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By John Chipman, Helen Towers

DEVELOPMENT of a simple radioactive tracer technique for measurement of the diffusion coefficient of calcium ion in liquid slag has already been reported. The investigation was of a preliminary nature designed to explore the possibilities of using radioactive isotopes and to establish a method, and no great accuracy was claimed for the results. It was shown, however, that Ca15 could be used successfully, and the values obtained for the diffusion coefficient appeared to be of the right order of magnitude. However, it was considered that a better technique could be devised for carrying out the diffusion. The experiments were, therefore, continued to find a more accurate method, to check the calcium results, and to extend the investigation to include measurements of the diffusion coefficient of silicon in the same slag. There were two flaws in the original technique. Convection was the cause of too many failures, and the interface between the two slags in the diffusion cell was curved rather than plane, probably due to a surface tension effect caused by the addition of the tracer Ca45 in the form of chloride. Two methods of overcoming these defects were tried. Since it was planned to study diffusion of the short-lived isotope Si"' also, the development of methods was restricted to those which gave promise of being reasonably rapid. Method 1—The principle was identical to that previously used with respect to the diffusion conditions, but there were three differences in technique. Temperature control was more rigid, the tracer was added to the slag as Ca45O rather than the chloride and, finally, an effort was made to translate to high temperatures the elegant method developed by Cohen and BruinV or bringing together the two liquid layers and beginning the diffusion. A master slag was melted in graphite, ground to a fine powder, and analyzed (38.5 pct Ca0-20.9 pct Al2O3-40.5 pct SiO2). The tracer was received as Ca45C12 in an aqueous solution of CaC12 + HC1. From this, calcium oxalate was precipitated, ignited to calcium oxide, and added as such to the slag to give an activity of approximately 5 µc per g. The mixture was then melted into the form of a cylinder 3/16 in. diam and about 1 in. long. A solution identical to the tracer solution without Ca45 was given exactly the same treatment. The resulting Ca40O was mixed with that slag which was to form the tracer-free half of the diffusion cell, and this was likewise melted into a cylinder of the same size. Slag cylinders, two with and two without Ca15, were set in graphite blocks as shown in Fig. 1, and the crucible was lowered into position in the fur-

Jan 1, 1958

By P. K. Kaiser, C. Mackay

A circular shaft with a diameter of 6m was excavated by the conventional drilling and blasting method to a depth of 235m through 60m of glacial till, 1 Om of water bearing basal sand, 1 1 Om of clay shale (Bearpaw Formation) and finally a strata of coal, mudstone, siltstone and sandstone (Oldman Formation). The lined shaft was instrumented at three levels by multipoint extensometers to determine the displacement field near the shaft bottom, embedment strain gauges to measure the strains in the liner and IRAD-stress change gauges to observe the radial and tangential stress changes in the rock mass. The data from these gauges were used to determine the in situ stress field. An attempt to measure in situ stresses by overcoring was also made at a higher elevation. The performance of the shaft and its support was then evaluated by use of the "Convergence-Confinement Method". For this purpose the measurements of stress changes and displacements were combined to determine by extrapolation the displacements ahead of the shaft and after the liner installation. The convergence curves calculated in this fashion were then used to evaluate the performance of the cast-in-place concrete liner and of an alternate shotcrete shaft support system.

Jan 1, 1983

By D. J. Carney, C. W. Boquist, E. C. Rudolphy

Effect of variations in sinter feed composition on sinter strength, bulk density, re-ducibility, chemical composition, and microstructure were determined by sintering experimental samples on a production sintering machine. Increasing amounts of roll scale, ore fines, return fines, and blast furnace slag were most beneficial to feed permeability, sinter bulk density, and strength. Burnt lime additions improved feed permeability but were not beneficial to sinter strength or bulk density. Sinter reducibility was adversely affected by all additives. DEVELOPMENT of methods for evaluating sinter quality, which would in some way predict the behavior of the sinter during charging and smelting in the blast furnace, has been given considerable attention in recent years. In a previous investigation at South Works of the United States Steel Corp., standard sinter sampling and testing procedures were developed.1,2 By modifying the sinter sampling device, a method of sintering experimental mix sinter samples upon a production Dwight-Lloyd sintering machine was also developed. This technique afforded a rapid and controlled method of investigating the effects of the various raw materials and additives on sinter quality and was used in this present investigation. Since the beginning of the present study in 1953, the results of numerous sinter investigations have been published, most of which were concerned with production tests of iron ore sinter, both here and abroad. Three groups of investigators reported results of experimental sinter studies that were related to this investigation. Voice et al.3 studied the effects of controlled variables on sinter quality by producing and testing experimental Northants iron ore sinter using an experimental sintering unit. Mor-rissey and Powers' determined the relationship between iron ore sinter quality and the moisture and coke content using a small laboratory sintering system. Burlingame et al.5 studied the effects of "additives" upon iron ore sinter using a laboratory sintering apparatus and laboratory grade raw materials. At South Works, it was considered desirable to study the effects of sinter mix composition and additives upon the quality of a flue dust-base sinter produced on a production sintering unit. Extrapolation of controlled laboratory test data to sintering plant operation lacking such precise control is not altogether satisfactory. Therefore, the present study was conducted in a manner which approximated production conditions as closely as possible. The raw materials used were those commonly encoun- tered in the production of flue dust and flue dust ore-type sinters and these were varied within extremes encountered in this type of sinter production. Experimental Procedure The experimental sinters were produced from 100 lb mixtures of sinter feed. The principal raw materials and additives used, their particle size, and approximate chemical composition are listed in Table I. The mixing of the raw materials was accomplished by means of a miniature single shaft pug mill shown in Fig, 1. The use of the pug mill as a mixer was decidea upon after encountering difficulty in reproducing the mixing and chopping effect of the sinter plant pug mill with other types of available small mixers. The miniature pug mill was constructed, consisting of 31/2x2x1/4 in, blades spaced 3 in. apart along a 3 ft shaft. Preliminary tests were run with this small mixer to establish the proper rotation speed and the required number of passes through the pug mill to thoroughly mix and distribute all the raw materials in a manner approximating the production Pug mill- Although the effects of varying the mosture content were determined in one particular series of tests, the amount of moisture added was changed as the composition of the experimental mix was varied. The aim in making water additions was to achieve a permeability as high as possible for each particular

Jan 1, 1956

By W. G. Wender

This report covers the area producing from limes and sands of Pennsylvanian age, roughly embracing the territory between the Red River on the north and the Llano Mountains on the south, and between Fort Worth on the east and Abilene on the west. It includes Archer, Cooke, Montague, Wichita, Wilbarger, Clay, Baylor and Foard counties in the North Central Texas or Red River Basin area, and Brown, Callahan Coleman, Comanche, Eastland, Erath, Palo Pinto, Stephens, Shackel-ford, Throckmorton, Young and Jack counties in the West Central Texas area. Furthermore, it includes a brief review of development in Jones, Runnels, Haskell and Fisher counties. North Central and West Central Texas during the year 1928 produced an approximate total of 50,948,7461 bbl. or oil. This represents a decrease of approximately 7,720,250 bbl. under 1927 total production. This decrease was due to a slump in production in Brown, Archer, Wichita, Stephens and Cooke counties. Brown County showed the greatest decrease. The 1928 prodction in this county was approximately 4,500,000 bbl. less than the 1927 production. Gross production during 1929 in the North and West Central Texas area can be expected to be lower than in the year 1928. Only one county showed a considerable increase in production. Wilbarger County production increased approximately 3,000,000 bbl. during 1928. Its daily average increased from 9000 bbl. in April to 36,000 bbl. in August. At the close of 1928 it was averaging close to 32,000 bbl. daily. Drilling activity in North and West Central Texas during 1928 showed but a slight increase in completions. The total number of completions during 1928 was 3902, of which 2094 (53 per cent.) were producers, as compared to 3805 completions and 2112 (56 per cent.) producers during 1927. Brown, Young, Wichita, Archer and Wilbarger counties were the leaders in development. The outstanding discoveries for the districts were the Consolidated pool, extensions in the Greyback pool of Wilbarger County, and the Stephens pool, Fisher County.

Jan 1, 1929

By T. Egleston

In the year 1881 I presented to the Institute two papers containing the resnlts of researches on gold, in which I endeavored to make plain some of the causes of the losses in the working of gold-ores. Since that time I have continued this investigation at intervals with the following results. In the papers previously presented to the Institute I made no attempt to make compounds containing more than two substances. Since then I have endeavored to make more complex compounds. The experiments consist in fusing mispickel free from gold with a certain amount of metallic gold, and experimenting with that; also fusing the same mineral with sulphide of antimony, and fusing iron pyrites with gold and compounds of antimony. The mixture was made with mispickel taken from a vein not far from Stamford, Conn., absolutely free from gold. It was fused

Jan 1, 1884

By Thomas M. Drown, P. W. Shimer

THE precipitation of phosphoric with titanic acid, by boiling an iron solution which had been reduced to the ferrous condition by sulphuretted hydrogen or sulphurous acid, was first noticed by E. H. Bogardus in 1874.* Since that time, as far as we are aware, not much has been published on the relation- of these two acids to each other, and to silicic acid, in the ordinary course of analysis of iron ores. The following investigation may perhaps aid in clearing up some of the obscure points in the analysis of titaniferous ores. THE DETERMINATION OP PHOSPHORUS. From two to five grams of the finely powdered ore are weighed into a beaker and treated with about 50 c.c. of hydrochloric acid (sp. gr. 1.12), evaporated to dryness, and heated in an air-bath for * American Journal of Science, III, 8, p. 334.

Jan 1, 1882

By Newell Hamilton

Some years ago, in the manufacture of seamless tubing from an alloy steel containing 0.07 per cent maximum carbon, 18 per cent chromium and 8 per cent nickel, at the plant of The Babcock & Wilcox Tube Co., a peculiar type of piercing defect was noticed. This defect was definitely associated with certain heats of the alloy and was independent of any of the variables of mill operation and billet-heating condition. A thorough analysis of the defective material yielded but one clue to the reason for its abnormal behavior in piercing and that was its oxygen content as determined by the vacuum fusion method. The oxygen content of the defective 18-8 alloy was found to be from two to three times that of the material that had pierced satisfactorily, and this incited an active interest in the vacuum fusion method for the analysis of alloy steels. After a critical survey of the literature on this subject, and considerable experimentation, an apparatus and technique were evolved that gave a fairly rapid, simple and reliable method of analysis. Samples selected from six years of tube production of 18-8 and other corrosion-resistant alloys were analyzed by this method. This paper describes the procedure and gives a correlation of the oxygen, hydrogen and nitrogen contents of a number of alloy steel samples representative of good and bad tube-piercing quality. The Apparatus Basically the apparatus used in this work was that of Jordan and Eckman,' employing a high-frequency induction furnace and the gravimetric method of analyzing the evolved gases, nitrogen being excluded from the determination. In addition, a magazine-type cap and a large-

Jan 1, 1934

By Donald L. Birkimer

GENERAL INTRODUCTION To paraphrase comments made by Black and Hoek(1) on the status of rock mechanics, the general methods of applied science related to rock mechanics are: a. Observe the phenomena of nature as they occur and, wherever possible, quantify the observations. b. Propound a model or theory to explain the phenomena observed. c. Test and develop the theory by further experimentation in the laboratory and in the field. d. Use the theory developed to predict behavior in similar or extended circumstances. e. Insure by measured experiment and observation that the predictions made are valid, or that deviations from the predicted behavior can be accounted for. f. Modify the theory and practice as necessary, and continue the process until more general laws can be formulated and applied, with a useful degree of confidence, to practical problems. This paper will present an infant concept. It will, in fact, propound a possibly useful theory to help explain commonly observed phenomena. It will test and develop the theory for a material similar in nature to some rocks. It will be used to predict behavior in the extended circumstances of a

Jan 1, 1971

By Ross C. Anderson, William I. Weisman

THE manufacture of anhydrous sodium sulphate or salt cake from natural deposits in the United States has been in general somewhat of a marginal undertaking. Competition from foreign sources and from large quantities of byproduct sodium sulphate produced domestically in the manufacture of hydro-chloric acid and other chemicals has existed and continues.

Jan 7, 1953

By Henry U. Ross

The behaviour during reduction of iron-ore pellets and sinters was investigated. Several methods for the preparation of agglomerates and their reduction were tried. Commercial agglomerates from world-wide sources as well as experimental samples were tested. The effect of coke additions to pellet and sinter plant feeds was given special consideration. An analysis of the test results has helped to explain many of the phenomena associated with the reduction of iron-ore agglomerates such as swelling, loss in strength and wear resistance, changes in porosity, changes in mineralogy and the formation of metallic iron and slag. A double-layer pellet with all of the coke concentrated in the core proved particularly interesting. Although large quantities of coke showed that partially reduced agglomerates containing metallic iron could be produced in the laboratory, the problem of producing reduced pellets and sinters by the existing agglomerating processes still remains.

Jan 1, 1977

There were present eleven Directors, the Secretary and Assistant Secretary of the Institute, and eleven guests. The Secretary, Bradley Stoughton, was appointed the representative of the Institute on the Board of. Directors of the American Bureau of Welding. A communication from a member of the Institute regarding simplified spelling was laid on the table. The following appropriations were made for the year. 1919: $250 to the Institute of Metals Division, $250 to the St. Louis Section, $100 to the Columbia Section. An invitation was received from the Western Society of Engineers to the Institute to use the facilities of that society during the A. I. M. E. Meeting in Chicago. The Bulletin of the Institute was presented to the French Congress of Engineers. There were elected twenty-eight members, eighteen associates, and three junior associates. The status of one member was changed from junior associate to associate. Four members were reinstated. An extension of time was granted to one member for payment of dues. The dues of four members on active military duty were suspended. Dues were remitted of four members who have been paying over thirty years, and who are each over seventy years of age.

Jan 5, 1919

By Frank Foote

IN recent years the constitution of the high-silver aluminum-silver alloys has been extensively investigated. Hansen1 has re-viewed the literature to 1935. More re-ently, Obinata and Hagiya,2 Hofmann and Volk,3 Taziri4 and Tishchenko5 have con-firmed the general features of the phase diagram in the region around 25 atomic per cent aluminum. In this paper we present the results of high-precision measurements of lattice con-stants of the silver-rich alpha solid solution in the homogeneous range and the neigh-boring two-phase regions. These results are used to establish the nature of the solid solution, the identity of directly measured densities with those calculated from lattice constants and the homogeneity limits of the alpha solid solution with respect to three different neighboring phases. A study of the earlier investigations indicated that the last two subjects in particular required new and accurate data.

Jan 1, 1940

By Wilbur Nelson

THE year 1923 has been a dull period in oil development in Kentucky and Tennessee, with the exception of the Kettle Creek area along the Tennessee-Kentucky line, in Clinton and Cumberland Counties, Kentucky, and Clay County, Tennessee. The price of oil during the year has been so low that wildcatters have shown little interest in drilling. At the beginning of the year, light oil sold for $2.31 per barrel and medium oil for $2.06 per barrel. Prices increased to the highest point for the year in February, when light oil brought $2.86 per barrel and medium oil, $2.61. In April, prices had declined 35 c. while in May an additional decline of 25 c. went into effect. During June, prices declined 20 c. per barrel; during July, 45 c. per barrel; remained stationary during August and September, and dropped during November and December to the low price of $1.36 per barrel for light and $1.21 for medium oil. At present, an increase of 29 c. has brought the price of light oil up to $1.55, and indications are that the price will continue to increase during the coming months. It can readily be seen that during 1923 the price of oil was such as to prevent any drilling except that necessary to hold leases and to maintain production enough to take care of overhead expenses.

Jan 3, 1924

By L. W. Saperstein, J. C. Mills, L. B. Phelps

Selective placement of toxic mine spoil has been advocated as a means of reducing environ¬mental pollution at the source. However, methods of burial to control environmental damage are not well understood. Using the finite element method, this paper investigates the burial of toxic material within low permeability packages below the water table. The effects of differing package and spoil permeabilities, anisotropy, and infiltration are modeled to provide information about their effect on the flow system. Projections can then be made that will assist in the design of the toxic spoil package to limit the amount of ground water flowing through them.

Jan 1, 1986

By C. G. Dunn

Nuclei that are formed during the recrystallization of a grain following plastic deformation generally have orientations that differ from the original. This aspect of recrystallization may be described in terms of orientation changes. It was shown previously, in an investigation on recrystallization in silicon ferrite,&apos; that the observed orientation changes were highly improbable on a chance basis, and that some mechanism must be involved. Analysis showed that the data could be satisfactorily classified into the smaller of two subclasses† of the 36 third-order twin transformations. No attempt was made at that time to classify the data within the special class of 12 third-order twin transformations, although results did indicate a greater probability for some of them to occur. A classification of this type would be more valuable, of course, with more data on orientation changes per old deformed grain. The present work fulfills this condition to some degree and also extends the scope of the investigation to include the effects of original orientation and the amount of plastic deformation. The effect of original orientation is of considerable interest because of the known effects of orientation on plastic deformation, particularly with regard to degree of fragmentation and the formation of deformation bands, and because the orientations produced by deformation should influence the orientations obtained through recrystallization. Barrett and Levenson2 reported that single crystals of iron deformed in the range 82 to 97 per cent could be put into three general classes; namely, crystals in class I maintained a reasonably sharp single orientation, those in class 2 transformed into two distinct orientations, and those in class 3 changed into a large number of major and minor orientations. Something similar would be expected for silicon ferrite crystals, and verification of this for a few cases of types class I and class 2 deformation has been reported elsewhere3 for single crystals of silicon ferrite cold-rolled in the range 10 to 20 per cent. As an example of class 2 deformation, it was shown that a crystal of silicon ferrite cold-rolled in a (110) plane in a <100> direction developed two layers, or deformation bands differing in orientation. When this happens it is possible to etch away one band and leave a single structure for use in studying the orientation changes that occur during recrystallization. when preferred crystal orientations are obtained in recrystallization, it is not particularly necessary to evaluate groups of common orientation, as was done previously (ref. I, Table 6); but an

Jan 1, 1947

By C. G. Dunn

Nuclei that are formed during the recrystallization of a grain following plastic deformation generally have orientations that differ from the original. This aspect of recrystallization may be described in terms of orientation changes. It was shown previously, in an investigation on recrystallization in silicon ferrite,&apos; that the observed orientation changes were highly improbable on a chance basis, and that some mechanism must be involved. Analysis showed that the data could be satisfactorily classified into the smaller of two subclasses† of the 36 third-order twin transformations. No attempt was made at that time to classify the data within the special class of 12 third-order twin transformations, although results did indicate a greater probability for some of them to occur. A classification of this type would be more valuable, of course, with more data on orientation changes per old deformed grain. The present work fulfills this condition to some degree and also extends the scope of the investigation to include the effects of original orientation and the amount of plastic deformation. The effect of original orientation is of considerable interest because of the known effects of orientation on plastic deformation, particularly with regard to degree of fragmentation and the formation of deformation bands, and because the orientations produced by deformation should influence the orientations obtained through recrystallization. Barrett and Levenson2 reported that single crystals of iron deformed in the range 82 to 97 per cent could be put into three general classes; namely, crystals in class I maintained a reasonably sharp single orientation, those in class 2 transformed into two distinct orientations, and those in class 3 changed into a large number of major and minor orientations. Something similar would be expected for silicon ferrite crystals, and verification of this for a few cases of types class I and class 2 deformation has been reported elsewhere3 for single crystals of silicon ferrite cold-rolled in the range 10 to 20 per cent. As an example of class 2 deformation, it was shown that a crystal of silicon ferrite cold-rolled in a (110) plane in a <100> direction developed two layers, or deformation bands differing in orientation. When this happens it is possible to etch away one band and leave a single structure for use in studying the orientation changes that occur during recrystallization. when preferred crystal orientations are obtained in recrystallization, it is not particularly necessary to evaluate groups of common orientation, as was done previously (ref. I, Table 6); but an

Jan 1, 1947

By N. Brown, J. Washburn, E. R. Parker

MOST previous quantitative work on creep of single crystals has been concerned primarily with developing empirical equations for the creep curve. Although the equations used by Cottrell and Aytekin¹ and Tyndall² represented the data quite well, it was often necessary to use different values of the constants for different specimens even though they were apparently tested under identical conditions. In the course of previous work on the effect of surface coatings on creep of zinc single crystals," it was found that equal resolved shear stress frequently did not produce equal creep rates in different specimens. The work of Chalmers&apos; in the very

Jan 1, 1954

By Pedro G. Salom

I HAVE had an opportonity, within the last few months, of making a large number of physical and chemical tests of steel for boiler and ship-plate, which has been, and is now being, used principally for the United States Government cruisers, now building in Mr. John Roach&apos;s yard, at Chester, Pa. Through the courtesy of the Messrs. Houston, of the Chester Rolling Mills, I have the honor to lay before the members of the Institate the results of these tests. These results have developed some points in regard to the nature of steel, which are more or less new, and which, I hope, will prove interesting. The original specifications, as regards the manner of testing, were so inipracticable (when their severity mas taken into consideration), that the keel of the first vessel, which will be launched next month, would, had they been carried out, probably not have been laid until next year. At my suggestion, in order to simplify and expedite the immense amount of testing that had to be done, the Naval Advisory Board was induced, after considerable discussion, to alter the specifications, so as to test each heat, instead of each lot of twenty plates, but reserved the right of making the quenching-test on a piece from each ingot, after it had been rolled. This relieved us from the anxiety of having a lot of plates rejected, after they had beell rolled and sheared, by reason of the presence of one or two plates which might have been injured in heating or rolling, or which might not have been able to stand the tests; while it insured the Government in obtaining a uniform quality of steel, and prevented the temptation to introduce a half-dozen or more had plates in a lot, and run the risk of their being selected as the testplates. I give below a portion of the original specifications, as prescribed

Jan 1, 1884

By Tom Westgarth

As papers are placed before you upon large gas-engines in Belgium and Germany, it was considered that some information should be given upon the same subject in Great Britain. I therefore agreed to compile these notes, which I have made very short in view of the somewhat full nature of the other papers presented to this meeting, and considering the complete nature of the many publications which have been made recently upon the subject of large gas-engines. I give below Tables I. to VI., showing the number and particulars of large gas-engines which have been built or are building by British makers, and in view of the growing size of gas-engines I have concluded that engines of less than 500 h.p. cannot now he included in the category of large gas-engines, and therefore I have not considered engines under that power. Table I.—-" Oechelhauser " Type Gas-Engines. Built or Building by William Beardmore Co., Limited, Glasgow Indicated ! Engines. Horse-Power Type. Nature of Work. Gas Used. 6 2,500 Twin cylinder. Dynamo. Producer. 1 in Single cylinder. Rolling-mill. Producer. 4 1,250 Twin cylinder. Dynamo. Producer. 2 1,250 Single cylinder. Dynamo. Producer. 4 625 Single cylinder. Dynamo. Producer. 1 625 Single cylinder. Rolling-mill. Producer. 1 625 Single cylinder. Air compressor. Producer. 2 500 Single cylinder. Air compressor. Producer. 7 500 Single cylinder. Cement-mill driving Producer. Total, 28 engines ; 32,600 indicated horse-power. * Presented at the Joint Meeting of the Iron and Steel Institute and the American Institute of Mining Engineers, London, July, 1906, and here published under a mutual agreement between the Councils of the two Institutes.

Jan 1, 1907

By B. Mueller

Altered concepts regarding the raw material used in conventional blast furnace plants as well as new technologies for the reduction of iron ores make it necessary to reconsider the design of pelletizing plants. The incorporation of a pelletizing plant within a conventional integrated steel mill involves considerations of the problems of using in-plant fines. A modern pelletizing plant in Mexico serves as an example of the technical solution. In recent times, pelletizing plants are also being integrated within steel mills based upon direct reduction processes. The design of such pelletizing plants must take into account special product quality requirements.

Jan 1, 1977