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By C. L. Magee, H. W. Paxton

PREVIOUS workersl'% ave found that as-quenched ferrous martensites can be plastically deformed at low stresses. They have also found that the stress to obtain small strains can be significantly increased by aging at temperatures up to 150°C. This behavior has been interpreted in two ways: 1) that the deformation at low applied stress is due to internal stresses and thus the aging phenomenon is due to relaxation of the internal stresses;' 2) that the microdeformation arises through the motion of unpinned dislocations and the aging process is the diffusion of carbon to the dislocations to pin them.293 In a recent paper,4 we have shown that under certain conditions the dominant microdeformation mechanism of as-quenched Fe-31Ni marten-site-austenite aggregates is the transformation of retained austenite. Our results on resistance changes during deformation and temperature dependence of the deformation also established that, at temperatures above 300° K, the microdeformation was not due to this transformation. The purpose of this note is to report results of experiments which indicate that explanation 1 is appropriate for this deformation. All results presented here are from conditions where transformation does not make a measurable contribution to the microplastic deformation, in Fe-31Ni-0.002C, or in Fe-29Ni-0.02C-0.25Ti. The experimental techniques that were used for measurement of the plastic deformation are described4 and analyzed5 elsewhere. Fig. 1 shows the microplastic response of 100 pct austenite at 300" and 350° K. The microplastic response of an austenite-martensite aggregate is also given in Fig. 1 and it is seen that, after formation of martensite, the initial plastic deformation occurs at lower stresses. Thus, the softness is not entirely due to retained austenite—the quenched structure can be deformed at lower stresses despite the fact that the macroscopic strength is significantly higher. A result which allows a distinction to be drawn between the alternative explanations for this behavior is derived from aging experiments on the low-carbon alloy containing titanium. We have previously shown4 that the presence of titanium in this alloy reduced the free carbon to a sufficiently low level that thermal stabilization of the austenite-martensite transformation was not detected. Despite this, Fig. 2 shows that the microplastic response is decreased by aging treatments. A similar aging effect in Fe-ZONi, with some titanium, has previously been reported by . Thus, carbon is not necessary for the aging process and explanation 2 is at best incomplete. Since internal stress relief can occur independently of carbon (any temperature dependence of the flow stress can result in decreased internal

Jan 1, 1969

By B. F. Buie

For over 200 years meerschaum has been a significant item of trade between the Near East and countries to the west. Best-known for its use in making smoking pipes and cigar and cigarette holders, it is also used in making a variety of decorative and ornamental items. It is easily carved, and is given an attractive, lustrous finish by rubbing. No published specifications are known, but compact form, purity, uniform whiteness or light color, and uniform, porous texture appear to be requisites. Fig. I a shows the appearance of a piece of crude meerschaum from Turkey; Fig. lb a carved item; and Fig. lc, d, and e show the fibrous and porous texture as revealed by the scanning electron microscope. Neither a major industrial mineral nor a precious stone, meerschaum nevertheless holds a record of long-and continuing-association with art and personal affairs of man. It is also a mineral to which modem methods of exploration and production probably could be profitably applied. An interesting account of the preparation and use of meerschaum in the early part of this century is given by Sterrett (1907). Geology and Mining Mineralogy Meerschaum is recognized now to be the compact variety of sepiolite, the claylike variety of which is one of the minerals included in the chapter on clays. The word meerschaum, from the German meaning "sea foam," was in earlier times used synonymously with sepiolite, a word of Greek origin suggestive of the resemblance of the compact variety-then the only variety known-to cuttlefish bone. At one time meerschaum was used as the commercial name, and sepiolite for the scientific name. However, to think of meerschaum as the name by which sepiolite is known commercially is no longer valid, in view of the recent emergence of the earthy variety as a competitor of bentonite and other clay materials. Present tendency is to restrict the term meerschaum to the compact variety, and to use the term sepiolite as a more general name to include both the compact and earthy varieties. This is the terminology followed in this publication. Meerschaum typically is white to light gray, has a hardness of 2 to 2 ½ , conchoidal to irregular fracture, and specific gravity varying with porosity from about 2 to less than 1. The composition is somewhat variable,- but is near that determined by Schaller (1936) for sepiolite as 2MgO.3SiO2.4H2O. A more modern for mula based on X-ray determination of the crystal structure is given by Caillére and Henin (1961) as (Site) (Mg9)030(OH)6(0H2)46H20. The reason for the firm, compact nature of meerschaum, in contrast with the earthy variety of sepiolite, is not fully understood. It may be due to the presence of a very minor amount of some bonding material such as silica. Scanning electron microscope (SEM) photographs of a specimen from Turkey (Figs. lc-le) indicate that the meerschaum is composed predominantly, if not entirely, of crystalline fibers which merge into sheetlike forms in a complex, intertwined mass. Detailed X-ray and crystal structure data, as well as some data on thermal stability range, are given by Caillère and Hénin (1961) for the sepiolite family of minerals. Mode of Occurrence and Origin Most authors have attributed the origin of meerschaum to alteration of serpentine or other magnesian minerals. The occurrence in alluvium and other surficial deposits does not necessarily indicate that the alteration was supergene. In fact, hydrothermal origin appears more likely for some deposits, though not for all.

Jan 1, 1983

By J. N. Ong, J. P. Ratledge, J. H. Boyce

Since German operators opened the Tsumeb mine in the early 1900's, continuous operation has been interrupted only by enforced shutdowns during two world wars and the depression of the 1930's. Original metallurgical practice was blast furnace smelting. This was applicable only to low zinc ore, leaving large tonnages of high zinc ore to be stockpiled on the surface. A gravity concentrator using tables, buddles, and jigs operated for several years, but differential flotation of the ore did not get beyond the experimental stage. When the property was put up for sale by the South African Custodian of Enemy Property there was an estimated 434,000 tons of ore on surface dumps. The dump material, assaying 4.48 pct Cu, 15.8 pct Pb, and 10.9 pct Zn, had become highly oxidized during a stay of many years on the surface. But these dump ores had to be used in evaluating possible metallurgy because the shaft became flooded after the 1940 shutdown and underground ore was unavailable. Many companies examined Tsumeb but quickly lost enthusiasm because of the formidable metallurgical problems presented by the dump ore. However, on the basis of extensive test work, the present company decided that differential flotation would be successful and purchased the property after competitive bidding.

Jan 4, 1955

By J. Norman Bulkley

Discussion of the paper of J. NORMAN BULKLEY, presented at the New York meeting, February, 1916, and printed in Bulletin No. 110, February, 1916, pp. 355 to 373. GRAHAM BRIGHT, E.. Pittsburgh, Pa.-On p. 265 mention is made of a change from steam hoist to electric hoist. The arrangement mentioned, of using a geared motor, and having the gearing and counter-shaft in a separate, self-contained unit, and then connecting that to the hoist by means of a flexible coupling, is very good. Sometimes, however, it is necessary to change a geared hoist over to an electric hoist. 'In that case the motor could be either direct-connected to the countershaft or geared to the countershaft, making a double-reduction gearing. Trouble has been experienced with this method on account of the hoist not being designed for electric drive. It may be of a rather light construction which will not stand the forces obtained by steam operation, the maximum being determined by the steam pressure which can be obtained in the cylinder. With motors of hoisting types, torques, can be obtained, which are so far in excess of anything that the steam engine could give, that this sometimes results in disaster when a motor is applied to a hoist of that type. If the operator gets a little careless, he may overstrain the hoist, And cause damage, so that this question should be looked into when changing from a steam hoist to an electric hoist. The hoist should be rugged enough to stand the torques which may be attained by careless operation, in which case, instead of using a three-bearing motor, with a pinion between two of the bearings, it is much better to arrange for a two-bearing motor, arranging for a coupling through a flexible coupler. In another place trouble is mentioned as due to the vibration of a geared hoisting motor. That can be overcome by supplying a flexible coupling between the motor and the hoist proper. You will find, if a flexible coupling is furnished, that the motor troubles will largely disappear. K. A. PAULY (communication to the Secretary*), Schenectady, N. Y. -This paper is deserving of careful consideration by all interested in general electrical mining problems and the recommendations made should be given weight because of the author's long experience in dealing with various problems encountered from the beginning of mine electrification.

Jan 5, 1916

By R. J. Cowan

In the art of cementation a controversy has been going on for years as to whether solid or gaseous carbon is the active agent in carburizing steel. More recently opinion has crystallized into a compromise to the effect that carburizing is a gaseous cementation of steel in the presence of solid carbon. The importance of this theory has a particular bearing upon the work to be described. In the art of carburizing, use is commonly made of such words as '' Catalytic" "atomic," "nascent" and "activated," in an attempt to describe the process. These words are used indiscriminately. For instance, the gas is said to be "catalytic" and carbon to be "nascent," or vice versa. In using these expressions, investigators are confirming the acceptance in their minds of the active conditions of both gas and carbon in the cementation process. Reactions at Metal Surfaces For many years attention has been directed to the consideration of reactions that occur on metal surfaces. When heated under the influence of certain metals a complex gas will be broken down and one of the constituents thereof usually found to be very active chemically in combining with the metal. The process of nitriding is an example of this type of reaction. In this case ammonia (NH3) breaks down at the metal surface and the nitrogen which is thus liberated reacts with the surface to form a nitride whereas molecular nitrogen not so liberated is inert and will not react chemically with the metal. Whatever term or terms may be used to describe such reactions, the fact remains that they are highly important and valuable in their commercial applications. Since the metal surface plays so important a part in these reactions, it is evident that any accumulation of reaction products thereon interferes seriously with the progress of the reactions. For this reason it is desirable to remove all such products as rapidly as they are formed in order to bring active gas into contact with the surface and thus facilitate the desired reactions. This is accomplished best by conducting the operation in a continuous manner, thereby causing the reacting gases to pass over the

Jan 1, 1931

By Edward Sampson, Allan B. Griggs

Surveying of many holes drilled by the U. S. Bureau of Mines in the Metaline district has shown surprising deviations. The holes start in the Ledbetter slate (Ordovician) and pass into the underlying gently dipping Metaline limestone (Cambrian) at varying depths, locally in excess of 1000 it. All holes start vertical, but one had deflected as much as 35° at a depth of only 300 it. One hole was found to be deflected 70' at a depth of 1000 ft. These deviations were not indicated to the drillers by any action of the rods or machines. Analysis of the survey data in the light of the observed geology indicates that the holes deviate most in the Ledbetter slate and scarcely at all in the Metaline limestone. The upper part of the "limestone'" in most holes is a massive rock strongly altered by hydrothermal action and essentially homogeneous. The slate is only obscurely bedded but has a cleavage, varying from slight to strong, which is unrelated to bedding. Drill holes have deflected to become nearly perpendicular to the cleavage. Several plans and cross sections are submitted showing the behavior of various holes. Introduction The Metaline district of northeastern Washington has received much attention recently and has promise of becoming even more important as a source of zinc than at present. Exploration has been conducted largely by deep diamond drilling, and in the course of this work it was found that holes became seriously deflected. This paper deals with the nature and causes of these deflections. The district lies along the Pend Oreille River in the northeastern corner of Washington, about loo miles north of Spokane, 9 miles from British Columbia, and 15 miles from Idaho. Three mines are now in operation and for a number of years have furnished a considerable production of zinc and lead. The ore contains zinc and lead in a ratio of about 31/2 to I, and occurs in the upper part of the Metaline limestone of Cambrian age, the upper member of which, where unaltered, is a rather pure limestone. This is overlain by Ledbetter slate of Ordovician age. Ore has formed by replacement of limestone, commonly 100 to 200 ft. below the slate, in areas of gentle dip, resulting in extensive tabular ore bodies. In and near ore, limestone has been intensely altered to granular dolomite and fine-grained quartz, which, where it predominates, forms "jasperoid." As part of their war program, the Geological survey and Bureau of Mines of the U. S. Department of Interior have been cooperating in an investigation of the district. The exploration by the Bureau of Mines in 1943 and 1944 was conducted largely by deep diamond drilling in which as much as 1000 ft. or more of Ledbetter slate was penetrated before the ore-bearing Metalin-2 limestone was reached. During the course of this drilling it was found that holes were seriously deflected while traversing the Ledbetter slate.

Jan 1, 1949

By Edward Sampson, Allan B. Griggs

Surveying of many holes drilled by the U. S. Bureau of Mines in the Metaline district has shown surprising deviations. The holes start in the Ledbetter slate (Ordovician) and pass into the underlying gently dipping Metaline limestone (Cambrian) at varying depths, locally in excess of 1000 it. All holes start vertical, but one had deflected as much as 35° at a depth of only 300 it. One hole was found to be deflected 70' at a depth of 1000 ft. These deviations were not indicated to the drillers by any action of the rods or machines. Analysis of the survey data in the light of the observed geology indicates that the holes deviate most in the Ledbetter slate and scarcely at all in the Metaline limestone. The upper part of the "limestone'" in most holes is a massive rock strongly altered by hydrothermal action and essentially homogeneous. The slate is only obscurely bedded but has a cleavage, varying from slight to strong, which is unrelated to bedding. Drill holes have deflected to become nearly perpendicular to the cleavage. Several plans and cross sections are submitted showing the behavior of various holes. Introduction The Metaline district of northeastern Washington has received much attention recently and has promise of becoming even more important as a source of zinc than at present. Exploration has been conducted largely by deep diamond drilling, and in the course of this work it was found that holes became seriously deflected. This paper deals with the nature and causes of these deflections. The district lies along the Pend Oreille River in the northeastern corner of Washington, about loo miles north of Spokane, 9 miles from British Columbia, and 15 miles from Idaho. Three mines are now in operation and for a number of years have furnished a considerable production of zinc and lead. The ore contains zinc and lead in a ratio of about 31/2 to I, and occurs in the upper part of the Metaline limestone of Cambrian age, the upper member of which, where unaltered, is a rather pure limestone. This is overlain by Ledbetter slate of Ordovician age. Ore has formed by replacement of limestone, commonly 100 to 200 ft. below the slate, in areas of gentle dip, resulting in extensive tabular ore bodies. In and near ore, limestone has been intensely altered to granular dolomite and fine-grained quartz, which, where it predominates, forms "jasperoid." As part of their war program, the Geological survey and Bureau of Mines of the U. S. Department of Interior have been cooperating in an investigation of the district. The exploration by the Bureau of Mines in 1943 and 1944 was conducted largely by deep diamond drilling in which as much as 1000 ft. or more of Ledbetter slate was penetrated before the ore-bearing Metalin-2 limestone was reached. During the course of this drilling it was found that holes were seriously deflected while traversing the Ledbetter slate.

Jan 1, 1949

Mr. Cottrell : I omitted to speak of the cost of installation. The precipitation-plant at the Balaklala smelter, up to the time of initial operation, including the construction of flues, installation of the apparatus, etc., cost $107,000, and subsequent modifications probably represented at least $15,000 more. Upon the information gained in this plant, the installation at the cement-mill, handling nearly twice as much gas, has been reduced in cost in a number of ways, but the overhead construction, carrying the precipitator at the top of the stacks, is naturally expensive, yet, even so, the total cost of construction will probably not greatly exceed $150,000. The mechanical details of the tubular form last shown have been worked out more recently than those of the plate form, and the tubular form promises to be still less expensive in construction, as you would naturally expect. The cost of operat-ing the plant varies somewhat with the character of the gases used. The amount of power consumed is not determined by the tonnage of the material collected, but by the volume of gas to be handled. It takes as much power to precipitate a thin cloud as a dense one. In the cement-plant they are getting a higher efficiency; i. e., a greater number of cubic feet treated per kilowatt than in the earlier plants. This is perhaps partly due to higher temperature of the gases, which here average about 450° C. The best figures on the cement-plant are between 3 kw. and 4 kw. Of

Jan 1, 1913

By E. S. Machlin

The wzodel of Blandin and Diplunt;, generalized to include a phase factor, is applied to the carbon-carbon interaction in iron. Darken&apos;s "energetic" model is generalized to include not only first neighbor interactions but further neighbor interactions as well. On the bases of these generalized models relations are derived for the activity of carbon in both austenite and ferrite in terms of the carbon-carbon Pair interaction energies. A single function then yields the pair interaction energies consistent with the experimental activities of carbon in both ferrite and austenite. Thus, a simple explanation is given for the observation that the nearest-neighbor interaction between carbon is repulsive in austenite and attractive in ferrite. Certain consequences of this approach are explored. OnE object of the present paper is to attempt to take into account the consequences of electrostatic contributions to the carbon-carbon pair interaction energy for carbon as a solute in iron. Friedel&apos; has shown that oscillations in electrostatic potential are to be expected about a solute atom in a metallic solution. Blandin and 6lant6&apos; have shown that such oscillations yield an interaction energy between pairs of solute atoms that obeys the relation: W{ = A cos(2ftFri + 4>)/(kFri)3 [l] where kF = Fermi wave vector, ri = distance between solute atoms comprising the pair7 <p = phase factor dependent only on electronic nature of solute and solvent, A = coefficient dependent only on electronic nature of solute and solvent. Machlin3 found that Eq. [I] accurately described the pair interaction energy derived from short-range order measurements based on field ion microscope observations of dilute alloys of platinum. He also found that the value of the phase factor $ derived from residual resistivity measurements agreed well with that obtained from the analysis of the short-range order data. Harrison and paskin4 were able to predict the long-range ordering energy of 0 brass using Relation [I] and residual resistivity values to predict the value of the phase factor $. Machlin5 has repeated their analysis and applied it to the prediction of the long-range ordering energy in AgZn and AgCd with excellent agreement between prediction and experiment. Both A and $ are independent of the crystal structure. The Fermi wave vector depends uniquely upon the conduction electron concentration per unit volume in the spherical approximation of the Fermi surface. Thus, Eq. [I] is expected to apply to both fer- rite and austenite with only one set of values of A and $. Mossbauer studies6 yield the result that iron has one 4s electron. We shall make an assumption found to hold previously for platinum3&apos;7 and nikel, which is that only the s electrons are involved in shielding the perturbing potential of carbon. With this assumption, kF = 1.35 A-l. Although A and $ may be obtained from certain mdels&apos;&apos;&apos; we shall take A and $ to be empirical constants in the spirit of Kohn and osko.&apos; Thus, Eq. [I] involves two adjustible parameters. Consequently, two independent relations in A and $I are required in order to evaluate them for carbon as a solute in iron. We may use a recent analysis of Aaronson, Domain, and poundg who showed that Darken&apos;s energetic model,1° as well as others, can be used to describe the activity-temperature data for carbon in iron in both the aus-tenitic and ferritic phases. Darken&apos;s model takes into account only first neighbor pair interactions. For our needs, all neighbor pairs need to be taken into account. It is convenient to generalize Darken&apos;s model. The result for the partition function for austenite is: over the temperature range 800" to 1200°C and where the uncertainty corresponds to one standard deviation. Eq. [4] effectively yields only one relation. Another relation is required to obtain unique values for A and $. One property of Eq. [4] is that it is independent of crystal structure. Hence, data for a iron can be used to obtain another relation. To arrive at this relation we must generalize Eqs. [2] and [3] so that they may be applied to the bcc a iron. The result is that:

Jan 1, 1969

By R. T. Pepper

DURING an investigation into the effect of heat-treatment on the creep properties of the magnesium alloy ZW1, (1 pct Zn, 0.6 pct Zr), the previously published methods of final polishing were found to be unsatisfactory. A new diamond-polishing technique has been developed to facilitate the study of fine precipitates in this and other magnesium alloys, and is described in this note. The sectioning and coarse grinding techniques are those of Fox and Hall,&apos; and Hess and Cieorge.&apos; Pre- liminary mechanical polishing is done with 6-µ, and 1-µ( grades of diamond compound on &apos;Microcloth&apos; using a lubricant of &apos;Hyprez&apos; oil. When the conventional technique is used with a 1/4- µ diamond wheel for the final polishing of magnesium alloys, scratching is likely to result from the abrasive action of the &apos;Microcloth&apos; nap on the soft metal surface. This problem has been overcome by the use of a cream on the wheel in order to separate the specimen surface from the polishing cloth. To prepare this cream, a solution of 6-ml tri-ethanolamine in 75-ml water is stirred into 12.5 g stearic acid at a constant temperature of 80° to 90°C. The cream is allowed to cool, and is then &apos;whipped&apos; to a smooth consistency with 100-ml &apos;Hyprez&apos; oil. Before polishing, the diamond loaded &apos;Microcloth&apos; is moistened with a few drops of &apos;Hyprez&apos; oil, then a small amount of cream is worked into the nap. For the best results a wheel speed of 500 rpm should be used for polishing, and the specimen should be held by hand with a light pressure while being rotated in the opposite direction to the wheel. After polishing it is necessary to swab the specimen thoroughly in methylated spirits to remove residual cream and oil from the surface in order to avoid uneven etching and drying stains. Fig. 1 shows the surface finish obtained on a specimen by polishing on a 1/4- ° diamond wheel using the cream, and Figs. 2 and 3 the precipitate observed in ZW1 after polishing, and etching for two seconds in nitric acid 15 pct in ethylene glycol. This new diamond-polishing technique has made a valuable contribution to the programme of metal-lographic research on ZW1 and has become a routine laboratory practice for other low alloy content magnesium alloys.

Jan 1, 1961

By A. U. Seybolt, R. L. Fullman

THE Hume-Rothery rule relating the relative sizes of the solvent and solute atoms in a substitutional solid solution for moderate to extensive solubility is, of course, well known and much used in the design of alloys. No such rule has been obtained for interstitial solid solutions, although a qualitatively similar relationship would be expected. Among the most common interstitial elements, oxygen, carbon, and nitrogen which can dissolve in important amounts in the transition metals, only in the case of oxygen is there enough solubility data available for an examination of the possibilities of a simple relationship between the extent of solubility and the properties of the metal solvents. Three properties were examined: 1—size of the octahedral space V into which oxygen atoms fit, 2— the elastic modulus E, and 3—the free energy ?F of formation of a low oxide, such as is known to be, or would be expected to be, in equilibrium with the terminal solid solution. The size factor or octahedral volume is so closely associated with the well known Hume-Rothery con- cept of size factor that additional development of this subject is hardly necessary. The octahedral volume used was not corrected to an elevated temperature, as this correction would have made no significant difference. The second factor, Young&apos;s modulus E, must be considered, since it is a measure of the strain energy required to force neighboring atoms apart so that an oxygen atom may enter the octahedral volume. The temperature dependence of the elastic modulus of many metals has been reported by Köster,1 but for a rather limited temperature range. Since the

Jan 1, 1955

By William Clark

A bean placed at the bottom of tubing in flowing wells is not a new idea. In fact, a device which in effect was a bottom bean was patented prior to 1890 by John D. Rockefeller. Because of the limited use of the bottom bean, prior to 1922, when it was installed in a few wells in the Santa Fe Springs field, California, the knowledge of the results of its operation is very meager. Since then various oil operators have experimented with bottom beans, but most of the records of the results obtained by their use are unavailable. For the past year or two, more attention has been directed to this method of producing wells; the theory and best means of application have been studied, and accurate records maintained. In theory, the use of bottom beans in flowing or gas-lift wells should secure certain advantageous results. With the exception of flow friction of the tubing and flow lines, there is no back-pressure held on the rising column of fluid. Thus severe beaning is possible with no danger of killing the well by too heavy a fluid column, a condition that often exists when a surface bean is used. The whole energy of the gas expanding to atmospheric pressure is utilized to lift the fluid in the well. The same effect is obtained when flowing a well through open tubing or casing. In using a surface bean this energy of expanding gas is wasted into the flow lines beyond the bean, because the fluid has reached the surface by the time the restriction is reached and the work of the gas performed. The bottom bean affords an efficient use of the expanding force of gas, utilizing less gas to raise the same amount of oil, hence allowing for lower gas-oil ratios. The flow restriction being at the entrance to the flow string, a more uniform mixture of gas and oil enters the tubing and a steadier backpressure is held on the well. The uniform mixture and high velocity attained while flowing through the bean, which is above the critical velocity required to suspend a spray condition of gas and oil, prevent slippage of gas, surging and heading with its resultant strain on the casing. The advantageous conditions allow positive control of production in gas-lift wells within limits set by the bean size and amount of input gas; and probably help to prevent sanding up of a well and the coning

Jan 1, 1931

By D. Roberts

SUMMARY In order to accommodate a new plant in a limestone quarry in the Mendip Hills, it became necessary to excavate a potentially unstable disused face of the quarry. A simple two-dimensional graphical method was used to analyse a failure, which occurred during a period of exceptionally heavy rain in 1968, and the results of this analysis were used in estimating the stability of the proposed excavation. The presence of water in vertical fissures and tension cracks was found to be a dominant factor in determining the stability of these faces. The results of this approximate analysis were used as a guide in deciding upon the final slope design and the purpose of presenting this example is to illustrate how the various factors involved in arriving at this design were weighed to arrive at a compromise between theoretical recommendations and practical considerations. INTRODUCTION The successful outcome of a geological and geochemical survey to prove adequate re- serves of high quality limestone, suitable for producing burnt lime, led to planning for the installation of the necessary plant at Amalgamated Roadstone Corporation&apos;s Batts Combe Quarry at Cheddar in Somerset. Topographic and property boundary limits added to restrictions which were likely to be imposed by any forthcoming planning consents and restricted the choice of plant location to one site. The particular site is, in fact, the main floor area of the original quarry which, like many hillside quarries, had been worked with just one face. Before a benching scheme had been introduced on higher ground, the original face had attained a height of 230 ft. and sloped at angles of 58º to 64º. Fig. I shows the present configuration of the disused quarry face and the present working area above. The floor area below the disused face accommodates the existing crushing, conveying, and screening plant. The new facilities for lime burning are to be in addition to the existing main line business of producing roadstone and concrete aggregates and, although a new aggregate production plant would be included in the new installation, no disturbance of current production was to be contemplated.

Jan 1, 1972

By Paul A. Beck, M. N. Parthasarathi

The vecrystallization texture. formed by selective growth of random nuclei in an 80 pct volled 99.997 pct A1 crystal of initial orientation mear (123) (41.21 was found to consist of components related to the single-component rolling texture by 40 deg. rota-tiows around [111]axes. The relative-volume fractiovz of the various recrystallization-texture componezts may be accouzted for 012 the basis of the Lou) mobility of twist boundaries, if it is assumed that the mobility of the tilt boundaries also varies with their orientation. Similar results with a, aluminum-alloy cystal of the (110) [112] orientation, containing iron, silicon, and zinc, show that these solute contents do not impair the effectivezess of the oriented growth mechanism of re cry s-tallization- texture formation. In a previous investigation1,2 it was found that a sharp recrystallization texture is formed as a result of the oriented growth of random artificial nuclei in an aluminum crystal rolled to 80 pct RA, on the (110) plane in the [ 112] direction. Four recrystallization-texture components were found to occur, with orientations corresponding to 40-deg rotations around [111 1 axes of the deformation texture. Reorientations of this type were already found in earlier work,3,4 where the presence of random nuclei could be reasonably assumed, but was not rigorously documented. The same orientation relationship was found also by Lucke and Liebmann, who actually measured the orientation dependence of boundary-migration rates in the recrystallization of A1 crystals slightly deformed in tension.5,6 The occurrence in the recrystallization texture of only four of the eight crystallographically equivalent orientations of the type referred to above remained unexplained,1,2 although it was clearly not a result of the absence of suitable nuclei. Recently Burgers7 suggested that this effect may be due to the aniso-tropy of boundary mobility observed2&apos;6; it was found that the recrystallized grains of the 40-deg [111]-rotated type grow much faster in directions perpendicular to the [ 111] they have in common with the matrix than parallel to this direction, i.e., the tilt boundaries have much higher mobility than the twist boundaries. The four orientations corresponding to

Jan 1, 1962

By Gary E. Butts, Paul R. Smith

Introduction The design of a mineral processing flowsheet involves many factors. The importance of the sample can not be overemphasized. Competent and thorough mineralogical examinations are important as an aid in designing the test program. Designing and conducting the laboratory test program is basic to the design of the flowsheets. In the project under consideration a flotation pilot plant was conducted to prove the process and to provide a realistic prediction of metallurgical results. Moreover, the pilot plant operation provides important pilot plant design data. Finally, accurate and clear reporting is essential so that the information developed can be utilized advantageously by the client and the engineering firm. The design of a minerals processing flowsheet is a team effort. Engineers from the mining company, the research organization, and the engineering firm all contribute to the effort.

Jan 1, 1978

By J. M. Lommel

DURING an investigation into the effect of heat-treatment on the creep properties of the magnesium alloy ZW1, (1 pct Zn, 0.6 pct Zr), the previously published methods of final polishing were found to be unsatisfactory. A new diamond-polishing technique has been developed to facilitate the study of fine precipitates in this and other magnesium alloys, and is described in this note. The sectioning and coarse grinding techniques are those of Fox and Hall,&apos; and Hess and Cieorge.&apos; Pre- liminary mechanical polishing is done with 6-µ, and 1-µ( grades of diamond compound on &apos;Microcloth&apos; using a lubricant of &apos;Hyprez&apos; oil. When the conventional technique is used with a 1/4- µ diamond wheel for the final polishing of magnesium alloys, scratching is likely to result from the abrasive action of the &apos;Microcloth&apos; nap on the soft metal surface. This problem has been overcome by the use of a cream on the wheel in order to separate the specimen surface from the polishing cloth. To prepare this cream, a solution of 6-ml tri-ethanolamine in 75-ml water is stirred into 12.5 g stearic acid at a constant temperature of 80o to 90°C. The cream is allowed to cool, and is then &apos;whipped&apos; to a smooth consistency with 100-ml &apos;Hyprez&apos; oil. Before polishing, the diamond loaded &apos;Microcloth&apos; is moistened with a few drops of &apos;Hyprez&apos; oil, then a small amount of cream is worked into the nap. For the best results a wheel speed of 500 rpm should be used for polishing, and the specimen should be held by hand with a light pressure while being rotated in the opposite direction to the wheel. After polishing it is necessary to swab the specimen thoroughly in methylated spirits to remove residual cream and oil from the surface in order to avoid uneven etching and drying stains. Fig. 1 shows the surface finish obtained on a specimen by polishing on a 1/4- µ diamond wheel using the cream, and Figs. 2 and 3 the precipitate observed in ZW1 after polishing, and etching for two seconds in nitric acid 15 pct in ethylene glycol. This new diamond-polishing technique has made a valuable contribution to the programme of metal-lographic research on ZW1 and has become a routine laboratory practice for other low alloy content magnesium alloys.

Jan 1, 1961

By T. Egleston

FOR a great part of the progress of the world we are indebted to the works of engineers. It is to them that we owe our means of rapid transportation, our canals, our railroads, our bridges, many of our automatic machines, and most of those appliances which, by facili tating or decreasing the amount of human labor to be expended and by utilizing the great forces of nature, have made the present progress of the world possible. Their education is a matter of momentous interest to the whole civilized world. I have, therefore, thought that some discussion of the theory upon which their education should be based would be of interest to this body, and have ventured a few reflections and suggestions upon the subject. The word education, in its original signification, meant the draw ing out of a man what there was in him. In our common schools the practical work of education consists in putting into the brain a larger number of facts than can be retained, which are consequently more or less understood and digested. It ordinarily consists simply of teaching a round of abstractions or facts which when not assim ilated are not only useless to the individual, but generate careless habits of thought and make more or less untruthful, unfaithful or unsuccessful men. In most of our schools a procrustean system is adopted; all are made to advance upon one general plan, the quick being kept back and the slow dragged on at a rate too great for their power of comprehension. Until within a very few years it has been a theory in common school education that the brain alone should be developed, and that little or no attention need be paid to the train-

Jan 1, 1888

By R. Fahn

Bentonites are best suited for the preparation of acid activated clays with efficient adsorption properties. They are weathering products of acid volcanic ashes and natural deposits are spread worldwide. The main constituent of bentonite is aluminum hydrosilicate montmorillonite with a high ability to swell. Physical and Chemical Properties of Montmorillonite The clay mineral montmorillonite is named after its place of discovery, near Montmorillon in southern France. The structure of this clay is shown in [Fig. 1]. The montmorillonite crystal consists of about 15-20 silicate plates. Each silicate plate is composed of three layers. The central one is formed by aluminum or by ferric hydrate octahedrons, the two outer ones consist of silicon dioxide tetrahedrons. In the presence of water, the montmorillonite crystal swells and water molecules become deposited between individual silicate layers. Two types of natural bentonites are known: the Western type, which is a natural sodium bentonite (high swelling grade), and the Southern type, an alkaline earth or calcium bentonite (low swelling grade). Southern bentonites have efficient adsorption properties of their own. They are called natural active earths or fullers earths. Acid Treatment of Bentonite Under the influence of a mineral acid, the exchangeable alkaline earth ions of bentonite are substituted by hydrogen ions. Moreover, depending on the acid concentration, temperature, pressure, and reaction time, a more or less pronounced leaching process takes place. Thereby Al-, Fe-, and Mg-ions are extracted from the octahedron layers. This results in a change in the crystalline structure of montmorillonite and in an increase of its specific surface area and porosity, as shown in [Fig. 2].

Jan 1, 1983

By C. W. Handy

ONE LAW cannot he evaded, the economic law of supply and demand. Silver, like any other commodity, is subject to this law; and its price in the long run is determined by existing conditions. I say "in the lone run because at times silver has appeared to mope contra to basic coalitions. Such movements, however, are, occasioned by the market&apos;s attempt to anticipate changes in these governing conditions. If the expected changes materialize then the new market level is justified, but if they do not then the market will revert to its previous status, A striking example of such a move occurred in November when the price advanced over 70, in ten days and then in the next two weeks lost more than it had gained. The reasons for this advance were that the speculative element interpreted certain events as favorable to silver namely, England suspension of the gold standard, higher shat prices, and the Chinese-Japanese crisis. When these expectations proved unjustified the inevitably, elapse followed became the governing conditions had not channel.

Jan 1, 1932

By J. Ruzicka

In creep testing, material is subjected to a constant load, preferably at a constant temperature, and its rate of deformation is measured. The method of loading can be of various types but in this paper only creep testing under tensile load will be considered. The ordinary tensile test is essentially a comparison test in conditions that frequently hear little or no relation to those under which the test material is to be used in service. The purpose of creep tests is to measure the strength of the test material at slow rates of deformation that more nearly approach the rates realized in service. One purpose of this paper is to illustrate that the creep test, in addition to its value as a service test, is superior to the ordinary tensile test as a sensitive tool for the comparison of certain metals in investigative testing. The other purpose is to describe equipment having distinctive features of design that make it especially suitable for such tests. Representative data obtained with this equipment on a group of rolled zinc-base materials are given. These data are compared with those from practical comparison tests of the creep type on weatherstrip fabricated from the same group of materials. The comparison illustrates the value of the fast creep test and of the equipment. The Equipment The creep equipment consists essentially of a tank containing a constant-temperature oil bath in which the creep of 14 specimens, loaded by means of levers, is measured by means of one movable extensometer. Figs. 1, 2 and 3 illustrate its general construction and appearance. Constant-temperalure Oil Balh.—A common constant-temperature bath requiring only one temperature-controlling equipment for a number of specimens was chosen as the best means of fulfilling the requirements of low cost and compactness. In addition, this allows the testing of a group of specimens under identical temperature conditions.

Jan 1, 1937