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By J. W. Fuller

DURING the last 20 years, experimenters have sought to utilize pulverized coal in boiler plants, but refractory and slag troubles have usually overbalanced any, gains in efficiency that were obtained. These troubles were caused largely by lack of knowledge of the proper methods of coal preparation and lack of a furnace design that would be adaptable to pulverized-coal firing. When this information was obtained the results were so much more satisfactory that within the last 5 years approximately, 80,000 boiler hp. have been installed in plants ranging from 1000 to 20,000 boiler hp. rated capacity, which are operating at an average of 174 per cent. of rating. The first commercial installation for burning pulverized coal under boilers was made at the Parsons shops of the M. K. & T. railroad in 1916. Of eight 250-hp. water-tube boilers thus fitted, six were operated continuously for 3 yr., when oil was obtained at such a low price as to warrant its use. Since then, this plant has been operating alternately on pulverized coal and oil, depending on prevailing prices. Recently gas has been discovered within 20 mi. of this plant, so that this fuel may also be used. No change in furnace design was made when changing from pulverized coal to oil or gas firing. One of the principal advantages of this method of firing is its ability to utilize, with maximum efficiency, all kinds of coal, irrespective of quality or physical characteristics. In fact, quite a number of the present pulverized-coal installations were made for the purpose of utilizing coal that could not be marketed or used in any other way. The Pacific, Coast Coal Co., at Black Diamond, Wash., formerly hand fired the boilers, using approximately 125 tons of prepared steam-size coal daily. The Black Diamond steam coal is the best quality of coal for steaming purposes mined in that section of the country, and there is a market for all that can be produced. By installing a pulverizing plant, it was possible to substitute coal of a size and quality that had no commercial value, so that 125 tons daily of the best steam coal formerly used at the mines is now marketed.

Jan 12, 1921

Forty-three years ago a record for low cost was made at the Spanish mine, in Nevada county, California. In 22 days of September, 1887, there was mined 2796 tons of ore at a cost of 37.5 cents per ton, of which 32.4 cents was for labor and 5.1 cents for supplies. The mill treated this ore for 23 cents per ton, of which 12.3 cents was for labor and 10.7 cents for supplies. Thus the total operating cost was 60.5 cents per ton. The yield was $1.16 in gold per ton, leaving a profit of 56 cents per ton, or 48 per cent of the yield. The mine was an open-cut in a schist formation on a hillside and the work was done by Chinese laborers that were paid $1.40 per shift. The ore was soft, and could be ground effectively in four Hunting- ton mills, supplemented by silvered amalgamating plates.* The engineer in charge was F. W. Bradley, a student from the University of California. As has been indicated, the conditions were unusually favorable in respect of softness of ore, accessibility to the mill, metallurgic simplicity, with cheap labor and power, but even at that the results were so remark- able as to attract general attention, which, as might be expected, was magnified, for advertising purposes, by the manufacturers of the Huntington mill, the firm of Parke & Lacy, at San Francisco. The record made at the Spanish mine therefore found its way into many textbooks on mining published at that time. The editor of the 'Mining and Scientific Press'† (at that date, Charles G. Yale) evidently took a warm interest in. the

Jan 1, 1932

By R. Lee-Aston

HALLOWAY mine of Tennessee Copper Co. at Copperhill, Tenn., has been under development for several years. It has two shafts, the A shaft, 1336 ft deep from the surface to the 16 level, and the B shaft, lying 500 ft to the southeast and extending 1385 ft deep from the 10 level down to the 24 level. A section through the two shafts, Fig. 1, shows the development work entailed by the proposal and the area involved. The Problem: For operational reasons it was necessary to extend the B shaft from the 10 level to surface, and the pilot hole and raising method was chosen. This method had been used to extend the Company's Boyd manshaft from the 10 to the 14 level in 1954, but no satisfactory hole surveying method had been employed. In that instance, when the hole was located it was found to be about 8 ft from its calculated position. The success of this shaft extension method lies in the ability to keep the pilot hole within the proposed shaft diameter for nearly the entire length. The approximate 670 ft of extension distance in one hole was thought to be excessive because of deflection encountered locally in other core drilling. Since a connection between the two shafts, intermediate between the surface and the 10 level, would be required at some future date, the pilot hole drilling was done in two sections. This intermediate level was fixed at the 6 level and distances became 470 ft from surface to the 6 level and 230 ft from the 6 to the 10 level. A rock pentice of 25 ft was left temporarily in place just above the 10 level.

Jan 3, 1958

IN THE past, we have, perhaps, been somewhat careless in our furnace practice, in the use of high-grade material, lowering the production costs through demanding high-grade ores, increasing the size of units, and eliminating heat losses by collecting and returning unused heat to our furnaces. Further economies would seem to be possible through keeping out of the furnace those materials that appear to serve no useful purpose and carry with them heat that should be used in reduction operations. In the manufacture of pig iron, about three tons of inert nitrogen pass through the furnace for each ton of iron produced. This nitrogen serves no useful purpose in the chemical actions involved, but when discharged into the atmosphere it carries away a considerable quantity of heat. Can not this loss be eliminated, at least in part, through the use of more oxygen in the blast? Many metallurgical chemists, during the past 20 years, have stated that they thought it can and have urged that the plan be tried. Others have expressed doubt, not being able to visualize how more oxygen could be used in present practice; they have regarded it as impracticable, without trying to conceive of an entirely new practice based on a new reagent. That more experimental work has not been done is due to the fact that no cheap oxygen has been available, but the committee believes that there is strong reason to expect that, should a demand exist, 99 per cent. oxygen may be made at a cost not to exceed $3 per ton. The theoretical studies of the committee have indicated such marked economy by using oxygenated air in various operations that its members strongly recommend experimental work to verify the anticipated economies. The committee has developed plans for experimentally determining the effects of oxygen-enriched air on the operation of an iron, blast furnace. A furnace with a height of 30 ft. has been built and it is recommended that the plans be put in, effect as the first step in the research.

Jan 11, 1924

By AIME AIME

CHARLIE WARNER, Chairman of the Petroleum Division, is no stranger to the problems of the oil industry or to those of the Petroleum Division, after more than 25 years of experience in locating and producing oil and more than 22 years of membership in the Institute. He was born at Jefferson, N. Y.. April 27, 1894, and educated in the public schools of New York State and at Cornell University where he studied geology and allied sciences from 1913 to 1917 and received a B.A. degree. Immediately upon completion of this training, he was employed by the Empire Gas & Fuel Co. as a field geologist in Oklahoma and Kansas. Two years later he became district geologist for the Emerald Oil Co. in Oklahoma and Kansas, and in 1920 he rejoined the Empire Gas & Fuel Co. in the capacity of district geologist in Oklahoma. In September of 1921 he began his association with the Houston Oil Co. of Texas. He was district manager for the company in the Mid-Continent area until 1932 when he was transferred to the head office at Houston, where he became superintendent of the land and lease department in 1934 and was elected a director of the company in 1941. In these capacities, and also as petroleum engineer for the company, he keeps in intimate touch with all phases of field activity and with the regulation of the industry by State and Federal agencies.

Jan 1, 1943

Until the end of 1960, the small primary aluminum industry in Australia was run by the government. The entire operation was at Bell Bay on the north coast of Tasmania. It consisted of an alumina plant and smelter, owned jointly by the Commonwealth and the State of Tasmania. Apparent domestic demand that year was about 48,000 long tons; 11% thousand came from Bell Bay; the rest was imported. By March 1964, Australia had two fully integrated aluminum companies. The government has stepped out of the picture and the key word of the industry from bauxite to metal is "growth." Present annual capacity of the two companies for making aluminum metal totals 92,000 long tons a year. Australian demand is about 60,000 tons. By 1968 Australian consumption should be 90,000 tons and by 1970 it is expected to reach 107,000 long tons per year. Export markets for bauxite, alumina and metal are developing.

Jan 10, 1964

By Eric Jette

THE unusual physical, electrical and magnetic properties of the iron-nickel alloys has given rise to a voluminous literature. This work will be reviewed critically in "The Alloys of Iron and Nickel," a monograph of the Alloys of Iron Research Series, soon to be published. In what follows we shall therefore confine ourselves to those of the earlier investi-gations that involved the use of X-ray crystal-structure methods. The earliest X-ray work on the iron-nickel system was by Miss Andrews1. Using the powder method of X-ray analysis purely as a means of identifying the phases present, she located a region between 20 and 30 weight per cent nickel in which body-centered and face-centered phases coexisted. No lattice constants nor details of heat-treat-ment were reported. Bain2 also reported some qualitative observations. McKeehan3 made a systematic investigation over the whole of the system, giving many of his alloys four and some five different heat-treatments. In alloys furnace-cooled from 900° to 950° C. he found two coexisting phases between 0.15 and 30 per cent nickel. The precision of the lattice-constant measurements was low in comparison with what can be obtained today.. Even for alloys of the same heat-treatment, differences in the constants were often between two and ten parts per thousand. In regions where no change of lattice constant with heat-treatment should occur, differences of the same order of magnitude were found. Since the maximum change in the lattice constant of nickel with change of composition is only about 2 per cent of the constant for pure nickel, these variations in the constants for a given alloy cause the points

Jan 1, 1936

By Northcutt Ely

The subject of this paper implies three questions: whether regulation is necessary; if so, what sort of regulation is wise; and, finally, by what government the power to regulate is to be exercised. In the year 1937 emphasis falls on the third of those questions. This contrasts with the situation prevailing a dozen years ago, when the question was whether regulation was necessary at all; and with the situation a few months ago, when the third question seemed answered by the Supreme Court decisions on the National Recovery Act, Agricultural Adjustment Act and Guffey Coal Control Act, and by the ratification of the Interstate Oil Compact. It then appeared settled that the State and not the Federal Government possessed the regulatory powers and, granting that conservation measures are a recognized necessity, the problem seemed to be to develop the wisest kind of regulation that the Constitution would permit. Today, by virtue of developments during the first months of 1937, the oil industry is faced again by the question of whether the Federal Government is to have power to control its operations, along with those of the other basic industries. Developments in Governmental Control There have been three recent developments. The dominating one is the President's proposal that he be authorized to increase the size of the Supreme Court to 15 members. The implications of that plan ought to be perfectly plain to the oil industry. This suggestion is made in lieu of offering an amendment to the Constitution, to reverse the Supreme Court decisions mentioned. In those decisions the Court held that production does not constitute commerce, and hence that the Federal power to regulate interstate commerce does not extend to the regulation of production. These holdings were contrary to the Government's contention that the stream of commerce begins in the factory and ends with the consumer and may be regulated at any point from beginning to end. That position was urged in the Government briefs in Amazon Petroleum Co. v. Ryan, defending the petroleum code, and repeated as late as Feb. 10, 1937, in the case of National Labor Relations

Jan 1, 1937

By José Geraldo Vieira

Companhia Vale do Rio Doce (CVRD), founded in 1942, is located near the town of Itabira, Brazil. Its iron ore deposits include over 500 million metric tons (mt) of high-grade hematite and about 2 billion mt of itabirite (banded rock formed by thin alternate layers of hematite and silica). These deposits are part of the Iron Ore Quadrangle, of which the overall reserves have been estimated at more than 30 billion mt. The magnitude of the project meant difficult early years for the company, including large investments, extensive railroad rehabilitation, and construction of ore port and ore handling facilities. Companhia Vale do Rio Doce was organized as a stock company, and 91% of its shares are presently owned by the Brazilian government. Financing has been accomplished in part through loans from international monetary agencies foreign banks, and foreign industry, as well as Brazilian banks. The company markets mainly abroad. In 1967, it exported 10.6 long tons (It) of ore, principally to West Germany, Japan, Netherlands, Italy, France, United Kingdom, and the United States. The Rio Doce geographic region where CVRD operates is strategically located among the large population centers of Rio de Janeiro, Belo Horizonte, Salvador, and Vitoria (Fig. 1). It covers an area of approximately 81,000 sq km in the states of Minas Gerais and Espirito Santo, and its population in 1968 was about 3.5 million. This region presents excellent prospects for development, with factors favorable for forestry, agriculture, grazing, and exploration for minerals other than iron ore, Electric power (hydroelectric plants) is available, as well as two main systems of transportation: the Rio-Bahia highway and the Vitoria-Minas Railroad. Pioneer activities at Itabira started about 1720 as small gold mining centers. The town is about 80 km northwest of Belo Horizonte and

Jan 1, 1969

By Roshan B. Bhappu, Raul A. Deju

The mineral olivine has been the subject of continued research by various authors. Paik1 conducted infrared and flotation studies of the adsorption of sodium alkyl benzene sulfonates on olivine. These studies are of interest from two points of view. First, in the metallurgical field it is of interest to understand the mechanism of silicate flotation using sulfonate collectors and second, hydrologists are interested in studying the chemical reactions that take place when water plus sulfonates encounter a porous silicate medium. On the basis of his study, Paik was able to postulate a possible mechanism for the attachment of RSO3- (sulfonate radical) to the olivine surface.

Jan 1, 1973

By Roger G. Rowe

In late 1980, Exxon Minerals Company performed rock mechanics testing on oriented 150 mm drill core from their 75Fi tonne massive sulfide deposit near Crandon, Wisconsin. Instrumented samples from depths of 300 meters indicate premining horizontal stresses in a north-south direction (parallel to pillar faces) to average 12,300 kPa, with the perpendicular plane yielding an average stress of 14,630 kPa. Rock strength versus sample size was compared using uniaxial compressive strengths from 47 mm, 95 mm and 150 mm core. Massive sulfide averaged 153,300 kPa, 139,845 kPa and 75,330 kPa respectively, while the hanging wall and foot- wall averaged 92,000 kPa, 76,560 kPa and 57,960 kPa respectively. Point load compressive strengths were calculated using formula suggested by both Hassani et al., 1980 and Broch et al., 1972. Values calculated using the Hassani formula closely resembled pre- existing point load and uniaxial compressive strengths, while values calculated using the Broch formula were 50 percent low.

Jan 1, 1982

By M. N. Dunlap

This article summarizes the successful incorporation of a flash-flooding stream into the tailing-disposal system at the St. Joseph Lead Company's Federal Division mill, in St. Francois County, Missouri. The mill was built in 1906, by the Federal Lead Co., as its No. 3 mill for the concentration of southeastern Missouri lead ores, and damming Davis Creek was first considered in 1908. Plans were made also in 1925 and in 1937. Dam layouts varied from a reinforced concrete structure to a barrier built of tailings alone. .All were abandoned because of liability that would be incurred by flash-flood rupturing of an incompleted dam. By 1942 mill capacity had reached 12,000 tons daily and increasing tailing-disposal costs again focused attention on the Davis Creek basin. This time the problem of riskless dam building was solved. Moreover, most of the items that appeared in the answer were materials that normally required wasting and the major portion of labor involved performed functions that it mould normally have done, without constructive benefit, elsewhere. The new layout also made possible advantageous changes in mill-water supply pumping; static head being reduced from 514 ft to 9; ft, friction head from 4900 ft to 2860 ft, and pumping can be done now at periods of low power demand. The following facts about the Davis Creek watershed explain the 36-year reluctance to reach these, and other, benefits. Size: 3600 acres. Outline: roughly pear-shaped, 21/2 by 3 miles at the largest dimensions. Topography: mostly hill land with steep valleys. Relief: 760 minimum to 1153 maximum. Maximum rainfall: 3.36 in. per hour. Permanent water: none natural. Now 2200 gpm discharged through 16-in. drill hole from mine pumps underground. Geology: the 17 acres near dam centerline is Bonne Terre dolomite covered with sand and gravel eroded from Pleistocene beds that cap some of the hills. The remainder of the pond basin is on Davis shale. Soil cover: mostly second-growth timber with some abandoned fields; all subject to careless burning, which reduces water-retaining ability. Flood history: flash-flooding that had taken at least one life. Downstream values: two railroad bridges before creek intersection with Flat River. Immediately below confluence, a highway bridge, a low-water crossing, a few business establishments and several blocks of residences. In July 1942 the following segments of an ingenious plan were put into operation. A ditch 270 ft long, 16 ft wide and 51/2 ft deep was excavated to bedrock in the gravelly soil along the proposed dam's centerline. This excavation, which exposed many gravel-filled channels, was run full of slimes drawn from a riser set in the top of an adjacent tailings-disposal

Jan 1, 1949

More than 400 members and guests registered for the 146th General Meeting of the Institute held in Mexico City Nov. 9 to 15, inclusive. Of these, 250 came by special train or automobile from 24 states of the Union, and the others were resident in Mexico. Mexican Government officials, headed by Manuel Santillan, Sub- secretary of the Department of National Economy, acting in. behalf of the President of the Republic, and including the Secretary of Foreign Relations and the Governor of the Federal District, were most hospitable in their official welcome and provided splendid entertainment of various kinds. A reception was tendered by Hon. Josephus Daniels at the U. S. Embassy. Among other hosts were officials of a number of large operating companies, including M. H. Kuryla, of the Real del Monte company; Jules Lacaud, of the CompaiLia Minera de Chontalpan; and Harry Wright, of the Consolidated Steel company.

Jan 1, 1937

By R. R. McNaughton

The Consolidated Mining and Smelting Company of Canada, Ltd. at Trail, B. C., inaugurated a comprehensive program of investigation about 15 years ago to develop the most economical process of recovering the metal in the large accumulated stock of by-products of the lead smelter and the zinc plant. Two principal methods of recovery were followed to a successful conclusion—an electrothermic process to treat zinc-plant residues and cold slag and the fuming of hot slag from the lead blast furnaces. The latter was selected because it showed a saving over the former in its ability to handle hot blast-furnace slag, thus obviating the necessity of granulating, handling and eventually remelting the same slag for the electrothermic process. The design of a fuming plant was commenced in 1928, and construction, which was started immediately, was completed in July 1030. Operating intermittently for a general tuning up, the plant was officially blown in for regular operation in August. During this month the vagaries of a slag-fuming plant were studied and an operating crew was trained. A history of slag fuming at Trail and the development of plant design is given in a paper by G. E. Murray in the Transactions of the Canadian Institute of Mining and Metallurgy for 1933. Fuming Plant The fuming plant at Trail (Fig. 1) is a separate unit although of necessity interlocked closely with the lead smelter. The plant consists essentially of a fuming furnace with its accessories, a waste-heat boiler followed by an economizer, and a suction-type baghouse. The plant was built as the first of two 400-ton units with the intention of adding the second unit within a year, so that flues, fans and buildings were built to handle double the original load. Furnace.—The furnace as originally built (Fig. 2) was of water-jacket construction, 10 ft. wide, 20 ft. long and 6 to 10 ft. high. The roof height was made variable to check experimental work, which had indicated that this dimension affected the rate of reduction. Coal and air were supplied

Jan 1, 1937

THE Boston meeting, August 29-31, was in many ways one of the pleasantest the Institute has enjoyed in years. Much hard work had been done by the committee, and with excellent results. The program had been purposely restricted with the idea that a smaller, more homogeneous audience formed the best basis for a regional meeting, and the event fully justified the plan. The one hundred and sixty-three members and guests attending were dominantly interested in geophysical methods or their application, and, despite the highly technical character of the papers and the unusual heat, attendance and interest in the technical sessions were well sustained. The exhibition of geophysical instruments and aerial maps added greatly to the meeting.

Jan 1, 1928

By E. H. Dix

The work of Merical and other investigators indicates that the phenomenon of age-hardening in alloys of the duralumin type is primarily dependent upon the variation in the solubility of copper with temperature. In addition to copper, however, these alloys contain small amounts of magnesium, silicon, manganese and iron, which may affect the age-hardening either directly or indirectly. The effect of these elements on the solubility of copper and on the manner in which this solubility varies with the temperature is of considerable interest, therefore. The effect of magnesium is of especial interest because apparently it exerts a marked effect on the natural or room-temperature aging of alloys of the type described.2 A series of investigations3 has been in progress in the research laboratories of the Aluminum Company of America to determine the functions * Metallurgist, Aluminum Research Laboratories. f Metallurgical Division, Aluminum Research Laboratories. Formerly with Metallurgical Division, Aluminum Research Laboratories. 1 P. D. Merica, It. G. Waltenberg and H. Scott: Heat Treatment of Duralumin. U. S. Bur. Stds. Sn. Paper 347 (1910). 2 M. Gayler: Constitution and Age-Hardening of Alloys of Aluminum with Copper, Magnesium, and Silicon in the Solid State. Jnl. Inst. Met. (1922) 28, 213. W. Fraenkel: Vergutbare Aluminiumlegiengen. Ztsch. Melallkunde. (1920) 12, 427. E. H. Dix, Jr.: Note on the Microstructure of Aluminum-Iron Alloys of High Purity. Proc. Amer. Soc. Test. Mat. (1925) 26, Pt. 2, 120. E. H. Dix, Jr. and H. H. Richardson: Equilibrium Relations in Aluminum-copper Alloys of High Purity. Trans. A. I. M. E. (1926) 73, 560. E. H. Dix, Jr. and W. D. Keith: Equilibrium Relations in Aluminum-manganese Alloys of High Purity. Proc. Inst. Met. Div., A. I. M. E. (1927) 315. E. H. Dix, Jr. and A. C. Heath, Jr.: Equilibrium Relations in Aluminum-silicon and Aluminum-iron-silicon Alloys of High Purity. Proc. Inst. Met. Div., A. I. M. E. (1928) 164. E. H. Dix, Jr. and F. Keller: Equilibrium Itelations in Aluminum-magnesium Alloys of High Purity. Proc. Inst. Met. Div., A. I. M. E. (1920) 351. E. H. Dix, Jr., F. Keller and R. W. Graham: Equilibrium Relations of Aluminum-magnesium Silicide Alloys of High Purity. Trans. A. I. M. E., Inst. Met. Div. (1931) 404. W. L. Fink and K. R. Van Horn: Constituents of Aluminum-iron-silicon Alloys. Trans. A. I. M. E., Inst. Met. Div. (1931) 383.

Jan 1, 1932

By Lester C. Uren

Today, a dozen or more universities and colleges in the United States are offering curricula designed for the specialized training of engineering students who plan to enter the petroleum industry. Many hundreds of students are following these curricula in their academic preparation, with the expectation that by so doing they will be better equipped to enter the petroleum industry in an engineering capacity than their competitors that seek to do likewise with training of less specialized character. Those who have helped plan and develop these curricula believe that such specialization should and does afford the student a superior preparation for his task. Others have questioned this and urge a broad preparation in fundamentals without specialization. Still others are suggesting even greater specialization than present petroleum engineering curricula afford. Some would have the student first prepare himself in one of the more general divisions of engineering, such as civil, mechanical or electrical engineering, and then seek some degree of specialized preparation in a graduate program. Which of these views is correct; or, if there is merit in each, which plan offers the greater advantage to the student? It is time that we paused to take stock of our objectives and of our way of attaining them. Is the training received by our petroleum engineering students what it should be? To what extent is the product of our petroleum engineering schools meeting the requirements of the industry? How may graduates be better equipped for the work they are called upon to do? These are questions that educators interested in the training of petroleum engineering students are ever asking. They must depend upon engineers and executives engaged directly in the industry for advice and helpful suggestions in better planning the training to be offered to our future engineers. This paper will have served its purpose if it is successful in focusing attention of men active in the industry on some of these educational problems, to the end that the ideas of men close to the needs of the industry may be made known to those who have responsibility in the control of our educational programs.

Jan 1, 1937

The President's Prizes, which consist of $30 and $20, were established for the best essays on some subject related to Mining, Economic Geology, or Metallurgy by a Junior Associate or a Member of an Affiliated Student Society of the Institute. In making the awards, special weight will be given to originality in investigation and treatment and to literary merit. As a general rule, the essays should not be less than 3000 nor more than 10,000 words.

Jan 1, 1923

By P. D. Proctor, M. P. Nackowski

Quantification in recording geologic phenomena and application of well-known geologic principles to engineering works continued at an increasing rate during the year. Highway departments, water resources agencies, private firms and governmental agencies involved in tunnel excavations, dam site locations and construction, consultants and government experts in subsurface liquid-waste disposal, designers of underground storage facilities and city and regional planners all confirmed greater use of applied geology in their planning and implementation of plans. Applications of quantified geologic data to highway locations, slope control of cuts, raw material sources, water sources and water run- off showed a striking increase in number. Environmental geology and geologic hazards became part of the jargon of the geologic profession, and the American public began to realize more fully the significance of where they live, and on what and near what geologic phenomena which might effect their well-being. Tunnel work for water projects of almost dream-like magnitude kept geologic engineers busily engaged in predicting and testing local geologic conditions for construction projects. Disposal of industrial and radioactive liquid wastes continued as problems, but use of stratigraphic data, fluid flow rates and direction of flow helped solve some critical waste disposal problems. Unusual applications of seismic networks, remote sensing methods and X-ray techniques in geological engineering applications added other tools to this increasingly important profession.

Jan 2, 1968

By R. D. Carnahan

The authors are to be complimented on their timely study of solution-hardening effects in a bcc metal. Unfortunately there are some misleading aspects of the paper that should be discussed and clarified which is the purpose of this letter. In particular the writer is concerned about the allusions to rate theory of deformation that are inferred by the authors. This position is taken on the basis first of the "weaker" temperature dependence of the yield and flow stresses of the alloy relative to pure niobium and second of the strong temperature dependence of the Young's modulus of elasticity. It is by now well-recognized that any collection of data points used to determine a flow-stress temperature-dependence relationship must be established under isostructural conditions, i.e., similar or identical sessile and mobile dislocation densities and arrangements. Admittedly this is a formidable experimental undertaking and not what would be expected in an exploratory investigation of the present kind. As an alternative to the former one can consider, however, the temperature dependence of flow stresses at comparable strains. In the present study the authors have elected to use the lower yield stress and ultimate strengths to exhibit the temperature dependence of their alloys except for the data points taken at liquid nitrogen temperature. Here they have used the proportional limit for the yield stress and the fracture stress for the ultimate strength. This seems to be an unrealistic choice particularly in view of the fact that this temperature is below the duc tile-brittle transition region for the alloy and no supporting data points were obtained between -55" and -196°C. If the authors' data in Fig. 2 are extrapolated and data points selected at a constant strain, for example a strain of 0.01, the reader can quickly verify that a temperature dependence exactly paralleling that of pure niobium is obtained.

Jan 1, 1967