costs, or in developing the full potentialities of the oil well. Multiple-zone completions are now frequently used, in contrast to the older practice of setting a solid water string over each zone to be produced. Gravel packing in unconsolidated formations often prevents sand troubles formerly experienced where a conventional perforated liner was used. Light-weight bentonitic clay muds and oil-base drilling fluids are definite steps toward eliminating mudding damage, which occurs when heavy rotary mud is used. Since in each case the new procedure developed is an alternate of older conventional methods, a problem of selection is presented. The purpose of this paper is to suggest methods of arriving at these choices and to present practical observations that may be of aid in their application.

Jan 1, 1942

By Rudolph G. Wuerker

With stepped-up work in rock mechanics, more and more data on strength and elastic properties of rocks has become available. Results of measurements of tensile strength, in addition to determinations of compressive strength, allow us to deter- mine, even if only in an approximate way, the third property influencing failure of a brittle material: shear strength. It is fairly generally agreed upon in rock mechanics, in drilling and blasting research, that Mohr's theory provides an acceptable method for explaining the failure of a brittle material. Mohr states that a material may fail either 1) through plastic slip when shearing stress Y in the planes of slips has reached a limiting value (which in general depends on the normal stress, X, acting normal to the surface), or 2) when the largest normal tensile stress has reached a limiting value. The mode of failure depends upon which of the two stresses is the smaller.

Jan 10, 1959

By S. Skowronski

PURPOSE OF INVESTIGATION Since cuprous chloride melts at 418° C., boils at 954° C. to 1033° C.,1 and is known to be volatile at a much lower temperature, the presence of chlorine in any form in or on copper to be melted has always been looked upon by copper refiners as a possible source of-serious copper loss. Although this fact has been known for some time, the copper literature contains little or no information regarding it and the field seems .never to have been properly investigated from a metallurgical standpoint. According to Greenawalt,2 cupric chloride, CuCl2, when ignited gives cuprous chloride; therefore cuprous chloride is always formed when copper enters into reaction with chlorine at a high temperature. Cuprous chloride melts somewhat below a dull red heat, and does not volatilize in closed vessels, even if strongly heated, but if heated in the air it goes off as a white vapor. Hofman3 gives the melting point of cuprous chloride

Jan 2, 1919