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By John Dasher

Getting spodumene to float quickly and cleanly can be a problem. The author has presented an excellent account of a valid and useful approach to the scale-up of such problem floats. This indicated advantages for doubling retention time, i.e., buying another set of flotation cells. The author states that 21 pct of the spodumene floated in 2 min in the laboratory cell, that the grade of the rougher was about 75 pct spodumene, and that the final tailing contained 4 to 12 pct spodumene in different sizes with the present cells and 1 to 9 pct spodumene with twice as many cells.

Jan 6, 1959

By Carl Wagner

J. Pearson (British Iron and Steel Research Association, London, England)—Dr. Wagner has referred to the work of Richardson and Dancy and Gellner and Richardson on the reduction at 900 °C of wiistite films on iron. He has assumed that iron ions and electrons migrate backwards to the iron-wustite interface and that the reduced iron grows on the metal substrate. This would be a possible explanation of the results of these workers were it not for the fact that, as stated by Gellner and Richardson but not stressed, this growth in the center of the specimen can occur even

Jan 1, 1953

By A. W. Hahn

THE importance, to geologists and metallurgists, of knowing the mineralogical forms in which the silver occurs in ores has increased during the past few years, and will continue to increase as long as working hypotheses are converted into proved theories and rule of thumb methods are supplanted by scientific data. The methods used for the determination of these silver minerals have been: (1) careful study of polished ore sections with the microscope, and more recently, (2) metallurgical separation of the ground ore by flotation, tabling and panning, supplemented by microscopic examination of these separated minerals, and chemical analyses. During the course of some experimental work carried on by the testing department of the International Smelting Co. and myself, it becomes important to determine, in a general way, the distribution of the silver values in the minerals, as they exist in Tintic Standard and North Lilly siliceous oxidized lead-silver ores. These mines are in the East Tintic Mining District, State of Utah. In this work the second method was used. Differential flotation tests were run, separating the sulfide from the oxidized minerals, and the products were assayed. Various concentrates were carefully panned and the separated products assayed; special samples of ore were selected and assayed. The microscope was used only for the purpose of determining whether the individual minerals were in the so-called "free" state.

Jan 1, 1929

By F. W. Osterwald, C. R. Dunrud

Coal mine bumps are a serious hazard to life and property in the mines of east-central Utah. Research into geologic factors associated with these bumps indicates that the bumps are spatially and genetically related to structural and stratigraphic features. Some bumps are directly related to stress accumulation along faults, either from natural causes or as a result of mining. Frictional properties of bedding planes between coal and roof rock, and between some rock units within the roof, directly affect the deformation of coal ribs, and hence the incidence of bumps. These frictional properties are related to the lithology of the roof rocks as well as to the sedimentary structures within the rocks. Commonly a sequence consisting of 1/3 ft of carbonaceous silt-stone, about 2/3 ft of rider coal, and several ft of massive siltstone or sandstone overlies the main seam. The sequence causes difficult roof conditions in the mines, difficult mining conditions and, directly or indirectly, many bumps. The U. S. Geological Survey has studied the relationships between geological features and coal mine bumps at Sunnyside, Utah, for about six years. The work, which was originally undertaken at the request of and in cooperation with the U.S. Bureau of

Jan 1, 1965

By Ven Mercade

The flotation and, more importantly, the depression of calcite has been extensively studied, especially in terms of collector, pH, and metal ions. A basic laboratory study was undertaken to determine the effect of metal cation, pH, and hydrosol concentration on the flotation of calcite. Results indicate that at constant pH and soluble-silicate and metal-ion concentration, flotation of calcite decreases in the order: [ ] In the case of metal-silicate hydrosols, a higher pH of formation results in higher calcite flotation recovery. Data are insufficient to permit any conclusions regarding the behavior of mono- and trivalent ions. Possible theories to explain the foregoing observations are developed in the paper.

Jan 1, 1981

By J. T. Eash, E. M. Wise

Many of the platinum metal alloys are hot-forged in the early stages of reduction from ingot and substantial quantities of platinum alloys are commercially employed at very high temperatures in ammonia oxidation units, orifices for forming glass rods and fibers and as cathodes in long-life thermionic amplifiers. They are used also for electrical heating resistors, safety blowout disks, thermocouples and crucibles. The tensile properties at elevated temperatures are important in many of these situations but data on the subject are limited. Creep data also are important, but will not be covered at this time. Scope and Conclusions Tensile tests were carried out at room temperature and elevated temperatures up to 1100" C. on previously well annealed samples of platinum. palladium and several of their important alloys with compositions shown in Table 1. The results are presented graphically in Figs. 1 to 4. The tensile strengths of platinum and the platinum-base alloys (with the exception of the 10 per cent rhodium-platinum alloy) at 1100" C. are from 16.6 to 18.8 per cent of the strengths of the same alloys (well annealed) at room temperature. The strength ratio of the 10 per cent rhodium-platinum alloy is 22.3 per cent, which is appreciably higher than that of the other materials tested. The tensile strengths of palladium and the palladium alloy at 1100" C. are from 10 to 11.2 per cent of the room-temperature values. The elongations of platinum and its alloys tend to increase at temperatures above 600" to 800" C., while the two samples of pure palladium show a maximum at 600" C.

Jan 1, 1938

By J. T. Eash, E. M. Wise

Many of the platinum metal alloys are hot-forged in the early stages of reduction from ingot and substantial quantities of platinum alloys are commercially employed at very high temperatures in ammonia oxidation units, orifices for forming glass rods and fibers and as cathodes in long-life thermionic amplifiers. They are used also for electrical heating resistors, safety blowout disks, thermocouples and crucibles. The tensile properties at elevated temperatures are important in many of these situations but data on the subject are limited. Creep data also are important, but will not be covered at this time. Scope and Conclusions Tensile tests were carried out at room temperature and elevated temperatures up to 1100" C. on previously well annealed samples of platinum. palladium and several of their important alloys with compositions shown in Table 1. The results are presented graphically in Figs. 1 to 4. The tensile strengths of platinum and the platinum-base alloys (with the exception of the 10 per cent rhodium-platinum alloy) at 1100" C. are from 16.6 to 18.8 per cent of the strengths of the same alloys (well annealed) at room temperature. The strength ratio of the 10 per cent rhodium-platinum alloy is 22.3 per cent, which is appreciably higher than that of the other materials tested. The tensile strengths of palladium and the palladium alloy at 1100" C. are from 10 to 11.2 per cent of the room-temperature values. The elongations of platinum and its alloys tend to increase at temperatures above 600" to 800" C., while the two samples of pure palladium show a maximum at 600" C.

Jan 1, 1938

By Frank Firmstone

By C. T. Young, J. L. Lytton

In recent investigations,1,2 the strength and thermal stability of dislocation substructures prepared by 5 to 25 pct room temperature tensile straining and recovery annealing at 120°, 160°, and 200°C have been studied in randomly oriented polycrystalline high purity aluminum. The techniques of transmission electron microscopy revealed that a major source of the strength and stability of dislocation substructures was the formation, during room temperature straining, of well-defined cells bounded by dislocation tangles which rearranged into nearly perfect dislocation networks during recovery, forming the boundaries of subgrains. The strength of such substructures increases with decreasing cell or subgrain size,2"6 and the formation of fine subgrain structures can provide thermally metastable strength at low temperatures and can favorably alter the course of primary creep at elevated temperatures.7'8 For maximum benefit, however, sub-grain growth should be reduced or eliminated. It was, therefore, decided to investigate the use of heterogeneous precipitation on dislocation networks as a means of imparting increased strength and thermal stability to subgrain structures through effective pinning. C.T. YOUNG, STUDENT MEMBER AIME, and J. L. LYTTON, Member

Jan 1, 1970

By J. R. Mihalisin, J. S. Iwanski

The response of Inconel "700" to heat treatment has been studied by light and electron microscopy combined with X-ray and electron diffraction techniques. A heat treatment which vesults in low ductility for this alloy appears to be associated with the formation of MC carbide in a Widmanstdtten distribution. This type of precipitation can be suppressed by suitable heat treatment with concurrent increase in ductility. Various other phases precipitated in this alloy are also identified. RECENT studies of commercial nickel base su peralloys have demonstrated the importance of the morphology of carbide phases upon physical properties.' For example, empirical heat treatment studies applied to Nimonic "80" and Inconel "X" have resulted in prescribing double aging treatments for optimum physical properties. These treatments have subsequently been related micro-structurally to grain boundary carbide morphology.2 The purpose of this study was to obtain information about the morphology and identity of some of the phases precipitated in Inconel "700" after heat treatment. It was hoped that some correlation could be made of micro structure with heat treatment similar to that observed with Inconel "X" and Nimonic "80." EXPERIMENTAL PROCEDURE Specimens were obtained from a hot-rolled bar of Inconel "700" of the following composition: C Mn Fe S Si 0.10 0707 0.42 0.007 0.12 Cu Cr -A1 -Ti- Co Mo Ni 0.02 -14.90 TM 2.22 27.61 2.92-- Bal. Specimens were prepared in the following heat-treated conditions: (A) 2275°F for 2 hr WQ (B) 2275°F for 2 hr WQ + 2000°F for 1 hr (C) 2275°F for 2 hr WQ + 1600°F for 48 hr. (D) 2275°F for 2 hr WQ + 2000°F for 1 hr + 1600°F for 48 hr. Empirical stress-rupture studies had shown that treatment (D) resulted in optimum stress-rupture life and ductility. Treatment (C), although giving a good aging response, resulted in low ductility. Treatments (A) and (B), respresenting individual. steps in treatments (C) and (D) were added here for microstructural comparison studies. The procedure was to make an optical and electron microscopic investigation supplemented by X-ray diffraction analysis of electrolytically extracted residues. Electron diffraction studies were made utilizing selected area diffraction techniques with extraction

Jan 1, 1960

By E. M. Wise

MANY of the platinum metal alloys are hot-forged in the early stages of reduction from ingot and substantial quantities of platinum alloys are commercially employed at very high temperatures in ammonia oxidation units, orifices for forming glass rods and fibers and as cathodes in long-life thermionic amplifiers. They are used also for electrical heating resistors, safety blowout disks, thermocouples and crucibles. The tensile prop-erties at elevated temperatures are important in many of these situations but data on the subject are limited. Creep data also are important, but will not be covered at this time. SCOPE AND CONCLUSIONS Tensile tests were carried out at room temperature and elevated temperatures up to 1100° C. on previously well annealed samples of platinum, palladium and several of their important alloys with composi-tions shown in Table 1. The results are presented graphically in Figs. 1 to 4. The tensile strengths of platinum and the platinum-base alloys (with the exception of the 10 per cent rhodium-platinum alloy) at 1100° C. are from 16.6 to 18.8 per cent of the strengths of the same alloys (well annealed) at room temperature. The strength ratio of the 10 per cent rhodium-platinum alloy is 22.3 per cent, which is appreciably higher than that of the other materials tested.

Jan 1, 1938

By G. W. Binkley, G. K. Dumbauld, F. A. Brooks, B. E. Morgan

In recent years, oil well cementing compositions have been developed with low densities, controlled set strengths, and satisfactory thickening times. With the introduction of the permanent-type well completion method for cementing wells, another property—that of rate of filtration or water loss to permeable formations— has become important. Laboratory data show that cement slurries prepared with oil, water, bentonite, and calcium lignosulfonate possess satisfactory thickening times, strengths, and filtration properties for primary cementing of casing and for squeeze cementing with the permanent-type well completion technique. Cementing compositions have been prepared with oil-in-water emulsions varying in composition from 60 cc water and 20 cc oil per 100 gm cement to 90 cc water and 45 cc oil per 100 gm cement. These compositions have contained from 0.4 to 5.0 per cent calcium lignosulfonate by weight of dry cement. Slurries prepared from these compositions weigh 11.4 to 13.1 lb/ga1 and have filtration rates of from 10 cc to approximately 100 cc in 30-min API tests at room temperature. The unfiltered emulsion cements develop one-day tensile strengths of 60 to 220 psi; and the filtered mass sets to tensile strengths of 60 to 150 psi in 12 hours and develops strengths of 320 to 515 psi in seven days when cured at 125° F. Field experience gained from 13 field mixing jobs demonstrates the utility of the emulsion cement for permanent-type squeeze cementing operations. INTRODUCTION In recent years, research in oil well cementing composition has been directed toward the development of cements having low densities, controlled set strengths, satisfactory thickening times, and low rates of water loss by filtration. Two well cementing compositions that have been developed with these properties are the modified cements containing, respectively, 12 and 25 per cent bentonite clay and various concentrations of calcium lignosulfonate1,2 In a search for other ways to incorporate these characteristics in a cementing composition, consideration was given to the rheological properties of oil-emulsion drilling fluids. Many of the desirable properties observed in oil-emulsion drilling fluids are equally advantageous in a cementing composition. For example, low water loss by filtration and low density, which are inherent characteristics of these oil-in-water emulsions, are desirable for many oil well cementing operations. Furthermore, oil-emulsion slurries have lubricating properties similar to those of oil-emulsion muds, a factor which should provide ease of rotation of casing during primary cementing operations. The properties of lubrication and low filtration may be of special value in both primary and squeeze cementing operations encountered in slim-hole drilling. Studies in the preparation of oil emulsion systems have pointed out the need for violent agitation in order to disperse the oil into the water phase. It was thought, therefore,

Jan 1, 1957

By Robert H. Merrill

During the period from 1960 through 1966, the U.S. Bureau of Mines and Kennecott Copper Corp. performed an experiment to determine the changes in stress, strain, and displacement created by changes in slope angles. The experiment was performed at Kennecott's Kimbley pit near Ely, Nev. The supporting laboratory studies were made in the Bureau's Denver Mining Research Center, where final reduction of the data and summary reports are now in progress. The experiment was divided into two phases. The first consisted of the laboratory and field investigations required to select a new slope angle and configuration; the second phase consisted of a full-scale instrumented study in the west wall of the pit. The west slope was changed from an average of 45º to a slope angle that started at 45º on the south wall and gradually in- creased to 57 ½ º at the center of the west wall, and to 61 º on the north wall. The pit was deepened from 500 to about 550 ft, and approximately 2.55 million tons of waste and ore were removed from the wall.

Jan 9, 1969

By Charles Austin

IT has been known for several years1 that certain alloys of the Konal type, containing commercial cobalt (99.32 per cent C0 and 0.42 per cent Ni) and varying amounts of ferrotitanium, exhibit very high tensile strengths at 600°C. However, their pro-portional limits and yield points are rela-tively low. Published data1 for the alloys quenched in water from 950°C. and then tested at 600°C. are summarized in the upper section of Fig. I. Similar specimens that were aged at 650°C. for 72 hr., after quench and prior to testing at 600°C., gave the results shown in the lower section of Fig. I. TABLE I.-Analysis of Material I Percentages Constituent Sample Sample Sample 3125 3124 3123 Si 0.25 0.51 o.6o Fe 4.15 10.70 13.17 Ti I.15 3.58 4.70 Mn 0.30 0.41 0.42 Co (by difference)^ 94.15 84.80 81.71 The cobalt from all three samples, united and tested for nickel, gave 0.54 per cent Ni based on the weight of cobalt. In the present work the investigation of the properties of these materials has been extended by a study of the tensile deforma- tion characteristics in moderately long-time tests at 600°, 700° and 800°C. after quenching from various solution tempera-tures. In addition, some metallographic studies have been made to correlate with the deformation tests, and to obtain in- FIG. 1.-EFFECT OF VARYING AMOUNTS OF FERROTITANIUM (FE2TI) ON PHYSICAL PROPER-TIES OF COMMERCIAL COBALT. (C. R. Austin.1) Upper section. Tested at 600°C. after water-quenching from 950°C. Lower section. Tested at 600°C. after water-quenching from 950°C. and aging 72 hr. at 650°C. FIG. 2.-PORTION OF QUASI-BINARY DIAGRAM COBALT-FE2TI AS DETERMINED METALLOGRAPH-ICALLY. formation on the quasi-binary system Cobalt-Fe2Ti. The material, very kindly furnished by the Westinghouse Electric and Manufac-turing Co. in the form of hot-swaged rods of 3/16-in. diameter, analyzed as shown in Table I. The alloys, when originally made up,1 were based upon an iron-titanium com-pound, Fe3Ti, as indicated by the work of

Jan 1, 1940

By J. E. Johnson

At the Cleveland meeting of the Institute in October, 1912, I had the honor to present a paper outlining the conditions surrounding the charcoal iron industry…

Jan 1, 1915

By Paul A. Farrar, Felix Ermains, Harold Margolin

The systems Ti-Crand Ti-Vhave been reinvesti-gated in the region up to 40 wt pct alloying addition using both conventional and rapid quenching techniques. The Ti-Cr eutectoid temperature was determined to be at 667° & 10° C and 14.5 wt pct Cr. The solubility of the Cr in a Ti was found to be less than 1 pctat 700"C. The P transus of the Ti-V system was found to be depressed to 510°C at 40 wt pct V and the solubility of V in a Ti was found to be less than 2 wt pct at 700°C. Investigation by a. d. McQuillan1-3and m. k. McQuillan4 on the systems Ti-Co, Ti-Cr, Ti-Cu, Ti-Fe, Ti-Mn, Ti-Ni, and Ti-V has cast doubt as to the position of the ß/a + ß boundaries in many of these systems. Their investigations were carried out using hydrogen pressure and/or rapid quenching experiments, as opposed to the conventional quartz capsule techniques employed by most other investigator.'" By these methods, the ß/a + ß boundary was found to be lower than that obtained by conventional techniques in all except the Ti-Fe system. In the latter, the ß/a + ß boundary was essentially the same as the boundary obtained by conventional technique.7' On the basis of rapid quenching results in the Ti-Cr system, M. K. McQuillan4 placed the eutectoid temperature below 550°C whereas other investigations using conventional techniques had placed the eutectoid variously as between 650' and 700°C,5 between 675' and 700°C,6 between 650" and 675°C,7 at 670°C,8 and above 625"C.la9l3 In order to check these results, a reinvestigation of four of the systems was undertaken using both conventional and rapid-quenching techniques. The Ti-Fe and Ti-Mn systems will be dealt with in anoth er paper, with only the Ti-Cr and Ti-V systems being discussed here. EXPERIMENTAL TECHNIQUES Alloys employed for the delineation of the systems under investigation were prepared from iodide titanium sheet capsules containing the alloying materials,

Jan 1, 1962

By G. R. Fritterer

INVESTIGATORS in the field of temperature measurement have long sought a thermoelectric couple fulfilling the following requirements: 1. It should be useful up to and including high industrial tempera-tures; i. e., 1000° to 1800° C. 2. Its thermoelectric variation with temperature should be linear and be maintained after heating to high temperatures for long periods of time. 3. It should be reproducible; i. e., different couples of the same elements should have similar calibration curves. 4. Its thermoelectric power should be large so as to allow the industrial use of rugged recording instruments. 5. Chemical reactions with, and physical changes within the elements of the couple should not alter its calibration. No thermocouple proposed to date exhibits simultaneously all of these characteristics, whereas the couple about to be described fulfills all requirements to a satisfactory degree.

Jan 1, 1933

By Kevin Clermont, William N. Kelley, William E. Bonini, John H. Vreeland

Gravitational field anomalies have been observed over many igneous intrusives of medium (4000 sq km) to small (100 sq km) size in outcrop area. These studies give good results because the residual anomalies can be separated from larger-scale crustal anomalies and density contrasts usually are present. Although unique solutions are not possible, the analysis of the gravity anomalies place important limits on both the areal and depth extent of the intrusive bodies. Of all possible geophysical techniques, gravity studies offer the most promise in the determination of the shape in depth of intrusive bodies.

Jan 1, 1972

By R. O. Scattergood, P. Beardmore, M. B. Bever

THE stored energy and microhardness of a Au-Ag alloy deformed by explosive loading were measured previously as functions of shock pressure' and compared with corresponding data for drawn wires.' The difference of the two processes has been explored further by investigating the annealing behavior of explosively loaded specimens and drawn wires. Sheet specimens, 0.042 in. thick, of a Au-Ag alloy containing 82.6 wt pct Au were explosively loaded in stacks of four.3 Wires prepared from the same melt of alloy were drawn through dies.' The annealing kinetics were determined by microhardness measurements on separate specimens for each annealing temperature and time. Several values of the stored energy were measured by tin-solution calorimetry Experimental details are given elsewhere. Wires were drawn until the microhardness or stored energy equalled the corresponding values of the explosively loaded specimens as nearly as possible. Wire drawn to a true strain 7 of 0.09 had approximately the same hardness and stored energy as specimens explosively loaded to a shock pressure of 70 kbar. The microhardness of specimens

Jan 1, 1963

By John T. Popp, Jodi A. Rulli, Anthony T. Iannacchione

Anomalous geological features in the coal and surrounding strata of a mine in northern West Virginia have fractured and deformed an inherently weak roof rock prior to mining. Horizontal stresses, as much as six times greater than overburden related horizontal stresses, have induced cutter roof failure. This failure was distinguishable from rock deformation associated with geological anomalies because it was induced by mining. The characterization of these features has allowed for the prediction of zones of unstable roof rock and the determination of failure trends on gateroad stability. Geological anomalies included clastic dikes and a narrow zone of sandstone roof. Clastic dikes, representing intrusions of shale and claystone, were invariably accompanied by local roof rock instability, and often formed the boundaries of roof falls. Shale was the dominant roof lithology except where a small sandstone occurred in the northwest portion of the longwall mining area. The sandstone occurs in two phases: a sandstone-filled channel, 5-m- thick and 60-m-wide, which eroded and replaced the shale roof and the upper part of the coalbed; and a sheet sandstone unit which was crossbedded to interbedded with the underlying shale. Horizontal stresses are naturally relieved through the initiation of cutter roof failure. This failure may extend from a few meters to several tens of meters horizontally, and from a few centimeters to several meters vertically. Orientations of entries and crosscuts has a greater influence on the direction and total length of cutter roof failure at the rib-roof intersection than does the principal directions of the in situ horizontal stresses. Seventy-four percent of the cutter roof failures occurred along the rib-roof intersection. Orientations of cutter roof failure away from the rib- roof intersection were clustered in the north-south direction and may have been influenced by the horizontal stress field.

Jan 1, 1984