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By Ta M. Li

A change in priorities is perhaps the underlying motivation reflective of governments and people in the Far East nations of the Philippines, Indonesia, and Thailand. While in the past, local governments have focused on feeding their large populations, the transfer of modern technology to the agricultural sector has produced record crop years in many of these countries. As a result, agricultural objectives have become more manageable, prompting governments to shift priorities to the accelerated development of their industrial sectors. The basis of any sustained industrialization program, the governments concede, is the development of a vibrant minerals sector.

Jan 8, 1979

By Harry R. Hall

THE proposition to make pig-iron from magnetic concentrates and cobbed ore with charcoal-fuel weighing from 12 to 20 lb. per bushel is, on the face of it, not inviting; but the successful work that has been done under these adverse conditions warrants a permanent record in our Transactions, especially as it furnishes a comparison with, coke blast-furnace practice under similar conditions. The record of the furnace-practice is briefly summarized as follows:-The charcoal was made of hemlock, pine, spruce, balsam, maple, beech and birch woods. All the concentrates containing from 62 to 65 per cent. of iron would pass in. screen, of which about 34 per cent.. would pass an 80-mesh sieve. The cobbed ore, varying in composition from 32 to 47 per cent. metallic iron and from 23 to 32 per cent. of. silica, would pass through a I-in. ring, of which about 25 per cent. would pass a 1/8 in. screen. The furnace was blown in October 20,1903, with charcoal which was supposed to weigh when dry 18 lb. to the bushel. Some charcoal similar to this was stored in the stock-house for about a year and was then found to weigh 12 lb. per bushel. During the first 10 days of the blast, the furnace produced 362 tons of pig-iron, using 200 bushels of charcoal per ton of iron. From November 1st to 12th, the volume of the blast was increased gradually from 2,808 to 5,460 cu. ft. per minute, with practically no increase of output. The silicon-content of the resultant pig-iron averaged 0.75 per cent., with sulphur about 0.035 per cent. A supply of freshly-burned dry charcoal was then used which increased the silicon-content and lowered

Sep 1, 1905

By Rollin E. Hook, Attwell M. Adair

The response of CrzO3 and C~304 to various heat treatments was studied in are-melted iodide chromizim over the temperature range 1000" to 1750°C. These oxides, which are present as impurity phases in this material, were identified by X-ray diffraction teclzniques which were supplemented by optical metallop-aphy. As a function of increasing temperature, Crs04 is first observable in samples annealed at 1300°C and coexists with Cr2O3 (the low-temperature oxide) over a temperature range exceeding 200°C. As the temperature decreases, Cr3O4 dissolves with the concomitant precipttation of Cr2Y2. Both oxides precipitate predominantly at pain boundaries. The reactions which occur are involved with at least ternary equilibria, possibly due to iron which is present as an impurity in arc-melted iodide chromium. HILTY, Forgeng, and Folkman' reported in their investigation of the Fe-Cr-0 system that Cr3O4 (with about 8 pct Fe substituted for chromium) is a primary phase found in alloys with 9 or more pct Cr. They reported that this phase is stable only at high temperatures and that below the liquidus Cr3O4 is disproportionated into Cr2O3 and chromium-rich metal for both Fe-Cr-O alloys and in oxygen saturated pure chromium. Further, they proposed that CrsO4 forms by a peritectic reaction between Cr2O3 and the liquid. On the other hand, Hook, Garrett, and Adair2 found in their investigation of impurity phases formed in "pure" chromium (material consolidated from iodide chromium crystals) that Cr3O4 forms intergranularly and is stable as low as 1500°C which is 375OC below the melting point of chromium. The purpose of the research described herein is to determine the temperature range of stability of Cr3O4, and to show the nature of its decomposition. This further investigation indicates that Cr3O4 undoubtedly occurs in this material as low as 1300°C. The chromium studied was consolidated and fabricated from iodide chromium crystals (ICr-5) and contained Fe r 135 ppm, Si = 20 to 100 ppm, and 0 = 35 to 137 ppm. A complete chemical analysis is given elsewhere.' Annealing was conducted in 1 atm of purified helium and all samples were rapidly cooled (-200°C per sec) by withdrawing them from the furnace hot zone under a high flow rate of helium. The details of the electrolytic-etching technique and electrolytic-digestion techniques for preparation of insoluble residues for X-ray examination are given elsewhere also.' EXPERIMENTAL RESULTS The Starting Material. The as-swaged rod (final swaging done at 900°C) had a wrought grain structure and contained a dispersion of CrzO3 inclusions of maximum particle size of about 2 or 3 p, Fig. 1. The microstructure also contained a dispersed

Jan 1, 1964

By Raymond E. Byler

THE challenge of unprecedented need for more metals to meet present-day re-armament and domestic requirements is being met with minerals beneficiation projects of great number and variety, and with new and improved methods, techniques, and. equipment. Iron Range Developments Much attention has been given during the year to the tremendous program for beneficiation of taconites and intermediate iron ores which is progressing through large pilot-plant tests preparatory to full-scale production operations. The greatest activity has been directed toward concentration of magnetic taconites on the Mesabi Range. The Reserve Mining Co. has let $75 million in construction contracts for the 2 ½ million-ton-per-yr project (concentrates) at Beaver Bay, Minn., and is building a 300,000-ton-per-yr pilot plant to prove up the magnetic separation and pelletizing operations. Oliver Iron Mining Co. has a pilot plant under construction near Mountain Iron for concentrating magnetic taconites, and is operating experimentally a sintering and nodulizing plant on fine ore screenings and concentrates at Virginia to fully develop agglomeration technique. The Erie Mining Co. plant at Aurora continues its production of concentrates from magnetic taconites which was begun three years ago. No plans have been announced to treat the Mesabi Range nonmagnetic taconites, but F. D. Devaney, Pickands Mather and Co., is studying a new process for magnetically roasting lean ores to make them amenable to low-intensity magnetic concentration. W. R. Van Slyke, Cleveland-Cliffs Iron Co., calls attention to several noteworthy developments in the field of intermediate ores, perhaps the most significant of which has been the first commercial operation of a Dutch State Mines (DSM) cyclone plant at the Buckeye mine of the M. A. Hanna Co. The plant concentrates the +1/4 in. fraction by means of conventional heavy-media treatment after suitable crushing, screening, and washing. The -1/4 in. +65 mesh material is treated in two 12-in. cyclones, the -65 mesh fraction being sent to tailing storage. The plant is operating successfully on feed rates up to 120 tons per hr, and indicates that successful treatment of the fine fractions of Mesabi intermediate ores is imminent. Another commercial-size DSM plant was placed in operation late in the year by Cleveland-Cliffs at the Holman mine, and two additional ones are expected to be in operation next year. Various other methods are also in use at different plants for treatment of the fine fractions, including classification, abrasion milling followed by classification, jigging, and Humphrey spirals. Where it can be economically justified, it seems at present that heavy-media treatment of the -1/4 in. fine fraction will also come into increasing use on the intermediate ores. During 1951 a one-unit, heavy-media plant to treat hematitic crude ore was erected at the Ohio mine on the Marquette Range by Cleveland-Cliffs and plans for another plant at Humboldt to produce 2000 tons of concentrates annually is contemplated, as is also the construction of a plant for agglomera-

Jan 1, 1952

By Arthur C. Simmons

Oil production and activity in northern and central Pennsylvania was slightly less in 1939 than in the previous year, but owing to higher average prices 1939 was undoubtedly a better business year. The last quarter showed markedly increased activities throughout all of the Pennsylvania fields. Production, Stocks and Price Storage of Pennsylvania crude oil at pipe lines and refineries totaled 5,413,000 bbl. on Dec. 31, 1938, and declined during the year 1,124,000 bbl. to a total of 4,319,000 bbl. at the end of 1939. The stocks of crude at the end of the year represent the lowest point reached in Pennsylvania-grade crude storage in recent years. Stocks increased slightly during April, May and June, but decreased during all other months of 1939. The Bradford field production within the state of Pennsylvania averaged 35,340 bbl. per day throughout 1939, which represents a decrease of 1419 bbl. a day from the 1938 average. The production in central and southern Pennsylvania increased 1176 bbl. per day, averaging 12,159 bbl. throughout 1939. Table 1 includes annual production for the part of Bradford field situated within the state of Pennsylvania, for central and southern Pennsylvania, and for the entire state of Pennsylvania. A definite segregation of production between the Bradford field and central and southern Pennsylvania is slightly ambiguous because a portion of the oil from the newly discovered Music Mountain pool is included statistically in each area. In all probability the entire increase and some small addition to the production from southern Pennsylvania can be attributed to oil produced from the Music Mountain pool. Within the Bradford field, six price changes occurred throughout the year. At the beginning of 1939 the price of Bradford crude oil was $1.80 per barrel, whereas by the end of the year it had risen to $2.50. The weighted average price for Bradford crude during 1939 was $2.059 per barrel.

Jan 1, 1940

By D. N. Witman

ONE of the special uses to which the electric furnace has been put recently is the melting of an alloy of nickel and cast iron for the production of electrical-resistance grids. The metal sections of these grids, Fig. 1, are quite uniform for each pattern, but there is, among the various patterns, a variety of thicknesses. The cross sections vary from 1/2 by 3/16 in. to as small as 1/8 by 1/8 in. The electrical resistance f a perfect casting lies within 10 per cent. above or below the fixed listed resistance for each pattern. Good molding is essential to success in the making of these grids, for with absolutely correct metal, a variation of 0.01 in. in width and thickness of section on some of the patterns may mean as much as 12 or 14 per cent. variation in resistance. The service for which these castings are intended demands that the metal, even in the smallest castings, be very soft, showing an open, gray, highly graphitic structure in order that they may be resistant to shock, and stand up well under rough usage. The metal used for this purpose is a gray iron alloyed with 4 to 5 per cent. of nickel, which element, when the composition of the alloy is correct, imparts toughness and pliability to the metal and helps to overcome the tendency of metal to run white and become brittle because of the rapid cooling action of the sand mold. When cold, these castings can be twisted into various shapes, taking a permanent set without breaking. The alloy has approximately double the electrical resistance of ordinary cast iron. The metal specification is as follows: PER CENT. Silicon 2.40 to 2.60 Sulfur Under 0.05 Phosphorus Under 0.08 Manganese Under 0.40 Total carbon 3.60 to 4.00 Nickel 4.00 to 5.00 Copper 0.50 to 0.70

Jan 8, 1921

By L. S. Panyity

THE State of Ohio is among the pioneers in the production of oil and gas. Numerous anticlinals, such as the Macksburg, Cow Run and Newport, have been thoroughly developed, and the pools found in connection with them are quite in accord with the structural theory. Numerous oil and gas pools found in the Berea sand, however, demand a different explanation. The study of these pools belongs to the sub-surface geologist, as it is possible to understand the factors controlling "off-structure" accumulations only after a careful study of well records. By carefully analyzing the various 'conditions over a large territory, it is possible to understand the otherwise meaningless mass of data that one may have at hand, and put it into tangible shape, from which various conclusions may be drawn. The territory here discussed includes Belmont, Guernsey, Muskingum, Noble, Monroe, Morgan, Washington, Athens and Meigs counties, containing the majority of the prolific oil and gas pools of the Carboniferous system in southeastern Ohio. The general dip of the strata is to the southeast, the entire territory lying on the northwestern flank of the Appalachian geosyncline. The best known oil- and gas-producing horizon in the territory is the Berea sand, which lies near the lower part of the Mississippian, with the Sunburry shales (the coffee-shales of the driller) above, and the Bedford shales below it. The Bedford is underlain by the thick Ohio shales. The Ohio and Bedford contact is considered to be the dividing line between the Carboniferous and Devonian systems. The Berea is one of the most persistent of recognizable oil and gas horizons; its outcrop has always been found in its expected place, and it has always been penetrated whenever the drill went deep enough. It is not expected, however, even of the most uniform formations, that no lithological variations should occur, and the Berea is no exception. Nevertheless, there appears to be a certain regularity in its variation, the main features of which directly affect the accumulation of petroleum.

Jan 8, 1918

ZAY JEFFRIES (written discussion*).-I have read with much interest Mr. Ruder's discussion of Professor Howe's paper, "The Supposed Reversal of Inheritance of Ferrite Grain Size from that of Austenite." I am yet of the opinion that my first explanation' of Mr. Ruder's samples is substantially correct. In that explanation I did not intend, however, to convey the impression that "reversed inheritance" was the general rule nor even of common occurrence but rather that." Non-inheritance" was the general rule. Mr. Ruder suggests that a " perfectly formed" grain is an indication of inheritance. The grains in my Fig. 52 are perfectly formed and in fact more nearly equiaxed than those in Mr. Ruder's Fig: C,3 yet the grains in the former are known not to be inherited but to have been formed by the partitioning of larger austenite grains. On close examination of Mr. Ruder's Fig. C the very shapes of the grain suggest partitioning. Again, the grain size (25 to 30 grains per square millimeter) is at least 10 or- more likely 20 times smaller than might be expected of the austenite from which these grains were .formed under the given time and temperature conditions. Mr. Ruder's newer results on electrolytic and Armco iron are most interesting and instructive. His results fit in. nicely with my conclusions 5, 6 and 10.4 His photographs, however, indicate that the thickness of the pieces of sheet metal are such that abnormal grain growth is promoted. He indicates that equilibrium grain size after heating to 950° C., with furnace cooling, is about the same as his Fig. 1, above. I estimate this to be approximately one-half -grain per square millimeter, or 40 times as large as I have obtained with the same material (Armco iron) after heating Y4-in. bars to 1300° C. for 2 hr. and cooling in the furnace. The effect of thickness of sample on grain size is one which needs more attention.

Jan 3, 1918

By G. C. Wallick, W. R. Foster, J. G. Savins

The theory of the differentiation method for the Couette flow experiment is reviewed. Particular attention is given to the requirements on data analyses in the case of the class of non-Newtonian materials described as viscoplastics, i.e., materials characterized by a yield point or yield stress. Here changes in boundary conditions arise when the shearing stress attains a critical value with the result that the form of the basic integral equation for Couette flow is determined by the flow conditions existing during the measurement. INTRODUCTION In the preceding papers in this series,l,2 the salient features of the differentiation method of rheological analysis in Poiseuille-type flow were discussed. It was shown that a dual differentiation-integration method analysis of the Poiseuille flow of idealized generalized Newtonian and visco-plastic models could be used to develop a spectrum of highly sensitive response patterns in terms of certain characteristic derivative functions. These functions were shown to optimize the selection of the most appropriate functional relationship between f(p) and p from the Poiseuille flow experiment. The present paper reviews the theory of the differentiation method as applied to the equally important Couette flow experiment. We will also discuss the range of variables over which the basic integral equation for Couette flow is applicable when the non-Newtonian material is of the viscoplastic type, i.e., characterized by a yield point or yield stress. THEORY Having described the application of the differentiation method to Poiseuille-type flow in the preceding papers, we now proceed to the case where the test liquid is confined to the annular space between coaxial cylinders of length L, one of which is in motion, i.e., Couette flow, formulating the basic integral equation after the method of Mooney.3 The observed kinematical and dynamical quantities are the angular velocity O and the torque T. Here, the one nonvanishing component of the shear-rate tensor is

By J. G. Montgomery

An increased drilling activity was apparent in the shallow sand fields of northwestern Pennsylvania during the year. This drilling, however, was confined to previously outlined productive areas and as new shallow sand pools of interest were discovered. Drilling for Oriskany gas proceeded at about the same rate as in previous years. One new area in Kinzua township, Warren County, was opened up during the year by a producing well, but later this well developed salt water and the productive capacities of the area are very indefinite at the present time. Production from the shallow sand areas remained approximately the same as in 1935. Production from the Oriskany or deep sand areas increased approximately 20 per cent. Two new markets were made available for the Oriskany gas during the closing months of the year by the completion of the Peoples Natural Gas Co. line from the Hebron field to Clarion County, Pa. and Penn York Gas Co. line from the Harrison field to points in northwestern New York State. With the exception of the Kinzua well, the few deep wildcat wells drilled during the year failed to discover new fields in the deep sands. Bradford Oil Field The accompanying data on the Bradford oil field include only the production obtained from the portion of that field that is in the State of Pennsylvania, for it appears probable that Cattaraugus County production, which consists mainly of the New York State portion of the Bradford field, will be included in annual oil production figures for New York State. The Bradford field production for 1936 totaled 14,533,000 bbl., and as it is necessary to estimate New York State production for the Bradford field, the accompanying data includes the production from the Pennsylvania end of the Bradford field of 13,208,000 bbl., which is an increase of approximately 8 per cent over 1935 production.

Jan 1, 1937

By Arthur C. Simmons

Oil production and activity in northern and central Pennsylvania was slightly less in 1939 than in the previous year, but owing to higher average prices 1939 was undoubtedly a better business year. The last quarter showed markedly increased activities throughout all of the Pennsylvania fields. Production, Stocks and Price Storage of Pennsylvania crude oil at pipe lines and refineries totaled 5,413,000 bbl. on Dec. 31, 1938, and declined during the year 1,124,000 bbl. to a total of 4,319,000 bbl. at the end of 1939. The stocks of crude at the end of the year represent the lowest point reached in Pennsylvania-grade crude storage in recent years. Stocks increased slightly during April, May and June, but decreased during all other months of 1939. The Bradford field production within the state of Pennsylvania averaged 35,340 bbl. per day throughout 1939, which represents a decrease of 1419 bbl. a day from the 1938 average. The production in central and southern Pennsylvania increased 1176 bbl. per day, averaging 12,159 bbl. throughout 1939. Table 1 includes annual production for the part of Bradford field situated within the state of Pennsylvania, for central and southern Pennsylvania, and for the entire state of Pennsylvania. A definite segregation of production between the Bradford field and central and southern Pennsylvania is slightly ambiguous because a portion of the oil from the newly discovered Music Mountain pool is included statistically in each area. In all probability the entire increase and some small addition to the production from southern Pennsylvania can be attributed to oil produced from the Music Mountain pool. Within the Bradford field, six price changes occurred throughout the year. At the beginning of 1939 the price of Bradford crude oil was $1.80 per barrel, whereas by the end of the year it had risen to $2.50. The weighted average price for Bradford crude during 1939 was $2.059 per barrel.

Jan 1, 1940

By V. H. Wilhelm

During the first half of the year 1935, the oil industry in California was on a fairly profitable basis, owing mainly to the operation of the Petroleum Marketing Agency. Coincident with the discontinuance of enforced curtailment, California production surged upward from an average of about 500,000 bbl. per day (over the first five-month period) to approximately 625,000 bbl. per day (over the last seven-month period). On Dec. 9 the state production had reached a peak of over 700,000 bbl., a figure that had not been approximated since the early days of voluntary curtailment (Fig. 1). A price cut was instituted during the last half of August, but had no deterring effect on operators that were determined to take advantage of the breakdown of curtailment and produce to capacity. New reserve figures, compiled from actual potentials, available after cessation of curtailment, revealed the startling fact that California reserves were rapidly declining. This situation, coupled with the desire among operators to obtain a more equitable price for their dwindling reserves, caused a restoration in November of a portion of the August price slash. A further rise in price was effected in early December, and crude quotations at the end of the year closely approximated those in effect during the first right months. At the close of the year, the industry felt confident that the production situation was under control. In all fields where competition is keen because of close spacing, production is gradually declining. In the Los Angeles Basin especially there is no likelihood of a large amount of overproduction, unless a new pool is discovered or deeper drilling reveals a prolific source of crude. As long as the fields that are operated by a few companies, such as Kettleman Hills, North Belridge, Ventura Avenue, West Coyote, Dominguez, and some others, can be controlled, it is believed that the overproduction problem in California will be solved.

Jan 1, 1936

By A. J. R. Curtis

THE Portland Cement Association was organized more than a third of a century ago by a group of cement manufacturers, to do cooperatively the educational and research work needed to ensure proper use of their product. Specifically, the Association has a threefold purpose: (1) to search out facts to ensure the best possible service from concrete; (2) to give the widest possible circulation to facts affecting the use of concrete; (3) to urge practical application of those facts on actual building projects. An organization of technically trained men conducts many research projects in the Association laboratories, interprets their findings and applies them practically in the field. The net effect of this work has been to improve the design and prolong the life of roads, bridges, industrial, commercial and public buildings, homes, farm structures and concrete products. The results of this technical research and experimentation are made available to the entire construction industry through bulletins and reports. Information is also released to the general public through newspapers, magazines and Association publications. In addition to a technical staff in the general office in Chicago, the Association has district offices in 22 cities. Field engineers cover 37 states, the District of Columbia and British Columbia, to give service to users of Portland cement. ACCIDENT PREVENTION During the early part of the century, there began a complete transformation in the processes of manufacturing cement. Electricity, with its attendant hazards, was beginning to replace steam; huge rotary kilns and tube mills were being substituted for the vertical kiln and "coffee grinder" mill. Only a few far-sighted leaders realized the import of these innovations, and they also recognized the fact that workmen must be protected against the hazards of the new machinery. By their sincerity and firm purpose they infused into the whole industry the concept of industry's responsibility for safeguarding employees. Even before effective compensation laws had been passed in most states, the Portland Cement Association had assigned to an Accident

Jan 1, 1937

By V. H. Wilhelm

During the first half of the year 1935, the oil industry in California was on a fairly profitable basis, owing mainly to the operation of the Petroleum Marketing Agency. Coincident with the discontinuance of enforced curtailment, California production surged upward from an average of about 500,000 bbl. per day (over the first five-month period) to approximately 625,000 bbl. per day (over the last seven-month period). On Dec. 9 the state production had reached a peak of over 700,000 bbl., a figure that had not been approximated since the early days of voluntary curtailment (Fig. 1). A price cut was instituted during the last half of August, but had no deterring effect on operators that were determined to take advantage of the breakdown of curtailment and produce to capacity. New reserve figures, compiled from actual potentials, available after cessation of curtailment, revealed the startling fact that California reserves were rapidly declining. This situation, coupled with the desire among operators to obtain a more equitable price for their dwindling reserves, caused a restoration in November of a portion of the August price slash. A further rise in price was effected in early December, and crude quotations at the end of the year closely approximated those in effect during the first right months. At the close of the year, the industry felt confident that the production situation was under control. In all fields where competition is keen because of close spacing, production is gradually declining. In the Los Angeles Basin especially there is no likelihood of a large amount of overproduction, unless a new pool is discovered or deeper drilling reveals a prolific source of crude. As long as the fields that are operated by a few companies, such as Kettleman Hills, North Belridge, Ventura Avenue, West Coyote, Dominguez, and some others, can be controlled, it is believed that the overproduction problem in California will be solved.

Jan 1, 1936

By Y. C. Liu

An analysis is presented to show that the formation of rolling textures in fcc metals can be rationalized in terms of flow mechanisms operative during the rolling process. First, a general approach used by Calnan is followed, where the rolling process is approximated on the basis of two axes, p and Q. In this treatement there are two separate sets of slip systems, one for each axis, and it is shown that a homogeneous rotation can he achieved by restricting the slip systems for the two axes to share common slip directions Then, two criteria are used to select the active slip systems for the axis P: they must have relatively high resoloed shear stresses, and dislocations on these slip systems must interact attractively in order to lower total energy content Finally, a method of analysis is introduced to locate the end position of an axis by knowing its acti7.e slip systems. The result of the analysis indi- cates that two main flow mechanisms operate in fcc metals. The ideal orientation derived from one oj-them is (8 13 21) (21 8 13) which is very close to the (358) (523) orientation observed experimentally on the rolling texture of copper. This flow mechanism should only he operative in metals containing dislocations extended into partials separated by less than five times their lattice parameter. The ideal orientations derived from the other flow mechanism are a combination of (1 10} (112) and a spread of orientations with (110) parallel to the rolling plane. This type of ideal orientations corresponds to those observed in the rolling texture of silver 30:70 brass, and binary alloys with high alloying content. This flow mechanism should be operative in any fcc metal regardless of its stacking-fauIt energy. When a polycrystalline metal is subjected to a large amount of plastic deformation, it is generally observed that grain orientations alter and align themselves towards certain positions, eventually reach-

Jan 1, 1964

By J. Campbell

The negative pressure developed within a solidifying sphere of pure iron is investigated theoretically assuming an elastic-plastic model. The maximum hydrostatic tension attainable is shown to be an order of magnitude smaller than that required for the homogeneous muclealion of pores in the liquid cove, and four orders of magnilude smaller than that predicted from) a rigid shell model. It is well-known that liquids can withstand large hydrostatic tensile stresses, or negative pressures. The various experimental investigations of the tensile strengths (often called the fracture pressures) of liquids are reviewed by Dean,1 and the theoretical attempts at estimating fracture pressures are critically assessed by wakeshima.2 Using Fisher's3 quation, the fracture pressure of pure liquid iron is about -70,000 atm, which may be too large by as much as a factor of 4, but is certainly correct to within an order of magnitude.' In view of the great importance of the problem of the nucleation of shrinkage cavities in castings it is of interest to determine exactly what tensile stresses can exist in the residual liquid in a solidifying casting; it has often been assumed that, because of the very low strengths of solid metals near their melting points, no interior stresses are developed at all. Nussey4 has determined theoretically the pressure in the liquid core of a solidifying metal sphere assuming that the solidified shell does not deform (i .e., is perfectly rigid), so that because of the contraction accompanying solidification (a) (about 3 pct for most metals) the progressive deposition of solid onto the inner surface of the shell causes the remaining liquid to be expanded to make up this difference in volume. This leads to a relation between the pressure P in the liquid, the initial pressure, PO, the bulk modulus of the liquid, K, and the inner and outer radii of the solid shell, o and b, respectively:

Jan 1, 1968

By R. W. Raymond

PROFESSOR W. P. BLAKE, in a note to his Catalogue of California Minerals, pointed out that the milling districts of the Pacific slope are arranged in parallel zones, following the prevailing direction of the mountain ranges. This interesting generalization has been more frilly illustrated and connected with the geological history of the country by Mr. Clarence King, who sums up the observed phenomena as follows : " The Pacific coast ranges upon the west carry quicksilver, tin, and chromic iron. The next belt is that of the Sierra Nevada and Oregon Cascades, which, upon their west slope, bear two zones, a foot-hill chain of copper mines, and a middle line of gold deposits. These gold veins and the resultant placer mines extend far into Alaska, characterized by the occurrence of gold in quartz, by a small amount of that metal which is entangled in iron sulphurets, and by occupying splits in the upturned metamorphic strata of the Jurassic age. Lying to the east of this zone, along the east base of the Sierras, and stretching southward into Mexico, is a chain of silver mines, containing comparatively little base metal, and frequently included in volcanic rocks. Through Middle Mexico, Arizona, Middle Nevada, and Central Idaho is another line of silver mines, mineralized with complicated association of tli6 base metals, and more often occurring in older rocks. Through New Mexico, Utah, and Western Montana lies another zone of argentiferous galena lodes. To the east, again, the New Mexico, Colorado, Wyoming, and Montana gold belt is an extremely well-defined and continuous chain of deposits." These seven longitudinal zones or chains of mineral deposits must

By P. W. George

THE rapid increase in cost of discovering new orebodies by churn drilling in the Tri-State district has led to some attempts to lessen the expense by using geophysical methods. Electrical prospecting was tried three or four years ago, but no successful results were recorded. In 1926, the Federal Mining and Smelting Co. engaged the North American Exploration Co., of Houston, Texas, to make some tests with the torsion balance. At first, it was thought that the most favorable conditions for discovery of ore deposits with the torsion balance would be in locations where the ore was known to occur at rather shallow depths, FIG. 1.-CROSS-SECTION OF DUENWEG LEASE. therefore the first trial was made at Duenweg, east of Joplin, where some zinc ore had been developed at a depth of 130 ft. The gravity gradients at 61 stations on a tract of about seventeen acres indicated plainly one large zone of maximum gravity and a smaller narrow zone of minimum gravity. Fourteen churn-drill holes, half of which struck ore, show that all the ore found was located outside the zones of maximum and minimum gravity. In the zone of maximum gravity the limestone beds were closest to the surface, and the first chert beds encountered were at the greatest depth. The results (shown in Table 1) indicated that the gravity of the, limestone was greater than the gravity of the fractured chert together with its orebodies, and probably also greater than the bouldery soil and clay on top of the limestone. A cross-section of the Duenweg lease is shown in Fig. 1.

Jan 1, 1928

By T. J. Whalen and Michael

The grain shape of the carbide in nickel-bowled ad cobalt-bonded titanium carbides was studied by microgiaphic examination, and the influcence of sintering atmosphere, sintering substl-after, ami the amount of metal binder on the grain shape was determined. If was found that the Carbide grain cross sections in the nickel and cobalt cermets ranged from round to angular, depending on the sintering conditions. The spheroidization of the carbides in both cobalt-bonded and nickel-bonded titanium carbides may be attribicted to oxygen. In the course of studies on titanium-carbide base cermets, various investigators have reported on the shape of the carbide grains, and it was noticed that grain shapes were obtained which were either spheroids, or polygons with rounded or square edges. It was also noted that the shapes of the carbide grains changed with time or composition. skolnickl showed that the titanium-carbide grains. after infiltration in vacuum with nickel tended to spheroi- dize with time. The titanium-carbide skeleton was located on a beryllia plate during infiltration. Gur-land,' who studied the microstructure of titanium carbide-cobalt compacts, showed that the carbide grains are round after 1 hr at 1450oC in a hydrogen atmosphere and angular after 7 hr at the same temperature. Goetzel3 has found that the carbide grains in compacts with a high binder content. 40 to 60 pet. tend to be spheroidized. whereas Blumenthal and silverman4 pointed out that the higher binder contents could yield either round or rectangular grains with rounded edges. depending on the nature of the binder. It is the purpose of this paper to present experi-

Jan 1, 1961

By P. W. George

THE rapid increase in cost of discovering new orebodies by churn drilling in the Tri-State district has led to some attempts to lessen the expense by using geophysical methods. Electrical prospecting was tried three or four years ago, but no successful results were recorded. In 1926, the Federal Mining and Smelting Co. engaged the North American Exploration Co., of Houston, Texas, to make some tests with the torsion, balance. At first, it was thought that the most favorable conditions for discovery of ore deposits with the torsion balance would be in locations where the ore was known to occur at rather shallow depths, FIG. 1.-CROSS-SECTION OF DUENWEG LEASE. therefore the first trial was made at Duenweg, east of Joplin, where some zinc ore had been developed at a depth of 130 ft. The gravity gradients at 61 stations on a tract of about seventeen acres indicated plainly one large zone of maximum gravity and a smaller narrow zone of minimum gravity. Fourteen churn-drill holes, half of which struck .ore, show that all the ore found was located outside the zones of maximum and minimum gravity. In the zone of maximum, gravity the limestone beds were closest to the surface, and the first chert beds encountered were at the greatest depth. The results (shown in Table 1) indicated that the gravity of the limestone was greater than the gravity of the fractured chert together with its orebodies, and probably also greater than the bouldery soil and clay on top of the limestone. A cross-section of the Duenweg lease is shown in Fig. 1.

Jan 1, 1928